[This Satety Data Sheet Is prepared voluntarily: itis not required according to Article 31 of Regulation (EC) No 1907/2008. fe 27000- WHITE SAFETY DATA SHEET [SECTION 1: Identification of the substance/mixture and of the company/undertaking 14 Product identifier Product name Phoenix 370490 = WHITE Product code + PHO70-90 1.2 Relevant identified uses of the substance or mixture and uses advised against Material uses Paint or paint related material Industrial use only, 1.3 Details of the supplier of the safety data sheet Sherwin-Willams UK Limited Protective & Marine Coatings Division EMEAL Tower Works Keslor Street Balton BL2 2aL United Kinggom +444 (0) 1204 62171 The Sherwin-Willams Company Inver France SAS 2 Rue Jean Revaus~ BP 80088 - 79102 Thouars CEDEX France ‘e-mail address of person: hse,pm,emea@sherwin,com responsible for this SDS 1.4 Emergency telephone number ‘National advisory body/Poison Centra Telephone number 111 (general public) 0344 892 111 (Medical professional (NHS) only) ‘Supplier Telephone number + $)-8708200 418 Hours of operation Emergency contact available 24 hours a day [SECTION 2: Hazards identification 2:1 Classification of the substance or mixture Product definition Mixture ‘lassification according to Regulation (EC) No, 1272/2008 [CLP/GHS] Repr, 2, H381 The product is dassiied as hazardous according to Regulation (EC) 1272/2008 as amended. See Section 16 forthe ful text ofthe H statements declared above. ‘See Section 11 for more detafed information on health effects and symptoms.[This Safety Data Sheet Is prepared voluntarily: itIs not required according to Article 31 of Regulation (EC) No 1907/2008. on s700- WHITE SECTION 2: Hazards identification 22 Label elements Hazard pictograms Signal word + Warring Hazard statements + Suspected of damaging ferly or the unborn chil. Precautionary statements Prevention Obtain special instructions before use, Wear protective gloves, protective clothing, eye protectin, face protection, or heating protection Response + IPexposed or concerned: Get medial avice or atention Storage + Not applicable Disposal Dispose of contents and container in accordance with ll loca, regional, national and ternational regulation, Hazardous ingredients: 1,3,5-Tiazine2.4.6iamine Supplemental labe! ‘Waring! Hazardous respirable droplets may be forred when sprayed, De nat elements breathe spray or mist. FOR INDUSTRIAL USE ONLY Setlalnackaoing coauirements Not applicable. 22.0ther hazatds “his mixture does not contain any substances that are assessed fo be a PBT ora ws. Other hazards which do: None known. ‘not result in classification SECTION 3: Gomposition/information on ingredients 32 Mixture Productingrediont Identifiers % Regulation (EC) No. 1272/2008 [CLP] | Type 136 Tiazine REACH si0 opr 2, W361 in 24 Bramine 01-21 194ss947-16 Ec: 203-615-4 cas: 108-761 Propylene Giyeol REACH 6 Notelassied. a or-2119458809-23 ec: 200-3380 cas: 57.556 Chioropropanal ec: 257-156-7 2 Acute Tox 4, H302 tn Phosphate cas: 13674-86-5 ‘See Section 16 for the fulltext of the H statements declared above. There are no addtional ingredients present which, within the current knowledge of the supper and in the ‘concentrations apdlicable, are classifed as hazardous to health or the envionment, are PBTS or vPvBs or have been assigned a workplace exposure bit and hence requite reporting in this section Type[This Safety Data Sheet Is prepared voluntarly:itIs not required according to Article 31 of Regulation (EC) No 1907/2008. on s700- WHITE SECTION 3: Composition/information on ingredients [1] Substance classified with a health or environmental hazard [2} Substance witha workdace exposure Brit [3] Substance meets the criteria for PBT according to Regudation (EC) No. 1907/2006, Annex XIII [¢] Substance mes the citeria for vPVB according to Reydation (EC) No 1907/2006, Annex XI [5] Substance of equivalent concem [6] Additional disclosure due to company policy Occupational exposure mts, f avaiable, ae ited in Section & [SECTION 4: First ald measures “41 Description of first ald measures General {mall cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an uneanscious person. If unconscious, place in recovery position and seek meaical advice, Eye contact Remove contact lenses, irigate copiously with clean, fresh water. holding the eyelids apart for atleast 10 minutes and seek immediate medical advice Inhalation + Remove to fresh ar. Keep person warm and at ret. If nt breathing, i breathing is Irregular or frespratory arest occurs, provide artificial respiration or oxygen by trained personnel, Skin contact Remove contaminated clothing ang shoes. Wash skin thoroughly wth soap anc water or use recognised skin deanser. Do NOT use solvents or thinners. Ingestion If swallowed, seek medical advice immediately and show the container or label Keep person warm and at rest, Oo NOT induce vomiting. Protection of firstaders No action shall be taken invelving any personal risk of without sutable traning, It ‘may be dangerous tothe person providing ad to give mouttrtormauth resuscitation, 4.2 Most important symptoms and effects, both acute and delayed There are no data avalatle on the mixture itselt Procedure used to derive the dassification according to Reguation (EC) No. 1272/2008 [CLPIGHS]. I splashed in the ‘eyes, the liquid may cause iitation and reversible damage. This takes into account, where known, delayed and immediate effects and also chronic effects of components from shorsterm and longeterm exposure by oral, Inhalation and dermal routes of exposure ane eye contact. 4.3 Indication of any immediate medical attention and special treatment needed Notes to physician In case of inhalation of decomposition products in a fre, symptoms may be delayed, The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments No specific treatment. See toxicological information (Section 11) SECTION 5: Firefighting measures 3:1 Extinguishing media Suitable extinguishing _:. Recommended: alcoholresistant foam, carbon dioxide, powders. media Unsuitable extinguishing: Do not use waterjet media 5.2 Special hazards arising from the substance or mixture Hazards from the Fire will produce dense tack smoke. Exposure to decomposition products may ‘Substance or mixture cause a health hazard, Hazardous combustion: Decomposition products may indude the following materials: carbon monoxide, products carbon dioxide, smoke, oxides of nitrogen.[This Satety Data Sheet Is prepared voluntarily: itIs not required according to Article 31 of Regulation (EC) No 1907/2008. on s700- WHITE SECTION 6: Firefighting measures 5.3 Advice for firefighters Special protective actions: Cool closed containers exposed to fire with water. Do not release runoff from fie to for fire-fighters drains or watercourses. Special protective Firesighters should wear posttve pressure seltcontained breathing apparatus equipment forfire-fighters (SCBA) and full turnout gear. SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures For non-emergency Avoid breathing vapour or mist. Refer to protective measures lsted in sections 7 personnel and 8. Keep unnecessary and unprotected personnel from entering, For emergency responders : \f specialised clothing is required to deal withthe spltage, take note of any information in Section 8 on suitable and unsultable materials, See also the information in "For nonsemergeney personnel’. 6.2 Environmental Do not allow to enter drains or watercourses. If the product contaminates lakes, precautions: rivers, or sewers, inform the appropriate authorities in accordance with local regulations. 6.3 Methods and material: Contain and collect spillage with non-combusille, absorbent material e.g. sand, for containment and earth, vermiculite or diatomaceous earth and place in container for disposal ‘cleaning up according to local regulations (see Section 13), Preferably clean with a detergent, Avoid using solvents. 6.4 Reference to other + See Section 1 for emergency contact information. sections See Section 8 for information on appropriate personal protective equipment See Section 13 for addtional waste treatment information [SECTION 7: Handling and storage The information in tis section contains generic advice and guidance, ThelIst of ldentified Uses in Section 1 should be ‘consulted for any avalable use-specifc information provided in the Exposure Scenario(). 7.4 Precautions for safe: Avoid contact with skin and eyes, Avoid inhalation of vapour, spray or mist handling Eating, drinking and smoking should be prohibited in areas where this materi is handled, stored and processed. Put on appropriate personal protective equipment (see Section 8). Never use pressure to emply. Container is not a pressure vessel ‘Always Keep in containers made from the same material as the original one. Comply with the health an safety at work laws. Do not allow to enter drains or watercourses. ‘When operators, whether spraying or not, have to work inside the spray booth, Ventlation is unlikely fo be sufficient to contol particulates and solvent vapour inal cases. In such cieumstances they should wear a compressed aifed respirator during the spraying process and untl such time as the particulates and solvent ‘vapour concentration has fallen below the exposure mis. 7.2 Conditions for safe Store in accordance with local regulations. ‘storage, including any Notes on joint storage incompatibilities: Keep away from: oxidising agents, strong alkalis, strong acids, Additional information on storage conditions Store in a dry, cool and wel-ventlated area. Keep container tghily closed. No smoking. Prevent unauthorised access, Containers that have been opened must be carefully resealed and kept upright to prevent leakage.[This Satety Data Sheet Is prepared voluntarily: itis not required according to Article 31 of Regulation (EC) No 1907/2008. on s700- WHITE SECTION 7: Handling and storage Contaminated absorbent mater ray pose the same hazard as the spi produek Store above 5°C (42"F) Protect from frost 7.3 Specitic end use(s) Recommendations Not available, Industrial sector specific: Not availabe, ‘solutions Good housekeeping standards, regular safe removal of waste materials and regular maintenance of spray booth ‘ters wll minimise the sks of spontaneous combustion and other fire hazards. Before use of this material please refer to the Exposure Scenario(s) it attached for the specitic end use, control measures and additional PPE considerations. ‘SECTION 8: Exposure controls/personal protection ‘The information in this section contains generic advice and guidance, The ist of Identified Uses in Section 1 should be consulted for any avalable use-specifc information provided in the Exposure Scensario(), 18.1 Control parameters Occupational exposure limits Productiingredient namo Exposure limit valuos Propylene Glycol |EH40/2008 WELs (United Kingdom (UK), 1/2020). TWA: 10 mgii* 8 hours. Form: Parteulate TWA 474 mgim? 8 hours, Form: total vapour and particulates. “TWA: 150 pom 8 hours. Form: total vapour and particulates. Recommended monitoring: If this product contains ingredients with exposure limits, personal, workplace Procedures atmosphere or biclogical monitoring may be required to determine the effectiveness ofthe ventilation of other contrdl measures andlor the necessity to use respiratory Protective equipment. Reference should be made to manitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres - Guidance for the assessment of exposure by inhalation to chemical agents for comparison with limit values and measurement strategy) European Standard EN 14042 (Workslace atmospheres - Guide for the apdication and use of procedures forthe assessment of expasure to chemical and biclogical agents) European Standard EN 482 (Workplace atmospheres ~ General requirements for the performance of procedures for the measurement of chemical agents) Reference to national guidance documents for methods for the determination of hazardous substances will so be required. Regular monitoring of all work areas should be carried out at all‘imes, induding areas that may not be equally ventlated. DNELS/DMELs Productiingredient name | Type | Exposure | Value | Population Effects Tae Tiazine2,4,etiamine NEL_[ong term [bo