Gaseous State

ABOUT EDUCATORS

BRIJESH JINDAL
• No. 1 Physical Chemistry educator on Unacademy.
• Mentor of AIR-1 and many top 100 AIRs of IIT-JEE.
• BTech MNIT Jaipur
• 14 year experience of IIT JEE in Physical Chemistry
• Ex. Senior Faculty of Vibrant Academy, Kota, Allen Career Institute, Kota and Bansal
Classes, Kota

PIYUSH MAHESHWARI
• No. 1 Inorganic Chemistry educator on Unacademy.
• Mentor of AIR-1 and many top 100 AIRs of IIT-JEE.
• BE (Hons.)
• 14 year experience of IIT JEE in InorganicChemistry
• Author of 'Super Problems in Inorganic Chemistry',
• Ex. HOD Bansal Classes, Kota
• Ex. Senior Faculty of Vibrant Academy, Kota and Allen Career Institute, Kota

DR. SHARAD KOTHARI

• MSc., PhD, NET, JRF
• 21 year experience of IIT JEE in Organic Chemistry
• Ex. Senior Faculty of Vibrant Academy, Kota and Bansal Classes, Kota
 GASEOUS STATE

s
EXERCISE-1 (Subjective Questions)

s er t
r t
GAS LAWS & IDEAL GAS EQUATION
e xp
x p ryE
E ist
Q.1 For 1 mol of an ideal gas, draw the following graphs

r y
(a) PV vs V with constant T

m ist
(b) P vs d with constant T
(c) Pd vs d with constant T
hem
e C
Ch
1
(d) P vs with constant T
V
PV
(e) vs P
T

ts r ts
r xpe
(f) T vs V with constant P

x p e
Q.2
E yE
Suppose two flasks are taken at same temperature, one of volume 2L and other of volume 3L. The 2L
y r
r ist
flask contains 4.8 g of gas A and the gas pressure is X atm. The 3L flask contains 0.36 g of gas B and

is t
gas pressure of 0.1X.Which gas is heavier ?
m
em e
Ch
Q.3
Ch
A volume of CO2(g) equal to 30L was collected at 27°C and 1 atm pressure. What would be the volume
of CO2(g) collected at 227°C and 0.8 atm.

Q.4 What is the increase in volume, when the temperature of 600 mL of air increases from 27°C to 47°C
under constant pressure?

r ts ts
Q.5
x p e er
A sample of 60 cm3 of Ar(g) at 27°C was contained at a pressure of 155 kPa in a J shaped tube with

E x p
mercury. Later the temperature was changed. When the mercury level was adjusted to give the same
y
r yE
ist
pressure of Argon the volume changed to 50 cm3. What was the final temperature of Argon?

ist r
Q.6
em If 500 cm3 of Krypton (Kr) gas at 101 kPa and 20°C is compressed to 50 cm 3 at same temperature.

Ch
What is the pressure of Krypton in the tank?
hem
Q.7 C
The temperature of 4L sample of gas doubles from 30°C to 60°C at constant pressure. Determine the
volume of gas after this change.

Q.8 A 15L tank is filled with H2 to a pressure of 201 atm. How many balloon(each 2L) can be inflated to a

r ts
pressure of 1atm from the tank? Assume there is no temperature change and tank can not be emptied

xpe
below 1 atm pressure.

E r ts
y
r xpe
Q.9 An inflated balloon has a volume of 6L at sea level (1atm) and is allowed to ascent until the pressure is

is t
0.40 atm. During ascent temperature of gas falls from 27°C to – 73°C. Calculate the volume of balloon

em at its final altitude.

r yE
Ch
Q.10
m ist
0.4 gm of He in a bulb at a temperature of 'T' K had a pressure of 'P' atm. When the bulb was immersed
e
Ch
in hotter bath at a temperature 50 K more than the first one, 0.08 gm of gas had to be removed to restore
the original pressure. Then value of 'T' is ?

Q.11 The temperature of a gas placed in an open container is raised from 27°C to 227°C. The percent of the
original amount of the gas expelled from the container will be : Page # 1
 GASEOUS STATE
Q.12 An evacuated glass vessel weighs 50.0 g when empty, 148.0 gm when filled with a liquid of density

r
0.98 g /mL and 50.5 g when filled with an ideal gas at 760 mm Hg at 300 k . Determine the molecular
ts
weight of the gas.
r ts xp e
x p e E
Q.13
ry
The pressure exerted by 12 g of an ideal gas at temperature t ºC in a vessel of volume V(litre) is one atm

r yE ist
. When the temperature is increased by 10 degrees at the same volume, the pressure increases by 10 %.

m ist
Calculate the temperature 't' and volume 'V'.
em
[molecular weight of gas = 120]

h
e C
Ch
DALTON'S LAW OF PARTIAL PRESSURE

Q.14 The gas from an active volcano had the following composition in mole percent; 65 % CO2, 25% H2; 5.4
% HCl, 2.8 % HF 1.7% SO2 and 0.1 % H2S. What would be the partial pressure of each of these gases
if the total pressure of volcanic gas were 800 torr?
ts r ts
Q.15
p er
A 400 ml flask contains 4 mg O2 and 1 mg He(g) at 27°C. [R = 0.08 atm-L/mol-K]. Calculate
x E xpe
y
(a) Total pressure of mixture.
yE r
r ist
(b) Partial pressure of He(g) and O2(g)

is t m
Q.16
em e
A non reacting mixture of gases A, B and C is kept into a 8.21 litre container at 27°C. If mixture consists

