Sr.

FOCUS REVISION CHEMISTRY ASSIGNMENT DAY-27

TOPIC: GOC Date: 26-12-2022
ELECTROPHILES AND NUCLEOPHILES
1. Which of the following is not a nucleophile ?
A) H2O B) CH3OH C) H2 D) NH3
2. Which of the following behaves both as a nucleophile and as an electrophile ?
A) CH3C  N B) CH3OH C) CH2 = CHCH3 D) CH3NH2
3. Which of the following has the highest nucleophilicity
A) F– B) OH– C) CH3– D) NH2–
4. Sulphur trioxide is
A) An electrophile B) A nucleophile C) A homolytic reagent D) A base

CARBOCATIONS
5. The numbr of electrons present in the valence shell of carbon of carbocation bearing
positive charge
A) 8 B) 7 C) 6 D) 4
6. The most stable carbocation amongst the following is (Q no 6 to 11)
 
A) CH 3  CH 2  C H 2 B) CH 3  C H  CH 2  CH 3

 
C) (CH 3 ) 3  C D) (CH 3 ) 3 C  C H 2

  
7. A) CH 3  C H 2 B) C H 2  CHCl2 C) C H 2  CH 2  Cl D)

C H 2  CH 2  NO2

CH2 CH2 CH2

CH2

8. A) B) C) D)

Cl NO2 OCH3

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 CH3
CH3 CH3 CH3

9. A) B) C) D)


10. A) CH3 B) (CH 3 CH 2 ) 2 C H


C) (CH 3 CH 2 )3 C D) CH2 CH2

 
11. A) C H 3 B) CH3 C H 2

 
C) H C2 4) C H 2 – O – CH3

CARBANIONS
12. Arrange the following carbanions in decreasing order of stability ( Q No. 12 to 16)
I II III IV

  
C H 2 – CH3 C H 2 – C(CH3)3 CH 2 C H3

A. III > IV > I > II B) III > IV > II > I C) III > I > IV > II D) IV > III > I > II

   
13. C H 2 – Cl C H 2 – CN C H 2 – NO2 C H 2 – CH3
A) III > II > IV > I B) III > II > I > IV C) III > I > II > IV D) II > III > I > IV
  


CH3 C CH C CH3 H C C H C  H OHC  C  CHO
14. C H 2 – CHO || || || || ||
O O O O O

A) IV > III > I > II B) IV > II > III > I C) IV > III > II > I D) III > IV > II > I

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 CH2 CH2 CH2
CH2

15.

CH3 NO2 OCH3

A) III > I > IV > I B) III > II > I > IV C) I > III > II > IV D) III > I > II > IV
16. Which of the following intermediate have the complete octet around the carbon atom
A) Carbonium ion B) Carbonion C) Free radical D) Carbene
FREE RADICALS
17. Arrange the radicals in their decreasing order of stability

CH 3  CH
I. CH.3

II. CH 3  CH 2 III. | IV.
CH 3

CH 3
|
CH 3  C .
|
CH 3

A) IV > I > III > II B) IV > III > II > I C) I > II > III > IV D) IV > III > I > II
18. Following is incorrect about radicals
A) They are planar in shape B) They are paramagnetic
C) They have incomplete octet
D) They are very less reactive as compared to other cations / anions
19. Most stable radical is

A) B) C) D)

KEY
1) C 2) A 3) C 4) A 5) C
6) C 7) A 8) C 9) C 10) C
11) C 12) A 13) B 14) C 15) B
16) B 17) B 18) D 19) C

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