5 Units of Measurements

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3.

1 Using and Expressing Measurements >

Chapter 2
Measurements in Science

• Precision and Accuracy


• Significant Figures
• Scientific Notation
• Units of Measurements

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3.1 Using and Expressing Measurements >

UNITS OF MEASUREMENTS
Learning Objective
At the end of the lesson, the students
should be able to:
1. identify different sources of errors in
measurements
2. identify basic and derived quantities
and their units of measurements; and
3. determine the density of liquids and
solids
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3.1 Using and Expressing Measurements > Units of Measurements

• The standards of measurement


used in science are those of the
metric system.

All metric units are based on


multiples of 10. As a result, you
can convert between units
easily.

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3.1 Using and Expressing Measurements > Units of Measurements

• The metric system was originally


established in France in 1795.

• The International System of Units


(abbreviated SI after the French name, Le
Système International d’Unités) is a
revised version of the metric system.

• The SI was adopted by international


agreement in 1960.

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3.1 Using and Expressing Measurements > Units of Measurements

Fundamental SI Units
• There are seven SI base
Name of
units. Quantity
Unit
Symbol

Length meter m
• From these base units,
Mass kilogram kg
all other SI units of
Temperature kelvin K
measurement can be
Time second s
derived.
Amount of
mole mol
substance
• Derived units are
Luminous
used for intensity
candela cd
measurements such Electric
as volume, density, ampere A
current
and pressure.
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3.1 Using and Expressing Measurements > Units of Measurements

This chart shows all metric –


imperial (and imperial –
metric) system conversions.
They each involve a certain
number of sig figs.

Metric - to – metric and


imperial –
to – imperial conversions are
exact quantities.

Examples:

16 ounces = 1 pound
exact
relationships
1 kg = 1000 g

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3.1 Using and Expressing Measurements > Units of Measurements

Units of Length
• In SI, the basic unit of length, or linear
measure, is the meter (m).

• All measurements of length can be


expressed in meters.

• For very large and very small lengths,


however, it may be more convenient to
use a unit of length that has a prefix.

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3.1 Using and Expressing Measurements > Units of Measurements

Units of Length
The table below lists the prefixes in common use.
Commonly Used Metric Prefixes
Prefix Symbol Meaning Factor
mega M 1 million times larger than the unit it precedes 106
kilo k 1000 times larger than the unit it precedes 103
deci d 10 times smaller than the unit it precedes 10-1
centi c 100 times smaller than the unit it precedes 10-2
milli m 1000 times smaller than the unit it precedes 10-3
micro μ 1 million times smaller than the unit it precedes 10-6
nano n 1 billion times smaller than the unit it precedes 10-9
pico p 1 trillion times smaller than the unit it precedes 10-12

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3.1 Using and Expressing Measurements > Units of Measurements

Units of Length
• For example, the prefix milli- means 1/1000
(one-thousandth), so a millimeter (mm) is
1/1000 of a meter, or 0.001 m.

• For large distances, it is most appropriate to


express measurements in kilometers (km).

• The prefix kilo- means 1000, so 1 km


equals 1000 m.

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How many millimeters are there in 3.0 ft?

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3.1 Using and Expressing Measurements > Units of Measurements

Units of Volume
• The space occupied by any sample of
matter is called its volume.

• You calculate the volume of any cubic or


rectangular solid by multiplying its length
by its width by its height.

• The unit for volume is thus derived from


the units of length.

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3.1 Using and Expressing Measurements > Units of Measurements

Units of Volume
• The SI unit of volume is the amount of space
occupied by a cube that is 1 m along each
edge.

• This volume is a cubic meter (m3).

• A more convenient unit of volume for everyday


use is the liter, a non-SI unit.

• A liter (L) is the volume of a cube that is 10


centimeters (10 cm) along each edge.
• (10 cm x 10 cm x 10 cm = 1000 cm3 = 1 L).
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3.1 Using and Expressing Measurements > Units of Measurements

Units of Volume
• A smaller, non-SI unit of volume is the
milliliter (mL); 1 mL is 1/1000 of a liter.

