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Chemistry
•••
STRUCTURE OF ATOM CHRONICLE
IAS ACADEMY
A CIVIL SERVICES CHRONICLE INITIATIVE
It was John Dalton who first enunciated matter to be (iii) Pi-mesons (Pions) and µ -mesons (muones) : These
composed of indivisible particles having an indepen- particles have a mass intermediate between that of the
dent existence and called them Atoms (meaning uncut). electron and the proton. The positively and negatively
But towards the end of the 19th century, modern atomic charged mesons were postulated by Yukawa in 1935.
theory, mostly from the works of Thomson, Rutherford, Neutral mesons ( π ) were postulated by Kemmer to
Chadwick, Milliken, Bohr, de Broglie proved that atom account for the binding forces between the nucleons.
is divisible and made up of three fundamental sub- Therefore, an atom, on the whole, is neutral because
atomic particles namely electron, proton and neutron. the no. of protons is equal to the no. of electrons. Almost
Atoms are very reactive and do not exist in the free state, the entire mass of atom is concentrated in a very small
except the atoms of noble gases. part of its total size. This part is called the nucleus and
all the protons and neutrons are embedded in it. Radius
Constituents of Atom of the nucleus is approx. 10-13 cm and that of the atom is
near about 10-8 cm.
An atom consists of three fundamental particles:
(i) Electron: The presence of electrons was discovered Rutherford’s Experiment - Atomic Model
by J.J. Thomson. Electrons are negatively charged
particles revolving around the nucleus in orbits of In 1911, Lord Rutherford bombarded a gold foil with
fixed energy. a beam of α -particles (an α -particle is a positively
charged helium ion - He2+).
(ii) Proton: The proton was observed by Goldstein in
1896. Protons are positively charged particles resid- He observed that:
ing in the nucleus. (i) Most of the α -particles passed straight through
(iii) Neutron: Neutron was identified by James the foil.
Chadwick in 1932. These are neutral particles (no (ii) Some were deflected away from the path near the
charge) residing in the nucleus with protons. centre.
In addition to the above fundamental particles, some un- (iii) A few were reflected back.
common sub-atomic particles have also been postulated: On the basis of the results of alpha -Scattering
(i) Positrons: These are the positive counterpart of the experiment, Rutherford proposed that
electrons. These were discovered by Anderson in (i) Atom is spherical.
1932. These are highly unstable and combine with
electrons producing γ-rays (energy radiations). (ii) Most part of the atom is empty.
(iii) Mass and positive charge of the atom are located
(ii) Neutrinos and Antineutrinos: These are the par-
at the centre of the atom i.e. in the nucleus.
ticles of small mass and zero charge. These were
postulated by Fermi in 1934. (iv) Electrons move around the nucleus in circular paths.
1
Electron e around the –1 – 1.60 × 10—19 coulomb 9.1 ×10 –28
gm
1840
nucleus
Proton p Nucleus +1 + 1.60 × 10–19 coulomb 1 1.67 × 10–24 gm
p-orbital
s-orbital p-orbital
px py pz
d-orbital
¯ ¯ ¯
l = 0, m = + 1 0 - 1 f-orbital
d-orbital
l=2
Hund’s Rule
d xy d zx d y z d x2 −y 2 d 2
z
When electron filling occurs in an orbital, each ori-
¯ ¯ ¯ ¯ ¯
entation of the orbital is first singly occupied and only
m= +2 +1 0 -1 -2 after this pairing occurs. The filling of two electrons in
Orientation of different orbitals are shown in the the p-orbital can be shown as:
figure given below :
+1 0-1+1 0-1
(A) (B)
In (A), electron pairing occurs leaving empty orien-
tation, hence this distribution is not valid according to
Hund’s rule. In B, single occupancy of orientation oc-
curs and this is valid distribution of electrons according
to Hund’s rule.
•••
Chronicle IAS Academy [8]
COMPOSITION OF MATTER CHRONICLE
IAS ACADEMY
A CIVIL SERVICES CHRONICLE INITIATIVE
Matter and its Nature 5. Elements are found in all forms of matter i.e. solid,
liquid and gaseous form.
Entire universe is made up of only two types of 6. Some elements like nitrogen, oxygen, noble gases and
entities – matter and energy. Matter occupies space and gold occur in the free state or the native state, while
has mass. It can be seen, tested, smelt or felt, but energy most other elements occur in the combined state.
can only be experienced, like light and heat.
7. Elements are represented by the symbol e.g. Mer-
Two types of change take place in matter: cury is represented by Hg, Bromine is represented
(A) Physical Change : It is a temporary change and by Br. etc.
does not involve any change in the composition of 8. Some elements like Technetium, Promethium, Asta-
matter. For example – conversion of
water into ice, stretching a spring,
evaporation of water etc. This change
is reversible, it means that matter can
be brought back to its original form
on removing the factors governing the
change.
(B) Chemical Change : It is a permanent
change in which the composition and
properties are changed. This change
is irreversible (original substance can
not be reobtained , even after remov-
ing the factors governing the change.)
For example, burning i.e. Combustion,
rusting of iron, respiration, cooking
food, etc.
Matter is made up of different kinds of substances. A tine, Francium and all the elements with atomic
substance is a material of which all parts are chemically number above 92 are found either in very slight
identical and of same composition. traces or not at all in nature.
ii. Heterogeneous mixture. 1. Composition is uniform throughout. Different components are not present
uniformly.
Separation of Mixtures 2. Exist in one phase either solid or Exist in different phases.
liquid or gas.
Some methods for the sepa- Examples: Examples: Smoke (mixture of air and
ration of mixtures are de- Air - Oxygen + Nitrogen + other Carbon particles), Milk, mixture of
scribed as below : gases iron filings and Sulphur.
Salt Solution - Sodium
1. Sublimation: A direct change Chloride in water
of state from solid to gas is Sugar Solution - Sugar + Water
called sublimation. In this Carbonated Water - CO2 + Water
process gaseous subtances on
Solute Chloride Cl– Sodium Na+ Sulphate So42– Magnesium Mg2+1 Calcium Ca2+ Potassium K+ Bromide Br–
Symbol of element O Si Al Fe Ca N K Mg Ti H P Mn
43.6 27.7 8.1 5.0 3.6 2.8 2.6 2.1 0.44 0.14 0.2 0.1
But according to the modern atomic concept atoms are Carbon atom combines with one Oxygen atom.
divisible i.e. made up of electrons, protons and neutrons. Hence the ratio of Oxygen combining with the fixed
amount of Carbon is 2 : 1 between CO2 and CO. This
Laws of Chemical Combination is also the ratio of their weights.
There are three important laws of chemical combina-
tion based on the Daltonian atomic concept as below: Kinetic Theory of Matter
1. Law of Conservation of Matter (or Mass): Accord- 1. All matter is made up of atoms or molecules of
ing to this law “Matter can neither be created nor independent existence.
destroyed in a chemical reaction”. Thus there is no
change in mass in a chemical reaction. For example, 2. These constituent particles of each substance are dis-
the reaction between Sodium Chloride and water tinct and have certain properties which are different
can be written as : from those of atoms or molecules of all other substances.
NaCl + H 2O → NaOH + HCl 3. Molecules of the same substance are identical in all
We see that the total no. of atoms before and after the respects.
reaction remains the same. Hence mass or matter is 4. There are empty spaces between molecules, which
conserved in this reaction. increase as in the following order:
2. Law of Constant Composition or Law of Definite solid < liquid < gas
Proportion: This law states that “the composition of a
pure compound is always the same.” Compound is 5. Forces of attraction being exerted between molecules
always made up of the same elements in the same are in the following decreasing order :
percentage. This law can also be explained on the solid > liquid > gas
basis of Daltonian theory : “The no. and kind of atoms 6. Molecules possess kinetic energy to move freely
in a given compound is fixed.” H2O molecule always through the bulk or volume of liquid or gas. Increas-
contains 2 atoms of hydrogen and 1 atom of Oxygen. ing order of kinetic energy is as below:
3. Law of Multiple Proportion : This law states that when
solid < liquid < gas
two elements combine to form two or more than two
compounds, a simple ratio of weight of both elements is 7. The molecules of a gas are in continuous random motion
maintained. For example, consider the formation of and exert pressure on the walls of the container.
Carbon dioxide (CO2. and Carbon monoxide (CO) by
8. The kinetic energy increases on increasing the tem-
the combination of Carbon and Oxygen atoms.
perature.
In Carbon dioxide one Carbon atom combines with
two Oxygen atoms. In Carbon monoxide (CO) one Molecules
Gaseous Composition of the Air It is one of the fundamental units
to form a chemical compound that
Gas Nitrogen Oxygen Argon Carbon Xenon, Neon, Krypton,
can take part in a chemical reaction.
dioxide Water Vapour
Molecules can be classified into two
Percentage 78 21 1 (just- 0.04 Very Small amounts
types:
(%) Under)
Equal volumes of all gases contain equal numbers 1 mole of atoms = 6.023 x 1023 atoms
of molecules at the same pressure and temperature. 1 mole of molecules = 6.023 x 1023 molecules
This statement is called Avogadro’s hypothesis. It is
A mole of any substance is related to :
true only for ideal gases. The actual no. of molecules in
a gram molecule is known as Avogadro’s number and a) mass of a substance,
its value is 6.023 x 1023 molecules. b) number of particles,
c) volume of a gaseous substance
Atomic Mass
One mole of all the gases at STP (Standard Tempera-
It is the average relative mass of an atom. It is calcu- ture and Pressure i.e. 0 0 C and 760 mm of Hg) occupy a
1
lated by how many times an atom is heavier than th volume of 22.4 litres or 22400 cc.
