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CN101987937A - Super-Thick Film Anticorrosion Coating of Splash Zone Marine Steel Structure - Google Patents
CN101987937A - Super-Thick Film Anticorrosion Coating of Splash Zone Marine Steel Structure - Google Patents
Patents
Abstract
CN101987937A
The invention provides a super-thick film anticorrosion coating of a splash zone marine steel
China
structure. The super-thick film coating consists of base paint, surface paint and mat coat surface
paint, wherein the base paint is double-component epoxy base paint; the curing agent is amine; the
surface paint comprises double components A and B; and the mat coat surface paint is one of Download PDF Find Prior Art Similar
double-component acrylic surface paint, double-component fluorocarbon surface paint and organic
silicon surface paint. The super-thick film anticorrosion coating ensures that a marine steel facility Other languages: Chinese
can safely serve for more than 30 years in the severe environment of a splash zone, and has
Inventor: 崔显林, 姜秀杰, 张卫国, 张学卿, 王同良, 冷晓飞, 王志超
extremely high application value; and the surface paint is thick film epoxy surface paint, so the
construction thickness can be reached by one to two procedures, the construction process is Current Assignee : RESEARCH INST OF OCEAN CHEMISTRY
simplified and the construction expense is reduced.
Worldwide applications
2009 CN
Status Pending
1. a wave spatters the super thick film corrosion protection coating of district's ocean steel construction, and it is characterized in that: described corrosion protection coating
comprises priming paint, finish paint and cover finish paint, it is characterized in that: described finish paint is A, B two-pack;
The composition of described A component and weight percent content are Resins, epoxy 30~60%, reactive thinner 1~10%, toughner 5~20%, thixotropic agent 1~5%,
auxiliary agent 1~5%, filler 20~60%;
The composition of described B component and degree are amine curing agent 60~99%, catalyzer 1~40%;
2. corrosion protection coating according to claim 1 is characterized in that: the Resins, epoxy in the described A component is bi-component epoxy, is in E54, E51, the
F51 epoxy one or more, above-mentioned epoxy viscosity≤13PaS; Amine curing agent in the described B component is one or more in polymeric amide, amido amine,
aliphatic amide, the aliphatic cyclic amine; Catalyzer in the described B component is DMP-30 or cashew nut oil modified phenolic aldehyde amine.
3. corrosion protection coating according to claim 2 is characterized in that: the thixotropic agent in the described A component is hydrogenated castor oil,
organobentonite, aerosil, polyamide wax or contains in functional group's liquid acrylonitrile butadiene rubber one or more.
4. corrosion protection coating according to claim 3 is characterized in that: the filler in the described A component is one or more in barium sulfate, talcum powder,
silicon powder, mica powder and/or the glass flake.
5. corrosion protection coating according to claim 4 is characterized in that: the toughner in the described A component is to contain the toughness reinforcing epoxy of
polypropylene glycol or among the CTBN one or more in urethane, polypropylene glycol glycidyl ether or the initiator.
6. corrosion protection coating according to claim 5 is characterized in that: the reactive thinner in the described A component is a glycidyl ether; Auxiliary agent in the
described A component is one or more in defoamer, wetting dispersing agent, the flow agent.
7. corrosion protection coating according to claim 6 is characterized in that: the coating thickness of described finish paint is 300~3000 μ m.
8. corrosion protection coating according to claim 7 is characterized in that: described finish paint adopts Airless spraying equipment to construct, 5~10% of
interpolation A component+B component total amount epoxide diluent dilution during spraying application.
9. corrosion protection coating according to claim 7 is characterized in that: described priming paint is bi-component epoxy, and solidifying agent is an amine, and
described Resins, epoxy is E51, E44, E42 liquid epoxy, and/or in 601,604 solids epoxies one or more; Described amine curing agent is one or more in polymeric amide,
amido amine, aliphatic amide, the aliphatic cyclic amine; The coating thickness of described priming paint is 50~200 μ m.
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10/1/23, 3:35 PM CN101987937A - Super-thick film anticorrosion coating of splash zone marine steel structure - Google Patents
10. according to the described corrosion protection coating of claim 9, it is characterized in that: described cover finish paint is wherein a kind of in bi-component acrylic
finish paint, two-component fluorine carbon finishing paint or the organosilicon finish paint, and the coating thickness of described cover finish paint is 50~200 μ m.
Description
Wave spatters the super thick film corrosion protection coating of district's ocean steel construction
Technical field
The present invention the invention belongs to corrosion protection coating, specifically, relates to a kind of wave and spatters the super thick film corrosion protection
coating of district's ocean steel construction.
