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Solution Manual For Fundamentals of Chemical Engineering Thermodynamics 1st Edition by Dahm ISBN 1111580707 9781111580704
Solution Manual For Fundamentals of Chemical Engineering Thermodynamics 1st Edition by Dahm ISBN 1111580707 9781111580704
Solution:
A)
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| |
Cancelling terms
185
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Find ̂
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At 40°C:
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q = 0.716
186
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Chapter 5: Thermodynamic Processes and Cycles
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Cancelling terms
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Find enthalpies of the inlet and outlet stream using the steam tables
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187
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Chapter 5: Thermodynamic Processes and Cycles
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B) Now given a turbine efficiency of 0.75. We calculated this entire problem based on
the assumption that the turbine was reversible, in other words, an efficiency of 1. The
boiler and pump conditions are unaffected by this change. The lower turbine efficiency
means less work is removed in the turbine and more heat is subsequently removed in the
condenser.
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188
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Chapter 5: Thermodynamic Processes and Cycles
Cancelling terms
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C)
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5-7) A refrigerator runs on the vapor-compression cycle. The boiler operates at T=265 K
and the condenser operates at 305 K. The compressor has an efficiency of 85%.
Thermodynamic data for two different refrigerants is located in Appendix F.
A) What is the maximum attainable coefficient of performance for Freon 22?
B) What is the maximum attainable coefficient of performance for refrigerant R-
422A?
C) Besides coefficient of performance, two considerations in choosing a
refrigerant are price and safety. Do a little research on Freon 22 and R-422A and
comment on their suitability as refrigerants.
Solution
A) Set an entropy balance on the reversible compressor
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Cancelling terms
̂̂
The condenser operates at 305 K, or 32°C. From the figure, the vapor pressure
corresponding to this temperature is ~13 bar.
189
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CHAPTER XXI.
THE GAIKA AND GEALEKA WAR.—COLONEL
WARREN AND “OUR BOYS.”—WARREN’S
BRILLIANT COUP.—THE RAPE OF THE GAIKA
MATRONS.—SIGNAL VICTORY AT DEBE NEK.—
COLONEL LANYON AND GASIBONE.—
BLOODLESS VICTORY AT PHOKWANE.—
RETURN OF VOLUNTEERS.—THE GRIQUALAND
WEST WAR.—ENGAGEMENTS AT WITTEHUIS,
LANGEBERG AND TAIKOON.—CRUEL
APPRENTICESHIP OF WOMEN AND CHILDREN.
—CLOSE OF THE GRIQUALAND WEST
REBELLION.—KORANNAS AT THE SALT PAN.—
HERMANUS LYNX AND HIS UNTIMELY DEATH.
—MR. G. BOTTOMLEY’S LIQUOR BILL.
Before touching upon what I will term our local wars, that
occurred during Major Lanyon’s term of office, I will very shortly
refer to the fourth Kafir war in which the Cape Colony was
engaged, and this I do because the contingent the Diamond Fields
sent to assist in this campaign played a far from unimportant part.
This outbreak arose from a dispute between the Gealekas and
their hereditary enemies, the Fingoes, the former looking with
envy upon the tract of country across the Kei occupied by the
latter, but which the former had at one time possessed. The war
arose from an affray at a beer drinking bout in August 1877, the
Gealekas attacking the Fingoes to revenge the murder of one of
their friends, which had been committed in a scuffle at the feast
which I have just mentioned. Directly after this, numerous
incursions began to be made by the Gealekas into Fingoland, and
old colonists could easily see that war was imminent, when in
September Kreli could not be induced to meet Sir Bartle Frere,
who at that time happened to be on the frontier.
Toward the latter end of the above-named year, the chiefs
Kreli and Sandilli massed their followings in open rebellion
against the government. Corps of volunteers were raised, and with
the regiments of regulars in the Colony were marched against the
savage hordes of the Kafir chiefs, under the control of General
Thesiger, afterward Lord Chelmsford. The turn of the year came
and no material change in the state of affairs had taken place. The
Gaikas and the Gealekas were gradually creeping toward a
fastness known as the Perie Bush. This bush is in reality a forest,
in length some thirty miles and in width varying from two to
seven, and terminating to the northwest in the Amatola
mountains, an almost impassable range, contiguous to the old
frontier town of Fort Beaufort. In consequence of the vast area to
be covered by the troops, it was impossible to prevent the natives
and their cattle in obtaining entrance into the bush.