12
•••
Volume of a fixed mass of a gas at constant Since none of the gases is known to behave according
temperature is inversely proportional to the pressure of to the ideal gas equation, these gases are called as real
the gas. It can be shown as: gases. Their behaviour is explainable on the basis of
Vander Waal’s equation as represented below :
1
Vα at constant T and n
P an 2
P + (V-nb) = nRT (for n mole of the gas.)
P = Pressure, V = Volume, T = Absolute temperature, V 2
n = no. of moles of gas.
It is the modification of the ideal gas equation PV = nRT
where pressure correction ‘a’ as well as volume correction
Charles’ Law ‘b’ have been applied; a and b are Vander Waal’s constants
whose values depend on the nature of the gas.
The volume of a given mass of gas at constant
pressure varies directly with absolute temperature.
Liquefaction of Gases
Mathematically it can be seen as:
V α T at constant P and n When gases are compressed and cooled (i.e.
subjected to high pressure and low temperature), they
Avogadro’s Hypothesis are converted to liquid. The process of gas → liquid is
known as liquifaction and the temperature at which a
At constant temperature and pressure, volume of a gas is converted to liquid is known as the liquifaction
gas varies directly with no. of moles of the gas. temperature. At high pressure and low temperature,
Mathematically it can be seen as : attractive forces between gaseous molecules is high and
molecules are drawn together to form a liquid. The
V α n at constant T and P. liquifaction of gases is indicative of the attractive forces
between the gaseous molecules.
Equation of State or Ideal Gas Equation
Critical Temperature
It is a combined gas law and is established with the help
of Boyle’s law, Charle’s law and Avogadro’s hypothesis. i.e. The temperature at which a gas can be liquified is
•••
A solution is a homogeneous mixture of two or more and oceans. Both examples are from the gas-liquid type.
substances whose properties vary continuously with vary- An example of a gas dissolving in solids is the solubil-
ing proportion of the components. Several types of solutions ity of gaseous Hydrogen in Palladium or Platinum
are possible because components of a solution can be in any when water evaporates in the air; the water is the solute
state of aggregation (i.e. solid, liquid or gas). They are solid – and the air is the solvent, thus it is an example of gas-
solid, solid – gas, liquid – liquid, liquid – gas and gas – gas. gas solution.
l It is sour in taste. It turns blue litmus paper into red. l It turns red litmus paper blue.
l Methyl orange turns red in colour. l Methyl orange turns yellow in colour.
l It is ionized in aqueous solution to give H ions
+
l It contains hydroxyl groups and form hydroxy
(hydrogen lions). It contains hydrogen. lions (OH–) in an aqueous solution.
l It donates protons in solution. l It accepts protons.
l Hydrochloric acid (HCl), Sulphuric acid l Sodium hydroxide (NaOH), Ammonium
(H2 SO4), Acetic acid (CH3COOH) etc. are the examples. hydroxide (NH4OH), Potassium hydroxide (KOH)
etc. are the examples.
l According to the modern concept (Lewis l It donates a lone pair of electrons.
concept), it accepts a lone pair of electrons.
l Electron deficient compounds such as l Compounds having a lone pair of electrons
ZnCl2, AlCl3, BF3, FeCl3, etc. are acids. such as HOH, : NH3, HF etc. are bases.
Chemistry
Chronicle[14]
IAS Academy [16]
creases with increase in the temperature. Fishes then
Emulsion may get short supply of Oxygen and have to come to the
surface to get air.
When we add cooking oil to water, the oil floats on
the water. Oil and water are immiscible. But on shaking
vigourously the oil and water, a milky-looking liquid is
Colligative Properties
obtained, this is called an emulsion. This milky liquid is Colligative properties of solutions are those proper-
due to the presence of tiny droplets of oil. Milk is an ties which depend on the number of solute and solvent
emulsion. It is made up of tiny droplets of fat floating in particles (molecules or ions) but not on the nature of the
water. solute. Examples of such properties are :
i. lowering of vapour pressure.
Importance of Solution in Human Body
ii. elevation of boiling points.
Human body is about 70% water. In water several iii. the depression of freezing point.
important reactions which are necessary for keeping
iv. the osmotic pressure.
alive, take place. For instance, respiration is a chemical
reaction which releases energy from food. It happens in
every cell in human body. These chemical reactions will Boiling and Freezing Points of Solution
happen only if the substances taking part in the reac-
Boiling point of a solution is higher than that of the
tion – the reactants – are in solution. Cells are jelly – like
pure solvent and freezing point of a solution is lower
solutions of many different substances in water. If the
than that of the solvent. For running the car in subzero
water was not there, the chemical reactions would not weather when its radiator is full of water, an antifreeze
take place. It would then result into death. material, ethylene, glycol or alcohol, is added to lower
the freezing point of the liquid in the radiator.
Solubility
Solubility is a measure of how much of a substance Osmosis
will dissolve. At saturation, the amount of solute in a
given solvent at a specified temperature is known as the Osmosis is the phenomenon where solvent molecules
solubility of the solute. It can also be defined as the no. of flow from a dilute solution to a more concentrated solu-
grams of solute that will dissolve in 100 gms of solvent at tion through a semipermeable membrane. There are two
a given temperature. For example, the solubility of table types of osmosis:
salt is 35.7 grams in 100 grams of water at solvent— i. Exosmosis: It is the outward flow of water from a
temperature of 0 0 C. It is 39.8 grams at 1000 Celsius. cell containing an aqueous solution through a semi-
Solubility of solids increases with increasing tem- permeable membrane e.g. grape in NaCl solution.
perature and solubility of gases decreases with increas- ii. Endosmosis: It is the inward flow of water from a
ing temperature. We take an example of gaseous solu- cell containing an aqueous solution through a semi-
bility such as in a pond on a cool day there is usually permeable membrane e.g., grape in water.
plenty of Oxygen dissolved in the water because solu-
bility of gas increases at low temperature. But on a hot Osmotic Pressure
day, the hot, fast – moving Oxygen molecules can es-
cape from the water into the air. Less Oxygen remains in Osmotic pressure is the pressure which just pre-
solution in the water because solubility of gases de- vents the passage of pure solvent into the solution
powder
•••
•••
•••
It is well known that the system naturally tends pressure and V is its volume. For an exothermic reaction
towards greater stability. This stability results from low- H is taken to be negative and for an endothermic
ering the energy because a lower energy state is more reaction H is taken to be positive. Enthalpy is also
stable than a high energy state. This drives a chemical known as heat content.
reaction in which the products would have lower en-
ergy than the reactants, after going through either evo-
lution or absorption of heat. All these things are dealt
Heat of Formation
with by thermochemistry. Heat absorbed or released in the formation of one mole
of a substance from its elements is called heat of formation
Exothermic Reaction and Hf is called enthalpy change of formation.
Chemical reaction in which heat is evolved is called 1 1
H (g) + Cl2(g) → HCl(g) + 22KCal
an exothermic reaction and is expressed as : A + B → C 2 2 2
+ D + Q where Q is heat evolved, A and B = reactants Heat of formation Q f = 22KCal
and C and D = products.
Hf = -22KCal
Endothermic Reaction
Heat of Combustion
Chemical reaction in which heat is absorbed is called
an endothermic reaction and is expressed as A + B + Q Heat released in complete combustion of one gram-
→ C + D or A + B → C + D – Q where Q is heat absorbed, atom of an element or one gram-mole of a compound is
A and B = reactants and C and D = products. called heat of combustion and H is called enthalpy
change of combustion.
Bond Dissociation Energy and Bond C(s) + O2(g) → CO2(g) + 94 KCal
Energy Heat of combustion of C = Q
= 94 KCal
Bond dissociation energy is the energy required to break
a particular type of bond in one mole of gaseous molecules. H combustion of C = -94 KCal
The energy released in the formation of one mole of This is the same reaction that we observe when we
bonds is known as bond energy. burn charcoal in stoves and ovens in the kitchen.
For example, the bond dissociation energy of hydro-
gen molecules is 435.6 KJ per mole. This means, 435.6 KJ Heat of Fusion
mol-1 of energy is required to break the H – H bonds in one
mole of hydrogen molecules. This may be expressed as Heat absorbed in the conversion of one mole of a
solid to liquid is called heat of fusion and DH is called
-1 Bond enthalpy change of fusion.
H 2 + 435. 6 KJmol 2H(g)
Breaking H2O(s) → H2O(l) – 1.44 KCal
1 mole Energy
of hydrogen absorbed Ice water
molecule. Q = -1.44 KCal
or 435.6 KJ/mol of heat energy is given out during Hfusion = + 1.44 KCal
the formation of one mole of hydrogen gas molecules.
Photochemical Reaction
Enthalpy
It is a chemical reaction caused by light or ultraviolet
It is denoted by H. A thermodynamic property of a radiation. The incident photons are absorbed by reac-
system is defined by H = U + PV, where H is the en- tant molecules to give excited molecules or free radicals
thalpy. U is the internal energy of the system, P is its
[27] Chronicle IAS Academy
which undergo further reaction. Photosynthesis in pres- AgNO3 + HCl → AgCl + HNO3
ence of sunlight, expands dissociation of I2 molecule ii. Reversible Reactions: These are chemical reactions
into two iodine atoms upon absorption of light. Photog- in which the products also react to give back the
raphy in which photographic film is coated with silver
reactants. Such reactions can be made to occur in
bromide which is sensitive to light and is chemically
either direction by suitable variations in the condi-
affected by light and hence the photographic image is
tions. If the reaction is carried out in a closed vessel,
obtained by developing the film in the dark are ex-
it is found that the reaction does not go to comple-
amples of photochemical reactions. In a photochemical
tion.
reaction light is required.