Ch Ch
12.5 gm A gas, 0.5 moles of B gas and 88 gm of C gas, then calculate total pressure and partial pressure
of each gas in the container. [Given molar masses (gm/mol): MA = 25, MB = 30, MC = 44]

Q.17 One mole of NH4Cl (s) is kept in an open container & then covered with a lid. The container is now heated

s
upto 600 K where NH4Cl (s) completely dissociates into NH3(g) & HCl (g). If volume of the container is

r t ts
24.63 litres, calculate what will be the final pressure of gases inside the container. Also find whether the lid
e
p er
would stay or bounce off if it can withstand a pressure difference of 5.5 atm. Assume that outside air is at 300
x p
r yE
K and 1 atm pressure.
E x
ist ry
ist
Q.18 Calculate the total pressure in a 10 litre cylinder which contains 0.4 g He, 1.6 g oxygen and 1.4 g of

em nitrogen at 27ºC. Also calculate the partial pressure of He gas in the cylinder. Assume ideal behaviour for

Ch
gases.
hem
GRAHAM'S LAW OF DIFFUSION AND EFFUSION C
Q.19 Calculate relative rate of effusion of O2 to CH4 through a container containing O2 and CH4 in 3 : 2 mass
ratio.

r ts
xpe
Q.20 Calculate relative rate of effusion of SO2 to CH4 :
(a) Under similar condition of pressure & temperature
E r ts
y
r xpe
(b) Through a container containing SO2 and CH4 in 3:2 mass ratio

is t
Q.21
em yE
For gaseous Ni(CO)x, what is value of x if under identical conditions CH4 effuses 10.5 times faster
r
Ch ist
than Ni(CO)x.

Q.22
em
Equal volumes of two gasesAand B diffuse through a porous pot in 5 and 8 seconds respectively, at

Ch
initial conditions If molar mass of A be 25. Find the molar mass of B.

Page # 2
 GASEOUS STATE
Q.23 A gas mixture containing equal number of molecules of N2 and SF6 , is passed through a gaseous

r ts
effusion apparatus. Calculate how many molecules of N2 are present in the product gas for every 100
molecules of SF6.
r ts xp e
x p e E
Q.24
ry
A space capsule is filled with neon gas at 1.00 atm and 290 K. The gas effuses through a pin-hole into

r yE ist
outer space at such a rate that the pressure drops by 0.3 torr/sec. If the capsule is now filled with

m ist em
ammonia at the same temperature and pressure, what would be the rate of pressure drop.

h
e C
Ch
Q.25 One mole of N2 gas at 0.8 atmp takes 38 sec to diffuse through a pin hole, whereas one mole of an
unknown compound of Xenon (Xe) with Fluorine (F) at 1.6 atm takes 57 sec to diffuse through the
same hole . Calculate the molecular formula of the compound.(At. wt. Xe = 138, F = 19)

Q.26 Two gases NO and O2 were introduced at the two ends of a one metre long tube simultaneously
ts r ts
r xpe
(tube of uniform cross- section). At what distance from NO gas end , Brown fumes will be seen.

x p e
Q.27
yE
At room temp, NH3 gas at one atm & HCl gas at “P” atm are allowed to effuse through identical pin
yE r
r ist
holes to the opposite ends of a glass tube 1m long & uniform cross-section. A white deposit is observed

is t
at a distance of 60 cm from the HCl end. What is “P”.
m
em e
Ch
Q.28
CONNECTED CONTAINERS
Ch
Carefully observe the given figure and information provided there and answer the questions which follows:
The container I is found to contain 2 mole H2 , 4 mole Ne and 4 mole CH4 when the connecting tube is

s
in opened position.

er t ts
x p p er
r yE E x
ist ry
em ist
Ch hem
(a)
C
Calculate total number of moles of gases in container maintained at 1200 K.
(b) Calculate partial pressure of H2 in container 'I' [R = 0.08 L-atm K–1 mol–1]

Q.29
r ts
Two glass bulbs A and B are connected by a very small tube having a stop cock. Bulb A has a volume

xpe
of 100 cm3 and contained the gas, while bulb B was empty. On opening the stop cock, the pressure fell
down to 40% at constant temperature. Calculate volume of the bulb B (in cm3).
E r ts
y
Q.30
is tr xpe
Determine final pressure after the valve is left opened for a long time in the apparatus represented in
E
em y
figure. Assume that the temperature is fixed at 300 K. Under the given conditions assume no reaction of
r
Ch ist
CO & O2.