• Thus, there are 1000 mL in 1 L.

• Because 1 L is defined as 1000 cm3, 1 mL


and 1 cm3 are the same volume.

• The units milliliter and cubic centimeter are


thus used interchangeably.
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3.1 Using and Expressing Measurements > Units of Measurements

Units of Volume
These figures give you some idea of
the relative sizes of a liter and a
milliliter.

1L

1 mL

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3.1 Using and Expressing Measurements > Units of Measurements

Units of Volume
• There are many devices for measuring liquid
volumes, including graduated cylinders,
pipets, burets, volumetric flasks, and
syringes.

• The volume of substances will change with


temperature, so accurate volume-measuring
devices are calibrated at a given temperature—
usually 20 degrees Celsius (20°C), which is
about normal room temperature.

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3.1 Using and Expressing Measurements > Units of Measurements

Units of Volume
The relationships among common metric units of
volume are shown in the table below.

Metric Units of Volume

Unit Symbol Relationship Example

Liter L base unit quart of milk ≈ 1 L

Milliliter mL 103 mL = 1 L 20 drops of water ≈ 1 mL


Cubic
cm3 1 cm3 = 1 mL cube of sugar ≈ 1 cm3
centimeter
Microliter μL 103 μL = 1 L crystal of table salt ≈ 1 μL

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3.1 Using and Expressing Measurements > Units of Measurements

Units of Mass
• The mass of an object is measured in
comparison to a standard mass of 1 kilogram
(kg), which is the basic SI unit of mass.

• Mass is the actual amount of matter that a


substance contains, while weight is a measure
of the gravitational attraction exerted by the
center of gravity upon a body.

• Mass can be measured using a platform balance.

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3.1 Using and Expressing Measurements > Units of Measurements

Units of Mass
The relationships among units of mass are
shown in the table below.

Metric Units of Mass


Unit Symbol Relationshi Example
p
Kilogram
kg 1 kg = 103 g small textbook ≈ 1 kg
(base unit)
Gram g 1 g = 10-3 kg dollar bill ≈ 1 g
Milligram mg 103 mg = 1 g ten grains of salt ≈ 1 mg
Microgram μg 106 μg = 1 g particle of baking powder ≈ 1 μg

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3.1 Using and Expressing Measurements > Units of Measurements

Units of Energy
• The capacity to do work or to produce heat is
called energy.

• The SI unit of energy is the joule (J), named


after the English physicist James Prescott
Joule (1818–1889).

• A common non-SI unit of energy is the calorie.

• One calorie (cal) is the quantity of heat that


raises the temperature of 1 g of pure water
by 1°C.
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3.1 Using and Expressing Measurements > Units of Measurements

Units of Energy

• Conversions between joules and calories


can be carried out using the following
relationships.
1 J = 0.2390 cal
1 cal = 4.184 J

• A kilojoule is 1000 joules; a kilocalorie is


1000 calories.

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3.1 Using and Expressing Measurements > Units of Measurements

Units of Temperature
• Temperature is a measure of how hot or
cold an object is.

• An object’s temperature determines the


direction of heat transfer.

• When two objects at different


temperatures are in contact, heat moves
from the object at the higher temperature
to the object at the lower temperature.
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3.1 Using and Expressing Measurements > Units of Measurements

Units of Temperature
• Temperature is measured by a device called
thermometer.

• Temperature scales have two fixed points: the


boiling point of water (212 ℉, 100℃ and 373 K)
and the freezing point of water (32 ℉, 0℃ and 273
K).

• William Thomson, Lord Kelvin (1824-1907)


invented a scale of absolute temperature, where at
absolute zero, an object contains absolutely no heat.

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3.1 Using and Expressing Measurements > Units of Measurements

Units of Temperature

• The zero point of the Kelvin scale


corresponds to -273℃ and to -
459.67℉.

• Absolute zero is the temperature at


which all motion of particulate matter
stops.

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3.1 Using and Expressing Measurements > Units of Measurements
• The figure below compares the Celsius, Fahrenheit and Kelvin
scales.
• The zero point on the Kelvin scale, 0 K, or absolute zero, is
equal to 273.15℃ and 32℉.

