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    This document provides the steps to calculate the density of saturated water vapor and liquid water at 20 bar using a cubic equation of state. The calculations involve determining the boiling point at 20 bar using Antoine's equation, then iterating the cubic equation to determine the compressibility factor Z for both phases. The specific volumes and densities are then calculated from Z, the temperature, and pressure. The resulting densities are 0.00053 mol/cm3 for saturated water vapor and 0.03199 mol/cm3 for saturated liquid water at 20 bar.

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    Teknik Kimia

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    This document provides the steps to calculate the density of saturated water vapor and liquid water at 20 bar using a cubic equation of state. The calculations involve determining the boiling point at 20 bar using Antoine's equation, then iterating the cubic equation to determine the compressibility factor Z for both phases. The specific volumes and densities are then calculated from Z, the temperature, and pressure. The resulting densities are 0.00053 mol/cm3 for saturated water vapor and 0.03199 mol/cm3 for saturated liquid water at 20 bar.

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    © All Rights Reserved
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    11 views3 pages

    Tugas Proses Transfer

    Uploaded by

    maruf
    This document provides the steps to calculate the density of saturated water vapor and liquid water at 20 bar using a cubic equation of state. The calculations involve determining the boiling point at 20 bar using Antoine's equation, then iterating the cubic equation to determine the compressibility factor Z for both phases. The specific volumes and densities are then calculated from Z, the temperature, and pressure. The resulting densities are 0.00053 mol/cm3 for saturated water vapor and 0.03199 mol/cm3 for saturated liquid water at 20 bar.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    of 3

    Jumat,15 September 2023 Karina Rizki Febriani

    23023047

    TK5109
    TERMODINAMIKA LANJUT - TUGAS 02

    Soal-5 Tentukan densitas air jenuh dan uap air jenuh pada 20 bar, dengan salah satu
    persamaan keadaan kubik (pangkat 3)
    1. Tentukan dahulu Titik Didih dengan persamaan Antoine.  Td = f(Psat)
    2. Ambil Pc dan Tc dari data Critical Condition.
    3. Dengan salah satu model Persamaan Kubik yang diinginkan (RK saja)
    4. Hitung nilai  =
    5. Hitung nilai q =
    6. Masukkan iterasi yang sesuai untuk mendapatkan Z (fasa gas dan fasa cair)
    7. Tentukan nilai volume spesifik dari nilai Z, V = Z.R.T/P
    8. Tentukan densitas,  = 1/V

    Jawaban :
    Psat = 20 bar = 2000 kPa
    Data dari tabel untuk air (H2O) diketahui :
    A = 16,3872
    B = 3885,70
    C = 230,170

    Persamaan Antoine
    B B
    ln Psat = A − Td = −C
    Td + C A − ln Psat

    3885,70
    Td = − 230,170 = 212,075°C
    16,3872 − ln(2000 kPA)

    Dari data critical condition untuk air (H2O) diketahui :


    Pc = 220.55 bar
    Tc = 647,1 K

    P 20 bar
    Pr = = = 0,091
    PC 220,55 bar

    T (212,075 + 273) K
    Tr = = = 0,750
    TC 647,1 K

    Gunakan model Persamaan Kubik RK sesuai tabel di bawah ini :

    1
    Jumat,15 September 2023 Karina Rizki Febriani
    23023047

    Pr 0,091
    β=Ω = 0,08664 × = 0,010512
    Tr 0,750

    Ψα(Tr ) 0,42748 × 0,75−1/2


    q= = = 7,596359
    ΩTr 0,08664 × 0,750

     Untuk fasa gas atau uap nilai Z dapat dihitung dari persamaan berikut :
    (Z − β)
    Z = 1 + β − qβ
    Z(Z + β)

    Iterasi dimulai dengan Z = 1

    Iterasi-1, isikan Z = 1 pada ruas kanan


    (Z−β) (1 − 0,010512)
    Z = 1 + β − qβ Z(Z+β) = 1 + 0,010512 − (7,596359 × 0,010512) × ( 1(1 + 0,010512) ) = 0,932320