For example,
Electrochemistry 2SO2(g) + O2(g) 2SO3(g)
3Fe(S) + 4H2O(g) Fe3O4(S)3 + 4H2(g)
The study of chemical properties and reactions in-
volving ions in solution, including electrolysis and elec-
tric cells is called electrochemistry. Equilibrium State
Chemiluminiscent Reaction: Light is evolved. When a reversible reaction is carried out in a closed
Electrolytic Reaction: Electricity is required. vessel, then it is observed that a constancy in properties
Electrochemical Reaction: Electricity is produced. like intensity of colour, pressure, concentration, etc., is
Respiration: It is the process of release of energy; it is achieved under a given set of conditions. Such a state is
an exothermic reaction. referred to as an equilibrium state. A chemical equilib-
rium is a state at which the composition of the chemical
C6H12O6 + 6O2 → 6CO2 + 6H2O system becomes constant under a given set of conditions.
Glucose Oxygen Carbon Water It must be noted that at equilibrium, the chemical reaction
dioxide does not stop but instead both the forward as well as the
backward reactions take place at the same rate.
Metallic Corrosion
Chemical Equilibrium
Many metals react with air or the environment to
form undesirable compounds on their surfaces. This When two reactants are mixed, they react to form the
process is called corrosion. Mostly metals, except like product as:
least active metals platinum, gold undergo corrosion. A+B→ C+D
Iron corrosion is called rusting. In contact with air, iron
forms red or orange materials. This material is the hy- A and B are reactants and C and D are products. At
drated form of ferric oxide (Fe2O3 xH2O). time 0, the concentration of the products is 0 and as time
progresses, concentration of the reactants decreases and
The reaction may be written as : the concentration of the products increases. As the con-
8Fe + 6O 2 + 6H 2O
→ 2Fe2 O3 + 4F3 (OH)3 centration of the products increases, they may also react
Iron Oxygen Water Iron Iron
(fromair) Oxide Hydroxide according to the reaction.
Fe2O3 + xH2O → Fe2O3xH2O C+D→ A+B
Rust Thus there is competition between
Iron rusting is not possible in dry air and vacuum. It A+B→ C+D
is prevented by coating the iron with Zinc. Zinc forms C+D→ A+B
zinc compounds with humid air and forms a protective
cover over the iron thus protecting it from rusting. This And backward C + D → A + B reactions
coated iron is known as galvanized iron or G.I. At a particular instant (time), the concentration of
the reactants no more decreases and there is no increase
Chemical Reactions in the concentration of the products i.e. at a particular
instant the concentration of both the reactants and the
The chemical reactions are primarily classified as : products are constant. This state is called equilibrium
i. irreversible; and state and is represented by
ii. reversible reactions. A+B C+D
i. Irreversible Reactions : These are chemical reac- ( sign of equilibrium)
tions in which the products do not react back to give The state of equilibrium continues indefinitely until
the reactants. it is disturbed by external factors like variation of con-
For example, 2KClO3 → 2KCl + 3O2 centration, temperature, pressure, etc. A catalyst does
not affect the final state of the equilibrium.
Rate = K[A]
Order = 1 Order of Reaction Molecularity of Reaction
A + B → Products (i) Sum of the exponents in rate (i) No. of moles of reactants involved
Rate = K[A][B] expression is called order of in the transition state of rate deter-
reaction. If rate expression is K mining step is called molecularity
Order = 1 + 1 = 2
[A]2, order or reaction is 2 and of the reaction.
2A → Products if rate expression is K [A], order
Rate = K[A]2 of reaction is l.
Order = 2 (ii) It may be a whole no. or fraction (ii) It is always a whole no.
Order of reaction is determined (iii) It is determined by actual (iii) It is determined by reaction
by experimental measurements and experimental data. mechanism.
it can be a whole number or even a
fraction.
Molecularity of Reaction: Before govern the rate of a reaction.
the discussion about molecularity we must study acti-
vated state or transition state. Before the reaction occurs, i. Concentration of reactants :
reactants collide and form the activated or the transition A→B
state Rate = K[A]
A + B → AB* If concentration of the reactant increases, rate of
A and B are reactants, AB* is the transition state or the reaction increases. When concentration of reactant in-
activated state. Product is formed from the activated state. creases, number of molecules increases. If there is an
AB* → Products increase in the number of molecules, no. of collisions
and consequently effective number of collisions in-
Thus the reaction can be given as A + B AB* → creases. With increase in the effective number of colli-
Products sions, rate of reaction increases.
The energy of activated or transition state is higher
ii. Temperature: Rate of reaction increases with in-
than both the of reactants and products. The number of
crease in temperature. With increase in temperature
moles of reactants involved in the transition state or
kinetic energy of the reactant molecules increases.
activated state or the rate determining step of a reaction
With increase in kinetic energy velocity of the mol-
is called ‘molecularity of reaction’. Let us consider the
ecules increases. Due to increase in velocity of the
reaction of CH3Cl (methyl chloride) and NaOH (Sodium
molecule, number of collision and hence effective
hydroxide):
number of collision increase. Due to increase in
K1 effective number of collision, rate of reaction in-
CH 3Cl → CH 3+ + Cl − creases.
i.
Slow
Chronicle IAS Academy [30]
iii. Chemical Nature of Reactants and Rate of Reac-
Manufacturing Catalysts Used
tion : Due to difference in chemical nature of reac-
tant activation energy of the reaction is different 1. To convert vegetable edible oil
and consequently rate is different. Activation en- into vanaspati Nickel
ergy is the minimum energy required for a chemical 2. In manufacturing of Fe
ammonia gas by ↓
reaction to take place. The reaction of FeSO4 with iron powder
KMNO4 in acidic medium is fast, but that of oxalic Haber process
acid with KMNO4 in acidic medium is slow. The
difference in rate is due to difference in the chemical 3. In the formation of Nitric
nature of FeSO4 and H2C2O4 (oxalic acid). acid by Ostwald’s process Platinum wire-gauge
4. Production of Sulphuric acid
iv. Physical State of Reactants : This effect is pro- by the Contact process platinum powder
nounced for heterogeneous reactions. In homoge-
5.. Lead Chamber process of
neous reaction, reactants are in a different phase.
production of sulphuric acid oride of nitrogen
A reaction between FeSO4 solution + KMNO4 solu- 6. Process of Ether formation
tion is homogeneous, but a reaction between CaCO3 from alcohol Hot alumina
(solid) and dilute HCL(l) is heterogeneous. The reac- 7. Deacon process for the
tion of one gram solid piece of CaCO3 with dilute HCL is
production of chlorine gas cupric chloride
slower than that of 1 gram powder of CaCO3. This is due
to increased surface area in the powdered form. Thus tive catalyst. The airy oxidation of chloroform is pre-
greater the surface area of the reactant, greater is the rate
vented in the presence of a few drops of alcohol. This is
of reaction. an example of negative catalysis. Auto—catalyst is the
v. Catalyst and its Effect on the Rate of Reaction: product of the reaction. No catalyst is added from out-
Substances which change the rate of chemical reac- side. The reaction of KMNO4 and Oxalic acid in acidic
tions by their presence are called catalysts and the medium is slow, but as soon as MN+2 is produced in the
phenomenon is called catalysis. The catalyst takes reaction, rate of reaction increases. Thus MN+2 acts as a
part in the reaction and is regenerated at the end of catalyst for the reaction. Na2SO3 is oxidized by air, but
the reaction. Thus the catalyst is not consumed in Na2ASO3 (arsenite) is not. However, when Na2ASO3 is
the chemical reaction and is recovered chemically mixed, both are oxidized. The oxidation of Na2SO3 in-
unchanged at the end of the reaction. duces oxidation of Na3ASO4 and the catalyst is an in-
There are four types of catalysts: (a) positive catalyst; duced catalyst.
(b) negative catalyst; (c) auto-catalyst; and (d) induced Catalysts change the rate of reaction by changing the
catalyst. activation energy and the mechanism of the reaction.
Positive catalyst increases the rate of reaction and Positive catalysts decrease the activation energy and so
negative catalyst decreases the rate of reaction. Thus in the reaction is faster. Negative catalysts increase the
the decomposition of KClO3 to O2, MNO2 acts as a posi- activation energy and so the reaction is slower.
•••
It is the branch that deals with the study of the Electrolytic Cell
following two types of reactions :
A cell in which electrolysis occurs i.e. one is which
i. Reactions in which chemical energy is converted to
current is passed through the electrolyte from an exter-
electrical- energy (electrochemical cell or Galvanic nal source.
cell or voltaic cell); and
In an electrolytic cell, usually two metallic or graph-
ii. Reactions in which chemical energy is required to ite rods or plates are used for allowing the electric cur-
bring about a chemical reaction (electrolytic cell). rent to pass through the electrolyte these are called
electrodes. The one electrode which allow the electric
Electrolysis current to enter into the electrolyte is called anode and
the other electrode which allow the current to leave the
The production of a chemical reaction by passing an electrolyte is called cathode. During electrolysis the elec-
electric current through an electrolyte. In electrolysis, trodes may or may not take part in the chemical change.
positive ions migrate to the
cathode (negative electrode) Electrolytic Cell Reactions
and negative ions to the an-
ode. (positive electrode) In electrolysis reactions the nature of reaction is oxi-
Hence the passage of electric- dation-reduction. Oxidation takes place at anode and
ity; through an electrolyte is reduction takes place at cathode.
called electrolysis.