em
Ch
Page # 3
 GASEOUS STATE

Q.31
s
Two closed vessels of equal volume containing air at pressure P1 and temperature T1 Kelvin are connected
r t
s e
to each other with a narrow tube. If the temperature in one of the vessels is now maintained at T1 Kelvin

r t
and that in the other at T2, what will be the pressure in the vessels?
e xp
x p ryE
E ist
Q.32 A container containing H2(g) was connected to another empty container as shown in diagram and

r y
ist
maintained at given temperature.

m 16.42 lit. 8.21 lit.

hem
e C
Ch
1 mol H2(g)

Container ‘A’ Container ‘B’

400 K 300 K
(a)
s
Calculate final pressure in each container.
t r ts
r xpe
(b) Calculate number of moles of H2 in container 'B'.

x p e
Q.33
E yE
A 50 litre vessel is equally divided into three parts with the help of two stationary semi permeable
y r
tr ist
membrane (SPM). The vessel contains 60 g H2 gas in the left chamber, 160 g O2 in the middle &

is m
140 g N2 in the right one. The left SPM allows transfer of only H2 gas while the right one allows the

em e
transfer of both H2 & N2. Calculate the final ratio of pressure in the three chambers.

Ch KINETIC THEORY OF GASEOUS AND MAXWELL DISTRIBUTION OF SPEEDS Ch

Q.34 A 100L flask contains a mixture of CH4 and He at 27°C. The mass of He present is 40 g and mole

r s
fraction of CH4 in the mixture is 0.5. Calculate total tanslational kinetic energy of gaseous mixture.
t ts
Q.35
x p e er
Consider two gases A and B each in 10L container with both gases at the same temperature and pres-

E x p
sure. The mass of gas A in the container is 0.3 g and mass of gas B in the container is 0.4g.
y
r yE
m ist Gas A Gas B
ist r
e 0.3g 0.4g

em
Ch (a) Which gas sample has more number of molecules present?
(b) Which gas sample has higher average kinetic energy? C h
(c) Which gas sample has higher average velocity?

Q.36
ts
There are 2.0 × 1022 molecules of an ideal gas, each of mass 6 × 10–23 gm in a sample with average
r
xpe
speed 4.6 × 104 cm/s. The total translational kinetic energy of gas molecules (in J) is :
8
E r ts
y
xpe
(Given :  0.92 )

is tr
3
Q.37
em yE
At 27ºC if temperature of 1 mol of gas is increased by 50ºC the % change in kinetic energy of system is-
r
Ch
Q.38
ist
Calculate Urms of molecules of H2 at 1 atmp if density of H2 is 0.00009 g/cc.
m
e
Q.39
Ch
A bulb of capacity 1 dm3 contains 1.03 × 1023 H2 molecules & pressure exerted by these molecules is
101.325 kPa. Calculate the average square molecular speed and the temperature.

Page # 4
 GASEOUS STATE
Q.40 The density of CO at 273 K and 1 atm is 1.2504 kg m–3. Calculate :
(a) root mean square speed
r ts
r ts
(b) the average speed and (c) most probable speed.
xp e
x p e E
Q.41 Translational kinetic energy possessed by 1022 molecules of CH4(g) at 27°C is :
ry
yE
[Given : NA = 6 × 1023, R = 8.3 J/mole-K]
r ist
Q.42
m ist hem
Calculate the temperatures at which the root mean square speed, average speed and most probable
e C
Ch
speed of oxygen gas are all equal to 1500 ms–1.

Q.43 The average velocity of gas molecules is 400 m/sec. Calculate its (rms) velocity at the same temperature.

ts r ts
r xpe
Q.44 The graph below represents the distribution of molecular speeds of hydrogen and neon at 200K

x p e
yE r yE
Relative number of molecules

r ist
A

is t m
em e
Ch B Ch
0 400 800 1200

s
1600 2000 2400

er t Molecular speed(m/s)

ts
x p
(a) Match each curve to the appropriate gas.
p er
r yE
(b) Calculate the rms speed (in m/s) for each of the gases at 200K.
E x
ist
(c) Which of the gases would you expect to have the greater effusion rate at 200 K? Justify your answer.
ry
ist
(d) Calculate the temperature at which the rms speed of the hydrogen gas would equal the rms speed of

em
em
the Neon at 200K.

Ch (e) From the graph calculate most probable speed(mps) of H2 and Ne at 200K.

COLLISIONS AMONG GASEOUS MOLECULES C h

Q.45 H2 gas is kept inside a container A and container B each having volume 2 litre under different conditions

r ts
which are described below. Determining the missing values with proper unit.
[R = 8 J mol–1 K–1 and NA = 6 × 1023 , N = No. of molecules]

x pe Container A ts
PE r
Parameter Container B
y
r
t T xpe
(i )      1 atm
is 300 K 600 K
E
em 6  10 20
(ii )     
r y
ist
N

Ch Total KE
Ratio U mps
(iii )      (iv )     
(v)        
em
Ch
Ratio Z11 ( vi )          

