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Dokumen - Tips - Cbse Xii Chemistry Project Variation of Conductance With Temperature in Electrolytes
Dokumen - Tips - Cbse Xii Chemistry Project Variation of Conductance With Temperature in Electrolytes
Variation of
Conductance with
Temperature in
Electrolytes
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CBSE XII Chemistry Project Variation of Conductance With Temperature in Electrolytes
Index
1. Certificate.................................................................3
2. Acknowledgements.....................................................4
3. Aim..........................................................................5
4. Apparatus..................................................................6
5. Important Terms........................................................7
6. Conductivity...............................................................8
7. Factors Affecting Electrical Conductivity.........................9
8. Procedure.................................................................10
9. Physical Constants.....................................................11
10. Observation Set
1.....................................................12
11. Graph of Observation Set
1........................................13
12. Observation Set
2.....................................................14
13. Graph of Observation Set
2........................................15
14.
Result.....................................................................16
15.
Conclusion...............................................................17
16.
Precautions..............................................................18
17.
Bibliography.............................................................19
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CBSE XII Chemistry Project Variation of Conductance With Temperature in Electrolytes
Certificate
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CBSE XII Chemistry Project Variation of Conductance With Temperature in Electrolytes
Acknowledgements
"There are times when silence speaks so much more loudly than
words of praise to only as good as belittle a person, whose words
do not express, but only put a veneer over true feelings, which
are of gratitude at this point of time."
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CBSE XII Chemistry Project Variation of Conductance With Temperature in Electrolytes
Aim
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CBSE XII Chemistry Project Variation of Conductance With Temperature in Electrolytes
Apparatus
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CBSE XII Chemistry Project Variation of Conductance With Temperature in Electrolytes
Important Terms
Faraday's Law s:
First Law: The mass of a substance produced or
consumed in electrolysis is directly proportional to the
quantity of charge passing through it.
or, mm= Z ×
QI × t
where, Z is electrochemical equivalent; I is current; t is
time in seconds; Q is charge.
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CBSE XII Chemistry Project Variation of Conductance With Temperature in Electrolytes
Conductivity
R=1/C
ρ (called 'rho')
conductivity of isthe
known as resistivity.
solution, which is Its reciprocal
denoted by gives the
κ (called
'kappa'). Its unit is Siemens/meter.
Κ=1/R*L/ A
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CBSE XII Chemistry Project Variation of Conductance With Temperature in Electrolytes
Procedure
1. The electrolyte chosen is ZnSO4 and the electrodes are of
Zn.
2. Readings for the measurement of conductance are taken at
intervals of 3 C.
3. Proper precautions are taken to avoid evaporation and to
keep other factors constant.
4. The vessel and electrodes are removed and the vessel is
cleaned and filled with ZnSO4 solution.
5. The electrodes are refitted in their original place so that
the distance between them does not change.
6. Current is passed and when the voltmeter and ammeter
show steady readings, they are noted.
7. The current is switched off.
8. It is seen that while the ammeter reading returns at once to
0 position. The voltmeter needle pauses for a while at a
9. particular reading
This reading which
indicates is back
the notedEMF
down.
in the electrolyte.
10. Similarly, more sets of reading are taken, and resistance is
calculated.
11. Thus, the value of conductance is calculated.
12. The switched on circuit readings in voltmeter and ammeter
are taken.
13. The current through the electrolyte is changed by adjusting
the rheostat and more sets of readings are taken.
14. Thus, the mean value of resistance is calculated.
15. Above steps are repeated for CuSO4 as electrolyte with
electrodes made of Cu.
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CBSE XII Chemistry Project Variation of Conductance With Temperature in Electrolytes
Physical Constants
Voltage
Nature of electrodes
Size of electrodes
Separation between the electrodes
Concentration of the electrolytes
Nature of the electrolytes
Resistance in the circuit
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Observation Set 1
For ZnSO4 electrolyte with Zn electrodes
I V R=V/I C=1/R
-1
1 23 C 100 mA 1.0 V 10 Ω 0.100 Ω
-1
2 26 C 100 mA 0.95 V 9.5 Ω 0.105 Ω
-1
3 29 C 110 mA 0.89 V 8.09 Ω 0.120 Ω
-1
4 32 C 110 mA 0.84 V 7.63 Ω 0.130 Ω
-1
5 35 C 120 mA 0.80 V 6.66 Ω 0.150 Ω
-1
6 38 C 125 mA 0.75 V 6.00 Ω 0.160 Ω
-1
7 41 C 130 mA 0.71 V 7.6 Ω 0.180 Ω
-1
8 44 C 130 mA 0.65 V 5.00 Ω 0.200 Ω
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CBSE XII Chemistry Project Variation of Conductance With Temperature in Electrolytes
0.2
) 0.2
o 0.18
h
M 0.16
n
0.15
i( 0.15
0.13
e 0.12
c
n 0.11
a
0.1
t 0.1
c
u
d
n
o 0.05
C
0
20 25 30 35 40 45 50
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CBSE XII Chemistry Project Variation of Conductance With Temperature in Electrolytes
Observation Set 2
For CuSO4 electrolyte
I V R=V/I C = 1/R
-1
1 25 C 75 mA 1.4 V 18.67 Ω 0.053 Ω
-1
2 28 C 75 mA 1.35 V 18.00 Ω 0.055 Ω
-1
3 31 C 75 mA 1.3 V 17.33 Ω 0.057 Ω
-1
4 34 C 75 mA 1.25 V 16.67 Ω 0.060 Ω
-1
5 36 C 80 mA 1.2 V 15.00 Ω 0.066 Ω
-1
6 38 C 80 mA 1.15 V 14.38 Ω 0.069 Ω
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CBSE XII Chemistry Project Variation of Conductance With Temperature in Electrolytes
0.1
0.1
0.09
0.08
0.08 0.08
) 0.07
o
h 0.07
M 0.07
n
i(
0.06
e
c
n
0.06 0.06
0.06
0.05
ta
c
u
d
n
o
C 0.04
0.02
0
20 25 30 35 40 45 50 55
Temperature (in degree Celsius)
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CBSE XII Chemistry Project Variation of Conductance With Temperature in Electrolytes
Result
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CBSE XII Chemistry Project Variation of Conductance With Temperature in Electrolytes
Conclusion
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CBSE XII Chemistry Project Variation of Conductance With Temperature in Electrolytes
Precautions
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CBSE XII Chemistry Project Variation of Conductance With Temperature in Electrolytes
Bibliography
Websites :
http:/ / w w w .cbseportal.com
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