Seat

No.
PRN
No.
B.Sc.(Part –II) (Semester – III) Examination, October – 2020
CHEMISTRY
Organic Chemistry (Paper – V)
Subject Code : 63603
Day and Date :Thursday, 1-10-2020 Total Marks : 50
Time: 2:00 p.m. to 3:00 p.m.
Instructions: 1) Attempt any 25 questions out of given 30.
Q. Choose the most correct alternative for each of the following 50

1) Electrophilc attack in pyrrole occurs readily at position -------

A) 1 B) 3 C) 5 D) 2

2) The most unstable conformation of cyclohexane is -----------

A) half chair B) chair C) both A & B D) twist boat

3) In Clemmensen reduction the reagent used is -------

A) Zn B) ZnO C) Zn-Hg/HCl D ) ZnS

4) Oxidation of Naphthalene using V2O5 at 733K yields ---------

A) phthalic acid B) acetic acid C) phthalic anhydride D) succinic acid

5) The product of Claisen condensation is ---------

A)  - hydroxy ester B)  -keto ester C) -bromo ester D) unsaturated acid

6) The concept of green chemistry was describe by -------

A) Paul Anastas and John Warner B) Komiya

C) Menzer D) Mendeleev

P.T.O
7) The product of Mannich reaction is ------

A) primary or secondary amine B)  -keto ester

C) unsaturated acid D)  - hydroxy ester

8) Bucherer reaction is used to prepare ------from  -napthol

A) azo dye B) - napthol C) phthalic acid D) - naphthylamine

9) Zeolites are ------substances

A) crystallin B) amorphous C) both A & B D) none of these

10) The valence angle in cyclobutane is -------

A) 600 B) 900 C) 1080 D) 1200

11) Green chemistry is set to achieve ----principles

A) 8 B) 10 C) 12 D) 16

12) The most stable conformation of n-butane is ------conformation

A) antiperiplanar B) synperiplanar C) gauche D) skew

13) Quinoline reacts with sodamide to give -----

A) 2- methyl quinoline B) 2- amino quinoline

C) 2- nitro quinoline D) 2- phenyl quinoline

14) The catalytic activity of zeolites depends on the presence of --------

A) crystalline nature B) acid centers C) amorphous nature D) none of these

15) Pyridine undergoes electrophilic substitution preferentially at position --

A) 1 B) 2 C) 3 D) 4

16) By passing a mixture of two parts of acetylene and one part of HCN over red hot tube
------ is obtained.

A) pyrrole B) indole C) pyridine D) furan

17) The product of Knoevengel condensation is ----------

A) primary amine B) unsaturated compound

C) - keto ester D) - hydroxy ester

18) The delocalized electron system in naphthalene carries ----pi electrons

A) 7 B) 16 C) 10 D) 12

19) Indole on Mannich reaction gives ---------

A) gramine B) 3- iodo indole C) 3- nitro indole D) 3- bromo indole

20) Bio catalytic reactions are -------

A) highly specific B) equilibrium is established rapidly

C) occur at room temperature D) all of these

21) The product of Perkin reaction is --------

A)  - keto ester B) unsaturated ester

C) unsaturated acid D) saturated ketone

22) 1- nitro naphthalene on reduction with Fe +HCl gives ---------

A) 1- naphthyl amine B) 2- naphthylamine

C) 1- naphthol D) 2- naphthol

23) Napthalene on reduction with Na and amyl alcohol gives------

A) 1,2 dialine B) tetralin C) 1,4 dialin D) decalin

24) Locking of conformation is observed in -------

A) cyclohexane B) methyl cyclohexane

C) bromo cyclohexane D) t-butyl cyclohexane

25) The utilization of mechanical energy to drive chemical reaction is called --

A) electrochemistry B) mechanochemistry

C) photochemistry D) microwave Chemistry

26) Self oxidation and reduction of aldehydes lacking alpha hydrogen atom in presence

of strong base to give alcohol and salt of carboxylic acid is called -------

A) Cannizzaro’s reaction B) Perkin reaction

C) Reformatsky reaction D) Knovengel reaction

27) Pyridine on heating with KOH gives --------

A) 2- amino pyridine B) 2- methyl pyridine

C) 2- hydroxy pyridine D) 2- butyl pyridine

28) Bardhan - Sengupta synthesis is used to prepare --------

A) naphthalene B) phenanthrene C) benzene D) naphthyl amines

29) The reaction between Carboyl Compound and - bromo ester in presence of zinc metal

to give  - hydroxy ester is called -------

A) Perkin reaction B) Mannich reaction

C) Reformatsky reaction D) Riemer – Timann reaction

30) Skraup’s synthesis is used for preparation of -------

A) indole B) pyrrole C) pyridine D) quinoline