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Principles of General Chemistry 3rd Edition Silberberg Test Bank 1
Principles of General Chemistry 3rd Edition Silberberg Test Bank 1
2. Hydrogen gas exerts a pressure of 466 torr in a container. What is this pressure in
atmospheres?
A) 0.217 atm B) 0.466 atm C) 0.613 atm D) 1.63 atm E) 4.60 atm
Ans: C
3. The pressure of hydrogen sulfide gas in a container is 35,650 Pa. What is this pressure in
torr?
A) 46.91 torr B) 267.4 torr C) 351.8 torr D) 3612 torr E) 27,090 torr
Ans: B
4. The pressure of sulfur dioxide in a container is 159 kPa. What is this pressure in
atmospheres?
A) 0.209 atm B) 0.637 atm C) 1.57 atm D) 21.2 atm E) 15,900 atm
Ans: C
Page 52
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Chapter 5 Gases and the Kinetic-Molecular Theory
6. "The volume of an ideal gas is directly proportional to the number of moles of the gas at
constant temperature and pressure" is a statement of _____________ Law.
A) Charles' B) Boyle's C) Amontons' D) Avogadro's E) Dalton's
Ans: D
9. "The total pressure in a mixture of unreacting gases is equal to the sum of the partial
pressures of the individual gases" is a statement of __________________ Law.
A) Charles' B) Graham's C) Boyle's D) Avogadro's E) Dalton's
Ans: E
10. “The rate of effusion of a gas is inversely proportional to the square root of its molar
mass” is a statement of _________________ Law.
A) Charles' B) Graham's C) Dalton's D) Avogadro's E) Boyle's
Ans: B
11. Which of the lines on the figure below is the best representation of the relationship
between the volume of a gas and its pressure, other factors remaining constant?
A) a B) b C) c D) d E) e
Ans: E
Page 53
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manner. This document may not be copied, scanned, duplicated, forwarded, distributed, or posted on a website, in whole or part.
Chapter 5 Gases and the Kinetic-Molecular Theory
12. Which of the lines on the figure below is the best representation of the relationship
between the volume of a gas and its absolute temperature, other factors remaining
constant?
A) a B) b C) c D) d E) e
Ans: C
13. Which of the lines on the figure below is the best representation of the relationship
between the volume of a gas and its Celsius temperature, other factors remaining
constant?
A) a B) b C) c D) d E) e
Ans: B
Page 54
© 2013 by McGraw-Hill Education. This is proprietary material solely for authorized instructor use. Not authorized for sale or distribution in any
manner. This document may not be copied, scanned, duplicated, forwarded, distributed, or posted on a website, in whole or part.
Chapter 5 Gases and the Kinetic-Molecular Theory
14. Which of the lines on the figure below is the best representation of the relationship
between the volume and the number of moles of a gas, measured at constant temperature
and pressure?
A) a B) b C) c D) d E) e
Ans: C
15. A sample of an ideal gas has its volume doubled while its temperature remains constant.
If the original pressure was 100 torr, what is the new pressure?
A) 10 torr B) 50 torr C) 100 torr D) 200 torr E) 1000 torr
Ans: B
16. A sample of the inert gas krypton has its pressure tripled while its temperature remained
constant. If the original volume is 12 L, what is the final volume?
A) 4.0 L B) 6.0 L C) 9 L D) 36 L E) 48 L
Ans: A
17. A sample of nitrogen gas at 298 K and 745 torr has a volume of 37.42 L. What volume
will it occupy if the pressure is increased to 894 torr at constant temperature?
A) 22.3 L B) 31.2 L C) 44.9 L D) 112 L E) 380 L
Ans: B
18. A sample of carbon dioxide gas at 125°C and 248 torr occupies a volume of 275 L. What
will the gas pressure be if the volume is increased to 321 L at 125°C?
A) 212 torr B) 289 torr C) 356 torr D) 441 torr E) 359 torr
Ans: A
19. A sample of oxygen gas has its absolute temperature halved while the pressure of the gas
remained constant. If the initial volume is 400 mL, what is the final volume?
A) 20 mL B) 133 mL C) 200 mL D) 400 mL E) 800 mL
Ans: C
Page 55
© 2013 by McGraw-Hill Education. This is proprietary material solely for authorized instructor use. Not authorized for sale or distribution in any
manner. This document may not be copied, scanned, duplicated, forwarded, distributed, or posted on a website, in whole or part.
Chapter 5 Gases and the Kinetic-Molecular Theory
21. A 0.850-mole sample of nitrous oxide, a gas used as an anesthetic by dentists, has a
volume of 20.46 L at 123°C and 1.35 atm. What would be its volume at 468°C and 1.35
atm?
A) 5.38 L B) 10.9 L C) 19.0 L D) 38.3 L E) 77.9 L
Ans: D
22. A sample of ammonia gas at 65.5°C and 524 torr has a volume of 15.31 L. What is its
volume when the temperature is -15.8°C and its pressure is 524 torr?
A) 3.69 L
B) 11.6 L
C) 20.2 L
D) 63.5 L
E) It is not possible, since the volume would have to be negative.
Ans: B
23. A 500-mL sample of argon at 800 torr has its absolute temperature quadrupled. If the
volume remains unchanged, what is the new pressure?