Example : Electrolysis of NaCl in molten state
The reactions occurring
depend on electron transfer NaCl Na+ + Cl-
at the electrodes and are at cathode Na+ + e- Na
therefore redox reactions. At at anode Cl— ½ Cl2 + e-
the anode, negative ions in
solution may lose electrons Sodium is deposited at the cathode and Cl2 is liber-
to form neutral species. Al- ated at the anode.
ternatively, atoms of the elec-
trode can lose electrons and Characteristics of Electrolysis
go into solution as positive
ions. In either case, the reac- i. The process of electrolysis starts when power is
tion is an oxidation. At the supplied and stops when power is cut.
cathode, positive ions in solution can gain electrons to
form neutral species. Thus cathode reactions are reduc- ii. The primary products are discharged ions and these
tions. are liberated only at electrodes.
iii. Electropositive elements like hydrogen and metals
Electrolyte and Non-electrolyte are liberated at the cathode.
iv. Electronegative elements like non-metals are liber-
In liquid state or in the form of solutions in some ated at the anode.
solvent (mostly water) substances allows electricity to
pass through are called electrolytes and those sub- v. The weight of a substance produced on an electrode
stances which do not allow the passage of electricity are during electrolysis is proportional to the quantity of
called as non-electrolytes. Water, Sodium Chloride and electricity passed through the electrolyte.
Molten Salts are electrolytes. Sugar, wax and naphtha-
lene etc. are non-electrolytes. Uses of Electrolysis
Cations and Anions: During electrolysis, positively
charged ions and negatively charged ions are formed. i. Electroplating: A method of plating one metal with
Positively charged ions are called cations and nega- another at the electrodes (the process of depositing
tively charged ions are called anions. ore metal on another by electrolysis).
•••
U = Uranium + 36
Kr 92
+ 30n1 + Energy
Th = Thorium
Chain Reaction
He = Helium
Emission of β -particle produces an element having During a nuclear fission a large number of chain
same mass but charge one unit greater than the parent reactions take place. If we initiate fission of one U235
element. nucleus by one neutron obtained either by cosmic rays or
by some radioactive source. In this fission process each
Y
AX → Y+1
BX + -1 β 0 U235 nucleus suffering fission will liberate three neutrons.
81
Tl206 → Pb206 + -1 β 0
82
These three neutrons will in turn cause the fission of
three other U 235 nuclei and will liberate three more neu-
The process of radioactive disintegration continues trons in the fission of each U 235 nucleus. Thus nine neu-
till a non-radioactive element is produced. In case of trons will be obtained and so on. Consequently, a self
92
U238, α and β particles are emitted and the final prod- propagating or self sustaining chain reaction (also called
uct is 82Pb206 auto catalytic reaction) starts in which the number of
U238 α ,β neutrons keeps on multiplying rapidly (in geometrical
→ 82Pb
208
92
progression). This chain reaction is also accompanied by
Thus the mass difference is 238 – 206 = 32 units and the liberation of a huge amount of energy which is called
this corresponds to emission of 8 α particles (mass of β fission energy. This energy can either be very fast result-
= 0). The charge difference is 92 – 82 = 10. Emission of ing in a violent explosion (as in an atom bomb) or it can be
8 α particles decreases the charge by 16 units and emis- controlled and maintained at a steady rate (as in chain
sion of each b increases the charge by one unit. Thus 16 reacting nuclear piles or nuclear reactors).
–10=6β particles are emitted.
Nuclear Reactor
Group Displacement Law
A nuclear reactor is a mechanism by which nuclear
When an a - particle is emitted, the new element is fission is produced in the form of a controlled self-
displaced 2 places left in the periodic table, and when a sustaining chain reaction. In other words, it is a con-
b -particle is emitted, the new element is displaced one trolled chain-reacting system supplying nuclear energy.
Chronicle IAS Academy [36]
Moderators 6CO2 + 6H2O → C6H12O6 + 6O2
Here a very important question arises – whether the oxy-
The explosive effect of the nuclear fission chain reac- gen evolved in this process comes from CO2 or from H2O or
tion can be reduced by using some substances called from both. This question has been answered by the use of
moderators which slow down the fast moving neu- radioactive O18 isotope H2O is made to react with Carbon
trons. The secondary neutrons (which are formed after dioxide containing O18 (i.e. CO218) and it is found that the
the first nuclear fission reaction) pass through the mod- oxygen evolved does not contain O18 i.e. O18 present in CO218
erator and lose some of their kinetic energy and their goes to sugar and water while that of water is evolved as free
speed is reduced. Thus the use of a moderator controls oxygen. Thus oxygen evolved in the process of photosynthe-
the explosive effect of the nuclear fission chain reaction. sis comes from H2O and not from carbon dioxide and conse-
When graphite is used as a moderator, the reactor is quently, the reaction shown above could be shown as :
called Atomic Pile and when D 2O (heavy water) is used 6CO218 + 12H2O → C6H12O618 + 6H2O18 + 6O2
it is called Swimming Pool reactor.
ii. Uses of tracers in the diagnosis of diseases : Radio –
iodine (1-131) has been used to locate and detect the
Nuclear Fusion presence of tumour.
Such a nuclear reaction in which two lighter nuclei are iii. Circulation of blood : Radioactive sodium (Na24)
combined or fused together to form a heavier (and hence has been used to study cases of restricted circula-
stabler) nucleus is called nuclear fusion. Nuclear fusion tion of blood.
occurs at reasonable rates only at very high temperatures. It iv. Pumping action of heart has been studied by using
is because of this that the nuclear fusion reactions are also radioactive sodium or radio iodine.
called thermonuclear reactions i.e. temperature – depen- v. Radioactive iodine (I131) is given to a patient with
dent reactions. Nuclear fusion adequately explains the:- thyroid disorders.
I. energy of the sun and other stars which is called vi. Tracer iron has been used in studying the disorders
Stellar energy. associated with pregnancy.
II. the basic principle of the hydrogen bomb (Fusion bomb). vii. Co60 emits high energy g (gamma) rays which are
i. Stellar energy : used for testing deeply seated cancer growth.
41H1 → 2He4 + 21e0 + Energy viii.The wear of piston rings and of gears in engines
and its prevention by means of suitable lubricants
Proton Helium Positron have been studied by radioactivity.
Above nuclear reaction indicates that four H-atoms ix. Radioactive uptake of phosphorus by plants from
(or protons) are fused together to produce one helium soil and fertilizer is determined by adding radio
nucleus and two positrons. On the sun the fusion of four phosphorus to the fertilizer.
H-nuclei into helium nucleus does not take place through
a single step but takes place through deuterium 1H2. x. Irradiation of maize with radioactive Cobalt produces
15% increase in the quantity of green parts over those
ii. Hydrogen Bomb: Nuclear fusion reaction depends plants growing in the same field, but not irradiated.
on high temperature. This is provided by the fission
of U 235 nucleus which is an explosive chain reaction. 2. Uses of radioisotopes in the treatment of diseases
This forms the principle of the hydrogen bomb. In the (Radiotherapy) :
preparation of hydrogen bomb a suitable quantity of ● Radioactive iodine I131 has been used for the
all the isotopes of hydrogen ( 1H1; 1H2 and 1H3 ) is treatment of certain thyroid complaints. Actually
combined with an atomic bomb. The function of I131 is utilized in the treatment of hyperthyroidism
atomic bomb is to provide the high temperature which and cancer of the thyroid.
is necessary for bringing about the nuclear fusion ● Radioactive phosphorus in the form of phosphate is
reactions in hydrogen bomb. In the hydrogen bomb widely used in the treatment of certain blood disorders.
the following nuclear fusion reactions take place:
● Radio Cobalt (Co60) is used in the treatment of cancer.
1
H1 + 1H2 → 2He3 + Energy « H2 + 1H2 → Co60 has been called Poor Man’s radium.
2He3 + 0n1 + Energy ● Radioisotope of phosphorus is being used for the
1
H3 + 1H2 → 2He4 + 0n1 + Energy treatment of leukaemia.
● Radio phosphorus (P30) is found good for skin diseases.
Uses of Radioisotopes ● U238 isotope is used for the determination of the
earth by rock dating method.
