SAMPLE PAPER (AC-01)

CHEMISTRY (043)

CLASS - XI

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1. Why rutherford model could not explain the stability of an atom ?
2. How does the intensity of light affect the photoelectric effect ?
3. States Heisenberg Uncertainty principle.
4. Calculate energy if the 2 mole photon of radiation whose frequency is 5 *
1015 Hz.
5. How is threshold frequency is differ from activation frequency ?
6. Calculate the mass of an electron.
7. Give the main properties of canal rays experiment.
8. Why cannot the motion of an electron around the nucleus determine
accurately ?
9. Calculate the uncertainty of an electron in the wagon whose mass is 4000
kg whose position is known accurately is ±10m.
4+ 3+ 2+ 2+
10. Write the electronic configuration of Mn , Fe , Zn and Cr . Also
calculate the number of unpaired electron in each case.
11. Give the drawbacks of J.J. Thomson’s experiment.
12. What did Rutherford conclude from the observations of the α−ray
scattering experiment?
13. Yellow light emitted from a sodium lamp has a wavelength (2) of 580 nm.
Calculate the frequency (v) and wave number (v) of yellow light.
14. A photon of wavelength 4 × 10 m strikes on metal surface ; the work
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function of the metal being 2.13 eV. Calculate (i) the energy of the photon,
(ii) the kinetic energy of the emission
(iii) the velocity of the photoelectron. (Given 1 eV = 1.6020 × 10 -19 J).
15. Which of the following are iso-electronic species ?
Na+, K+, Mg2+, Ca2+, S2-, Ar.
16. (i) An atomic orbital has n = 3. What are the possible values of l and m l ?
 (ii) List the quantum numbers ml and l of electron in 3rd orbital.
(iii) Which of the following orbitals are possible ?
1p, 2s, 2p and 3f.
17. Show that the circumference of the Bohr orbit for the hydrogen atom is an
integral multiple of the de Broglie wavelength associated with the electron
revolving around the orbit.
18. The work function for cesium atom is 1.9 eV. Calculate (a) the threshold
wavelength and (b) the threshold frequency of the radiation. If the cesium
element is irradiated with a wavelength 500 nm, calculate the kinetic
energy and the velocity of the ejected photoelectron.
19. Calculate the wavelength for the emission transition if it starts from the
orbit having radius 1.3225 nm and ends at 211.6 pm. Name the series to
which this transition belongs and the region of the spectrum.
20. A nickel atom can lose two electrons to form a Ni2+ ion. The atomic number
of element nickel is 28. From which orbital would the nickel lose two
electrons.
21. The unpaired electrons in Al and Si are present in the 3p orbital. Which
electrons would experience a more effective nuclear charge from the
nucleus?
22. The Balmer series in the hydrogen spectrum corresponds to the transition
from n₁ = 2 to n₂ = 3,4,… This series lies in the visible region. Calculate the
wave number of the line associated with the transition in the Balmer series
when the electron moves to n = 4 orbit. (RH = 109677 cm-¹).

In the following questions a statement of Assertion (A) followed by a statement of

Reason (R) is given. Choose the correct option out of the choices given below each
question.

23. Assertion (A): All isotopes of a given element show the same type of chemical
behaviour. Reason (R): The chemical properties of an atom are controlled by the
number of electrons in the atom.

1. Both A and R are true and R is the correct explanation of A.

 2. Both A and R are true but R is not the correct explanation of A.
3. A is true but R is false.
4. Both A and R are false.

24.. Assertion (A): Black body is an ideal body that emits and absorbs radiation of
all frequencies.

Reason (R): The frequency of radiation emitted by a body goes from a lower
frequency to a higher frequency with an increase in temperature.

25. Assertion (A): It is impossible to determine the exact position and exact
momentum of an electron simultaneously.

Reason (R): The path of an electron in an atom is clearly defined.

-------------------------------------------------All The Best ------------------------------------

23.