Page # 5
 GASEOUS STATE
Q.46 Calculate the mean free path in CO2 at 27°C and a pressure of 10–9 bar. (molecular diameter = 500 pm)

r ts
s e
25 22
[Given : R =
3
J mol–1 K–1,
er t 2  1.4 , p =
7
, NA = 6 × 1023]
xp
Q.47
x p ryE
The mean free path of the molecule of a certain gas at 300 K is 2.0 × 10–5 m. The collision diameter of

yE
the molecule is 0.2 nm. Calculate
r ist
ist em
(a) number of molecules per unit volume of the gas, and

em(b) pressure of the gas

C h
Ch
25 1
[Given : R = J mol–1 K–1,  0.225 , NA = 6 × 1023]
3 2
REAL GAS AND VANDER WAAL'S EQUATION OF STATE

ts r ts
r xpe
Q.48 The density of liquid mercury is 13.6 g/cm3. Estimate the b value for Hg(g).Atomic mass of Hg = 200.

x p e
Q.49

yE r yE
Calculate the pressure exerted by 22 g of carbon dioxide in 0.5 dm3 at 300 K using:

r ist
(a) the ideal gas law and

is t
(b) Vander Waals equation. Given:
m
em [a = 360 kPa dm6 mol–2 and b = 40 cm3 mol–1]
e
Ch Ch
[Use : R = 0.08 atmL/mol K, 1 atm = 105 Pascal]

Q.50 Calculate from the vander waal's equation, the temperature at which 128 gm of SO2 would occupy a
vol. of 10 dm3 at 15 atm pressure.[a = 25 atm lit2 mol2, b = 0.05 lit mol–1]
[Use : R = 0.08 atmL/mol K]

r ts ts
Q.51
p e er
Calculate the pressure exerted by 1.00 mole of methane (CH4) in a 250 mL container at 300 K using van
x
E
der Waals equation. What pressure will be predicted by ideal gas equation ?
y x p
r
(Given : a = 2.253 L2 atm mol–2, b = 0.0428 L mol–1)
yE
Q.52
m ist
N2 molecule is spherical of radius 100 pm.
ist r
e em
Ch
(a) What is the volume of molecules of one mole gas?
(b) What is the value of vander waal's constant b?
4 C h
[Use :   4.2 , NA = 6 × 1023]
3
Q.53 Using Vander Waals equation, calculate the constant "a" when 2 moles of a gas confined in a 4 litre flask

r ts
exerts a pressure of 11.0 atmp at a temperature of 300 K. The value of "b" is 0.05 litre mol -1.

E xpe COMPRESSIBILITY FACTOR

r ts
y
Q.54
s tr xpe
The compression factor (compressibility factor) for one mole of a vander Waals gas at 0° C and 100
i E
em y
atmosphere pressure is found to be 0.5. Assuming that the volume of a gas molecule is negligible, calculate
r
Ch ist
the vander waals constant 'a'.

Q.55
em
The density of water vapour at 240 atm and 527°C is 90 gm/dm3.

Ch
Determine the molar volume, (Vm) of water and the compression factor.
[Use : R = 0.08 atmL/molK]

Page # 6
 GASEOUS STATE

s
Q.56 At 300 K and under a pressure of 10.1325 MPa, the compressibility factor of O2 is 0.8. Calculate the
mass of O2 necessary to fill a gas cylinder of 100 dm3 capacity under the given conditions.
s er t
er t xp
Q.57
x p
mol–2 and 0.125 Lmol–1. Calculate compressibility factor under
ryE
1 mole of CCl4 vapours at 27°C occupies a volume of 40 lit. If Vander Waals constant are 24.6 L2 atm

r yE
(a) Low pressure region (b) High Pressure region
ist
Q.58
m ist
One way of writing the equation for state for real gases is,
hem
e C
Ch
 B 
P V = R T 1  ...... where B is a constant.
 V 
Derive an approximate expression for 'B' in terms of Vander Waals constant 'a' & 'b'.

ts r ts
r xpe
Q.59 For one mole of a real gas, curves are plotted under different conditions at the same temperature as
shown in diagram :
x p e
yE r yE
tr ist
–2

s
slope = 10
i Z (In low pressure region)

m
24.63

m e
 slope = –0.1

e Z=1

Ch
Ch
(a) (b) PV
(atm L)
P atm
–1
1/V(litre )

ts
(i) What is the temperature at which the curve is plotted?
r ts
p e
(ii) Find vander waals constant 'a' and 'b'.
x er
yE x p
Q.60
r E
The vander waals constant for O2 are a = 1.59 atm L2 mol–2 and b = 0.0318 L mol–1. Calculate the
y
m ist
temperature at which O2 gas behaves, ideally for longer range of pressure.
ist r
e
[Use : R = 0.08 atmL/molK]

Ch hem
Q.61
CRITICAL PARAMETERS

The Vander Waals constants for gases A, B and C are as follows

C
Gas a/dm6 kPa mol–2 b/dm3 mol–1
A 405.3 0.027
B
r ts1215.9 0.030

xpe
C 607.95 0.032
Which gas has
E r ts
y
r xpe
(a) the highest critical temperature,

is t
(b) the largest molecular volume, and

em (d) most ideal behaviour around 1800K?