Once there, they thought that they had an immunity from
danger, for on the top of the range a vast plateau extends, where
they might obtain luxuriant pasturage for their cattle and cool,
refreshing springs of water for themselves. It almost appeared, as
the first moon of 1878 rose upon that portion of the Colony, that
the guerilla warfare would be interminable, and a cry for help was
raised through the Colony, which reached the province of
Griqualand West. One hundred and twenty of our young bloods
volunteered for service five hundred miles away, and with that
military ardor which characterizes all colonists, they slung their
guns across their shoulders, sprang into the saddle, and were at
once ready for the toilsome, dusty, wearisome journey by road to
King William’s Town, for those were the days of no railways.
Colonel Warren, now Sir Charles Warren, the chief commissioner
of the metropolitan police, was their trusted leader. The force,
though small, was plucky and inured to hardships, just the right
stuff to fight the wily savage, whilst their commander was highly
popular with his men. It was on Jan. 10th, 1878, that this compact
band started from the Diamond Fields, and a fine sight it was
when Colonel Lanyon, the administrator, made them a parting
address at Du Toit’s Pan in the presence of at least 3,000, who had
assembled to wish “our boys” “God speed.”
Marching some forty miles a day under a “sky of molten
brass,” they arrived in King William’s Town on the 25th of the
same month. At that time the chief Sandilli was on the move, so
the Diamond Fields horse were stationed about fifty miles out of
King William’s Town in conjunction with the hapless 24th,
afterward annihilated at Isandhlwana during the now historical
Zulu campaign. Patroling the country around was their main duty
for some six weeks, during which time, although the commissariat
department was fairly well attended to, much hardship was
endured by reason of the daily rains and the inadequate tent
provision supplied by the colonial government. Strange to say,
little sickness was engendered, nor did the hardy fellows suffer
subsequently from their exposure. The rebels having in the
meantime congregated in the Perie Bush, an order was issued for
the Diamond Fields horse to repair thither.
Just at this juncture the Pondoland difficulties were drawing
to a crisis, and when the Hon. Mr. Lyttleton was deputed to go to
Kokstadt, it was thought the little force under Colonel Warren
would be ordered to escort him.
It turned out otherwise; the Diamond Fields horse was
required for action, and all the men were delighted. They had not,
they urged, come down country for escort duty, but to show their
qualities as fighting men. At all events they had not long to wait,
for after a short period of duty in the dense demesne of the Perie
Bush a brush with the enemy took place. Such was the thick and
jungle-like nature of the underwood, and such the natural
advantages of the position which the enemy had chosen, that two
officers of the corps, Captain Donovan and Lieutenant Ward, a
gallant young fellow, well known in Kimberley, were shot by the
savage horde, and there was no chance at that moment for their
comrades to avenge their death. The little force bided its time. In a
few days it was reported to Colonel Warren that a vast body of the
enemy, advancing on foot, according to Kafir custom, in
battalions, and headed by petty chiefs on horseback, were making
for the Perie Bush. This was at an outlying station known as Debe
Nek, midway between King William’s Town and Fort Beaufort,
and in sight of the fastness wherein they believed their safety
would be assured.
The Diamond Fields horse (increased at this time by colonial
recruits) was detached, but yet there were fifty-seven men of the
original corps who volunteered to go out to meet the enemy. The
latter was estimated at 1,500, or in other words the odds were
twenty-five to one against our men.
They came on, one huge phalanx, singing their war songs, and
fired with an enthusiasm peculiar to the Kafir race. Taking in the
situation at once Colonel Warren ordered his men to dismount
and secure the protection of a wide sluit running to the left of the
Fort Beaufort road. Telling off three or four to hold the horses, and
holding fully a dozen himself, he ordered the men to commence
firing, and many of the enemy fell, but, as the front row dropped,
on came the vast mass behind.