A) 200 torr B) 400 torr C) 800 torr D) 2400 torr E) 3200 torr
Ans: E
24. A 750-mL sample of hydrogen exerts a pressure of 822 torr at 325 K. What pressure does
it exert if the temperature is raised to 475 K at constant volume?
A) 188 torr D) 1.20 103 torr
B) 562 torr E) 1.90 103 torr
C) 1.11 10 torr 3
Ans: D
25. A sample of methane gas, CH4(g), occupies a volume of 60.3 L at a pressure of 469 torr
and a temperature of 29.3°C. What would be its temperature at a pressure of 243 torr and
volume of 60.3 L?
A) -116.5°C B) 15.2°C C) 15.5°C D) 57.7°C E) 310.6°C
Ans: A
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Author: Anonymous
Language: English
NUMBER 135
CONTENTS
Precision Locating Methods 3
Accurate Dividing and Spacing Methods 21
Locating Work for Boring on Milling Machine 32
No. 31—T T G
No. 64—G M L
No. 107—D F D S
No. 130—G T M
M
The Leading
Mechanical Journal
M D
C
S P
Disk-and-Button Method of
Locating Holes
Two other jobs that illustrate this method may be of interest. The first
one, shown in Fig. 11, required the locating of nine equally-spaced holes
on a circumference of 7⅜ inches diameter. In any such case, the size of
the smaller disks is found by multiplying the diameter of the circle upon
which the centers of the disks are located by the sine of half the angle
between two adjacent disks. The angle between the centers of adjacent
disks equals 360 ÷ number of disks. 360 ÷ 9 = 40; hence, in this case, the
diameter of the smaller disks equals 7⅜ multiplied by the sine of 20
degrees, or 7⅜ × 0.34202 = 2.5224 inches. 7⅜-2.5224 = 4.8526 inches,
which is the diameter of the central disk.
The templet shown in Fig. 12 required two holes on a circumference
6½ inches diameter, with their centers 37 degrees 20 minutes apart. To
find the diameter of the smaller disks, multiply the diameter of the large
circle by the sine of one-half the required angle, as in the preceding
example; thus 6½ × sin 18 degrees 40 minutes = 2.0804 inches, which is
the diameter of the two smaller disks. The diameter of the larger disk
equals 6½-2.0804 = 4.4196 inches.
Very accurate results can be obtained by the disk-and-button method.
Of course, absolute exactness is equally unattainable with buttons and a
micrometer, or any other method; the micrometer does not show the
slight inaccuracy in any one chordal measurement, while in using the
disks the error is accumulative and the insertion of the last disk in the
series shows the sum of the errors in all the disks. It is only in cases like
the one illustrated in Fig. 9 that we note this, and then, though in
correcting the error, we may change the diameter of the circle a very
slight amount, an exceedingly accurate division of the circumference is
secured.
Use of Two- and Three-Diameter Disks
Fig. 13 illustrates, on an enlarged scale, a piece of work requiring
great accuracy, which was successfully handled by an extension of the
three-disk method. Fourteen holes were required in a space hardly larger
than a silver half-dollar, and, although the drawing gave dimensions
from the center of the circle, the actual center could not be used in doing
the work, as there was to be no hole there; moreover, a boss slightly off
center prevented the use of a central disk, unless the bottom of the disk
were bored out to receive this boss, which was not thought expedient.
Hence, the method adopted was to make the plate thicker than the
dimension given on the drawing, and then bore it out to leave a rim of
definite diameter, this rim to be removed after it had served its purpose
as a locating limit for the disks.
Fig. 10. (A) Layout of Jig-Plate.
(B) Disk-and-Button Method of Locating Holes
As the holes A and B, which were finished first, were 0.600 inch
apart and 0.625 inch from the center, the rim was bored to 1.850 inch and
two 0.600-inch disks, in contact with the rim and with each other, located
these holes. As hole C was to be equi-distant from holes A and B, and its
distance from the center was given, the size of the disk for this hole was
readily determined. The disks for holes A, B and C have two diameters;
the upper diameters are made to whatever size is required for locating the
disks of adjacent holes, and they also form a hub which can be used
when setting the disks with an indicator. Hole D was 0.4219 inch from B,
and calculations based on this dimension and its distance from the center
showed that it was 0.4375 inch from hole C.
A “three-story” disk or button was made for hole D. The diameter of
the large part was 0.46875 inch and it overlapped disks C and B (the
upper sections of which were made 0.375 inch and 0.4062 inch,
respectively), thus locating D. Then hole F and all the remaining holes
were located in a similar manner. The upper diameters of disks E and D
were used in locating disks for other adjacent holes, as well as a hub for
the indicator; for instance, to locate a hole with reference to holes C and
D, the diameter of the new disk and the diameter of the upper part of disk
D, were varied to give the required location. The relation between the
disks B, D and F is shown by the side view.
The accompanying table gives the sizes of the larger disks to the
nearest 0.0001 inch for whole degrees ranging from 5 to 40 degrees
inclusive. Incidentally, the usefulness of these disks can be increased by
stamping on each one its diameter and also the angle which it subtends
when placed in contact with the standard 1-inch disk.