mgrm™ [Workers Systeme rnalation NEL Long term Dermal [12.6 mg! |Workers systemic kg bwiday NEL hor term Ht mgim? Workers systemic ralation NEL Bhort term Derma |126 moka |Workers systemic lbwiday NEL Long term 12.2 mgfm* |General systemic ination population NEL bong term Dermal [6.3 mgikg |General systemic lbwiday [population NEL Jong term rad [0.83 mgim? |General systemic[This Satety Data Sheet Is prepared voluntarily: itis not required according to Article 31 of Regulation (EC) No 1907/2008. none 3 [SECTION 8: Exposure controls/personal protection, ware [Population ‘ENECS No PNECs avatatle 8.2 Exposure controls Appropriate engineering Provide adequate ventlation. Where reasonably practicable, this should be controls Achieved by the use of local exhaust ventlation and good general extraction Users are advised to consider national Occupational Exposure Limits or other equivalent values {Individual protection measures Hygiene measures + Wash hands, forearms and face thoroughly ater handling chemical products, before eating, smoking and using the lavatory and atthe end of the warking perioa Approprate techniques should be used to remove potentially contaminated dothing, ‘Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location, Eyeltace protection Use safety eyewear designed to protect against splash of liquids. ‘Skin. protection Hand protection + Wear suitable gloves tested to ENS74, Gloves Gloves for short term exposuredong term exposure (breakthrough time >480 min): Nitrle loves >0.12 mm Gloves for splash protection need to be changed immediately when in contact with chemical. ‘There is no one glove materid or combination of materials that will give unlimited resistance to any individual or combination of chemicals. ‘The breakthrough time must be grealer than the end use time of the product. ‘The instructions and information provided by the glove manufacturer an use, storage, maintenance and replacement must be followed. Gloves should be replaced regulary and if there is any sign of damage to the dove materia ‘Always ensure that gloves are free from defects and that they are stored and used correctly. ‘The performance or effectiveness of the dove may be reduced by physicalichemical damage and poor maintenance, Barrer creams may help to protect the exposed areas ofthe skin but should not be applied once exposure has occurred. “The user must check that the final choice of type of glove selected for handing this product is the most appropriate and takes info account the particular conditions of Use, as included in the user's isk assessment Body protection Personnel should wear protective clotiing Personal protective equipment for the body should be selected based on te task being performed and the 'sks Involved and should be approved by a specialist before handling this product, Other skin protection = Appropriate footwear and any adkitiondl skin protection measures should be selected based on the task being performed and the risks involved and shoud be approved by a specialist before handling this product Respiratory protection: Appkcation methods: Brush or roller. Approvedicertified respirator with organic vapour cartridge. Fiter type: ‘AZ P2 (EN14387). Manual spraying, Use a properly fited, aiepuritying or alsfed respirator complying with an approved standard ia isk assessment incicates this is necessary. Environmental exposure = Do not alow to enter drains or watercourses. controls Bs cae a Oran TE FD, FOE ‘Dit of previous ste 770 Noy TORT Vortion EOF[This Satety Data Sheet is prepared voluntarily: itIs not required according to Article 31 of Regulation (EC) No 1907/2008. none 3 SECTION 8: Exposure controls/personal protection me Before use of this material please refer (o the Exposure Scenarlo(s) Wattached for the specific end use, control measures and additional PPE considerations. The information contained in this safety data sho does not constitute the user's own assessment of workplace risks, as required by other health and safety legistation. The provisions of the national health and safety at work regulations apply to the use of this product at work. SECTION 9: Physical and chemical properties ‘The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicates 9.1 Information on basic physical and chemical propertios ‘Appearance Physical state Lau. Colour White. Odour Paint Odour threshold Not Avatable (Not Tested). pH 8 ‘Melting pointvtreezing point = Notrelevantlapplicable due to nature ofthe product Initia! bolting point and 100°C boiling range Flash point (Closed cup: 499°C [Pensky+Martens Closed Cup] Evaporation rato 0.09 (buty! acetate = 1) Flammability (solid, gas) Not relevant/applicable due to nature of the product, Upper/iower flammability or: LEL: 2.5% (Propylene Glyca)) explosive limits UEL: 12.5% (Propylene Glycol) Vapour pressure 2.3 kPa (17.5 mm Hg) Vapour density 1IAir= 1] Relative density 1.45 Solubilityies) [Not relevantiapplcable due to nature ofthe product Partition coefficient: n-octanol/ : Not relevantiapplcable due to nature of the product, water Autosignition temperature Not relevantlapplcabe due to nature ofthe product Decomposition temperature Notrelevantlapplicable due to nature ofthe product Viscosity Kinematic (40°C): 20.5 mms Explosive properties Under normal conditions of storage and use, hazardous reactions will nt occur. Oxiaising properties Under normal concitions of storage and use, hazardous reactions willnt occur. SECTION 10: Stability and reactivity 10.4 Reactivity, No specific test data related to reactivity avaliable for this product or its ingredients, 10.2 Chemical stability ‘Stable under recommended storage and handling consitions (see Section 7) 10.3 Possibility of Under normal conditions of storage and use, hazardous reactions will not occur. hazardous reactions 10.4 Conditions to avoid —_: When exposed to high temperatures may produce hazardous decomposition products. 10.5 Incompatible materials: Keep away rom the following materials to prevent strong exothermic reactions: oxidising agents, stong alkalis, strong acids.[This Safety Data Sheet Is prepared voluntarily: itIs not required according to Article 31 of Regulation (EC) No 1907/2008. on 27000- WHET SECTION 10: Stability and reactivity 10.6 Hazardous Decomposition products may include the following materials: carbon monoxide, decomposition products carbon dioxide, smoke, oxiges of nitrogen. Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. SECTION 11: Toxicological information Tt Information on toxicological effects ‘There are no data avadable on the mixture itself Procedure used to derive the dassification according to Regation (EC) No. 127212008 [CLPIGHS] If splashed in the eyes, the liquid may cause irtation and reversitle damage. This takes into account, where known, delayed and immediate etfects and also chronic effects of components from short-term and long-term exposure by oral, inhalation and derma routes of exposure and eye contact. Acute toxicity Producingredient name Result Species Dose Exposure 735-Tiiazine-2,4,6-riamine |LD50 Oral Rat ‘atet mag | ~ Chloropropancl Phosphate _|LD50 Oral Rat 100mg | = ‘Acute toxicity estimates Route ATE value Oral 5046435 MONG iitaion/Cerresion Producvingrodient namo Result ‘Species | Score | Exposure | Observation 7.3.5 Triazine-2.4 Briamine | Eyes Mid iitant Ravbit = [ee hours 600 |= Img Conelusion/Summary Not available, Sensitisation No data avatadle Conclusion/Summary —_: Not available. Mutagenicity No data avatadle Carcinogenicity No data avaladle Reproductive toxicity No data avaladle Teratogenicity No data avaladde ‘Spacific target organ toxicity (single exposure) Product/ingredient name Category Route of | Target organs: exposure No data avalade ‘Specific target organ toxicity (eneated exposure)[This Satety Data Sheet is prepared voluntarily: itIs not required according to Article 31 of Regulation (EC) No 1907/2008. on 27000- WHITE SECTION 11: Toxicological information Torndctingrediont name Category Route of Target organs] exposure No data avaladle ‘Aspitation hazard Productingredient name Result No dala avaiable Other information Not available SECTION 12: Ecological information 12.4 Toxicity There are no data avalatle on the mixture isel, Do nat allow to enter drains or watercourses, Procedure used to derive the dassification according to Regulation (EC) No, 1272/2008 [CLPIGHS] 12.2 Persistence and degradability Productingredient name [Test Result Dose Inoculum No data avalatle Conelusion/Summary _: Not available. Productiingredient name [Aquatic halflife Photolysis Biodegradability No data avaladle 12.3 Bloaccumulative potential Product/ingredient name [LogPo Bor Potential 7.3 ScTraine-2.4 Etamine |= [a8 low Chloropropancl Phosphate |- [0.8 02.8 low 12.4 Mobility in soit Sollwwater partition Not available. Coefficlent (Koc) Mobility Not available. 12.5 Results of PBT and vPvB assessment This mixture does not contain any substances that are assessed to be @ PBT or a vPvB, 12.6 Other adverse effects = No known significant effects or enical hazards. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.[This Satety Data Sheet Is prepared voluntarly: itis not required according to Article 31 of Regulation (EC) No 1907/2008. fs 27000- WHITE ‘SECTION 13: Disposal considerations 13:4 Waste treatment methods Product ‘Methods of disposal ‘The generation of waste shold be avoided or minimised wherever possible. Disposal ofthis product, slutions and any by-products should at all imes comely with the requirements of environmental protection and waste disposal legilation and any regional local authority requirements, Dispose of surplus and non- recyclable products visa licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant withthe requitements of all authorities with jurisdiction. Hazardous waste Yes. European waste catalogue (EWC) Disposal considerations = Do not allow to enter drains or watercourses. Dispose of according to all federal, state and local appicadle regulations. If this product is mixed with other wastes, the original waste product code may no longer apply and the appropriate code should be assigned, For futher informaton, contact your local waste authority. Packaging Methods of disposal ‘The generation of waste should be avoided or minimised wherever possible. Waste packaging should be recydled, Incineration or landfill should only be considered ‘when recyding isnot feasible. Disposal considerations = Using information provided in this safety data shoet, advice should be obtained from the relevant waste authoriy on the classiieation of emply containers. Empty Containers must be scrapped or reconditioned, Dispose of containers contaminated by the product in accordance with lal or national legal provisions, European waste packaging containing residues of or contaminated by hazardous substances 15 01 catalogue (EWC) 40 Special precautions ‘This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out Empty containers or liners may retain some product residues. Avoid dispersal of spit material and runoff and cantact with soll, waterways, drains and sewers, SECTION 14: Transport information "ADRIRI 1MDG TATA UN number [Not regufated. Not regulated Not regulated 14.2 UN proper |- - : shipping name 143 Transport - Hazard Class(esy/ Labels) 4a Packing — |- - loroup 148 No, No. No, Environmental hazards [adtitional - - 7 information[This Satety Data Sheet Is prepared voluntarily: itis not required according to Article 31 of Regulation (EC) No 1907/2008. oer 37080 WATE [SECTION 14: Transport information This mixture Is not classified as dangerous according to Intemational ansport regulations (ADRIRID, IMDG, ICAONATA). 148 Special precautions for : Transport within user's premises: always transpor in closed containers that are user Upright and secure, Ensure that persons transporting the product know what to doin the event of an accident or spillage. 