    Iterasi-2, isikan Z = 0,932320 pada ruas kanan


    (Z−β) (0,93232 − 0,010512)
    Z = 1 + β − qβ Z(Z+β) = 1 + 0,010512 − (7,596359 × 0,010512) × ( 0,93232(0,93232 + 0,010512) ) =0,926772

    Iterasi-3, isikan Z = 0,926772 pada ruas kanan


    (Z−β) (0,926772 − 0,010512)
    Z = 1 + β − qβ = 1 + 0,010512 − (7,596359 × 0,010512) × ( ) = 0,926282
    Z(Z+β) 0,926772 (0,926772 + 0,010512)

    Iterasi-4, isikan Z = 0,926282 pada ruas kanan


    (Z−β) (0,926282 − 0,010512)
    Z = 1 + β − qβ = 1 + 0,010512 − (7,596359 × 0,010512) × ( 0,926282 (0,926282 + 0,010512) ) = 0,926239
    Z(Z+β)

    Iterasi-5, isikan Z = 0,926239 pada ruas kanan


    (Z−β) (0,926239 − 0,010512)
    Z = 1 + β − qβ = 1 + 0,010512 − (7,596359 × 0,010512) × ( 0,926239 (0,926239 + 0,010512) ) = 0,926235
    Z(Z+β)

    Iterasi menghasilkan nilai Zuap air = 0,926239

     Penentuan nilai Z fasa cairan jenuh dengan persamaan berikut :


    (1 + β − Z)
    Z = β + (Z + ϵβ)(Z + σβ)
    qβ

    Iterasi dimulai dengan Z = β = 0,010512

    Iterasi-1, isikan Z = 0,010512 pada ruas kanan


    (1+0,010512−1)
    Z = 0,010512 + (1 + 0 × 0,010512)(1 + 1 × 0,010512) = 0,013280
    7,596359×0,010512

    Iterasi-2, isikan Z = 0,013280 pada ruas kanan


    (1+0,010512−0,013280)
    Z = 0,010512 + (0,013280 + 0 × 0,010512)(0,013280 + 1 × 0,010512) = 0,014458
    7,596359×0,010512

    2
    Jumat,15 September 2023 Karina Rizki Febriani
    23023047

    Iterasi-3, isikan Z = 0,014458 pada ruas kanan


    (1+0,010512−0,014458)
    Z = 0,010512 + (0,014458 + 0 × 0,010512)(0,014458 + 1 × 0,010512) 7,596359×0,010512
    = 0,015015

    Iterasi-4, isikan Z = 0,015015 pada ruas kanan


    (1+0,010512−0,015015)
    Z = 0,010512 + (0,015015 + 0 × 0,010512)(0,015015 + 1 × 0,010512) = 0,015290
    7,596359×0,010512

    Iterasi-5, isikan Z = 0,015290 pada ruas kanan


    (1+0,010512−0,015290)
    Z = 0,010512 + (0,015290 + 0 × 0,010512)(0,015290 + 1 × 0,010512) = 0,015429
    7,596359×0,010512

    Iterasi-6, isikan Z = 0,015429 pada ruas kanan


    (1+0,010512−0,015429)
    Z = 0,010512 + (0,015429 + 0 × 0,010512)(0,015429 + 1 × 0,010512) = 0,015500
    7,596359×0,010512

    Iterasi-7, isikan Z = 0,015500 pada ruas kanan


    (1+0,010512−0,015500)
    Z = 0,010512 + (0,015500 + 0 × 0,010512)(0,015500 + 1 × 0,010512) = 0,015536
    7,596359×0,010512

    Iterasi menghasilkan nilai Zair = 0,015500

     Tentukan nilai volume spesifik dari nilai Z, V = Z.R.T/P

    cm3 . bar
    Zuap air R T 0,926239 × 83,14472 mol. K × (212,075 + 273) K
    Vuap air = = = 1.867,827 cm3 /mol
    P 20 bar

    cm3 . bar
    Zair R T 0,015500 × 83,14472 mol. K × (212,075 + 273) K
    Vair = = = 31,257 cm3 /mol
    P 20 bar

     Tentukan densitas,  = 1/V

    1 1
    uap air = = = 0,00053 mol/cm3
    V 1.867,827 cm3 /mol

    1 1
    air = = = 0,03199 mol/cm3
    V 31,257 cm3 /mol

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