Background technology
Ocean environment is very harsh corrosive environment, and the steel construction facility that is exposed in the ocean environment very easily is subjected to heavy
corrosion with surrounding medium generation electrochemical reaction, particularly spatters the district at wave.This zone is the harshest ocean environment, because
seawater splashes, alternation of wetting and drying and ultraviolet ray ageing, corrosion protection coating are difficult to keep, and corrode the most serious.At present,
wave spatter the district ocean steel construction corrosionproof protection generally adopt the bituminous epoxy system.Make priming paint with epoxy zinc-rich,
bituminous epoxy is made finish paint, and through repeatedly application, thickness reaches 300~500 μ m.Its main drawback is: 1. long construction period, expense
height; 2. contain strong carcinogenic coal tar pitch, big to human body harm; 3. VOC content height; 4. impact resistance is poor, damages easily.In order to improve the
work-ing life of corrosion protection coating, prolong maintenance cycle, save expensive maintenance expense, guarantee that facility normally moves, prolong the work-
ing life of steel construction facility, be necessary to spatter the corrodible property in district, supporting coating system is carried out specialized designs according to
wave.
The invention provides a kind of wave and spatter the super thick film corrosion protection coating of district's ocean steel construction; should form by priming paint,
finish paint and cover finish paint by super thick film coating; cooperate underwater cathode protection, be applied to the anti-corrosion protection that wave spatters
district's ocean steel construction, can reach good preservative effect.
In order to reach the purpose that solves the problems of the technologies described above, technical scheme of the present invention is, a kind of wave spatters the
super thick film corrosion protection coating of district's ocean steel construction, and it is characterized in that: described corrosion protection coating comprises
priming paint, finish paint and cover finish paint, it is characterized in that: described finish paint is A, B two-pack;
The composition of described A component and weight percent content are Resins, epoxy 30~60%, reactive thinner 1~10%, toughner 5~20%, thixotropic agent 1~5%,
auxiliary agent 1~5%, filler 20~60%;
The composition of described B component and degree are amine curing agent 60~99%, catalyzer 1~40%;
Resins, epoxy in the described A component is bi-component epoxy, is in E54, E51, the F51 epoxy one or more, above-mentioned epoxy viscosity≤13PaS; Amine curing
agent in the described B component is one or more in polymeric amide, amido amine, aliphatic amide, the aliphatic cyclic amine; Catalyzer in the described B component
is DMP-30 or cashew nut oil modified phenolic aldehyde amine.
Thixotropic agent in the described A component is hydrogenated castor oil, organobentonite, aerosil, polyamide wax or contains in functional group's liquid acrylonitrile
butadiene rubber one or more.
Filler in the described A component is one or more in barium sulfate, talcum powder, silicon powder, mica powder and/or the glass flake.
Toughner in the described A component is to contain the toughness reinforcing epoxy of polypropylene glycol or among the CTBN one or more in urethane, polypropylene
glycol glycidyl ether or the initiator.
Reactive thinner in the described A component is a glycidyl ether; Auxiliary agent in the described A component is one or more in defoamer, wetting dispersing agent, the
flow agent.
Described finish paint adopts Airless spraying equipment to construct, and can add 5~10% epoxide diluent dilution of A component+B component total amount during
spraying application.
Described priming paint is bi-component epoxy, and solidifying agent is an amine, and described Resins, epoxy is E51, E44, E42 liquid epoxy, and/or in 601,604 solids
epoxies one or more; Described amine curing agent is one or more in polymeric amide, amido amine, aliphatic amide, the aliphatic cyclic amine; The coating thickness of
described priming paint is 50~200 μ m.
Described cover finish paint is wherein a kind of in bi-component acrylic finish paint, two-component fluorine carbon finishing paint or the organosilicon finish paint, and
the coating thickness of described cover finish paint is 50~200 μ m.
The super thick film corrosion protection coating of the present invention is exclusively used in the anti-corrosion protection that wave spatters district's ocean steel
construction, and the galvanic protection of hydrous water inferior segment is to satisfy the corrosion protection design of the large-scale iron and steel facility in ocean
more than 30 years
Wherein, 1) priming paint adopts bi-component epoxy, be in liquid epoxies and/or 601 such as E51, E44, E42, the solids epoxies such as 604 one or more, solidifying
agent is one or more in the middle of polymeric amide, amido amine, aliphatic amide, the aliphatic cyclic amine, coating thickness is 50~200 μ m, and the steel
construction of coating need carry out sandblasting or grinding process.
Priming paint can adopt toughner to carry out toughening modifying, to improve the sticking power of priming paint to steel construction.Toughner is one or more in the
middle of urethane, polypropylene glycol glycidyl ether, the CTBN.
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10/1/23, 3:35 PM CN101987937A - Super-thick film anticorrosion coating of splash zone marine steel structure - Google Patents
Priming paint adopts the anti-corrosion primer of epoxy zinc rich primer or other types.The filler of epoxy zinc rich primer mainly adopts zinc powder; The filler of the anti-
corrosion primer of other types can adopt one or both rust-stabilising pigments in the middle of zinc phosphate, iron mica, the aluminium triphosphate.