1. Uses of radioisotopes as radioactive tracers: ● The age of animal and plant fossil is is determined
i. Uses of tracers in studying reaction mecha- by using the radio carbon (C14) dating method.
nisms like photosynthesis as : •••
[37] Chronicle IAS Academy
CHEMICAL BONDING CHRONICLE
IAS ACADEMY
A CIVIL SERVICES CHRONICLE INITIATIVE
Except noble gases atoms of all other elements have Generally metals have the tendency to donate elec-
a tendency to combine either with each other or with the trons and non metals have tendency to gain electrons.
atoms of other elements to form clusters or aggregates of So in this stage an electrovalent bond forms. For ex-
atoms with a definite composition. Thus, a chemical ample, in the formation of NaCl (Sodium Chloride), Na
bond is defined as the attractive force that holds two or (Sodium) donates an electron to chlorine to get an octet.
more atoms together in a molecule or an ion. Atoms Na → Na+ + e (2,8,1 → 2,8)
combine chemically for the following reasons:
Cl + e- → Cl— (2,8,7 → 2,8,8)
1. When two atoms come closer to combine together to Donors are Cations and Gainers are Anions.
form a bond between them, the attractive and repulsive
forces begin to operate them. Attractive force is due to ii. Covalent Bond : The chemical bond between two
attraction between one atomic nucleus and electrons of atoms in which the electrons (in pairs) are shared
another atom. Repulsive force is due to repulsion be- by both the participating atoms is called Covalent
tween electrons of different atoms. If attractive force is bond. The covalent bond formed by the sharing of
dominant over repulsive force then bond formation one, two or three electron pairs between the partici-
occurs and if the repulsive force is dominant over the pating atoms is called single, double and triple co-
attractive force there is no bond formation. valent bond respectively. Single bond is represented
by a single dash (-) in which one pair of electrons is
Molecule Shape
involved as in H – H (H2) and H – Cl (HCl). Double
BaCl 2 Linear shape Covalent bond is represented by double dash (=) in
Co 2 Linear shape which 2 pairs of electrons are involved as in O = O
Bcl3 Trigonal planar shape (O2). Triple Covalent bond is represented by Triple
CH 4 Tetrahedral shape dash ( ≡ ) in which 3 pairs of electrons are involved
NH 3 Trigonal pyramidal shape as in N ≡ N (N2). H 2, HCl, NH3, CH4, CCl4, BF3, CO2
H2 o V shaped (angular or bent are examples of covalent compounds.
PF5 Trigonal bipyramidal
iii. Co-ordinate Bond: A covalent bond which is formed by
Xef2 Linear shape
the mutual sharing of two electrons both of which are
SF6 Octahedral shape
provided entirely by one of the linked atoms (or ions) is
[Cu(NH 3)2]2+ Square planar
called a co-ordinate bond. For example in O3 molecule,
2. Chemical bond is formed for getting stability. This one lone pair of one oxygen atom of O2 is donated to the
stability occurs by acquiring a stable outer-shell of other oxygen atom to form O3 molecule as in
eight electrons. O = O → O2
In the formation of a chemical bond atoms interact → denotes co-ordinate bond.
with each other by losing, gaining or sharing of
electrons so as to acquire stable octet electrons. Shapes of Molecules
3. The process of chemical bonding between the atoms In ionic compounds, the bond exists due to electro-
decreases the energy of the combining atoms and static attraction between oppositely charged species
gives rise to the formation of a system which has which are non-directional. So the structure is deter-
lower energy and hence greater stability. mined almost entirely by the relative sizes of the ions.
Covalent bonds are however directional and the shape
Types of Chemical Bonds of a covalently bonded molecule is decided by the direc-
There are mainly two types of chemical bonds as below : tion of the covalent bonds.
i. Electrovalent Bond : It is also known as ionic or Many physical and chemical properties are decided by
polar bond. The chemical bond formed between two the shape of molecules. Specific properties of H2O are
atoms by the transfer of one or more valence elec- decided by its angular shape. Similarly, the biologically
trons from one atom to the other is called an ionic important DNA molecule which has special
bond. This bond is also called Electrovalent bond. physiochemical behaviour, is due to its double spiral shape.
Generally, non-metals have a tendency to gain elec- hydrogen respectively. When hydrogen is burnt with
trons to complete their octets and thus they form nega- pure oxygen in oxyhydrogen blow torch, it gives a very
tive ions. Hence they are called electronegative elements. hot flame (2800°C) which is employed for welding pur-
For example, Nitrogen, Oxygen, Phosphorus, Bromine, poses and for melting platinum and quartz. Hydrogen
etc. are non-metals. Non-metallic elements are placed is also used as a fuel in rockets and guided missiles.
on the right-hand side of the periodic table. Out of ap-
3. For Filling Air-Ships and Balloons: Due to its low-
proximately 22 non-metallic elements, 11 are gases (oxy-
est density, hydrogen is used as a gas for inflating
gen, nitrogen and chlorine), one is liquid like bromine
meteorological balloons and in air-ships. As it is
and rest are solids (e.g. Carbon, Sulphur, Phosphorus
combustible and has a tendency to leak, a non-
and Iodine).
inflammable mixture of 85% He and 15% H 2 is used
for the purpose.
Hydrogen
4. In Metallurgy : Hydrogen is used in producing
There is great importance of hydrogen in our life. It is pure metals from their oxides.It is also used in pro-
found in water, acids, carbohydrates (sugars, starch, ducing a reducing atmosphere within the furnaces
cellulose), plants, animals, proteins, vitamins, wood, in the heat treatment of metals.
coal tar, oil, natural gas, etc. The atomic number and
atomic weight is one and 1.00797 respectively. It is the Various Forms of Hydrogen
first chemical element in the periodic system. Hydrogen
is manufactured by Lane’s process (By the action of 1. Nascent Hydrogen : It is a reactive form of hydro-
steam on hot iron) and Bosch Process (from water gas). gen generated in situ in the reaction mixture (e.g. by
Under normal conditions hydrogen is a colourless, the action of acid on zinc). Nascent hydrogen can
odourless, tasteless gas composed of diatomic molecules, reduce elements and compounds that do not readily
H2. It is the lightest substance known. At normal tem- react with normal hydrogen. It was once thought
peratures, hydrogen is comparatively unreactive but at that the hydrogen was present as atoms in the atmo-
higher temperature, it becomes highly reactive. sphere but this is not the case.
2. Adsorbed or Occluded Hydrogen: Some metals like
Uses of Hydrogen Pd, Pt, Au, Fe, Ni etc. can absorb under, certain
conditions relatively large volumes of hydrogen.
1. In Chemical Industries: Hydrogen has a great im- The gas thus adsorbed by metals is given off when
portance in the formation of ammonia by Haber’s the metal is heated especially under reduced pres-
process, formation of hydrochloric acid and metha- sure. The phenomenon was termed occlusion or
nol, vanaspati ghee from vegetable oils such as co- adsorption. The gas so adsorbed by the metal is
conut oil, cotton seed oil, etc. by the action of hydro- termed occluded or adsorbed hydrogen. Occluded
gen in the presence of finely divided Nickel under 5 hydrogen is more active and a stronger reducing
atmospheric pressure and at 150° - 200°C. Petrol agent than ordinary hydrogen.
substituents by the action of hydrogen, under pres-
sure on finely – powdered coat suspended in oil 3. Active Hydrogen : When ordinary hydrogen at room
(Bergins process) or by the hydrogenation of CO temperature is subjected to the action of silent elec-
(Fischer – Tropsch process). tric discharge at an electrical pressure of more than
30,000 volts, it changes into an active variety of
2. In Engineering : Hydrogen is used as a valuable hydrogen. This is called active hydrogen.
fuel, because its heat of combustion is very high.
Heat of combustion is the amount of heat produced 4. Atomic Hydrogen : When molecular hydrogen in con-
when one gram of a substance is completely burnt. tact with a tungsten or platinum wire was heated by
It is a constituent of many fuel gases like coal gas, an electric current at low pressure, it dissociates into
water gas which contain 50% and 45% by volume of atomic hydrogen. This is an endothermic reaction.
•••
[45] Chronicle IAS Academy
ORGANIC CHEMISTRY CHRONICLE
IAS ACADEMY
A CIVIL SERVICES CHRONICLE INITIATIVE
Nitrogen nitric acid. This acid is washed down by rain into the
soil, where it reacts with limestone and alkalies of the
Atomic number = 7 soil to form nitrogen and is stored there as plant food.
Atomic weight = 14.008 By Symbiotic Bacteria: The atmospheric nitrogen is
Nitrogen occurs free gaseous state in atmosphere. It being constantly transferred to the soil through the
is present in air to the extent of 78.03% by volume and agency of certain bacteria called symbiotic bacteria.
75.51% by weight of dry air. It is also found in nature in These grow in small nodules in the roots of plants
the combined state as nitrates (Nitre KNO3, Chile Salt belonging to the family of leguminacea (pea, gram, etc.)
Petre NaNO3) or ammonium salt. It is also present in and directly assimilate atmospheric nitrogen and con-
living animals or plants in the form of proteins. Nitro- vert it into products useful for plant growth.
gen is obtained for industrial purposes by fractional Nitrogen Cycle: Nitrates in the soil are taken up by
distillation of liquid air. plant roots and may then pass along food chains into
Fixation of Nitrogen: The conversion of atmospheric animals. Decomposing bacteria convert nitrogen-con-
nitrogen into useful nitrogenous compounds by natu- taining compounds (especially ammonia) in plant and
ral or artificial methods is called fixation of nitrogen. animal wastes and dead remains back into nitrates,
Nitrogen present in these nitrogenous compounds is which are released into the soil and can again be taken
called fixed or combined nitrogen. up by plants. Though nitrogen is essential for all forms
of life, the huge amount present in the atmosphere is not
Nitrogen is fixed in nature by the following meth- directly available to most organisms. It can however be
ods: assimilated by some specialized bacteria and algae and
By lightning Discharge: Under the influence of light- is thus made available to other organisms indirectly.
ning discharges the nitrogen and oxygen in air form Lightning flashes also make some nitrogen available to
plants by causing the combination
of atmospheric nitrogen and oxy-
gen to form oxides of nitrogen,
which enter the soil and form ni-
trates. Some nitrogen is returned
from the soil to the atmosphere by
denitrifying bacteria.
Ammonia Gas: It is present in
atmospheric air in traces being pro-
duced by the purification of animal
or vegetable matter or from the de-
composition of urine.