14. Transport in bulk Not applicable, according to MO instruments ‘Multimodal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, ar, etc), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for ‘suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. SECTION 15: Regulatory information 15:1 Safely, health and environmental requlations/legislation specific for the substance or mixture EU Regulation (EC) Nos 1907/2006 (REACH) Annex XIV - List of substances subject to authorisation ‘Annex xly None of the components ae ised. ‘Annex XVII- Restrictions: Not applicable, con the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles, Other EU requlations, VOC content (201073) : 2.1 ww 4 fl Seveso Directive This product is not controlled under the Seveso Directive, ‘National zagulations 15.2 Chemical safety + No Chemical Safety Assessment has been carried out assessment, SECTION 16: Other information 7 Incicates information that has changed from previously issued version. Abbreviations and ‘Acute Toxiety Estimat ‘acronyms. Classification, Labeling and Packaging Regulation [Regulation (EC) No. 1272/2008), DMEL = Derived Minimal Effect Level DNEL = Derived No Effect Level EUH statement = CLP-speciic Hazard statement Persistent, Bioaccumulative and Toxic Predicted No Effect Concentration RRN = REACH Registration Number \vPVB = Very Persistent and Very Bioaccumuative[This Satety Data Sheet Is prepared voluntarily: itis not required according to Article 31 of Regulation (EC) No 1907/2008. on 27000 WHET SECTION 16: Other information WR = Not available Key literature references: Regulation (EC) No. 1272/2008 [CLP] ‘and sources for data ‘ADR = The European Agreement concerning the International Carriage of Dangerous Goods by Road IATA= International Air Transport Association IMDG = Intemational Maritime Dangerous Goods Conforms to Regulation (EC) Na. 1807/2008 (REACH), Annex ll, a amended by Commission Regulation (EU) 2075/830 Directive 2012/18/EU, and relative amendments & additions Directive 2008/98/EC. and relaive amendments & additions Ditectve 2009/161/EU, and relative amendments & additions CEPE Guidelines Procedure used to derive the classification accordina to Reaulation (EC) No, 1272/2008 [CLP/GHS] Classification Justification Repr.2, H361 (Calculation method Full text of abbreviated H =: H302 Harmful if swallowed. ‘statements H361 Suspected of damaging fertility or the unborn chit. Full text of classifications = Acute Tox. 4 ACUTE TOXICITY Category 4 IcLPiGHs) Repr.2 RODUCTIVE TOXICITY = Category 2 Date of printing 10, Feb, 2022. Date of issue/ Date of 10, Feb, 2022 Date of previous issue 20, Nov, 2021 If there is no previous vakdation date please contact your supplier for more information, Version 02 ‘Notice toreader {tis recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carotully and consult resources, as necessary or appropriate, to become make themselves aware of and understand the ‘ata contained in this SDS and any hazards that may be associated with the product. This Information 's provided in good faith and believed to he accurate as of the effective date mentioned herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can may change later the composition, hazards and risks of the product. Products shall should not be repackaged, modified, or tinted except as specifically instructed by the manufacturer, including but not limited to, the incorporation of products not specified by the manufacturer, or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements are ‘subject fo change and may differ between varlous locations and jurisdictions, The customerfbuyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or focal laws. The conditions for the use of the product are not under the manufacturer's control of the manufacturer; the ‘customer/buyerluser is responsible to for determine determining the conditions necessary for the safe use of this product. The customer/buyerluser should not use the product for any purpose other than the purpose ‘shown in the applicable section of this SDS, without first referring to the supplier and obtaining written hhandling instructions. Due to the proliferation of sources for information such as manutacturer-specitic SDS, the manufacturer cannot be held responsible for SDSs obtained from any other source.Sonforms to Regulation (EC) No. 1907/2006 (REACH), Annex Il \CROLON C137V2 Aen Urethane Gloss Fish -Adaive SAFETY DATA SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking 111 Product identifier Product name ACROLON €137V2 Acrlic Urethane Gloss Finish - Additive Product code c137V2A 1.2 Relevant identified uses of the substance or mixture and uses advised against Material uses Paint or pant related material Industrial use only, 1.3 Details of the supplier of the safety data sheet Sherwin-Willams Protective & Marine Tower Works Kestor Street Bolton BL2 20L United Kingdom +644 (0) 1204 52171 The Sherwin-Willams Company Inver France SAS 2 Rue Jean Revaus~ BP 80088 - 79102 Thouars CEDEX France ‘e-mail address of person: hse.pm.emea@sherwin.com responsible for this SDS 1.4 Emergency telephone number ‘National advisory body/Poison Centre Telephone numbor + 111 (general public) 0344 892 111 (Medical professional (NHS) onk) ‘Supoliar Telephone number +: 64)-870-8200 418 Hours of operation Emergency contact available 24 hours a day [SECTION 2: Hazards identification 2:1 Classification of the substance or mixture Product definition Mixture Classification according to Regulation (EC) No, 1272/2008 [CLP/GHS| Flam, Lig, 3, H226 ‘Acute Tox. 4, H332 ‘Skin Sens. 1, 317 STOT SE 3, H335 ‘The product is dassified as hazardous according to Regulation (EC) 1272/2008 as amended. ‘See Section 16 forthe full ext ofthe H statements declared above. ‘See Section 11 for more detafed information on health effects and symptoms,Sonforms to Regulation (EC) No. 1907/2006 (REACH), Annex Il {CROLON C137V2 Acne Urethane Glos SECTION 2: Hazards identi ification 2.2 Label elements Hazard pictograms Signal word Hazard statements Precautionary statements Prevention Response Storage Disposal Hazardous ingrodionts ‘Supplemental label elements Annex XVII- Restrictions ‘on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles : Waring Flammable liquid and vapour May cause an allergic skin reaction, Harmful if inhaled. May cause respiratory iitation. + Wear protective gloves. Keep away from heat, hot surfaces, sparks, open fames and other ignition sources, No smoking, Avoid breathing vapour. +: IFINHALED: Call a POISON CENTER or doctor ifyou feel unwell. Take off contaminated dathing and wash itbefore reuse. IF ON SKIN: Wash with plenty of water, Not applicable. + Not applicable, Hexamethylene Disocyanate Palymer N Hexametiylene isocyanate (max) Contains isocyanates. May produce an allergic reaction. FOR INDUSTRIAL USE ONLY {As from August 24 2023 adequate training is required before industrial or N professional use, ‘Special packaging requirements Not applicable, 22.0ther hazards Other hazards which do not result in classification This mixture does not contain any substances that are assessed to be a PBT ora vee. None known SECTION 3: Composition/information on ingredients 3.2 Mixture Productiingredient Wdentifiors % Regulation (EC) No. 1272/2008 [CLP] | Type Hexamethylene REACH 275~<80 | Acute Tox 4, H332 nan Diisocyanate Polymer 01-21 19485796-17 ‘Skin Sens, 1, H317 IEC. 500.060.2 STOT SE 3, 1335 cas: 28182-81-2 amethoxys REACH # 210-<20 | Flam. Lia. 3, 228 te ‘emethylethyl acetate }ot-7119475791-29, STOT SE 3, 1336 Ec: 203-603-9 cas: 108-65-6 Index: 607-195-00-7Sonforms to Regulation (EC) No. 1907/2006 (REACH), Annex Il SCROLON C137V2 Aerie Urethane Gloss Fish -Adatve SECTION 3: Composition/information on ingredients Trexametnvfone REACT = Teale Tox & W302 rer Diisocyanate (max) _|o1-2119457571.07 ‘Acute Tox, 1, H330 Ec: 212-485-8, ‘Skin Irit. 2, H315 cas: 622.06-0 Eye lt 2, H319 Index: 618-01 1-001 Resp. Sens. 1, H34 ‘Skin Sens. 1, H317 STOT SE 3, 1935 ‘Soe Section 16 for the full toxt of the H statements declared above, ‘There are no adkitional ingredients present which, within the current knowledge ofthe supplier and in the ‘concentrations aprlicable, are classified as hazardous to heath or the environment, are PBTs or vPvBs or have been ‘assigned a workplace exposure mit and hence requite reporting inthis section Ime [1] Substance dassified vith a health or environmental hazard [2] Substance with a workplace exposure Bit [3] Substance meets the erteriafor PBT according to Regation (EC) No, 1907/2006, Annex Xill [4] Substance meets the criteria for vPvB according to Regulation (EC) No, 1907/2006, Annex Xill [5] Substance of equivalent concer [5] Additional disclosure cue to company policy Occupational exposure limits, it available, are listed in Section 8 [SECTION 4: First aid measures “4A Description of first ald measures General + Inallcases of doubt, or when symptoms persist, seek medical attention, Never give anything by mouth to an unconscious person. If unconscious, place in recovery Position and seek medical advice. Eye contact, + Remove contact lenses, irrigate copiously with clean. fresh water. holding the eyelids apart for at least 10 minutes and seek immediate medical advice. Inhalation Remove to fresh air. Keep person warm and at rest. f not breathing, if breathing is irregular or ifresp ratory arrest occurs, provide artical respiration or oxygen by. trained personnel ‘Skin contact + Remove contaminated clothing and shoes, Wash skin thoroughly with soap and ‘water or use recognised skin deanser. Do NOT use solvents or thinners, Ingestion + If swallowed, seek medical advice immediately and show the container or label Keep person warm and at rest. Oo NOT induce vomiting Protection of first-aiders = No action shall be taken involving any personal risk or without suitable training. iit Is suspected that fumes are stl present, the rescuer should wear an appropriate mask or sel*contained breathing apparatus. It may be dangerous tothe person providing aid to give moutreto-mouth resuscitation. Wash contaminated dlothing thoroughly with water before removing i, or wear gloves. 4.2 Most important symptoms and effects, both acute and delayed ‘There are no data avalable on the mixture itself. Procedure used to derve the dassification according to Reguation (EC) No. 1272/2008 [CLPIGHS}, See Sections 2 and 3 for detals. Exposure to component sdlvent vapour concentrations in excess ofthe stated occupational exposure Imit may result in adverse health effects such as mucous membrane and respiratory system Irtation and adverse effects on the kidneys, Iver and central nervous system, Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, loss of consciousness, Sdlvents may cause some of the above effects by ansorption through the skin If splashed inthe eyes, the liquid may cause irtation and reversidle damage, Repeated or prolonged contact with the mixture may cause remaval of natural ft from the skin, resuking in nor- allergic contact dermatis and absorption through the skin. This takes into account, where known, delayed and immediate effects and also chvonic effects of components from shortem and long-term exposure by oral, inndation ‘and dermal routes of exposure and eye contact Based on the properties ofthe isocyanate components and considering toxicological data on similar mixtures, this Ba esate Travan — Sap TOT ‘Det ot previous sa FT TOT Vortion STE $aSonforms to Regulation (EC) No. 1907/2006 (REACH), Annex I {CROLON C137V2 Aen Urethane Gloss Finish -Adatve SECTION 4: First aid measures Tnivlure may Cause acute Walon andlor Senslisalion of tha respiratory System, leading to an asihmalie condivon, wheezing and tightness of the chest, Sensitsed persons may subsequently show asthmatic symptoms when exposed to atmospheric concentrations well below the OEL. Repeated exposure may lead to permanent respiratory disability. Repeated or prolonged contact wih imitants may cause dermatitis. Contains Hexamethylene disocyanate, oligomers, hexamethylene-dtisocyanate. May produce an allergic reaction. 