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3.1 Using and Expressing Measurements > Units of Measurements

Units of Temperature

5 ∘
∘C = × ( F − 32)
9
K = ∘ C + 273.15
9
∘F = °C + 32
5

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3.1 Using and Expressing Measurements > Units of Measurements

Dimensional Analysis:
Interconversion by the Factor Unit Method

• The term, “dimensional analysis,” refers to


a procedure that yields the conversion of
units, and follows the general formula:

 Desired _ Units 
Given _ Units  = Desired _ Units
 Given _ Units 

conversion factor

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3.1 Using and Expressing Measurements > Units of Measurements

Dimensional Analysis:
Interconversion by the Factor Unit Method
• Advantages of learning/using dimensional
analysis for problem solving:
• Reinforces the use of units of measurement
• You don’t need to have a formula for solving
most problems

How many moles of H2O are present in


27.03g H2O?

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3.1 Using and Expressing Measurements > Units of Measurements

Dimensional Analysis:
Interconversion by the Factor Unit Method
Changing from one unit to another is based on developing
a relationship between different units expressing the
same physical parameter. The following examples
illustrate the use of the factor-unit method.

Sample Problem 1:
Convert 310 pounds to kilograms. Round off your answer
to the correct number of significant figures.
1 pound (lb) = 454 grams (g)
1000 grams (g) = 1 kilograms (kg)

Answer: 1.4 x 102 kg


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3.1 Using and Expressing Measurements > Units of Measurements

Dimensional Analysis:
Interconversion by the Factor Unit Method

Sample Problem 2:
Calculate the number of milligrams in 2
metric tons.
1 metric ton (t) = 2204.62 pounds (lbs)
1 pound (lb) = 454 grams (g)
1000 milligrams (mg) = 1 gram (1)

Answer: 2 x 109 mg

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3.1 Using and Expressing Measurements > Units of Measurements

Dimensional Analysis:
Interconversion by the Factor Unit Method

Sample Problem 3:
Convert 70.0 miles to centimeters.
1 mile (mi) = 5280 feet (ft)
1 foot (ft) = 12 inches (in)
1 inch (in) = 2.54 centimeters (cm)

Answer: 1.1 x 107 cm

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3.1 Using and Expressing Measurements > Units of Measurements

Dimensional Analysis:
Interconversion by the Factor Unit Method

Sample Problem 4:
Calculate the number of seconds in 3
days.

Answer: 3 x 105 s

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3.1 Using and Expressing Measurements > Units of Measurements

Derived units involve


measuring more than one
parameter, resulting in a
combination of basic units.
Dervied Units
Speed or
Pressure Density
Velocity
1 atm = 101.325 Pa = 760 mmHg = 760 torr Units: Units:
= 14.7 pounds per square inch (psi) kg/m3 m/s
1 bar = 100 000 Pa = 0.9869 atm g/cm3 km/hr
1 Pa = 1 N/m2 g/mL mi/hr

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3.1 Using and Expressing Measurements > Units of Measurements

Unit of Pressure

• Pressure is force applied per unit area.


Force N
P = =
Area m 2
• The pressure exerted by air in the
atmosphere as a result of its mass and
gravitational attraction is called
atmospheric pressure.

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3.1 Using and Expressing Measurements > Units of Measurements

Unit of Pressure

• It is expressed in units of force per


unit area.
• The SI unit for force is the Newton (N)
and 1 N/m2 is called Pascal (Pa).
• Another unit of pressure is the
atmosphere (atm) and the bar.
• Atmospheric pressure is measured
using the barometer.

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3.1 Using and Expressing Measurements > Units of Measurements

Units of Density
• The relationship between an object’s mass and
its volume tells you whether it will float or sink.

• This relationship is called density.

• Given a mixture of two substances, the less


dense will float and the denser one will sink.

• It is expressed as units of mass divided by


units of volume, e.g., g/cm3, kg/m3, or lbs/in3.