Ammonia is manufactured on a
large scale by the following process :-
1. Haber’s process for the manu-
facture of ammonia on a large scale
includes the following catalysts :
i. Finely divided iron with traces
of molybdenum and calcium met-
als; or
ii. Ferric oxide with traces of SiO2
•••
Metallurgy is the branch of applied science con- Hence, gangue + flux = slag
cerned with the production of metals from their ores, the An example is the use of SiO2 flux to remove basic
purification of metals, the manufacture of alloys and the FeO gangue during the extraction of copper (Cu) from
use and performance of metals in engineering practice. Copper Pyrite (CuFeS2).
Process metallurgy is concerned with the extraction
FeO + SiO ® FeSiO3
and production of metals, while physical metallurgy
concerns the mechanical behaviour of metals. Gangue Flux Slag
Hence, except a few metals such as Cu, Ag, Au, Pt Calcination: It is the process of heating an ore below
etc., most of the metals are found in nature in the form of its melting point to remove volatile impurities from the
minerals. Metals are extracted from the minerals by ore.
several methods.
Fe2O3 × H2O Calcination Fe2O3 + × H 2O -
•••
The chemistry which deals with the chemical rela- organic matter present in water. It should not exceed
tions among various factors like atmosphere, earth, wa- 3mg per litre of water.
ter, plants and animals is called environmental chemis- The different values of DO and BOD for Ganga water
try. Thus, an environmental chemical balance exists for at different cities are given below:
the easy survival of living things, but some human
City DO (mg/l) BOD(7 mg/l)
activities such as rapid population growth, industrial-
ization, modern technology are hampering our lives. Rishikesh 8.3 1.4
Hence, Air, land and water are increasingly becoming Haridwar 8.1 1.9
more polluted and the survival of living beings is threat- Kanpur 8.1 20.4
ened. Varanasi 7 9.4
There are two main classes of pollutants those that Patna 8.9 2.1
are biodegradable (e.g. sewage), i.e. can be rendered Kolkata 7.8 3.5
harmless by natural processes and, therefore, cause no Radioactive Pollution
permanent harm if adequately disposed off or treated
and those that are non bio-degradable (e.g. heavy met- Nowadays, nuclear tests are occurring in different
als (such as lead and DDT), which eventually accumu- parts of the world and atomic reactors are also being
late in the environment and may be concentrated in established for peaceful purposes. Due to careless ac-
food chains. tivities exposure to radiations (from radioactive materi-
als) causes death or genetic defects in man.
Air Pollution
Ozone Layer
Air is essential for living things. Waste substances
like smoke and gases from chimneys escape into the air It is a layer of the earth’s atmosphere in which most
and pollute it. Air so changed is said to be polluted and of the atmosphere’s ozone is concentrated. It occurs 15-
the substances causing pollution are called pollutants. 50 km above the earth’s surface. In this layer most of the
The main air pollutants are carbon dioxide, ammonia, sun’s ultraviolet radiation is absorbed by the ozone
sulphur dioxide, smoke, carbon monoxide and other molecules, a rise in the temperature of the stratosphere
waste gases let out through the chimneys of industry, and preventing vertical mixing so that the stratosphere
automobiles (motor, buses) and others (like fuels). Since forms a stable layer. By absorbing most of the solar
plants take in carbon dioxide and release oxygen dur- ultraviolet radiation the ozone layer protects living or-
ing photosynthesis, therefore growing trees and plants ganisms on earth. The fact that the ozone layer is thin-
in big cities and industrial towns is one way of control- nest at the equator is believed to account for the high
ling of air pollution. equatorial incidence of Skin Cancer as a result of expo-
sure to unabsorbed Solar ultraviolet radiation. The ex-
Water Pollution istence of the ozone layer is maintained with creation
and destruction of O 3. Oxygen molecules are destroyed
Like air, water is also an essential factor for living by high energy ultraviolet radiation and form ozone
beings. Various types of wastes such as sewage, indus- (O3). This ozone has an appreciable lifetime in the atmo-
trial wastages are liberated into rivers, lakes, etc. Thus sphere until, it is effected from ultraviolet radiation and
water becomes toxic for fish and other living beings. once again forms common oxygen gas. Ozone molecules
are stable, however ozone can be broken down by stable
The extent of pollution of river water (or any other
organic chlorine compounds mainly Chlorofluoro car-
type of water) is usually measured by oxygen stan-
bons, where an active chlorine atom can catalytically
dards. One is dissolved oxygen (DO) which should not
destroy ozone. Due to this destruction ozone hole is
be less than 4 mg per litre of water. The other is the
developing.
biological oxygen demand (BOD) and is a measure of
Fertilizers
Fertilizers are the substances which are added to
the soil in order to make up the deficiency of essential
elements like nitrogen, phosphorous and potassium
Agricultural Chemistry required for the growth of the plants.
Chemistry plays a vital role in agriculture particu- 1. Nitrogenous Fertilizers: These fertilizers mainly
larly of fertilizers and pesticides. By the use of fertilizers supply nitrogen to the plants or soil. Ammonium
we improve the quantity of nutrients in soil for plants. sulphate (NH4)2SO4, calcium ammonium nitrate,
Pesticides are such chemicals which are used to destroy basic calcium nitrate, calcium cyanamide, urea, etc.
the harmful insects, fungi and others which are harmful are the examples of nitrogenous fertilizers.
to crops. 2. Phosphatic Fertilizers: It provides phosphorus to
the soil. Superphosphate of lime, triple superphos-
Pesticides phate and phosphate slag are examples.
Pesticides are chemicals which are subdivided into 3. Potash Fertilizers: It supplys potassium to the plant.
the following: These are useful to the plants especially to mead-
ows, tobacco, cotton, coffee, potatoes and corn. All
1. Insecticides: Insecticides kill those harmful insects, these fertilizers occur in nature. Potassium chloride
which attack growing and harvested crops, live- (KCl), Potassium nitrate (KNO3) Potassium Sulphate
stock, buildings and man himself. There are four (K2SO4. are examples.
ways in which insecticides may act:
4. NP Fertilizers: It provides two elements namely,
i. directly nitrogen and phosphorus. These are obtained by
ii. by passage mixing together nitrogenous and phosphatic fertil-
izers in suitable proportions. Examples are –
iii. by ingestion
dihydrogen ammoniated phosphate (NH4H2PO4),
iv. by inhalation as a lethal vapour. Calcium superphosphate nitrate Ca (H2PO4)2.
2. Herbicides: These are used to discourage weed 2Ca(NO3)2 and ammoniated phosphate sulphate
growth without damaging the crop. NH4H2PO4. (NH4)2SO4.
3. Fungicides: It controls parasitic and saprophytic 5. NKP or Complete Fertilizer: These fertilizers supply
fungi which are responsible for damaging the crops. all the three essential elements namely, nitrogen, phos-
It prevents further attack of fungi on plants. phorus and potassium to the soil and are produced
4. Nematicides: It kills the parasitic worms residing by mixing nitrogeneous phosphatic and potash fer-
in soil which feed on growing crops. Nematicides tilizers in suitable proportions. It is observed that
these fertilizers produce much better results.
iv. Semi-water gas iii. The space shuttle uses liquid hydrogen, liquid oxy-
gen along with solid boosters in the lower stages.
v. Coal gas: Mixture of hydrogen, methane, ethylene,
carbon monoxide, nitrogen, oxygen and carbon di- iv. The Russian rockets such as PROTON generally
oxide. use a liquid propellant consisting of kerosene and
liquid oxygen.
vi. Natural gas: CH4-methane (~75%) + ethane(~10%)
Propane (~7%) and butane (~2%) v. In the Indian scenario, the SLV-3 and ASLV rocket
use composite solid propellants. The PSLV- rocket
Rocket Fuels: Rocket propulsion requires fuels that which is still in the experimental stage, will use a
are known as “Rocket fuels”. Some important rocket solid propellant in the first and third stages while
fuels are liquid ammonia, alcohol, hydrazine, paraffin, the second and fourth stages will use liquid propel-
liquid hydrogen and kerosene oil. It is a combination of lants consisting of N2O4 and unsymmetrical dim-
oxidising agents like liquid oxygen, liquid fluorine, hy- ethyl-hydrazine (UDMH) and N 2 O 4 and
drogen peroxide or nitric acid. These fuels liberate a monomethyl-hydrazine (MMH), respectively.
huge amount of hot gases which pass through the nozzle
of the rocket motor and provide the necessary thrust for Fire Extinguishers
the rocket to move forward according to Newton’s Third
law of motion. Any combustible substance catches fire if some re-
Rocket propellants are classified on the basis of their quired conditions are made available to it. Such condi-
physical state into three types: tions are ignition temperature (i.e. lowest temperature at
which a substance catches fire), heat, supporter of com-
1. Solid propellants: These are a mixture of a solid bustion and combustible substance. If any of these con-
hydrocarbon and an oxidising agent. A mixture of ditions is removed burning stops. Hence to extinguish
paraffin with potassium nitrate is a suitable ex- the fire a device is used that is known as the fire extin-
ample in which paraffin is the solid hydrocarbon guisher. For an extinguisher it must be one that uses
and potassium nitrate is the oxidizing agent. carbon dioxide.