4.3 Indication of any immediate medical attention and special treatment needed Notes to physician + Incase of inhalation of decomposition products in a fre, symptoms may be delayed. ‘The exposed person may need to be kept under mecical surveillance for 48 hours. Specific treatments + No specific treatment. See toxicological information (Section 11) [SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing Recommended: alcohol resistant foam, carbon dioxide, powers media Unsuitable extinguishing: Do not use waterjet media 6.2 Special hazards arising from the substance or mixture Hazards from the Fire will produce dense black smoke. Exposure to decomposition products may ‘Substance or mixture cause a health hazard Hazardous combustion Decomposition products may include the following materials: carbon monoxide, products carbon dioxide, smoke, oxides of nitrogen, hyerogen cyanide, monomeric isocyanates. 5.3 Advice for firefighters ‘Special protective actions: Cool closed containers exposed to fire with water. Do not release runoff from fie to for fire-fighters drains or watercourses, Special protective + Firesighters should wear postive pressure self-contained breathing apparalus ‘equipment forfire-fighters (SCBA) and full turnout gear, SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures For non-emergency Exclude sources of ignition and ventilate the area. Avoid breathing vapour or mis. personnel Refer to protective measureslisted in sections 7 and 8, Keep unnecessary and unprotected personnel from entering. For emergency responders : If specialised clothing is required to deal withthe spilage, take note of ary information in Section 8 on Suitable and unsultable materials. See ako the information in "For non-emergency personnel’. 6.2 Environmental + Do nat allow to enter drains or watercourses. If he product contaminates lakes, precautions rivers, or sewers, inform the appropriate authorites in accordance with local regulations, Bt eae oT rion — Sap TOT ‘Date ot previous Tse OTT TOT Version $7 $FSonforms to Regulation (EC) No. 1907/2006 (REACH), Annex I SCROLON C137V2 Aen Urethane Gloss Fah = Adative SECTION 6: Accidental release measures ‘3 Methods and material _* Contain and collect spllage wih nor-combustdle, absorbent materiale. sand for containment and earth, vermiculite or diatomaceous earth and place in container for disposal ‘cleaning up according to local regulations (see Section 13). Place in a suitable container. The contaminated area should be deaned immediately with a suitable decontaminant ‘One pass ble (fammable) decontaminant comprises (by volume). water (45 parts), ethandl or isopropyl aleohd (50 parts) and concentrated (d: 0,880) ammonia solution (5 parts). A noreflammable alternative is sodium carbonate (5 parts) and ‘water (95 paris). Add the same decontaminant to the remnants and let stand for several days until no further reaction in an unsealed container, Once this stage Is reached, close container and dispose of according to local regulations (see section 13), 6.4 Reference to other + See Section 1 for emergency contact information sections ‘See Section 8 for information on appropriate personal protective equipment. See Section 13 for additional waste treatment information, SECTION 7: Handling and storage ‘The information in his section contains generic advice and guidance. The Ist of Identified Uses in Section 1 should be consulted for any avalable use-specific information provided in the Exposure Scenario(s), Persons with a history of asthma, allergies or chronic or recurrent respiratory disease should not be employed in any process in which this product is use Examination of lung function should be carried out on a regular basis on persons spraying this mixture, 7.1 Precautions for safe Prevent the creation of flammable or explosive concentrations of vapours in air and handling avoid vapour concentrations higher than the occupational exposure limits. In 2dtion, the product should orly be used in areas from which all naked lights and other sources of ignition have been excluded, Electrical equipment should be protected to the appropriate standard, Mixture may charge electostatcaly. always use earthing leads when transferring {rom one container to another. Operators should wear antistatic footwear and clothing and floors shoukl be of the conducting type. Care should be taken when re-opening partyused containers. Precautions should be taken to minimise exposure to atmosphenc humility or water, CO. willbe formed, wich, in closed containers, could result in pressurisation, Keep away from heat, sparks and flame. No sparking tools should be used. ‘Avoid contact with skin and eyes, Avoid the inhalation of dust, particulates, spray or mmist arising from the application ofthis mixture, Avoid inhalation of dust fram sanding. Eating, drinking ané smoking should be prohibited in areas where this materi is handled, stored and processed. Put on appropriate persond protective equioment (see Section 8) Never use pressure to empty. Container is not a pressure vessel ‘Always keep in containers made from the same material as the original one, Comply withthe heath and safety at work laws. Do not alow to enter drains or watercourses, Information on fire and explosion protection \Vapours are heavier than air and may spread along floors. Vapours may form explosive mixtures wih ai. ‘When operators, whether spraying or not. have to work inside the spray booth, ventlation is unlikely to be sufficient to control particulates and solvent vapour in all cases. In such circumstances they should wear a compressed ai-fed respirator during the spraying process and unti such time as the particulates and solvent ‘vapour concentration has fallen below the exposure limits. Bats cae a OT rvton Sap FORT ‘Date of previous Ta TTT TOT Vortion STE a5Sonforms to Regulation (EC) No. 1907/2006 (REACH), Annex Il {CROLON C137V2 Aen Urethane Gloss Finish -Adative SECTION 7: Handling and storage 72 Conditions Tor safe Store mn accordance win local regulations. ‘storage, including any Notes on joint storage incompatibiities Keep away from: oxidising agents, strong alkalis, strong acids. ‘Additional information on storage conditions Observe label precautions. Store in a dry, cocl and well {rom heat and direct sunlight Keep container tightly closed. Keep away from sources of ignition. No smoking. Prevent unauthorised access. Containers that have been opened must be carefully resealed and kept upright to preventlleakage. Contaminated absorbent material may pose the same hazard as the spill product Store in closed original container at temperatures between §°C and 25°C. tated area. Keep away 7.3 Specitic end use(s) Recommendations Not avaitale. Industrial sector specific: Not available, solutions Good housekeeping standards, regular safe removal of waste materials and regular maintenance of spray booth ‘ters will minimise the sks of spontaneous combustion and other fie hazards. Before use of this material please refer to the Exposure Scenario(s) i attached for the specific end use, control measures and additional PPE considerations. SECTION 8: Exposure controls/personal protection The infomation n his seston corlains gener advice and guidance. Thelst of lniffed Uses n Seaton 1 shoddbe consuted for any avatable use-specfe information provded in the Exposure Scenarios), 8.4 Control parameters Occupational exposure limits Productingradient name Exposure limit values Hexamethyne Disocyanate Polymer EH40/2005 WEL (United Kingdom (UK), 1/2020). naation lsensitser STEL: 0.07 mai, (as-NCO) 15 minutes. TWA 0,02 mgim?(a8-NCO) 8 hours 2-methoxy-t-methylethyl acetate |EH40/2005 WELs (United Kingdom (UK), 1/2020). Absorbed Itrough skin STEL: S48 mol? 15 minutes TWA. 50 ppm B hours. TWA. 274 mgin? 8 hours. STEL: 100 ppm 15 minutes. Hexamethylene Diisocyanate (max.) \EH40/2005 WELs (United Kingdom (UK), 1/2020). Inhalation lsenstiser. STEL: 0.07 main, (as-NCO) 15 minutes. TWA. 0.02 main, (as -NCO) 8 hours. Recommended monitoring + I this product contains ingredients with exposure ims, personal workplace procedures atmosphere or bielogical monterng may be required to Geterine the effectiveness ofthe ventilation or other contra measures andlor the necessity to use respiratory protective equipment. Reference should be made to monitoring standards, such as, the following: European Standard EN 689 (Workplace atmospheres - Guidance for the assessment of exposure by inhalation to chemical agents for comparison with limit values and measurement strategy) European Standard EN 14042 (Workdlace atmospheres Guide for the application and use of procedures for the assessment of expasure to chemical and bidogical agents) European Standard EN 482 (Workglace atmospheres ~ General requirements for the performance of procedures for the measurement of chemical agents) Reference to national guidanceSonforms to Regulation (EC) No. 1907/2006 (REACH), Annex I SCROLON C137V2 Aen Urethane Gloss Fish -Adative SECTION 8: Exposure controls/personal protection documents for methods Tor the determination of hazardous substances wil Aso be required, Regular monitoring of all work areas should be carried out at alltimes, induding areas that may not be equally ventilated. NELS/DMELs Productingredient name | Type | Exposure | Value | Population Effects Hexamethylene Disocyanate INEL__fong term lo morm® [Workers Local Polymer nalation NEL. Bhort term Hi maim? Workers Local nalation ‘methoxy-temetnyletnyl acetate [NEL Long term [33 mgim* |General Local nation lpopulation [Consumers] NEL Long term Ord — [26 mgikg |General systemic lbwicay "population [Consumers] NEL Long term Dermal [220 mgkg |General systemic population [Consumers] NEL Long term ls mgm* |General systemic rnalation lpopulation [Consumers] NEL. Long term 1550 moim* |Workers Local rnalation NEL [ong term Dermal |726 moka |Workers systemic lbwiday NEL. Long term 1275 moim* |Workers [systemic nalation ENECS Productingredient name ‘Compartment Detail Value Method Detail Hexametnylene Dilsooyanate Polymer Fresh water 127 mall Fresh water sediment 68700mgkg + Marine water 0127 mg | Marine water sediment P8670 makkg + Sewage Treatment 8,3 mal LC Plant lsot 3182 mgika dwt |= ‘Amethoxy-t-methyletnyl acetate Fresh water 635 makg | Marine water 9.0635 magi Fresh water sediment 6.29 malkg E Marine water seciment p.329mg/kg + sot "29 mghkg E lSewage Treatment 00 mg Plant 8.2 Exposure controls Persons with a history of asthma, allergies, chronic or recurrent respiratory dist to any process in which this product is used, 10 should not be exposed Examination of Jung function should be carried out on a regular basis on persons spraying this mixture,Sonforms to Regulation (EC) No. 1907/2006 (REACH), Annex I SCROLON C137V2 Aen Urethane Gloss Fah -Adatve SECTION 8: Exposure controls/personal protection ‘Appropriate engineering + Provide adequate vertiaton, Where reasonady practeable, Tis should be controls achieved by the use of cal exhaust venilation and good general extraction. Ai-fed Protective respiratory equipment must be wom by the spray operator, even when 800d ventilation is provided. In other operations, local exhaust ventilation and 0d general extraction are not sufficient to maintain concentrations of particles and solvent vapours below the OEL, suitable respiratory protection must be worn {See Occupational exposure contra.) + Users are advised to consider national Occupational Exposure Limits or other equivalent values. Individual protection measures Hygiono measures + Wash hands, forearms and face thoroughly after handing chemical products, before ealing, smoking and using the Lavatory and a the end ofthe working perio “Appropriate techniques should be used to remove potently contaminated dothing Contaminated work clthing sho not be allowed out of the workplace. Wash contaminated dothing before reusing, Ensure that eyewash stations and safety showers are dase tothe workstalion location, Eyettace protection + Use safety eyewear designed to protect against splash of lauds. Skin orotection Hand protection Wear suitable gloves tested to EN374, Gloves Gloves for short term exposure/splash protection (less than 10 min): Nile =0.35 Gloves for splash protection need tobe changed immediately when in contact with chemicals. For long term exposure or spils (breakthrough time >480 min): Use PE laminate gloves as under gloves. Due to many concitons (e.g. temperature, abrasion) the practical usage of a chemical protective glove in practice may be much shorter than the permeation time determined through testing, ‘There is no one glove materid or combination of materials that will give unlimited