Density = mass
volume
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3.1 Using and Expressing Measurements > Units of Measurements

Units of Density

This figure compares the density of four


substances: lithium, water, aluminum, and lead.

Increasing density (mass per unit volume)

10 g 10 g 10 g 10 g
19 cm3 10 cm3 3.7 cm3 0.88 cm3

0.53 g/cm3 1.0 g/cm3 2.7 g/cm3 11 g/cm3


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3.1 Using and Expressing Measurements > Units of Measurements

Units of Density

Density is an intensive property that


depends only on the composition of a
substance, not the size of the sample.

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3.1 Using and Expressing Measurements > Units of Measurements

Units of Density
• Because of differences in
density, liquids separate
into layers. Corn oil

Water
• As shown at right, corn
oil floats on top of water
because it is less dense. Corn syrup

• Corn syrup sinks below


water because it is more
dense.
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3.1 Using and Expressing Measurements > Units of Measurements

Densities of Some Common Materials


Solids and Liquids Gases
Density at Density at
Material Material
20°C (g/cm3) 20°C (g/L)
Gold 19.3 Chlorine 2.95
Mercury 13.6 Carbon dioxide 1.83
Lead 11.3 Argon 1.66
Aluminum 2.70 Oxygen 1.33
Table sugar 1.59 Air 1.20
Corn syrup 1.35–1.38 Nitrogen 1.17
Water (4°C) 1.000 Neon 0.84
Corn oil 0.922 Ammonia 0.718
Ice (0°C) 0.917 Methane 0.665
Ethanol 0.789 Helium 0.166
Gasoline 0.66–0.69 Hydrogen 0.084
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3.1 Using and Expressing Measurements > Density Examples

Example 1. A gas fills a volume of 1200. mL and


has a mass of 1.60 g. What is the density of the
gas?

m = 1.60 g = 0.00133 g/mL


D= 1200. mL
V

Example 2. A cube of pure silver measures 2.0


cm on each side. The density of silver is 10.5
g/cm3. What is the mass of the cube?
V = L× H × W = 2.0 cm x 2.0 cm x 2.0 cm = 8.0 cm3

m = D× V = 8.0 cm3 x 10.5 g/cm3 = 84. g


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3.1 Using and Expressing Measurements > Density Examples

Example 3: The density of air is 1.25 x 10-3 g/cm3. What


is the mass of air in a room that is 5.00 meters long, 4.00
meters wide and 2.2 meters high?
V = L× H × W
V = 5.0 m x 4.0 m x 2.2 m = 44 m3 Hmm, not so helpful.

V = 500. cm x 400. cm x 220 cm = 44000000 cm3

D= m m = D× V
V
m = (4.4 x 107 cm3) x (1.25 x 10-3 g/cm3) = 55000 g or 55 kg

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3.1 Using and Expressing Measurements > Units of Measurements

Units of Specific Gravity


• Specific gravity is the density of a substance
compared with the density of water at a given
temperature.
density of substance at a given temperature
Specific Gravity=
density of water at the same temperature

• Generally, density and specific gravity are


numerically equal, but specific gravity has no unit.

• For solids and liquids, density is expressed as


g/mL, lb/ft3, or lb/gal. For gases, the unit used is
g/L. In the SI, the unit used for solids, liquids, and
gases is kg/m3.
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3.1 Using and Expressing Measurements > Specific Gravity Examples

Example 1. Calculate the density of a metal with


a mass of 5.85 g and a volume of 1.45 mL.

m 5.85 g
D= = 1.45 mL
= 4.03 g/mL
V

Example 2. Calculate the specific gravity of the


metal at 20℃, given the density of water at 20℃ is
0.95 g/mL.

4.03 g/mL
specific gravity at 20℃ = = 4.24
0.95 g/mL

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3.1 Using and Expressing Measurements > Specific Gravity Examples

Example 3. Calculate the mass in grams of 250


mL of ether at 25℃. The density of ether at 25℃ is
0.71 g/mL.

Density = mass
volume

mass = density x volume= (0.71 g/mL)(250 mL) = 1.8 x 102 g

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