2) finish paint is A, B bi-component epoxy, select in the less small molecules epoxy of viscosity ratio such as E54, E51, F51 one or more for use, and urethane,
polypropylene glycol glycidyl ether have been added, or contain one or more toughner in the middle of the toughness reinforcing epoxy, the toughness reinforcing Resins,
epoxy of organosilicon etc. of polypropylene glycol in the initiator, or match with other high viscosity toughner, toughness reinforcing etc. as CTBN;
Solidifying agent is one or more in the middle of polymeric amide, amido amine, aliphatic amide, the aliphatic cyclic amine.Filler is one or more in barium sulfate, talcum
powder, silicon powder, mica powder and/or the glass flake.
Thixotropic agent is hydrogenated castor oil, organobentonite, aerosil, polyamide wax, contain in the middle of the liquid acrylonitrile butadiene rubber of functional group
one or more, so that high thixotropic property to be provided, is convenient to the thick film application.And contain auxiliary agents such as reactive thinner, defoamer,
wetting dispersing agent, flow agent.The coating thickness of finish paint is 300~3000 μ m.
Wherein the composition of A component and degree are, Resins, epoxy 30~60%; Reactive thinner 1~10%; Toughner 5~20%; Thixotropic agent 1~5%; Auxiliary agent 1
~5%; Filler 20~60%.The composition of B component and degree are amine curing agent 60~99%; Catalyzer 1~40%.
Finish paint can adopt Airless spraying equipment to construct, and can add 5~10% thinner dilution during spraying application as required.
3) the cover finish paint is a kind of in bi-component acrylic finish paint, two-component fluorine carbon finishing paint or the organopolysiloxane finish paint, and coating
thickness is 50~200 μ m.
The present invention is used for protecting ocean steel facilities to spatter the harsh and unforgiving environments in district at wave, can be on active service safely
more than 30 years, has high using value; and finish paint adopts the thick film epoxy; 1~2 road can reach construction thickness, has simplified construction
technology, has reduced executive cost.
Embodiment
For better explanation the present invention, the spy enumerates following embodiment, but the present invention is not limited only to following embodiment.
Priming paint
Embodiment 1
A component: 601 epoxies 16%, zinc powder 48%, organobentonite 1%, dimethylbenzene 25%, pimelinketone 10%;
The A component: the B component is 4: 1, and volume ratio is solidified, and coating thickness is 50~80 μ m.
Embodiment 2
A component: 601 epoxies 12%, polyurethane modified epoxy 4%, zinc powder 40%, ferrophosphorus powder 8%, organobentonite 1%, dimethylbenzene 25%,
pimelinketone 10%;
The A component: the B component is 4: 1, and volume ratio is solidified, and coating thickness is 50~80 μ m.
Embodiment 3
A component: 601 epoxies 28%, zinc phosphate 20%, aluminium triphosphate 10%, iron mica 20%, organobentonite 1%, other auxiliary agents 1%, dimethylbenzene 10%,
pimelinketone 10%;
The A component: the B component is 5: 1, and weight ratio is solidified, and coating thickness is 80~150 μ m.
Embodiment 4
A component: 601 epoxies 20%, polyurethane modified epoxy 5%, zinc phosphate 23%, aluminium triphosphate 10%, iron mica 20%, organobentonite 1%, other auxiliary
agents 1%, dimethylbenzene 10%, pimelinketone 10%;
The A component: the B component is 5: 1, and weight ratio is solidified, and coating thickness is 80~150 μ m.
Finish paint
A component: E51 epoxy 30%, F51 epoxy 10%, polyurethane toughened dose 6%, polypropylene glycol glycidyl ether 4%, 5748 reactive thinners 2%, barium sulfate 28%,
mica powder 6.4%, titanium dioxide 10%, aerosil 1%, organobentonite 1%, dispersion agent 0.3%, defoamer 1%, flow agent 0.3%;
The B component: amido amine 82%, DMP-30 3%, amino terminated butadiene acrylonitrile rubber 15%
Embodiment 2
A component: E54 epoxy 40%, CTBN modified epoxy 6%, polypropylene glycol glycidyl ether 4%, 5748 reactive thinner 2%, silicon powder 34.4%, titanium dioxide 10%,
aerosil 1%, organobentonite 1%, dispersion agent 0.3%, defoamer 1%, flow agent 0.3%;
B component: modified fatty amine 60%, modification aliphatic cyclic amine 40%;
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10/1/23, 3:35 PM CN101987937A - Super-thick film anticorrosion coating of splash zone marine steel structure - Google Patents
The A component: the B component is 4: 1, and weight ratio is solidified.