resistance to any individual or combination of chemicals. ‘The breakthrough time must be greater than the end use time of the product. ‘Tre instructions and information provided by the glove manufacturer an use, storage, maintenance and replacement must be followed. Gloves should be replaced regularly and if there is any sign of damage to the dove material. ‘Always ensure that gloves are free from defects and that they are stored and used correcdy. The performance or effectiveness of the glove may be reduced by physicalichemical damage and poor maintenance. Barrer creams may help to protect the exposed areas of the skin but should not be applied once exposure has occurred. “The user must check that the final choice of type of glove selected for handing this praduet is the most appropriate and takes info accaunt the particular conditions of tse, as included in the user's risk assessment Body protection + Personnel should wear antistatic dothing made of natural fees or of high temperature-resistant synthetic fibres. Personal protective equipment for the body should be selected based on the task being performed and the r'sks involved and should be approved by a specialist before handling this product. When there is a risk of ignition rom state electricity, ‘wear antestatc protective dothing. For the greatest protection from static discharges, clothing should indude antestatic overall, boots and gloves, Refer to European Standard EN 1149 for futher information on material and design Fequirements and test methods, Other skin protection = Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and shoud be approved by a specialist before handling this product. Ba cama OT ravton Sap TOT Date o previous ea 777 TaSonforms to Regulation (EC) No. 1907/2006 (REACH), Annex SCROLON C137V2 Aen Urethane Gloss Finish - Adve SECTION 8: Exposure controls/personal protection Respiratory protection + Use a propery Tied, al-puriiying of alrTed respirator complying wit an approved standard ifa risk assessment indicates this is necessary. Respirator selection must be based on known or antcipated exposure levels, the hazards ofthe product and the safe working limits ofthe selected respirator. Environmental exposure + Do not allow to enter drains or watercourses. controls. Before use of this material please refer to the Exposure Scenario(s) if attached for the specific end use, control measures and additional PPE considerations. The information contained in this safety data shot does not constitute the user's own assessment of workplace risks, as required by other health and safety legislation. The provisions of the national health and safety at work regulations apply to the us ofthis product at work, SECTION 9: Physical and chemical properties ‘The conditions of measurement of al properties are al slandard lemperalure and pressure unless otherwise Indicated 9.1 Information on basic physical and chemical properties ‘Appearanc Physical state Lui. Colour Colourtess. Odour Paint Odour threshold Not avallale. pH Not applicable. ‘Melting polntvtreezing point = Notrelevantlapplcable due to nature ofthe product Initia! bolting point and 140°C boiling range Flash point Closed cup: 58°C [Pensky-Martens Closed Cup] Evaporation rate 0.35 (butyl acetate = 1) Flammability (solid, gas) Not relevant/applcable due to nature of the product, Upperiiower flammability or —: LEL: 1.3% (2methoxy--methylethyl acetate) explosive limits UEL: 18.1% emethoxy temethyethyl acetate) Vapour pressure 0.24 kPa (1.8 mm Hg) Vapour density 48 [Air= 1] Relative density or Solubilityies) Not relevanv/applcable due to nature ofthe product, Partition coefficient: n-octanol/ : Not relevantiapplcatle due to nature of the product, water Autosignition temperature Not relevanviapplcable due to nature ofthe product Decomposition temperature Not relevantlapplicatle due to nature ofthe product. Viscosity Kinematic (40°C): »20.5 mms Explosive properties Under normal concitions of storage and use, hazardous reactions willnot occur. Oxidising properties Under normal concitions of storage and use, hazardous reactions will occur. SECTION 10: Stability and reactivity 70:4 Reactivity The product reacts slowly with water, resulting in the production of carbon dioxide, 10.2 Chemical stability ‘Stable under recommended storage and handling consitions (see Section 7) 10.3 Possibility of In closed containers, pressure buldbup coud result in distortion, expansion and, in hazardous reactions extreme cases, bursting of the container.Sonforms to Regulation (EC) No. 1907/2006 (REACH), Annex I SCROLON C137V2 Aen Urethane Gloss Fah -Adatve SECTION 10: Stability and reactivity 10.4 Conditions to avoid _: Ina fre, hazardous decomposition products may be produced. 10.5 Incompatible materials: Keep away from: oxidising agents, strong alkals, strong acids, amines, alcohls, ‘water. Uncontrolled exothermic reactions occur with amines and akzohals- 10.6 Hazardous Decomposition products may include the following materials: carbon monoxide, decomposition products carbon dioxide, smake, oxides of nitrogen, hydrogen cyanide, monomeric isocyanates. Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. SECTION 11: Toxicological information 11. Information on toxicological effects ‘There are no data avalabte on the mixture itself. Procedure used to derve the dassification according to Reguation (EC) No, 1272/2008 [CLPIGHS}, See Sections 2 and 3 for detals, Exposure to component sclvent vapour concentrations in excess of the stated occupational exposure Imit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, Iver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and. in extreme cases, loss of consciousness. Sdlvents may cause some of the above effects by absorption through the skin If splashed inthe eyes, the liquid may cause irtation and reversidle damage, Repeated or prolonged contact with the mixture may cause removal of natural fat from the skin, resuing in nor- allergic contact dermatits and absorption through the skin. This takes into account, where known, delayed and immediate effects and also chvonic effects of components fram shortte:m and long-term exposure by oral, inhaation ‘and dermal routes of exposure and eye contact. Based on the properties ofthe isocyanate components and considering toxicological data on similar mixtures, this mixture may cause acute iritation and/or sensitisation ofthe respiratory system, leading to an asthmatic condition, wheezing and tightness af the chest. Sensitised persons may subsequently show asthmatic symptoms when exposed to atmospheric concentrations well slow the OEL. Repeated exposure may lead to permanent respiratory disability. Repeated or prolonged contact with iritants may cause dermatitis, Contains Hexametiylene disocyanate, olgomers, hexamethylene-dhisocyanate, May produce an allergic reaction. ‘Acute toxicity ProdueUingredient name Result Species Dose Exposure Hexamethylene TBO Inhalation Vapour Rat E500 maim? | Thours Disocyanate Polymer Zmethoxrtmeiyletn’ —|LDS0 Dermal Rabbit 25 hg : acetate L050 Oral Rat s532mang | = Hexamethylene L050 lahalation Dusts and mists Rat ‘ea main — | & hours Disocyanate (max) ‘Acute toxicity ostimates Route ATE value Infalaton (vapours) 73.03 mal Inhalation (dusts and mists) 1.48 mal ctation\Corrosion Produevingrodiont namo Result ‘Species | Score | Exposure | Observation Texamethylene Eyen= Moderate tant Rast |= /i00me—)= XN Disooyanate Palymer Skin - Moderate irtant Raobt—|- _|s00me + Conctusion/Summary = Notavalable.Sonforms to Regulation (EC) No. 1907/2006 (REACH), Annex Il SCROLON C137V2 Aen Urethane Gloss Finish - Adve SECTION 11: Toxicological information ‘Sensitization No data avatatle Conclusion/Summary Not avaiable Mutagenicity No data avadatle Carcinogenicity No data avaiable Reproductive toxicity No data avatatle Toratoaenicity No data avadalde Specific target organ toxicity (single exposure) Product/ingredient name Category Route of | Target organs, exposure Hexamethylene Disooyanate Palmer Category Respiratory wact irtation 2-methoxy-t-methylethd acetate category3 Narcotic effects Hexamethylene Diisocyanate (max.) Gategory3 + Respiratory tract ration ‘Specific taraet organ toxicity repeated exposure) Produevingrediont name Category Route of Target organs exposure No data avaladle ‘Aspiration hazard Productingredient name Rest No data avaladle Other information Notavailable, SECTION 1 ‘cological information 12:4 Toxicity ‘There are no data avalatle on the mixture itself Do not alow to enter drains or watercourses, Procedure used to derive the classification according to Reguation (EC) No. 1272/2008 [CLPIGHS] 12.2 Persistence and degradability Productiingredient name [Test Result Dose Inoculum No data avaiadle Conclusion/Summary Not availble Productingrodient name [Aquatic halflife Photolysis Biodegradability No data avaadle 12.3 Bioaccumulative potentialSonforms to Regulation (EC) No. 1907/2006 (REACH), Annex SCROLON C137V2 Aen Urethane Gloss Finish - Adve SECTION 12: Ecological information Productiingredient name _[LogP= [Bor Potential Hexamethylene = 367.7 Tow q Diisocyanate Polymer Hexamethje - 57.63 low Diisocyanate (max) 12.4 Mobility in soil ‘Sollwater partition Not available Coefficient (Koc) Mobility Not available. 12.5 Results of PBT and vPvB assessment ‘This mixture does not contain any substances that are assessed to be a PBT or a vPVB. 12.6 Other adverse effects: No known significant effects or ential hazards. ‘Avoid dispersal of spilt material and runoff and contact with sol, waterways, drains and sewers [SECTION 13: Disposal considerations 13:4 Waste treatment methods Product Methods of disposal ‘The generation of waste should be avoided ar minimised wherever possible. Disposal of ths product, sclutions and any by-products should at alltimes comply vith the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non- recyclable products via alicensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant withthe requirements of all authorities with jurisdiction. Hazardous waste Yes, European waste waste isocyanates 08 05 01" catalogue (EWC) Disposal considerations = Do not alow to enter drains or watercourses. Residues in empty containers should be neutralised with a decontaminant (see section 8). Dispose of according to all federal, state and local applicable regulations. If this product is mixed with other wastes, the original waste product code may no longer apply and the appropriate code should be assigned. For futher informaton, contact your local waste authority. Packaging Methods of disposal ‘The generation of waste should be avoided or minimised wherever possible, Waste packaging should be recyded. Incineration or landfill should only be considered ‘when recyding i nat feasible, Disposal considerations = Using information provided in this safety data sheet, advice should be obtained from the relevant waste authority on the classification of empty containers. Empty containers must be scrapped or reconditioned. Dispose of containers contaminated by the product in accordance with local or national legal provisions, European waste packaging containing residues of or contaminated by hazardous substances 16 01 catalogue (EWC) 10"Sonforms to Regulation (EC) No. 1907/2006 (REACH), Annex I SCROLON C137V2 Aen Urethane Gloss Fish -Adatve SECTION 13: Disposal considerations ‘Special precautions ‘This rateral and fs container mustbe deposed ofin a safe way, Care shoud be taken when haneling emotied containers that have not been cleaned or rinsed out. Empty containers oriners may retain some product residues. Vapour from product residues may create a highly fammable or explosive atmosphere inside the container. Do not cut. weld or grind used containers unless they nave been deaned thoroughly internally. Avoid dispersal of spit material and runoff and contact with soll waterways, drains and sewers, [SECTION 14: Transport information 14.2 UN proper PAINT RELATED MATERIAL | PAINT RELATED MATERIAL | paint RELATED MATERIAL al 2 ° Additional jZunnelcode D/E Emermenoy schedules’: - 148 Special precautions for : Transport within user's promises: always transpor in closed containers that are user Upright and secure, Ensute that persons transporting the product know what to doin the event of an accident or spillage. 