There are two types of solid propellants: Electrical Fire Extinguisher: In extinguishing the
i. Composite Propellants: Polybutadiene and acrylic fire caused by electricity, carbon tetrachloride is used,
acid are solid fuels in which aluminium perchlor- because vapours of carbon tetrachloride are heavier
ate, nitrate or chlorate are used as oxidising agents. than air, so they settle down on the burning material
In composite propellants magnesium or aluminium and cut off the air supply. Here carbon dioxide and dry
is used to burn solid propellants. sand may also be used.
ii. Double base Propellant: These types of solid pro- Soda-acid Extinguisher: Here water is the main ex-
pellants consist of nitroglycerine and nitrocellulose. tinguishing agent but carbon dioxide is also used be-
cause it is denser than air and does not support com-
2. Liquid Propellants: Alcohol, liquid hydrogen, liq- bustion. Soda-acid extinguisher’s principle is based on
uid ammonia, kerosene oil, hydrozines, hydrides of cooling down the temperature of the burning substance
boron, methyl nitrate, nitromethane, hydrogen per- below the ignition temperature.
oxide, etc. are liquid propellants. Liquid oxygen,
liquid fluorine hydrogen peroxide and nitric acid Foam Extinguisher: Water is not used in extinguish-
are used as oxidising agents. ing the burning oil because water is heavier than oil or
petrol so oil floats on water and burns fire but if carbon
3. Hybrid Propellants: These type of propellants con- dioxide, sand or soil are used then foam-type fire is
sist of a solid fuel and a liquid oxidising agent. N 2O4 stopped by cutting off air supply.
and acrylic rubber are common examples in the use
of rocket propellants. Water as Fire Extinguisher: Water is used as a fire
extinguisher except fire caused by burning oil or by
i. Saturn booster rocket used in the American Space electricity. It extinguishes the fire by cooling down the
Programme derives its thrust from a combination of burning substance below the ignition temperature.
•••
l Solid CO2 is called dry ice. It is soft, white snow like amounts, it acts as an anaesthetic for minor opera-
substance. It is used as a refrigerant under the name tions. It can be prepared by heating ammonium ni-
drikold. trate.
l SiC is known as carborundum. It is manufactured as : Heat
NH 4 NO3 → N 2O + 2 H 2O
2000 – 2500 °C
SiO 2 + 3C
→ SiC + 2CO l HN3 is called hydrazoic acid.
It is extermely hard, as hard as diamond. l HNO3 attacks proteins giving a yellow nitro com-
l Butter of tin, SnCl4, 5H2O and pink salt, (NH4)2 SnCl6 pound called xanthro protein. Therefore, HNO3 stains
are used as mordant in dyeing. the skin and renders wood yellow.
l Portland cement got its name because of its resem- l Radioactive Phosphorus (P-32) is used for treatment
blance with the famous Portland rock of England. of leukemia (blood cancer).
Its main constituent is calcium oxide and other l Phosphine is used for preparing Holme’s signals for
constitutents are SiO 2, Al2O3, MgO, Fe2O3, SO3, ships to know about the position of the rocks in the
Na2O, etc. sea.
l CO2 is used with ether or acetone as refrigerant. l Phosphine is used to prepare smoke screens in war-
l A mixture of 95% of oxygen and 5% carbon dioxide fare. Calcium phosphide reacts with water to form
(called Carbogen) helps in the artificial respiration. phosphine which burns to give smoke.
l Kr also forms KrF2. l Mixture of CaCN2 and coke is called nitrolium and is
used as a nitrogenous fertilizer.
l Noble gases form a number of compounds in which
the gases are trapped within the crystal latties of l BiClO (Bismuth oxychloride) is called Pearl white.
certain organic or inorganic substances. These sub- l Suspension of calcium hydroxide in water is called
stance are called clathrates. For example clathrates of milk of lime.
Ar, Xe, Kr in β -quinol.
l Lime water is clear solution of calcium hydroxide.
l He and Ne do not form clathrate compounds.
l Sodium metal can be easily cut with a knife. Its sur-
l Neon lamps are used in botanical gardens and in face when freshly cut is very shining.
green houses because it stimulates growth and is
effective in the formation of chlorophyll. l A mixture of Na2CO3 and K2CO3 is called fusion
mixture.
l A mixture of 20% oxygen and 80%. It is used by
divers for respiration. l 28% NaCl solution is called brine solution.
l Neil Bartlett prepared the first noble gas compound, l NaOH + CaO is called soda lime.
XePtF6. l K-40 is radioactive and emits β rays.
l HF dissolves XeF6 forming highly conducting solu- l Sodium hydroxide is used in textile industry for
tion : mercerising cotton fabrics.
l Sylvinite is a mixture of NaCl and KCl.
XeF6 + HF → XeF5+ + HF2–
l We cannot store sodium in water.
l Kr and Xe are used in filling incandescent metal
filament electric bulbs. l Mg(OH)2 is called milk of magnesia.
l Radon is used in treatment of cancer (radiotherapy). l MgCl2. 5MgO. xH2O is called magnesia cement or
Sorel cement.
l N2O is called laughing gas. When inhaled in small
quantities, it causes hysterical laughter. In small l Magnesium is present in chlorophyll, which is
widely distributed in plants.
l Soda Lime: A mixture of Ca(OH)2 + NaOH - used as l Carbon Dioxide, CO2: Colourless, faint, pungent
an absorbent for a number of gases, and in decar- smell, heavier than air (1.5 times) and can be poured
boxylation of sodium salts of fatty acids. downward like water, fairly soluble in water. Acidic,
non-poisonous, can be liquefied and solidified.
l Fusion Mixture: A mixture of Na2CO3 + K2CO3- used
as laboratory reagent. l Nitrogen N2: Colourless, odourless, tasteless,
slightly lighter than air, slightly soluble in water,
l Lithopone: A mixture of ZnS + BaSO4 - used as white non-posionous, can be liquefied.
paint.
l Nitrogen Oxide, N2O (laughing gas): Colourless,
l Carbogen: A mixture of O2 and 5 -10% CO2 - used for faint pungent smell, fairly soluble in cold water but
artificial respiration. not in hot water, heavier than air, poisonous.
l Nessler’s Reagent: K2HgI4- used for detecting NH4+ l Nitric Oxide, NO: Colourless, slightly heavier than
ions. air, sparingly soluble in water, paramagnetic, neu-
l Nitrolim: Calcium cyanamide + graphite- used as tral, can be liquefied with great difficulty.
fertilizer. l Dinitrogen Trioxide: Nitrous anhydride; N2O3. Reddish
l Superphosphate: Calcium dihydrogen phosphate + brown gas which on cooling gives a deep blue liquid.
[71] Chronicle IAS Academy
l Nitrogen Dioxide, NO2: Reddish brown gas, para- perature) is used in high temperature thermometers
magnetic. used for finding temperature above the b.p. of mer-
l Nitrogen Tetroxide, N 2O4: Colourless solid (exists cury.
below 10°C), diamagnetic. l Sodium Peroxide, Na2O2: Oxidising agent, source
l Ammonia, NH3: Colourless, characteristic pungent of oxygen under the name of oxone, purification of
smell, lighter than air, extremely soluble in water, air, bleaching agent (soda bleach- Na2O2 + dil. HCl)
brings tears in eyes, basic in nature, can be liquefied l Sodium Hydroxide, NaOH: For mercerizing cotton
and solidified. to make cloth unshrinkable.
l Oxygen, O2: Colourless, odourless, tasteless, slightly l Sodium Carbonate, Washing Soda Na2CO3: In
heavier than air, slightly soluble in water, can be liquefied laundries, manufacture of glass, fusion mixture
and solidified, non-inflammable, paramagnetic. (Na2CO3 + K 2CO3)
l Ozone, O3: Pale-blue fishy smell, heavier than air, l Sodium Bicarbonate, Baking Soda, NaHCO3:
slightly soluble in water, poisonous due to its de- Preparation of baking powder, sieditz powder, ef-
structive action on tissues, can be liquefied, turns fervescent drinks and furit salts, in fire extinguish-
starch iodide paper blue, Hg loses its meniscus in ers, as antacid.
contact with O3. l Sodium Sulphate, Glauber’s Salt. Na2SO4: 10H2O.
l Hydrogen Sulphide, H 2S: Colourless, smell of rot- Craft paper, window glass, mild laxative.
ten eggs, soluble in water, poisonous. l Potassium Metal. Used in photoelectric cells.
l Sulphur Dioxide, SO2: Colourless pungent and suf- l Potassium Carbonate. K2CO3: Soft soap, hard glass,
focating odour, heavier than air, soluble in water, fusion mixture, washing wool.
pisonous, can be liquefied and solidified.
l Potassium Bicarbonate, KHCO3: Used in medicine
l Chlorine, Cl2: Greenish-yellow, suffocating smell, and baking powder.
heavier (2.5 times) than air, fairly soluble in water,
l Potassium Sulphate, K2SO4: As fertilizer, in pot-
poisonous, can be liquefied.
ash alum and glass, as a purgative in medicines.
l Bromine, Br2: Reddish brown, heavier than air,
highly soluble in water, poisonous, turns starch l Magnesium Metal: Preparation of Grignard reagent
paper yellow. (RMgX) used in organic chemistry, as a fuse in
aluminothermic process, a source of light in pho-
l Iodine, I2: Violet, sparingly soluble in water. tography.
l Hydrogen Halides, HX: Colourless, pungent smell- l Magnesia, MgO: As antacid, as refractory lining, as
ing, acidic taste, fairly soluble in water, heavier than basic lining, as insulator, rubber, filler, Sorel’s ce-
air, can be liquefied. ment (MgCl2. 5MgOxH2O) used in filling teeth and
l Some Important Mixture of Gases: Water gas (CO as a substitute for tiles.