r yE
Ch
Q.62 ist
For a real gas (mol. mass = 30) if density at critical point is 0.40 g/cm3 and its Tc =
m
2  105
K, then
calculate Vander Waal's constant a (in atm L2mol–2).
e 821

Ch
Page # 7
 GASEOUS STATE

EXERCISE-2 (Objective Questions)

r ts
r ts xp e
Single Correct:

x p e E
ry
E ist
Q.1 If 4 litre of H2 gas at 400 mmHg and 47°C is transferred to 19 litre flask at 107°C. Then pressure of H2
r y
ist
gas is :
(A) 191.7 mm of Hg
m em
(B) 100 mm of Hg
h
e
(C) 158.4 mm of Hg
C
(D) 200 mm of Hg

Q.2
Ch
At constant temperature of 273 K,
1
vs P are plotted for two ideal gases A & B as shown below. Ratio
V
of number of moles of gas A & gas B are
ts
gas B

r ts
er xpe
3 1 1
p
gas A
(A) (B)
1
E x 3 V

yE
tr y r
ist P
60°

is
(C)
1
(D)
3
m
45°

em 3 1
e
Ch
Q.3 Ch
Calculate the number of moles of gas present in the container of volume 10 L at 300K. If the manometer
containing glycerin shows 3.8 m difference in level as shown diagram. [volume of gas in limb is negligible]
[Take R = 0.08 atm-lit K–1 mol–1 , Density of glycerin = 2.72 gm/ml, dmercury = 13.6 gm/ml]

r ts Patm=1 atm
ts
xp e er
yE x p
s tr
3.8m

ryE
em i ist
Ch hem
(A) 0.81 mol (B) 0.49 mol C
(C) 0.64 mol (D) 0.55 mol

Q.4 At the top of a mountain the thermometer reads 0°C and barometer reads 710 mm of Hg. At the bottom
of the mountain the temperature is 30°C and pressure is 760 mm of Hg. The ratio of density of air at the

r ts
xpe
top with that at the bottom is
(A) 1 : 1
E
(B) 1.04 : 1 (C) 1 : 1.04 (D) 1 : 1.5

r ts
y
s tr xpe
Q.5 The pressure of mixture of equal weights of two gases of molecular weight 4 and 40 is 1.1 atm. The

m i
partial pressure of the lighter gas in the gas mixture is
yE
e (A) 0.55 atm (B) 0.11 atm (C) 1 atm
istr
(D) 0.1 atm

Ch
Q.6
em
If two gases are taken at same temperature, the density of a gas A is three times that of gas B, while

Ch
molecular mass of gas B is twice that of A. The ratio of pressure of A and B will be:
1 2 3
(A) (B) 6 (C) (D)
6 3 2
Page # 8
 GASEOUS STATE

Q.7 A gaseous mixture (He and CH4) has density

64
gm/litre at 1 atm & 300 K is kept in a container..
r ts
r ts 246.3

xp e
x p e
Now a pinhole is made on the wall of the container through which He (g) and CH4(g) effuses. What will
E
n
be the composition of the gas mixture [ : n CH 4 ] effusing out initially..
ry
E ist
He

r y
ist
(A) 4 : 1 (B) 8 : 1 (C) 2 : 1 (D) 16 : 1

m hem
Q.8
e
If density of an ideal gas when plotted against pressure exerted, shows the below variation at 273K.
C
Ch
Find the molar mass (in gm/mol) of the gas?

s
d(gm/L)

ts r t
r xpe
60°

x p e P(atm)
(A) 19.4
yE
(B) 38.8 (C) 77.6
E
(D) 100
r y
Q.9
is tr ist
An ideal gas follows following process P2V = constant.Then on expansion, the temperature of gas.
m
em (A) decreases (B) increases
e
(C) remains constant (D) none of these

Ch
Q.10 Ch
n moles of Helium gas are placed in a vessel of volume V litre. at T K. If VI is free volume of Helium then
diameter of He atom is
1 1 1 1
 3 VI 3  3 (V  VI ) 3  6 (V  VI )3  6 VI 3
(A)  
 2 N A n 
(B) 
r ts
 2 N A n 
 (C) 
  N A n 
 (D)  
  N A n 
ts
xp e er
Q.11
E
The ratio of speeds of diffusion of two gases A and B is 1 : 4. If the mass ratio of A to B present in the
y x p
r yE
ist
given mixture is 2 : 1, then which of the following is the ratio mole-fraction of A to B?
(A) 2 : 3 (B) 1 : 8 (C) 2 : 1 (D) 1 : 2
ist r
em
Ch
Q.12
hem
The number of effusion steps required to convert a mixture of H2 and O2 from 240 : 1600 (by mass) to
3072 : 20 (by mass) is
(A) 2 (B) 4 (C) 5 C
(D) 6

Q.13 Temperature at which most probable speed of O2 becomes equal to root mean square speed of N2 is
[Given : N2 at 427°C]
(A) 732 K
r ts
(B) 1200 K (C) 927 K (D) 800 K