14.7 Transport in bulk Not applicable, according to MO Instruments ‘Multimodal shipping descriptions are provided for informational purposes and do not consider container ‘izes. The presence of a shipping description for a particular mode of transport (sea, ar, etc), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for ‘Suitability prior to shipment, and compliance with the applicable regulations Is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. SECTION 15: Regulatory information 18:4 Safety, health and environmental regulations/legislation specific for the substance or mixture EU Regulation (£0) No. 1907/2006 (REAGH) ‘Annex XIV. List of substances subject to authorisation ‘Annex XIV None of the components are listed,Sonforms to Regulation (EC) No. 1907/2006 (REACH), Annex I SCROLON C137V2 Aen Urethane Gloss Fish - Adatve SECTION 15: Regulatory information “Annex XVI Restrictions —~ Fs Wom August P4 2003 adequate aring fe requred below Wavatvavor ST on the manufacture, professional use placing on the market and use of certain dangerous substances, mixtures and articles ‘Other EU regulations VOC content (2010756) : 15.1 ww 166 gil Seveso Directive This product may add to the calculation for determining whether a site is within the scope of the Seveso Directive on major accident hazards. National regulations 15.2 Chomical safety + No Chemical Safety Assessment has been carried out assessment ‘SECTION 16: Other information 7 Indicates information that has changed from previously issued version. Abbreviations and ‘Acute Toxiety Estimate acronyms Classification, Labeling and Packaging Regulation [Regulation (EC) No, 1272/2008) Derived Minimal Effect Level erived No Effect Level EUH statement = CLP-specific Hazard statement PBT = Persistent, Bioaccumulative and Toxic, PNEC = Predicted No Effect Concentration RRN = REACH Registration Number \PvB = Very Persistent and Very Bioaccumuative NIA = Not available Key iiterature references: Regulation (EC) No. 1272/2008 [CLP] ‘and sources for data ADR = The European Agreement conceming the Intemational Carriage of Dangerous Goods by Road TATA= International Air Transport Association IMDG = International Maritime Dangerous Goods Conforms to Regulation (EC) Na. 1907/2006 (REACH), Annex ll, & amended by Commission Regulation (EU) 207/830 Directive 2012/18/EU, and relative amendments & additions: Ditectve 2008/98/EC and relative amendments & additions Directive 2005/161/EU, and relative amendments & additions CEPE Guidelines ‘Procedure used to derive the classification according to Regulation (EG) No, 1272/2008 [CLPIGHS) Classification Justification Flam. Lia. 3, H226 (On basis of test data ‘Acute Tox. 4, H332 (Calculation method Skin Sens. 1, H317 (Calculation method STOT SE 3, H335 (Calculation methocSonforms to Regulation (EC) No. 1907/2006 (REACH), Annex I SCROLON C137V2 Aen Urethane Gloss Fish -Adative SECTION 16: Other information Full ext of abbreviated = 1276 Flammabietiquid and vapour ‘statements 302 Harmful i swallowed. Ha15, Causes skin tation. #317 May cause an allergic skin reaction, H319 Causes serious eye Iittion, 330 Fatal inhaled, H332 Harm f inhaled 334 May cause allergy or asthma symptoms or breathing dficuties if inhaled, 335, May cause respiratory itation, 1336 May cause drowsiness or dizziness, Full ext of classifications: Acute Tox. 1 ACUTE TOXICITY Category 1 IcLP/GHs) Acute Tox 4 ‘AGUTE TOXICITY. Category 4 Eye lt. 2 SERIOUS EYE DAMAGEIEYE IRRITATION - Category 2 Flam. Lia. 3 FLAMMABLE LIQUIDS - Category 3 Resp. Sens. 1 PIRATORY SENSITISATION - Category 1 Skin fat, 2 ‘SKIN CORROSIONIRRITATION - Category 2 Skin Sens. 1 ‘SKIN SENSITISATION - Category 1 STOT SE3 SPECIFIC TARGET ORGAN TOXICITY « SINGLE EXPOSURE = Category 3 Date of printing 29, Sep, 2021 Date of issue/ Date of 29, Sep, 2021 Date of previous issue 27, Jul 2021 If there is no previous vabdation date please contact your supplier for more information. Version 7.04 ‘Notice to reader {tis recommended that each customer or recipient ofthis Safety Data Sheet (SDS) study it carefully and ‘consult resources, as necessary or appropriate, fo become make themselves aware of and understand the data contained in this SDS and any hazards that may be associated with the product. This information Is provided in good faith and believed to be accurate as of the effective date mentioned herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can may change later the composition, hazards and risks of the product. Products shall should not be repackaged, modified, or tinted except as specifically instructed by the ‘manufacturer, including but not limited to, the incorporation of products not specified by the manufacturer, or ‘the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements are subject to change and may differ between Various locations and jurisdictions. The customer/buyerluser Is responsible to ensure that his activities comply with all country, federal, state, provincial or focal laws. The ‘conditions for the use of the product are not under the manufacturer's control of the manufacturer; the ‘customer/buyerluser is responsible to for determine determining the conditions necessary for the safe use of this product. The customer/buyerluser should not use the product for any purpose other than the purpose ‘shown in the applicable section of this SDS, without first referring to the supplier and obtaining written hhandling instructions. Due to the proliferation of sources for information such as manutacturer-specific SDS, the manufacturer cannot be held responsible for SDSs obtained from any other source.Sonforms to Regulation (EC) No. 1907/2006 (REACH), Annex I SCROLON C137V2 Aen Urethane Finish Base SAFETY DATA SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking 111 Product identifier Product name ACROLON 6137V2 Acrylic Urethane Finish - Base Product code c137v28 1.2 Relevant identified uses of the substance or mixture and uses advised against Material uses Paint or pant related material, Industrial use only, 1.3 Details of the supplier of the safety data sheet Sherwin-Willams UK Limited Protective & Marine Coatings Division EMEAL “Tower Works. Kestor Street Balton BL2 2aL United Kinggom +44 (0) 1204 62171 ‘The Sherwin-Williams Company Inver France SAS 2 Rue Jean Revaus - BP 80088 - 79102 Thouars CEDEX France e-mail address of person: hse,pm,emea@sherwin.com responsible for this SDS 1.4 Emergency telephone number ‘National advisory body/Poison Centra Telephone number 111 (general public) /0244 892 111 (Medical professional (NHS) only) ‘Supplier Telephone number + ¥(64)-870-8200 418 Hours of operation Emergency contact available 24 hours @ day [SECTION 2: Hazards identification 2:1 Classification of the substance or mixture Product definition + Midure Flam, Li, 3, H226 Skin frit, 2, 315 Eye rit. 2, #319 STOT SE 3, H335 STOT RE 2, H373 ‘Asp. Tox. 1, H304 ‘Aquatic Chronic 3, H412Sonforms to Regulation (EC) No. 1907/2006 (REACH), Annex I SCROLON C137V2 Aen Urethane Finish - Sane SECTION 2: Hazards identification "The productis lassiied as hazardous according to Regulation (EC) 12722008 as amended. See Section 16 forthe full text of the H statements declared above. ‘See Section 11 for more detailed information on health effects and symptoms. Hazard pietograms Signal word + Danger Hazard statements Flammable liguid and vapour May be fatal f swallowed and enters airways, Causes skiniiation, Causes serious eye irritation, May cause respiratory imation, May cause damage to organs through prolonged or repeated exposure. Harmful to aquatic ie with fong lasting eects. Precautionary statements Prevention + Wear protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Avoid release to the environment. Do not breathe vapour. Response IF SWALLOWED: Inmesiately calla POISON CENTER or doctor, Do NOT induce vomiting. Storage Not applicable. Disposal Not applicable, Hazardous ingredients Xylene, mixed isomers NX Hydrocarbons, C9, aromatics ‘Supplemental label Contains isocyanates. May produce an allergic reaction. ‘slements Contains Reaction mass of Bis(1,22,6,6-pentamethy-4-piperiy)) sebacate and Methyl 1.2.2.6, €-pentamethyl-4-piperidyl sebacate. May produce an allergic reaction. Waring! Hazardous respirable droplets may be formed when sprayed, Do not breathe spray or mist, FOR INDUSTRIAL USE ONLY Annex XVII- Restrictions Not applicable. ‘on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles ‘Special packaging requirements Not applicable, 2.2.0ther hazards This mixture does not contain any substances that ae assessed to be a PBT or a vPvB. Other hazards which do: None known, not result in classificationSonforms to Regulation (EC) No. 1907/2006 (REACH), Annex I SCROLON C137V2 Aen Urethane Finish - Base SECTION 3: Composition/information on ingredients 32 Mixture Productiingrediont Wdentifiors % Regulation (EC) No. 1272/2008 [CLP] | Type Xylene, mixed isomers [REACH # 210-325 | Flam. Lig. 3, 228 nay lot-2113486216.32 Acute Tox. 4, H312 IEC: 215-626.7, ‘Acute Tax. 4, H332 Icas: 1330-20-7 ‘Skin It, 2, 4318 index: 601-022-00-8 Eye lt. 2, 4319 STOT SE 3, 1335 STOT RE 2.373 ‘Asp, Tox. 1, H304 Ett IREACH & st Flam. Lig. 3,226 ta 2-Ethoxypropionate [01-21 13463267-94 EUHO6S IEC: 212-112.9, Icas: 763-69-9 Hydrocarbons, C8, REACH <8 Flam, Lig, 3,228 ta ‘aromatics lor-21134ss851-35 ‘STOT SE 3, H335 cas: 64742-05-5 STOT SE 3, 1336 Index: 649-356-0044 ‘Asp, Tax. 1, 304 ‘Aquatic Chronie 2, H411 EUHO6S Ethylbenzene IREACH # 3 Flam. Lig. 2, #225 eset lot-2113489370.35 ‘Acute Tox. 4, H332 IEC: 07-840-4 STOT RE 2, 1373 (hearing organs) Icas: 100.41-8 ‘Asp, Tox. 1, H304 index: 601-023-0044 ‘Aquatic Chronie 3, H412 Reaction mass of Bis |REACH # 078 ‘Skin Sens. 1, H317 tn (1.22.6,6-pentamethyt- [01-21 19491304-40 ‘Aquatic Acute 1, H400 (M=1) ‘piperidyd sebacate |CAS: 1055336-91-5 ‘Aquatic Chronic 1, H410 (M=1) ‘and Methyl 1.2.2.8 Sepentamethyt- Apiperidyl sebacate 2Ethy2= REACH # 03 Rept. 2, H361 tn (bydroxymethyh lor-2118486799-10 “1,3-propanediol IEC: 201.0749 Icas: 77-09-6, ‘See Section 16 for the fulltext ofthe H statements declared above. ‘There are no additional ingredients present which, within the current knowledge ofthe supplier and inthe ‘concentrations applicable, are classified as hazardous to heath or the environment, are PBTS or vPVBs or have been ‘assigned a workplace exposure mit and hence require reporting inthis section. Tyme [1] Substance dassified with a health or environmental hazard [2] Substance with a workplace exposure br [3] Substance meets the criteria for PBT according to Reguation (EC) No. 1907/2008, Annex Xill [4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1807/2006, Annex Xill [5] Substance of equivalent concern [5] Additional disclosure cue to company policy Occupational exposure limits, ifavailable, are listed in Section 8, Bas ec a Orava ET FOET ‘Date of previous ste Sap TOT Vorrion TE a5Sonforms to Regulation (EC) No. 1907/2006 (REACH), Annex Il SCROLON C137V2 Aen Urethane Finish Base SECTION 4: First aid measures “41 Description of first ald measures General + Inallcases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery Position and seek meaical advice. Eye contact, + Remove contact lenses, irrigate copiously with clean, fresh water. okiing the eyelids apart for at least 10 minutes and seek immediate medical advice. Inhalation Remove to fresh air. Keep person warm and at rest fnot breathing, if breathing is. irregular or ifresp ratory arest occurs, provide arificial respiration or oxygen by trained personnel ‘Skin contact Remove contaminated clothing ang shoes. Wash skin thoroughly wth soap anc ‘water or use recognised skin cleanser. Do NOT use solvents o- thinners. Ingestion If swallowed, seek medical advice immediately and show the container or label. Keep person warm and at rest Do NOT induce vomiting Protection of first-aiders = No action shall be taken involving any personal risk or without suitable training. it is suspected that fumes are stil present, the rescuer should wear an appropriate ‘mask or sel-contained breathing apparatus. It may be dangerous tothe person Providing aid to give moutr-iosmouth resuscitation. 