As our brave fellows peppered away with the skill of sharp-
shooters some seventy of the savage horde were laid low, and then
dismay seized the remainder. From the advantageous position
selected by Colonel Warren it was impossible for the enemy to
know the strength of its opponents. Consternation, as I have said,
seized the sable host, and like Sennacherib’s army they melted
away even as snow, not, however, before several of the Diamond
Fields horse got into hand-to-hand combat with them. Although
the slaughter was great on the side of the rebels, yet of the little
force under Colonel Warren only one man was wounded, who
through his own neglect afterward succumbed. The news of this
gallant defence filled the inhabitants of the Diamond Fields with
exultation. Congratulations were telegraphed down to Colonel
Warren and his men, while the friends of the brave band under
him were highly delighted. The back of the rebellion had been
virtually broken. The news spread, as news only can spread among
Kafir tribes, and Colonel Warren was looked upon by the Kafirs as
possessed of supernatural powers. It only required tact to
complete the subjugation of the rebels, and the leader was not
lacking in this quality. It had been known that the women folk of
the Kafir tribes intrenched within the Perie Bush were habitually
allowed free ingress and egress. This they made use of for the
purpose of bringing supplies from King William’s Town.
Reporting this fact to the late Sir Bartle Frere, the then
governor of the colony, Colonel Warren was advised to
communicate with General Thesiger. That red-tape entangled
officer, however, deigned no reply, and seeing the waste of public
treasure involved by General Thesiger’s indifference, Colonel
Warren decided to act, knowing full well, if successful, that he
would have the full support of Sir Bartle Frere.
An opportunity of carrying out his plan quickly offered itself.
Out of the Perie Bush, seeking supplies, and almost in a starving
condition, came 600 women and children. Surrounded and made
prisoners by the Diamond Fields horse they were fed and taken
into King William’s Town and there handed over to the civil
authorities, to be afterward sent to Capetown and apprenticed as
domestic servants.
The husbands and fathers, rather than that those they held
most dear should be separated from them, possibly for ever,
appealed to the chiefs, some of whom perhaps were sufferers from
Colonel Warren’s coup de main, and so ended the Gaika-Gealika
rebellion.
This sudden termination to the war, however, I believe was
also the termination in the friendship previously existing between
General Thesiger and Colonel Warren.
About this time bad news was received from the northern
border of Griqualand West. Bolasike Gasibone, it was reported,
was committing acts of plunder and generally exhibiting a total
disregard of the laws of meum and tuum, and in consequence
Major Lanyon, the administrator of the province, left on January
21st, 1878, with 150 volunteers for Phokwane to punish him. The
major was absent from Kimberley some twelve days, found that
there had been no fighting, found no one with whom to fight,
merely old women, children and cows; he collared the cows, and
returned with the spoil to the diamond fields. Many laughed at the
whole affair, but a more serious view was afterward presented for
consideration when the Revs. Messrs. Bevan and Ashton, two
well-known missionaries, appealed to the public for assistance for
the poor natives, who, they stated, were starving. Major Lanyon to
stay public indignation sent a so-called independent commission
to report on the state of affairs, consisting of Mr. Lord, acting
attorney general, a submissive admirer of every act of government,
and Mr. Baillie, merely a subordinate in the survey department.
The report framed was of almost interminable length, occupying
fifteen pages in the government Gazette of March 16th, but before
it was issued the public had openly expressed their anticipations
respecting the document. The public was not, however, prepared
for its “highfalutin” rhapsodies on the “duty of man,” nor for the
strange citing of Holy Writ in its concluding sentence, in which
natives, owners of the soil and living an independent pastoral life,
were told, after all their cattle had been forcibly removed, “if any
man will not work neither shall he eat.”
Two months later (April 13th, 1878), the administrator of the
Transvaal solicited assistance against Sekukuni, and as
preparations were being made to give him assistance news arrived
of trouble on our southwestern border, which was confirmed by a
dispatch on April 21st from Mr. H. B. Roper, the magistrate of
Griqua Town. A call to arms was at once made and readily
responded to. Major Lanyon again left Kimberley, in three days’
time, with 100 men for Koejas. As soon as he arrived at his
destination he called upon the natives to put down their arms,
which they refused to do, and as they occupied a position from
which it was impossible to dislodge them without cannon, Major
Maxwell was telegraphed to at King William’s Town to at once
bring up some field-pieces. In the meantime volunteers were
leaving Kimberley almost every day for the front to strengthen
Major Lanyon.