+ H2)- used for the production of H2 and as a fuel. l Magnesia Alba (MgCO3)x [mg(OH)z]y.ZH2O: In
Producer gas (CO + N 2 + little CO2) used as fuel gas. medicines as an antacid, laxative and in teeth pow-
l Some Gases used in Warfare: Phosgene (COCl2), ders and pastes and in silver polishes.
mustard gas (ClC2H4-S-C2H4Cl), tear gas (CCl3 NO2), l Magnesium Carbonate: Refractory material, filler
lewisite (CHCl = CHAsCl2). for rubber and paper.
l Pink Salt, (NH4)2SnCl6: Mordant l Hydrogen Sulphide, H 2S: Reducing agent, labora-
tory reagent.
[73] Chronicle IAS Academy
l Sulphur Dioxide, SO2: Bleaching agent, antichlor, l Vinly Acetate, CH2 = CHOCOCH3: In plastic in-
solvent (liquid SO2). dustry.
l Sulphur Trioxide, SO3: Manufacture of H2SO4, l Vinly Chloride, CH2 = CHCl: In preparing polyvi-
oleum; for drying gases. nyl chloride (PVC).
l Oil of Vitriol, H 2SO4: In preparing dyes, fertilizers, l Gammexene, g-B.H.C: (g-benzene hexachloride).
detergents, explosives, lead storage batteries, dehy- Insecticide.
drating agent, pickling agent. l Chloroform: Anaesthetic, preparing chloropieren (in-
l Hypo, Na2S2O3.5H2O: Fixing agent in photography, secticide) and chloretone (hypnotic), preservative for
as an antichlor in volumetric analysis, in the extrac- anatomical specimens.
tion of Au and Ag from ores. l Iodoform: Antiseptic.
l Chlorine, Cl2: Bleaching agent, purification of drink- l Freon-12, CCl2F2: As refrigerant and propellent.
ing water, as germicide, as disinfectant in swim-
l Carbon tetrachloride, CCl 4: Fire extinguisher
ming pools, preparation of domestic antiseptic so-
(pyrene), solvent, anthelmentic (elimination of hook-
lution (NaOCl), bleaching powder, chlorates, DDT,
worms), fumigant.
poisonous gases like COCl2, tear gas and mustard
gas. l Ethyl alcohol, C2H5OH: Beverages, solvent, anti-
freeze for automobile radiators, in apparatuses like
l Sodium and Potassium Bromides: Sedatives, AgBr spirit levels, power alchol.
is used in photography.
l Phenol, C6H5OH: Antiseptic, preparing, salol
l Iodine, I2 and Kl are used in treating goitre; for (intenstinal antiseptic,) aspirin (antipyretic and an-
increasing production of eggs. tiseptic). picric acid (explosive), phenolphthalein
l Bleaching Powder, CaOCl2: Bleaching agent, (indicator), bakelite (a synthetic plastic, used in but-
sterilising drinking water, for making wool tons, electric switches, etc.)
unshrinkable. l Ether: General anaesthetic, refrigerant, perfumes,
l Green Vitriol (Hara Kasis), FeSO4. 7H2O: Prepara- solvent; for preparing Grignard reagent, in Wurtz
tion of blue-black (writing) ink, as mordant in dye- reaction.
ing and tanning industries, as insecticide in or- l Phenacyl chloride, C6H5.CO.CH2Cl: Lachrymator
ganic analysis. to disperse mobs.
l Ferric Oxide, Fe2O3: As a red pigment, as a polish- l Urotropine (Hexamethylene Tetramine): Urinary
ing powder in jewellery, as a catalyst for the oxida- antiseptic.
tion of CO to CO2.
l Formaldehyde: (40% solution is known as forma-
l 2, 2, 4-Trimethlpentane (iso-octane), Increases the lin). As a preservative for biological and anatomical
anti-knock quality of petrol (gasoline). specimens, in preparation of urotropine, bakelite, in
l Tetratethyl Lead (TEL), (C2H5)4Pb: Anti-knocking silvering of mirror.
agent. l Acetaldehyde Ammonia: A rubber accelerator.
l Carbon Black: In black paints, printer’s ink, as filler l Paraldehyde, (CH2O)n: A hypnotic and sporofic.
in rubber. l Metaldehyde, (CH2O)3: Solid fuel in spirit lamp.
l Ethylene Bromide: Increase the efficiency of TEL. l Acetone: For storing acetylene.
l Ethylene: General anaesthetic. l Chloretone: Hypnotic and sedative.
l Acetylene: Illumination of hawker’s lamps, artifi- l Formic Acid: In tanning for removing lime from
cial ripening of fruits. hides, as a reducing agent.
l Westron and Westrosol: Solvents. l Acetic Anhydride: Acetylating agent; preparation
l Chloroprene: In preparing polymer neoprene (a syn- of dyes, acetate rayon, aspiring.
thetic rubber). l Ethyl Acetate: In perfumes, in skin diseases.
l Acrylonitrile, CH2 = CHCN: In preparing buna N l Aniline: In preparation of dyes and dye intermedi-
(synthetic rubber) and orlon (synthetic fibre). ates, accelerators, antioxidants, sulpha drugs.
l Acetanilide: Antipyretic under the name of antifebrin.
•••
Chronicle IAS Academy [74]
CHEMISTRY
CHEMISTRY CHRONICLE
(SAMPLE QUESTIONS) IAS ACADEMY
A CIVIL SERVICES CHRONICLE INITIATIVE
1. Which of the following types of clothes is manu- (b) The density of mercury is greater than that
factured by using petroleum products? of water.
(a) Rayon Silk (c) The specific heat of mercury is greater than
(b) Terelyne that of water.
(c) Silk (d) Mecrury has greater visibility than that of
water.
(d) Cotton
7. Chemical composition of pearls is
2. Which chemical weathering process affects lime- (a) Calcium carbonate
stone the most?
(a) Oxidation (b) Calcium carbonate and magnesium carbon-
ate
(b) Sulphonation
(c) Calcium sulphate
(c) Hydration
(d) Calcium chloride
(d) None of the above
8. Which one of the following is likely to be the
3. Temporary hardness of water is due to the end product of the chemical weathering of
presence of potash feldspar?
(a) Chlorides of calcium and magnesium (a) Bauxite
(b) Sulphates of calcium and sodium (b) Calcite
(c) Hydroxides of calcium and sodium (c) Kaolin
(d) Bicarbonates of calcium and magnesium (d) Muscovite
(c) Lakes would freeze from top to bottom. (c) Silver bromide
(d) Rocks will crack due to freezing of internal (d) Silver oxide
water.
11. Alloys used in making airplane parts contain
6. Mercury is commonly used as thermometric (a) Zinc and aluminium
fluid rather than water. This is because (b) Copper and zinc
(a) The specific heat of mercury is smaller than
(c) Magnesium and zinc
that of water.
(d) Magnesium and aluminium
Chemistry 1
12. Match the following: (d) It does not contain oxygen
(A) Lead 1. Pitchblende
18. 'Epsom Salt', a well known laxative, is chemi-
(B) Aluminium 2. Monazite cally named as
(C) Thorium 3. Bauxite (a) Sodium chloride
(D) Uranium 4. Galena (b) Sodium sulphate
A B C D (c) Magnesium chloride
(d) Magnesium sulphate
E
(a) 4 1 2 3
(b) 2 3 1 4 19. An alcohol will always contain
Y
(c) 1 4 3 2 (a) Oxygen, carbon and nitrogen
AD L
(d) 4 3 2 1 (b) Carbon, hydrogen and oxygen
(c) Nitrogen, hydrogen and oxygen
13. Why does hard water not lather with the soap
EM
profusely? (d) Hydrogen, oxygen and chlorine
C
(a) Hard water contains sulphates and chlo- 20. Reduction is a reaction in which
rides of magnesium and calcium which (a) There is loss of electrons
form insoluble compounds with soap?
(b) An atoms gains electrons
(b) Hard water does not contain calcium
AC I
(c) hard water does not contain chlorides
(c) Transfer of negative valency takes place
(d) Gain of negative valency takes place
(d) Hard water does not contain sulphates
S ON
21. An oil can be made fat by the process of
14. Which of the following is used in photogra- (a) Hydrogenation
phy?
(b) Hydrolysis
(a) Silver bromide
(c) Oxidation
(b) Silver iodide
(d) Saponification
(c) Silver nitrate
(d) None of the above 22. The nucleus of deuterium contains
(a) One proton and one neutron
15. Ripening of green fruits is hastened artificially
(b) One proton and one electron
IA R
by using
(a) Acetylene (c) One neutron and one electron
(c) Sulphur dioxide 23. Which one of the following statements is incor-
CH
2 Chemistry
(c) Oxygen I II III IV
(d) Nitrogen (a) D A B C
(b) B C A D
25. Match the following :
I. Washing soda A. Sodium hydroxide (c) A D B C
II. Caustic soda B. Copper sulphate (d) D A C B
III. Blue vitriol C. Sodium thiosulphate
IV. Hypo D. Sodium carbonate
❖❖❖
Chemistry 3
CHEMISTRY SAMPLE QUESTIONS CHRONICLE
(ANSWERS) IAS ACADEMY
A CIVIL SERVICES CHRONICLE INITIATIVE
Y
1 (b) 14 (a)
E
2 (c) 15 (a)
EM
AD L
3 (d) 16 (a)
4 (d)
C 17 (b)
AC NI
5 (b) 18 (d)
6 (d) 19 (b)
S O
7 (a) 20 (b)
8 (c) 21 (a)
IA R
9 (c) 22 (a)
CH
10 (c) 23 (d)
11 (d) 24 (a)
12 (d) 25 (a)
13 (a)
Chemistry