4.2 Most important symptoms and effects, both acute and delayed ‘There are no data avalable on the mixture itself. Procedure used to derve the classification according to Regulation (EC) No, 1272/2008 [CLPIGHS}, See Sections 2 and 3 for detals Exposure to component sdlvent vapour concentrations in excess ofthe stated occupational exposure Imit may result in adverse health effects such as mucous membrane and respiratory system irtation and adverse effects on the kidneys, Iver and central nervous system. Symptoms and signs indlude headache, dizziness, fatigue, muscdar weakness, drowsiness and, in extreme cases, loss of consciousness, Solvents may cause some of the above effects by asorption through the skin. If splashed inthe eyes, the liquid may cause irtation and reversidle damage. Repeated or prolonged contact with the mixture may cause removal of natural fal from the skin, resuking in nor» allergic contact dermatits and absorption through the skin. This takes into account, where known, delayed ard immediate effects and also enronic effects of components from short-term and long-term exposure by oral, innaation ‘and dermal routes of exposure and eye contact, Based on the properties ofthe isocyanate components and considering toxicological data on similar mixtures, this mixture may cause acute iritation andior sensitisation ofthe respiratory system, leading to an asthmatic condition, wheezing and tightness of the chest, Sensised persons may subsequently show asthmatic symptoms when exposed to atmospheric concentrations well below the OEL. Repeated exposure may lead to permanent respiratory disability Repeated or prolonged contact with ritants may cause dermatitis, Contains Reaction mass of Bis(1,2,2,6,6-pentamethy\-spiperidl) sebacate and Methyl 1,2.2.6,6-pentamethy- 4 piperidyl sebacate. May produce an allergic reaction. 4.3 Indication of any immediate medical attention and special treatment needed Notes to physician + Treat symptomaticaly. Contact poison treatment specialist immediately ilarge ‘quantities have been ingested or inhaled. Specific treatments + No specifi treatment. ‘See toxicdlogical information (Section 11) SECTION 5: Firefighting measures 5:1 Extinguishing media Suitable extinguishing Recommended: alcohol resistant foam, carbon dioxide, povelers media Unsuitable extinguishing: Do not use waterjet. media Bt eae aT ran PE Wi POT ‘Date of previous sie Sap TOT Vernon TE aSonforms to Regulation (EC) No. 1907/2006 (REACH), Annex Il SCROLON C137V2 Acne Urethane Finish Base SECTION 5: Firefighting measures 5.2 Special hazards arising from the substance or mixture Hazards from the Fire will produce dense black smoke. Exposure to decomposition products may ‘substance or mixture cause a health hazard Hazardous combustion: Decomposition products may include the following materials: carbon monoxide, products carbon dioxide, smoke, oxides of nitrogen, hyerogen cyanide, monomeric isocyanates. 5.3 Advice for firefighters ‘Special protective actions; Cool closed containers exposed to fire with water. Do not release runoff from fie to for fire-fighters drains or watercourses. Special protective Firesighters should wear postive pressure self-contained breathing apparatus equipment forfire-fighters (SCBA) and full turnout gear. SECTION 6: Accidental release measures 6:1 Personal precautions, protective equipment and emergency procedures For non-emergency Exclude sources of ignition and ventilate the area, Avoid breathing vapour or mist personnel Refer to protective measureslisted in sections 7 and 8. Keep unnecessary and unprotected personnel from entering For emergency responders : I specialised clothing is required to deal wth the spllage, take note of any information in Section 8 on suitable and unsultable materials. See also the information in "For non-emergency personnel’. 6.2 Environmental Do not allow to enter drains or watercourses. If the product contaminates lakes, precautions rivers, or sewers, inform the appropriate authors in accordance with local regulations. 6.3 Methods and material = Contain and collect spilage with non-combustible, absorbent material e.9. sand, for containment and earth, vermiculite or diatomaceous earth and place in cantainer fr disposal ‘leaning up accotding to local regulations (see Section 13). Place in a suitable container, The Contaminated area should be deaned immediately with a suitable decontaminant. ‘One possible (lammable) decontaminant comprises (by vohime). water (45 parts, ethanol or isopropyl alcohol (50 parts) and concentrated (d: 0,880) ammonia solution (5 parts). A non-flammable alternative is sodium carbonate (5 parts) and water (95 parts). Add the same decontaminant to the remnants and let stand for several days until no further reaction in an unsealed container, Once this stage Is reached, close container and dispose of according to local regulations (see section 13), 6.4 Reference to other ‘See Section 1 for emergency contact information. sections ‘See Section 8 for information on appropriate personal protective equipment See Section 13 for additional waste treatment information SECTION 7: Handling and storage The information inthis seation contains generic advice and guidance. The Ist of Identified Uses in Section 1 should be ‘consulted for any avalable use-specifc information provided in the Exposure Scenario(). Persons with a history of asthma, allergies or chronic or recurrent respiratory disease should net be employed in any process in which this product is used. Examination of lung function should be carried out on a regular basis on persons spraying this mixture,Sonforms to Regulation (EC) No. 1907/2006 (REACH), Annex I SCROLON C137V2 Aen Urethane Finish - Sane SECTION 7: Handling and storage 771 Precautions Tor safe Prevent the creation of flammable or explosive conentalione of vapour in air and handling avoid vapour concentrations higher than the occupational exposure limits In ation, the product should only be used in areas from which all nakedlights and. other sources of ignition have been excluded. Electrical equipment should be Protected to the appropriate standard, Mirture may charge electrostatically: alvays use earthing leads when transferring {rom one container to another. Operators should wear antistatic footwear and clothing and floors should be of the conducting type. Care should be taken when re-opening partlyised containers, Precautions should be taken to minimise exposure to atmospheric humility or water. COz willbe formed, wich, in closed containers, could result in pressurisation. Keep away from heat, sparks and flame. No sparking tools should be used Avoid contact with skin and eyes. Avoid the inhalation of dust, particulate, spray or mist arising from the application of this mixture. Avoid inhalation of dust from sanding Eating, drinking and smoking should be prohibited in areas where this materi is handled, stored and processed. Put on appropriate personal protective equioment (see Section 8) Never use pressure to emply, Container is not a pressure vessel ‘Always keep in containers made from the same material as the original one, Comply witn the heath and safety at work laws. Do not alow to enter drains or watercourses, Information on fire and explosion protection \Vapours are heavier than air and may spread along floors. Vapaurs may form explosive mixtures with ait. When operators, whether spraying or nat, have to work inside the spray booth, ventilation is unlikely o be sufficient to control particulates and solvent vapour in all cases. In such citcumstances they should wear a compressed ai-fed respirator during the spraying process and untl such time as the parliculates and solvent ‘vapour concentration has fallen below the exposure limits. 7.2 Conditions forsafe _: Store in accordance wi local regulations, storage, including any Notes on joint storage incompatibilities Keep away from: oxidising agents, strong alkalis, strong acids. ‘Additional information on storage conditions Observe labd precautions. Store in a dry, cocl and well-ventilated area. Keep away ‘rom heat and direct sunlight Keep container tightly closed. Keep away from sources of ignition. No smoking. Prevent unauthorised access. Containers that have been opened must be carefully resealed and kept upright to preventleakage. Contaminated absorbent materi may pose the same hazard as the spi product Store in closed original container at temperatures between §°C and 25°C. 7.3 Specitic end use(s) Recommendations + Not avalable. Industrial sector specific + Not availabe, ‘solutions Good housekeeping standards, regular safe removal af waste materials and regular maintenance of spray booth ‘iters will minimise the sks of spontaneous combustion and other fire hazards. Before use of this material please refer to the Exposure Scenario(s) if attached for the specific end use, control measures and additional PPE considerations. Bats ecm a Orava EW FORT ‘Date of previous ste Sap TOT Vorrion TE aSonforms to Regulation (EC) No. 1907/2006 (REACH), Annex SCROLON C137V2 Aen Urethane Finish - Sane SECTION 8: Exposure controls/personal protection ‘The information in his section contains generic advice and guidance. The Ist of Identified Uses in Section 1 should be cconsuiked for any avalable use-specific information provided in the Exposure Scenario(). 8.1 Control parameters Occupational exposure limits Productiingredient namo Exposure limit valu Xylene, mixed isomers [E}40/2005 WELs (United Kingdom (UK), 1/2020). Absorbed “Y {through skin. STEL: 441 mgim? 15 minutes. TWA: 50 ppm 8 hours. ‘TWA. 220 mgli 8 hours. STEL: 100 ppm 15 minutes. Ethybbenzene [EH40/2008 WELs (United Kingdom (UK), 1/2020). Absorbed {through skin. STEL: 552 mgim? 15 minutes. STEL: 125 ppm 15 minutes, ‘TWA: 100 ppm 8 hours, TWA. 441 mgim* 8 hours, Recommended monitoring: If this product contains ingredients with exposure limits, personal, workplace procedures atmosphere or biological monitoring may be required to determine the effectiveness ofthe ventlation or other contrdl measures anlor the necessity to use respiratory Protective equipment. Reference should be made to monitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres - Guidance for the assessment of exposure by inhalation to chemical agents for comparison with limit values and measurement strategy) European Standard EN 14042 (Workolace atmospheres - Guide forthe application and use of procedures forthe assessment of expasure to chemical and biclogical agents) European Standard EN 482 (Workplace atmospheres » General requirements fr the performance of procedures {or the measurement of chemical agents) Reference to national guidance documents for methods for the determination of hazardous substances wil also be required, + Regular monitoring ofall work areas should be carried out at al times, including areas that may not be equally ventilated. DNELS/DMELs Productiingredient name | Type | Exposure | Value | Population Effects Xone, mixed isomers (ONEL [ong term Dermal [760 moikg Workers [Systemic lbwiday NEL [ong term Dermal |108 mg/kg |General [systemic lbwiday [population [Human via the lenvironment] NEL Long term I77 mgim* |Workers [systemic nhalation NEL. Bhar term L269 mgim* |Workers systemic nation NEL Bhor term [288 mgim* |Workers Local nalation NEL. bong term 14,8 mgim* |General systemic rnalation [population [Human via the lenvironment] NEL. hort term 174 mgim* |General systemic nalation [population [Consumers] NEL Bhort term 174 mgim* |General Local nvalation population ia eee a Orato ET FOET ‘Date of previous sae —30 Sap TOT Version TETSonforms to Regulation (EC) No. 1907/2006 (REACH), Annex I SCROLON C137V2 Aen Urethane Finish - Sane SECTION 8: Exposure controls/personal protection [eonsumersy Ethyl 2-Gthoxypropionate DNEL Long term Dermal |102 mglm* |Workers systemic NEL Long term [610 mgim* |Workers [Systemic nnalation NEL Long term Dermal |102 mglm* |Workers Local NEL. Long term [510 mgim* |Workers Local nalation NEL Long term Dermal [24.2 mglm* |General systemic [population [Consumers] NEL Lang term 172.6 mgim? |General systemic rnalation [population {Consumers} NEL Longterm Ord [1.2 maim? |General systemic [population [Consumers] NEL Long