During Major Lanyon’s encampment at Koejas the Griquas,
who had up to that time remained quiet (the rebellion having
broken out among a number of colonial Kafirs and Korannas
living on the banks of the Orange River), rose en masse and
besieged Griqua Town, which was surrounded by them for eight
days. On the night of the eighth day Major Lanyon rode through
them with twenty men undiscovered and joined some 100
volunteers who had managed, the same day, to get into Griqua
Town from the Kimberley side. On the following day the rebels
were completely routed at Driefontein in a decisive engagement
which lasted twelve hours and driven into their fastnesses in the
Langeberg. Major Maxwell, whose arrival was eagerly looked for,
arrived at Koejas on May 25th with the cannon, just in the nick of
time, as on the 31st 600 natives attacked the camp, when the guns
which he had brought up materially assisted to secure the success
of the day. During the time all these events had been occurring
Colonel Warren and “our boys” had been burning to respond to
the calls for assistance which had reached them from Griqualand
West. They had heard how volunteers had been raised and had
taken the field under the command of the administrator, and how
the country on the southwestern border was in a state of tumult
and insurrection. Springing to saddle the plucky band made forced
marches, this time in the cold, pinching month of May. “The air bit
shrewdly and ’twas bitter cold,” but with no covering save a
blanket and the saddle for a pillow, they quickly reached the
junction of the Vaal and Orange Rivers. Scarcely had the force
(numbering then about 200 men) crossed the Vaal River than
Colonel Warren scented the disaffected Griquas at Wittehuis,
where they had “enschanged” themselves in a formidable position
between the Kaap Range and the Vaal River. Here the rebels were
attacked and routed, and after completing their defeat Colonel
Warren and his men pushed on to Griqua Town.
Thence he and Major Lanyon proceeded to the Langeberg,
where several engagements took place, in all of which the rebels
were defeated. The most important of these skirmishes was that of
Paarde-Kloop, at which an immense quantity of wagons, oxen,
horses and sheep were captured. There is nothing which makes a
native regret rebellion more than the loss of his worldly goods.
Capture his stock and he is defeated.
After these engagements the administrator returned to
Griqua Town, leaving Colonel Warren in command, and there
received the sad intelligence of the skirmish at Manyeering,
resulting in the death of Messrs. Paterson, Rawstorne and several
other well-known persons. While proceeding as quickly as possible
on his road to Kimberley, he was attacked by and succeeded in
defeating a body of rebels at Campbell, some thirty miles from
Kimberley, where he arrived in safety after being some two
months absent from the seat of government.
Colonel Warren now made a detour, suspecting the enemy to
be lodged in a mountain situated to the northeast, and distant
from the Griqua Town road some twenty miles. Here he only
found groups of chattering monkeys, instead of the Griquas he
expected.
The rebels had fled!
TAIKOON PASS.
J. W. M , V. P.
G. B .
I. P .
H. G .”
This sight was enough of itself to make all the Zulus stop work
and “wau” with curiosity. Seeing some wounded men
accompanying the ambulances one Zulu bursting with fun and
grinning from ear to ear, shouted out, “Sakubona,” (“I see you,” a
form of greeting) “Johnny! upi lo Dutchman?” (“Where is the
Dutchman?”) of course a regular peal of laughter at once followed
this sally of native wit. I can assure my readers, that as an
Englishman I sincerely felt for our wounded soldiers thus
tauntingly jeered at, and I was able to estimate the tremendous
shock that our prestige had received among the aborigines. The
Zulus recognized the situation at once, the only thing our poor
fellows could do was to grind their teeth and curse their fate as
they wearily trudged along, victims of vanity[67] and misjudgment,
the defeated of Laing’s Nek, Ingogo and Majuba!