Q.14
E xpe
A rigid container containing 10 gm gas at some pressure and temperature. The gas has been allowed to
r ts
y
tr xpe
escape (do not consider any effusion or diffusion) from the container due to which pressure of the gas

is E
becomes half of its initial pressure and temperature become 2 3rd of its initial. The mass of gas (in gms)
em r y
Ch ist
escaped is
(A) 7.5 (B) 1.5 (C) 2.5 (D) 3.5
em
Q.15
(A) 4 (B) 2 (C) 1 Ch
The ratio between the r. m. s. velocity of H2 at 50 K and that of O2 at 800 K is :
(D) 1/4

Page # 9
 GASEOUS STATE
Q.16 A gas in open container is heated from 27° C to 127° C, The fraction of the original amount of the gas
remaining in the container will be
r ts
(A) 3/4
r
(B) 1/2
ts (C) 1/4 (D) 1/8
xp e
x p e E
ry
E ist
Q.17 Two flask A and B have equal volumes, A is maintained at 300 K and B at 600 K, while A contains H2

r y
gas, B has an equal mass of CO2 gas. Find the ratio of total translational kinetic energy of gases in flask

m ist
A to that of B.
hem
e
(A) 1 : 2 (B) 11 : 1 (C) 33 : 2 (D) 55 : 7
C
Ch
Q.18 X ml of H2 gas effuses through a hole in a container in 5 sec. The time taken for the effusion of the same
volume of the gas specified below under identical conditions is :
(A) 10 sec, He (B) 20 sec, O2 (C) 25 sec, CO (D) 55 sec, CO2

ts r ts
r xpe
Q.19 A gas obeys the equation of state P (V – b) = RT. The slope for an isochore will be
(A) R/(V – b)
x p e
(B) R / V (C) R / b (D) None of these

yE r yE
tr ist
Q.20 A gas will approach ideal behaviour at :

is
(A) low temperature and low pressure
m
(B) low temperature and high pressure

em e
Ch
(C) low pressure and high temperature (D) high temperature and high pressure .

Ch
Q.21 The density of a gaseous mixture containing equal moles of N2 and a hydrocarbon 'X', is 3.75 g/L at 0°C
and 1 atm. The molar mass of 'X' is :
(A) 84 (B) 28 (C) 56 (D) None of these

r ts ts
Q.22
(A) NH3
x e
Which of the following gases will have smallest value of Vander-waal constant 'a'?
p
(B) H2O (C) H2 (D) CO2
er
yE x p
r yE
ist
Q.23 The root mean square velocity of an ideal gas at constant pressure varies with density as
(A) d2 (B) d (C) d1/2
ist r
(D) 1/d1/2

em
Ch
Q.24
hem
Which one of the following V, T plots represents the behaviour of one mole of an ideal gas at one atmp?

C
(A) (B) (C) (D)

r ts
Q.25
xpe
Positive deviation from ideal behaviour takes place because of
E r ts
y
xpe
PV

is tr
(A) molecular attraction between atoms and
nRT
>1

em PV
r yE
Ch ist
(B) molecular attraction between atoms and <1
nRT

em
Ch
PV PV
(C) finite size of atoms and >1 (D) finite size of atoms and <1
nRT nRT

Page # 10
 GASEOUS STATE
Assertion & Reason :

r ts
Q.26 Statement-1
r ts p e
: If we increase temperature in a closed-rigid vessel mean free path will remain
x
unchanged.
x p e E
ry
Statement-2 : Mean free path depends on number of gaseous molecules per unit volume.

r yE ist
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.

m ist
(C) Statement-1 is true, statement-2 is false.
hem
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.

e C
Ch
(D) Statement-1 is false, statement-2 is true.

Q.27 Statement-1 : Two identical balloons A and B are inflated in open with equal moles of He and Ar
respectively will have same volume initially.
Statement-2 : After sometime balloons A will have more number of moles than balloon B.
ts r ts
r xpe
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.

p e
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
x
(C) Statement-1 is true, statement-2 is false.
yE r yE
r ist
(D) Statement-1 is false, statement-2 is true.

is t m
m
More than one correct:
e e
Ch
Q.28 Ch
Two flask A and B of equal volume are taken. Flask A contains H2(g) at 27°C and 1 atm pressure. Flask
B contain N2(g) at 27°C and 2 atm pressure. Then select incorrect statements.
(A) Average kinetic energy per molecule is same for both

s
(B) Number of molecules in both compartment are same.
(C) Mass of H2 is more than N2.
er t ts
x
(D) ( U rms ) H 2  ( U rms
)
p N2
p er
r yE E x
ist ry
ist
Q.29 Select the correct option(s) for an ideal gas

em (A) Most probable speed increases with increase in temperature

Ch em
(B) Fraction of particles moving with most probable speed increases with increase in temperature

similar condition of T, P & V. C h

(C) Fraction of particles moving with most probable speed are more for Cl2 than H2 under

(D) Most probable speed is more for Cl2 than H2 at same temperature

Q.30 Two containers are connected by stopcock as shown.