A component: E51 epoxy 40%, polyurethane toughened dose 6%, polypropylene glycol glycidyl ether 4%, 5748 reactive thinner 2%, barium sulfate 27%, talcum powder
7.4%, titanium dioxide 10%, aerosil 1.4%, hydrogenated castor oil 0.6%, dispersion agent 0.3%, defoamer 1%, flow agent 0.3%;
The B component: amido amine 62%, polymeric amide 20%, DMP-30 3%, amino terminated butadiene acrylonitrile rubber 15%;
A component: E51 epoxy 50%, polyurethane toughened dose 6%, polypropylene glycol glycidyl ether 4%, 5748 reactive thinner 2%, barium sulfate 24.4%, titanium dioxide
10%, aerosil 1%, organobentonite 1%, dispersion agent 0.3%, defoamer 1%, flow agent 0.3%;
B component: amido amine 65%, cashew nut oil modified phenolic aldehyde amine 20%, amino terminated butadiene acrylonitrile rubber 15%
A component: E51 epoxy 40%, polyurethane toughened dose 6%, polypropylene glycol glycidyl ether 4%, 5748 reactive thinner 2%, barium sulfate 24.4%, glass flake 10%,
titanium dioxide 10%, aerosil 1%, polyamide wax 1%, dispersion agent 0.3%, defoamer 1%, flow agent 0.3%;
The B component: polymeric amide 52%, modified fatty amine 30%, DMP-30 3%, amino terminated butadiene acrylonitrile rubber 15%
In the above-described embodiments, the Resins, epoxy viscosity in the A component all≤13PaS.
Above-mentioned finish paint embodiment 1~5 all can adopt Airless spraying equipment to construct, and can add 5~10% the epoxide diluent dilution of A
component+B component total amount during embodiment 1~4 spraying application, and per pass all can reach 1000 μ m.Embodiment 5 can add 10~20% epoxide
diluent dilution because viscosity is big slightly during spraying application, per pass can reach 500 μ m.And existing bituminous epoxy protective system, even
application 500 μ m also will spray 5~7 roads.Increase executive cost greatly, and prolonged construction period.
The model of spraying embodiment priming paint, spray paint embodiment 1~4 again, and 2 roads, coating thickness are about 2000 μ m; Embodiment 5,2 roads,
coating thickness are about 1000 μ m, contrast as following table with contrast model (the 500 μ m) resistance to impact shock that sprays 6 road bituminous epoxy
protective systems, acceleration sea water resistance, 5000 hours salt-fog resistant test results:
Super thick film epoxy The bituminous epoxy protective Resistance to impact shock
Test event ≥2 ≥0.3
coating system (Kgm)
Quicken sea water resistance (40 Do not pass
6 months, no change 3 months, bubbling 5000 hours salt spray resistances By
℃) through
As can be seen from the above table, the shock resistance of super thick film epoxy coating and acceleration sea water resistance, salt spray resistance all are better
than the bituminous epoxy protective system.
Embodiment 1
A component: acrylic resin 34%, titanium dioxide 20%, barium sulfate 20%, auxiliary agent 2%, dimethylbenzene 10%, N-BUTYL ACETATE 14%;
B component: 3195 solidifying agent 70%, dimethylbenzene 20%, N-BUTYL ACETATE 10%;
The A component: the B component is 4: 1, and weight ratio is solidified, and coating thickness is 50~150 μ m.
A component: fluorocarbon resin 34%, titanium dioxide 20%, barium sulfate 20%, auxiliary agent 2%, dimethylbenzene 10%, N-BUTYL ACETATE, 14%;
B component: 3195 solidifying agent 70%, dimethylbenzene 20%, N-BUTYL ACETATE, 10%;
The A component: the B component is 4: 1, and weight ratio is solidified, and coating thickness is 50~150 μ m.
A component: epoxy silicone resin 38%, titanium dioxide 20%, barium sulfate 20%, auxiliary agent 2%, dimethylbenzene 10%, N-BUTYL ACETATE 10%;
B component: aminosilane;
The A component: the B component is 7: 1, and weight ratio is solidified, and coating thickness is 50~200 μ m.
Experiment shows, the model of spraying embodiment priming paint, and spray paint sprays cover finish paint embodiment 1~3 at last again, tans by the sun the surface
through outdoor 2 years and powder phenomenon-tion do not occur, and the contrast model that is not coated with the cover finish paint then breaks up more serious.
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CN101397472A * 2007-09-26 2009-04-01 洛阳七维防腐工程材料有限公司 Thick paste type epoxy heavy duty paint capable of spraying
Title
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10/1/23, 3:35 PM CN101987937A - Super-thick film anticorrosion coating of splash zone marine steel structure - Google Patents
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Legal Events
2013-10-30 RJ01 Rejection of invention patent application after publication Application publication date: 20110323
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