There is no doubt that the retrocession of the Transvaal was a
violation of a series of guarantees which had been previously
given. Not only Mr. Gladstone and Lord Kimberley, but also Sir
Garnet Wolseley, Sir Bartle Frere, Sir Theo. Shepstone and Sir
Owen Lanyon had over and over again declared that the Transvaal
would remain English territory, and that under no circumstances
could the annexation be reversed. These emphatic utterances were
made long before the outbreak of hostilities, and consequently the
withdrawal of English rule after the Dutch had gained four signal
victories within nine weeks, could be interpreted only by both
Dutch and natives as an act, not of principle and equity, but of
weakness and defeat. My friend, Mr. C. K. White, one of the
nominees appointed by Sir Garnet Wolseley to the legislative
council, which he gave as a sop to the Transvaal Boers, in a letter
at the time appealed to Mr. Gladstone in the following touching
words: “If, sir, you had seen, as I have seen, promising young
citizens of Pretoria dying of wounds received for their country,
and if you had had the painful duty, as I have had, of bringing to
their friends at home the last mementoes of the departed; if you
had seen the privations and discomforts which delicate women
and children bore without murmuring for upward of three
months; if you had seen strong men crying like children at the
cruel and undeserved desertion of England; if you had seen the
long strings of half desperate loyalists, shaking the dust off their
feet as they left the country, which I saw on my way to Newcastle;
and if you yourself had invested your all on the strength of the
word of England, and now saw yourself in a fair way of being
beggared by the acts of the country in which you trusted, you
would, sir, I think, be ‘pronounced,’ and England would ring with
eloquent entreaties and threats which would compel a hearing.”
Mr. Gladstone, however, changed his previously declared
convictions. On January 21st, 1880, he stated in the House of
Commons: “I must look to the obligations entailed by the
annexation, and if in my opinion, and in the opinion of many on
this side of the house, wrong was done by the annexation itself,
that would not warrant us in doing fresh, distinct and separate
wrong by a disregard of the obligations which that annexation
entailed;” or again on June 8th, 1880, when in answer to Messrs
Kruger and Joubert who had written to him, asking him to rescind
the annexation of the Transvaal, he said “our judgment is that the
Queen cannot be advised to relinquish her sovereignty over the
Transvaal.” Yet little more than a year saw this “pronounced”
opinion totally changed, and all confidence in Mr. Gladstone and
his ministry almost annihilated throughout the length and breadth
of South Africa.
Proceeding on my journey I crossed the Ingagane, passed the
forts in course of erection by our soldiers close to the river, the
heliograph twinkling in the sun, and after a long, tiring journey
arrived at Newcastle in the afternoon.
Newcastle lies on a large grassy plain and in the centre of a
district containing no less than 1,350 square miles of workable
coal[68] close to the surface; and in the near future destined to keep
up the credit of its name when the mines have been properly
opened up, it will be noted for this production, and then no doubt
a railway to the coast being by that time un fait accompli will
supply the traffic of the eastern seas.[69] Newcastle was in the
zenith of its commercial prosperity during the late war, and even
when I visited it its glory had not quite departed.
Wishing to proceed and see Majuba without loss of time, I
found this would be an impossibility, at least for some days, had
not Mr. Greenlees, an old resident, kindly given me his assistance
and offered to drive me there himself the next day.
As a pleasurable interlude, especially in a place like
Newcastle, a grand concert was advertised, which took place on
the evening of my arrival, and the band of the 97th put forward as
a special inducement. I went and saw a sight that I shall not soon
forget. The “gods” were very uproarious and demonstrative, and
not at all reticent in expressing their opinion. One singer, well
known as a notorious bouncer about the power of England and the
valor of her troops, on coming on was most cynically received. To
me it was a mystery, but this was explained when he commenced
to sing:
“In days of old, when knights were bold,
And barons held their sway;
A warrior bold, with spurs of gold,
Sang merrily his lay,”
while Colonel Deane’s spoke the truth of a valiant soldier “who fell
in action at Laing’s Nek, at the head of a storming party, ten yards
in front of the foremost man.” Alongside these were two little
wooden crosses, pointing out the graves of Doctors Landon and
Cornish. On Surgeon Major Cornish’s grave there was a beautiful
wreath, with the touching words:
“Now the laborer’s task is o’er,
Now the battle’s day is passed;
Lands the voyager at last,
Safe upon that further shore.”
In fact the whole cemetery was like a garden of flowers, the graves
covered with beautiful wreaths of immortelles, tributes from all
parts.
I may here mention that I had the pleasure in August, 1886,
just five years after making this visit and five years after the peace
was signed, of being introduced at Barberton-the principal town
on the Kaap gold fields, and elsewhere described—to
Commandant General Piet Joubert and General Smit, who were
the Boer commanders at Majuba. I had long been anxious to hear
a viva voce statement of the Boer side of the question from some
of the chief actors, and I eagerly seized the opportunity of