Yashwantrao Chavan Warana Mahavidyalaya, Warananagar.

DEPARTMENT OF CHEMISTRY
M.Sc. Part-I (Semester-II) Practical Examination May 2018
PHYSICAL CHEMISTRY
Date:14/15/05/2018 Time:10.30 a.m. to 2.00 p.m.
Seat No.: …………………………………. 2.30 p.m. to 6.00 p.m.
Q.1.Non Instrumental Experiment
Chemical Kinetics:To investigate reaction between bromic acid and hydroiodic acid and
dertermine rate constant by calculation and graph. 20
Given: - 0.05N KBrO3;0.005N KI;0.1NHCl;0.01N Na2S2O3
Partial Molar Volume:To determine partial molar volume of ethyl alchohol in mixture of
ethyl alchohol and water.
Given:ethyl alchohol;water.
Q.2.Instrumental Experiment
Conductometry: 1) Determine the normality and strength of each acid from the given acid
Mixture conductometrically.
Given: -, Acid Mixture;0.1N NaOH
Conductometry
2) Determine the relative strength of chloroacetic acid and acetic acid conductometrically.
Given:-. 0.1 N KCl, 0.1 NCH3COOH;0.1NCH3COOH
Potentiometry:
3) To determine the molar refractivities of methyl acetate, ethyl acetate, n-hexane & carbon
tetrachloride and calculate the refraction equivalents of C,H and Cl atoms.
Given: - methyl acetate, ethyl acetate n-hexane , & carbon tetrachloride
Potentiometry
4) To determine the formal redox potential (E0R) of fe3+ / fe2+ system potentiometrically.
Q.3.Oral and journal
10

Yashwantrao Chavan Warana Mahavidyalaya, Warananagar.

DEPARTMENT OF CHEMISTRY
M.Sc. Part-I (Semester-II) Practical Examination May 2018
PHYSICAL CHEMISTRY
Date:14/15/05/2018 Time:10.30 a.m. to 2.00 p.m.
Seat No.: …………………………………. 2.30 p.m. to 6.00 p.m.
Q.1.Major Experiment
To investigate the kinetics of iodination of acetone
20
Given: - 2 N H2SO4 , 0.1 M. I2 in 10 % KI, 1 M CH3COONa,
0.01 N Na2S2O3, Starch etc
Q.2.Minor Experiment
 Conductometry
20
1) To verify the validity of onsagar equation at low concentration for a 1:1type electrolyte
conductometrically.
Given: - 0.1 N KCl, 0.02 N KCl, Conductivity water,
Conductometry
2) Titration of mixture of trichloroacetic acid, monochloro acetic acid and acetic acid
conductometrically.
Given:-Ternary acid mixture, 0.1 N NaOH.
Refractometry
3) To determine the molar refractivities of methyl acetate, ethyl acetate, n-hexane & carbon
tetrachloride and calculate the refraction equivalents of C,H and Cl atoms.
Given: - methyl acetate, ethyl acetate n-hexane , & carbon tetrachloride
Potentiometry
4) To determine the formal redox potential (E0R) of fe3+ / fe2+ system potentiometrically.
Q.3.Oral and journal