term Dermal [24,2 mgim* |General Local ipopulation [Consumers} Hydrocarbons, C9, aromatics NEL Long term Dermal [25 mgikg [Workers [systemic lbwiday NEL. Long term 150 mgfm* |Workers systemic nalation NEL Long term Dermal [11 mgikg |General systemic lbwicay "population {Consumers} NEL. Long term [32 mgim* |General systemic rnaation population {Consumers} NEL Longterm Ord — [11 mgikg |General [systemic lbwiday "population [Consumers] Reaction mass of Bis NEL Bhort term Dermal [2.5 mg/kg |Workers [systemic (1.22,6,6-pentamethyl-+-piperdy!) /sebacate and Methyl 1.2.2.6 epentamethy4-piperiay sebacate NEL hort term 12.8 mgim |Workers systemic rnalation NEL. Long term 13.53 mgim? |Werkers [systemic nalation NEL Long term Dermal [2 mghkg —_|Workers systemic DNEL Bhor term Dermal [1.25 mglkg |General [Systemic [population Consumers} NEL. Bhort term 0.58 maim? |General systemic nalation [population [consumers} DNEL Bhortterm Oral [1.25 mglkg |General systemic [Population [Consumers] NEL Long term Dermal |t mg/kg |General systemic [population {Consumers} NEL. Long term 0.87 maim? |General systemic nalation [population [Consumers] NEL Longterm Ord [0.5 mgikg |General systemic ipopulation {Consumers} Bs ecm a Orato ET FORT ‘Date of previous sia 30 Sap TOT Vorrion TESonforms to Regulation (EC) No. 1907/2006 (REACH), Annex I SCROLON C137V2 Aen Urethane Finish - Sane SECTION 8: Exposure controls/personal protection PRECS Productingredient name ‘Compartment Detail Value Method Detail Xylene, mixed isomers Fresh water 327 mall - Marine water 327 mall Fresh water sediment [12.46 mail Sewage Treatment. .58 mgi Plant lsoa 31 marks L Marine water sediment [12.48 mai hy! -Ethoxypropionate Fresh water 608mg | Marine water 3.00809 mg | Sewage Treatment 6 mgf Plant Marine water sediment po4iamgt |. Sot 3.048 mal - Fresh water sediment pata mg/kg dwt [+ Reaction mass of Bis(1,2.2.6.6-pentamethyl |Fresh water 9.0022 magi ‘4 piperidy) sebacate and Metiyt 1.2.2.6, E-pentamethyepipercyl sebacste Marine water 9.00022 mall Fresh water sediment [1.05 mglkg Marine water seciment P.11 makkg - Sot 21 marks L Sewage Treatment ‘magi LC Plant 8.2 Exposure controls Persons with a history of asthma, allergies, chronic or recurrent respiratory disease should not be exposed to any process in which this product is used, Examination of lung function should be carried out on a regular basis on persons spraying this mixture. Appropriate engineering + Provide adequate ventilation, Where reasonably practicable, this should be controls achieved by the use of local exhaust ventilation and good general extraction, Aisfed Protective respiratory equipment must be woe by the spray operator. even when {00d ventilation is provided. In other operations, iflocal exhaust ventilation and good general extraction are not sufficient to maintain concentrations of particulates land solvent vapours below the OEL, suitable respiratory protection must be worn, (Gee Occupational exposure contrls.) + Users are advised to consider national Occupational Exposure Limits or other equivalent values. Individual protection measures Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and atthe end of the warking periog, Appropriate techniques should be used to remove potentially contaminated clothing ‘Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location Eyeltace protection Use safety eyewear designed to protect against splash of liquids. ‘Skin protection Hand protection Wear suitable gloves tested to ENS74, Gloves Gloves for short term exposure/splash protection (less than 10 min): Nile >0,35 Gloves for splash protection need to be changed immediately when in contact with chemicals For long term exposure or spills (breakthrough time >480 min): Use PE: laminate gloves as under gloves. Due to many conettons (e.g. temperature, abrasion) the practical usage of a chemical protective glove in practice may be much shorter than the permeation timeSonforms to Regulation (EC) No. 1907/2006 (REACH), Annex Il SCROLON C137V2 Aen Urethane Finish Base SECTION 8: Exposure controls/personal protection dalarmined trough Tesing: There is no one glove material or combination of materials that will give unlimited resistance to any individual or combination of chemicals. “The breakthrough time must be greater than the end use time of the product, The instructions and information provided by the glove manufacturer on use, storage, maintenance and replacement must be fellowes. Gloves should be replaced regulary and if there is any sign of damage to the dove material. ‘Always ensure that gloves are free from defects and that they are stored and used correctly. “The performance or effectiveness of the dove may be reduced by physicalichemical damage and poor maintenance. Barter creams may help to protect the exposed areas of the skin but should not be applied once exposure has occurred. The user must check that the final choice of type of glove selected for handling this, product is the most appropriate and takes into account the particular conditions of Use, as included in the user's risk assessment Body protection Personnel should wear antistatic dothing made of natural fibres or of high temperature-resistant synthetic fibres, Personal protective equipment for the body should be selected based on the task being performed and the sks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from state electricity, ‘wear ant-staic protective dothing. For the greatest protection from static discharges, clothing should indude ant-atatic overalls, boots and gloves, Refer to European Standard EN 1149 for futher information on material and design Fequirements and test methods, Other skin protection Appropriate footwear and any adeitional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product Respiratory protection: Use a propery fited, ai-puriying or ai-fed respirator complying with an approved standard ifa risk assessment indicates this is necessary, Respirator selection must be based on known or anticipated exposure levels. the hazares ofthe product and the safe working limits ofthe selected respirator. Environmental exposure: Do not allow to enter drains or watercourses, controls Before use of this material please refer to the Exposure Scenario(s) i attached for the specific end use, control measures and additional PPE considerations, The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risks, as required by other health and safety legislation. The provisions of the national health and safety at work regulations apply to the use of this product at work. SECTION 9: Physical and chemical properties The conditions of measurement of al properties are at standard temperature and pressure unless otherwise indicated, 9.1 Information on basic physical and chemical properties ‘Appearance Physical state gui. Colour White. Odour Paint Odour threshold Not available pH Not applicable. Melting pointtreezing point Not relevantlappcable due to nature ofthe product. Initial boiling point and 136°C boiling range Flash point (Closed cup: 30°C [Pensky-Martens Closed Cup]Sonforms to Regulation (EC) No. 1907/2006 (REACH), Annex Il SCROLON C137V2 Aen Urethane Finish =-Base SECTION 9: Physical and chemical properties Evaporation rate OB (puifacctate =) Flammability (sol, gas) Notretevantiappicable due to nature ofthe produc. Upperiower flammability or: LEL:0.7% (Uight Aromatic Hydrocarbons) explosive limits UEL: 12.1% tn 3-thoxypropionate) Vapour pressure 0.95 kPa (7-1 mm Hg) Vapour density 3.66 (r= 1] Relative density 14a Solubley(es) Not relevantiappicable due to nature ofthe product. Parton coefficient: n-octanol : Not elevanvapplcable due to nature ofthe product, water ‘Autocignition temperature Not retevantiappicabe due to nature ofthe produc. Decomposition temperature Not relevanvappleabe du to nature ofthe product, Viscosity Kinematic (40°C): <20.5 mms Explosive properties Under normal conditions of storage and use, hazardous reactions wil net occur Oxidising properties Under normal conditions of storage and use, hazardous reactions wil ot occur. [SECTION 10: Stability and reactivity 10.4 Reactivity, The product reacts slowly with water, esuling in the production of carbon dioxide. 10.2 Chemical stability Stable under recommended storage and handling conditions (see Section 7). 10.3 Possibility of In closed containers, pressure bullkup could result in distortion, expansion and, in hazardous reactions extreme cases, bursting of the container 10.4 Conditions to avoid _: Ina fre, hazardous decomposition products may be produced. 10.5 Incompatible materials: Keep away from: oxidsing agents, strong alka, strong acids, amines, alcohdls, ‘water, Uncontrolled exothermic reactions occur with amines and alcohols, 10.6 Hazardous Decomposition products may include the fllowing materials: carbon monoxide, decomposition products carbon dioxide, smoke, oxiges of nitrogen, hydrogen cyanide, monomeric isocyanates. Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL. PROTECTION for additional handling information and protection of employees. SECTION 11: Toxicological information 11.4 Information on toxicological effects “There are no data avalable on the mixture itself. Procedure used to derve the classification according to Regulation (EC) No, 1272/2008 [CLPIGHS}, See Sections 2 and 3 for details Exposure to component sdlvent vapour concentrations in excess of the stated occupational exposure Imit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, Iver and central nervous system, Symptoms and signs Include headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, loss of consciousness, Solvents may cause some of the above effects by aosorption through the skin If splashed inthe eyes, the liquid may cause ination and reversible damage. Repeated or prolonged contact with the mixture may cause remaval of natural fat from the skin, resuking in nor» allergic contact dermatits and absorption through the skin. This takes into account, where known, delayed and immediate effects and also envonic effects of components from short-term and lang-term exposure by oral, innaation ‘and dermal routes of exposure and eye contact‘onforms to Regulation (EC) No. 1907/2006 (REACH), Annex I \CROLON C17¥2 Aen Urethane FishBase SECTION 11: Toxicological information Based onthe proparies afte ocyanate companenis and considarng Toxicological data on Sar ntures Ns mixture may cause acute iritaon andor senatsation ofthe resplretory system, leacng a an asthmatic conlion, Wwineezing and tghtness of the chest. Sensised persons may subsequently show asthmatic symptoms when exposed {o atmospheric concertvatons wal below the OEL. Repeated exposure may lead to permanent respratory dsabiiy Repeated or prolonged contact wth irtanis may cause dermal, Contains Reaction mass of Bis(1,2.2.6,6-pentamethy-tpipei) sebacate and Methyl 12.28 &pentamathyi- ‘piperal sebacste, May produce an allergic reaction ‘Acute tonicity Productingredient name Reside Species Dose Exposure Xyfene, mixed isomers |LOSO lahalaion Ga Rat @700 ppm | Ahours 080 Oral Rat 300mg |= Ethyl3-Ethoxypropionate | LD50 Oral Rat s200mgrkg |= Hydrocarbons, C3 L050 Oral Rat e400 mang | = aromatics Ethyenzene L080 Derma Rabbit >s000mgkg | = L080 Oral Rat 3500 maixg) | = 2-Etny-2eydroxymethy) | LDE0 Oral Rat 14000 maka | = 1 3-propanectol ‘Acute toxicity estimates Route ATE value Dermal waramans Inhalation (gases) 50843.23 ppm Inhalation (vapours) 472.24 moh Inntation/Gorresion| Productingredient name Result Species | Score | Exposure | Observation ‘Xylene, mixed isomers Eyes - Mild initant Rabbit = [a7mg = qj Eyes = Severe imtant Ravot [> feanoues | Ima ‘Skin = Mie tant Rat = |Brours 60 ut | Skin - Moderate itant ravot —|> faa hours 500 |- Ima ‘Skin - Moderate irtant a Ethyl3-Ethorypropionate | Skin= Mi tant Ravbt —|> faa hours 00 |- Ima Hydrocarbons, 08, Eyes «Mid intant Ravot —|- —_f24nours 100 |- aromatics Imicroiters Ethybenzene Eyes - Severe irtant rast |- — ffo0me | Skin = Mid irtant, Ravbt |= faarours 18. |= Ima Conciusion/Summary Not avalste, Sensitisation No data avalable Conclusion/Summary +: Notavalable Mutagenicity No data avataole ‘Sarcinonenicity No data avatadle ‘Reproductive toxicity No data avalable “aratoganicity