r ts
xpe
X mol O2 X mol He

E
V = 10 L V = 20 L
r ts
y
xpe
300 K 'T' K

is tr
em yE
If initially PO2  PHe  P when stopcock is closed. Then after opening the stopcock (after a long time
r
Ch keeping initial temperature in each same as intially ) .
m ist
e
(A) Pfinal = P (B) PO 2 
P
2 Ch
(C) PHe  P (D) T = 600 K

Page # 11
 GASEOUS STATE
Q.31 Equal number of He and Ne atoms are placed in two flask of volume V1 and V2(V1 > V2) respectively
and temperature of both vessels are same 400 K. Then identify the correct statement(s):
r ts
(A) (Urms)He = (Urms)Ne
r ts (B) Average KEHe = Average KENe
xp e
(C) PHe > PNe
x p e (D) PHe < PNe
E
ry
Q.32
r yE ist
Select the correct observation for a 8.21 lit container, filled with 2 moles of He at 300 K

m ist
(A) It has pressure 6 atm
hem
e C
(B) If it is an open rigid container, its pressure increases to 8 atm on heating to 400 K

Ch (C) If it is closed non-rigid (like thin skin balloon), its volume increases to 16.42 lit. on heating to 600 K
(D) When connected with another similar empty container maintained at 150 K while maintaining originl

s
2
container at 300 K, pressure reduces to
ts 3
atm.
r t
Q.33
x p er
E xpe
In the maxwell plot at two different temperature. Which of the following statements may be true.
yE r y
tr ist
T1
is 1 dN T2
m
em e
Ch
N du

Ch u1 u2 u
(A) Area under the two plots is same
(B) fraction of molecules with speed u1 at T1 > fraction of molecules having speed u2 at T2.
(C) u2 > u1 and T2 > T1
r ts ts
p e
(D) Umps at T1 < Umps at T2 ; Urms at T1 < Urms at T2
x er
yE x p
Match the column :
r yE
m ist ist r
e
Q.34 A container contains 3 mole O2 gas at 27°. It is heated to 327°C. Match the following

Ch
Column I
hem Column II

(A)
(Parameter)

l (Mean free path)

C(Increases by a factor)

(P) 1 (at constant V,n)

s
(B) Z1 (No. of collision by a molecule in unit time) (Q) 2 (at constant V,n)

er t
x p 1
ts
(C)
E
Z11 (Bimolecular collision frequency per unit
y
(R)
r
(at constant P,n)
r xpe
2

is t
volume per unit time)

em r yE
Ch ist
(S) 2 (at constant P,.n)

em
Ch
Page # 12
 GASEOUS STATE
Q.35 Column I Column II
(All gases are ideal)
r ts
r ts xp e
x p e E
ry
E ist
1
(A)
r y
log V v/s log , at constant n & P (P)

ist
T

m hem
e C
Ch
(B) Pd v/s P, at constant T for particular gas (Q)

ts r ts
x p er
E xpe
yE r y
is
(C) tr
T2 v/s VT, at constant P & n (R)
m ist
em e
Ch Ch
(D)
r ts
V v/s ln T, at constant n & P (S)
ts
xp e er
yE x p
r yE
m ist ist r
e em
Ch
Q.36 Column I consists of compressibility factor (Z) and column II consists of conditions in which the gas is
present. Match Column I with Column II.
C h
Column I Column II
(A) Z=1 (P) Any Vander Waal gas at its critical temperature.

r ts
xpe
(B) Z>1 (Q) Ideal gas at any Pressure and temperature

E r ts
y
xpe
(C) Z<1 (R) H2 gas at normal temperature and high pressure.

is tr
em 3
r yE
Ch ist
(D) Z= (S) NH3 gas at normal temperature and low pressure
8

em
Ch
(T) Any real gas at pressure close to zero and normal
temperature.

Page # 13
 GASEOUS STATE

s
Q.37 Instruction : Column I represents graph and column II represents the conditions to which an ideal gas
is subjected and the parameters plotted. Match the two columns.
s er t
er t xp
Column I
x p Column II

ryE
r yE ist
m
(A)
ist (P)
em
V v/s ln T at constant P and n
h
e C
Ch (B) (Q)
P
v/s log P at constant T and n
V

ts r ts
(C)
x p er (R)
E
log P v/s log T at constant V and n. xpe
yE r y
is tr (S)
ist
Pd v/s d2 at constant T and for a fixed
m
em gas.
e
Ch Ch

r ts ts
x p e er
yE x p
r yE
m ist ist r
e em
Ch C h

r ts
E xpe r ts
y
is tr
E xpe
em r y
Ch m ist
e
Ch
Page # 14
 GASEOUS STATE

ANSWER KEY
r ts
r ts EXERCISE-1

xp e
x p e E
ry
r yE ist
ist em
PV P Pd P
Q.1
em
(a) (b) (c)
C h (d)

Ch
V d d 1/V

PV
ts r ts
r xpe
T T

e
(e) (f)
P
x p V
E
yE r y
Q.2
is tr
gas A is heavier Q.3 62.5 L Q.4 40 mL

m ist
Q.5 250 K

em e
Ch Ch
Q.6 1010 kPa Q.7 4.4 L Q.8 1500 ballons Q.9 10 L

Q.10 200 K Q.11 40% Q.12 123 Q.13 –173°C , 0.82 L

Q.14
r ts
p CO2 = 520 torr; p H 2 = 200 torr; p HCl = 43.2 torr;
ts
x p e er
p HF = 22.4 torr; pSO 2 = 13.6 torr;
yE
p H 2S = 0.8 torr
x p
r yE
m ist (b) PO 2 = 0.75×10–2 atm; PHe =1.50 × 10–2 atm
ist r
Q.15
e (a) 2.25 × 10–2 atm

em
Ch
Q.16 Ptotal = 9 atm, PA = 1.5 atm = PB, PC = 6 atm Q.17 C h
6 atm, lid would stay on the container

3 2 1 3
Q.18 0.492 atm ; 0.246 atm

r ts Q.19
8
Q.20 (a)
2
; (b)
16

xpe
Q.21 4 Q.22 64 gm/mol Q.23 228 Q.24 0.33 torr/sec

E r ts
y
s tr xpe
Q.25 XeF6 Q.26 0.15 m Q.27 2.2 atm Q.28 (a) 15 mol; (b) 7.2 atm

m i yE
e istr
Ch
2 P1T2 6 2
Q.29 150 cm3 Q.30 3.284 atm Q.31
em
T1  T2 Q.32 (a)
5
atm; (b)
5

Q.33 4:7:5 Q.34 KEtotal = 74.826 kJ

Ch
Page # 15
 GASEOUS STATE

s
Q.35 (a) As P,V and T are same for both container so
nA = nB
s er t
er t
both contains has same number of molecules.
xp
3
x p ryE
yE ist
(b) KEavg = KT = same for both as it only depend on temperature

istr2
(c) ‘A’ has fast average velocity
m hem
e C
Q.36
Ch
0150 Q.37 16.67 Q.38 183,800 cm/sec

Q.39 8.88×105 (m /s)2 ; 71.27 K Q.40 URMS = 493 m/s ,Ump = 403m/s ,Uav=454.4 m/s

ts r ts
er xpe
Q.41 62.25 Joule Q.42 TRMS= 2886 K, Tav = 3399 K, Tmp=4330K

x p E
yE r y
r ist
Q.43 434.17 m/sec

is t m
em e
Ch
Q.44 (a) (A) Ne; (B) H2 (b) 1579.3 m/s, 499.4 m/s (c) H2 (d) 20 K

Ch
(e) 400 m/s and 1290 m/s (approx)
1
Q.45 (i) 0.012 atm; (ii) 2.5 ×1022; (iii) 3.6 J; (iv) 300 J; (v) ; (vi) 0.4 × 10–3 : 1
2

r ts ts
Q.46 3.788 × 103 cm
x p e
Q.47 (a) 2.81 ×1023 m–3 ; (b) 1.17 ×103 Pa
er
yE x p
r yE
ist
Q.48 58.82 cm3 Q.49 (a) 24 atm, (b) 21.40 atm Q.50 717°C

ist r
em
Ch em
Q.51 82.82 atm, 98.5 atm Q.52 (a) 2.52 × 10–3 l mol–1, (b) 10.08 × 10–3 dm3 mol–1

Q.53 6.52 atmp L2 mol–2 Q.54 1.2544 atmp L2 mol–2 C h

Q.55 Molar vol = 0.2 L/mol; Z = 0.75 Q.56 16.67 kg Q.57 (a) 0.975; (b) 1.003

B = b 
a 

r ts
xpe
Q.58 Q.59 (i) 300 K, (ii) a = 0.1, b = 0.2463 Q.60 625 K
 RT 

E r ts
y
Q.61 (a) B, (b) C, (c) A Q.62 1.6875

is tr
E xpe
em r y
Ch m ist
e
Ch
Page # 16
 GASEOUS STATE

s
EXERCISE-2

s er t
Q.1 B Q.2 D
er t Q.3 A Q.4 B
xp
Q.5 C

x p ryE
yE ist
Q.6 B Q.7 B Q.8 B Q.9 B Q.10 B
tr
Q.11 D
m is Q.12 C Q.13 B
hem Q.14 C Q.15 C
e C
Q.16 Ch
A Q.17 B Q.18 B Q.19 A Q.20 C

Q.21 D Q.22 C

ts
Q.23 D Q.24 C Q.25

r ts C

Q.26 A Q.27
xp
C er Q.28 BC Q.29 AC
E xpe
yE r y
Q.30 ABD
is tr Q.31 BD Q.32 AC

m
Q.33
ist
ABCD

em e
Ch Ch
Q.34 (A) P, S ; (B) Q, R ; (C) Q Q.35 (A) S ; (B) Q ; (C) R ; (D) P

Q.36 (A) QT (B) R (C) PS (D) P Q.37 (A) P&Q (B) R (C) RS

r ts ts
x p e er
yE x p
r yE
m ist ist r
e em
Ch C h

r ts
E xpe r ts
y
is tr
E xpe
em r y
Ch m ist
e
Ch
Page # 17