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RESEARCH ARTICLE
Introduction
way its formability, ductility and impact toughness
Regulations imposed to reduce fuel consumption, and [7–12].
their corresponding effect on emission of green-house An alternative to casting in conventional moulds is
gases, in light and heavy-duty vehicles, have promoted that of thin-slab casting in which the steel is poured
the development of materials with enhanced mechan- into moulds that produce slabs that range from 50 to
ical properties that are used in the manufacture of 90 mm in thickness, in contrast to conventional moulds
structural components. Such improvement in fuel con- that produce slabs of 250–350 mm. The faster solid-
sumption will result as consequence in diminishing ification rate that takes place within thinner sections
the weight and size of components manufactured with promotes microstructural refining and the reduction of
better and stronger materials [1,2]. The iron and steel the central line segregation [13–15]. A further advan-
industry has responded by offering advanced high- tage that the thin-slab casting technology offers is the
strength steels (AHSS), in which chemical composition reduction of size of the processing line by connect-
and processing conditions are tailored to obtain vari- ing the caster with continuous reheating furnaces and
ous microstructures made of a wide range hard and soft the rolling-mill [15–18]. The surface quality of the
components that are responsible for enhancing their rolled strip is assured by the design of descaling prac-
strength [3,4]. tice that takes place before the stock enters the rolling
AHSS are cast, hot-rolled, cooled in the run-out table mill [18].
and coiled [3,4]. Most of these steels are cast in conven- The aim of this work is to study the behaviour of
tional moulds where the surface freezes rapidly, while samples from two different AHSS produced by the
the centre solidifies at a lower rate. Such differences in thin-slab route; the microstructure was analysed by
cooling and solidification rates promote the enrichment microscopical techniques, their mechanical behaviour
of alloying elements towards the centre of the slab in was studied by means of tension tests conducted along
what is known as central segregation, or macrosegre- three different directions in hot-rolled sheets. The
gation, that cannot be removed from the final product stress–strain curves were fitted to different constitu-
due to the high temperatures and long times required tive equations. This study was conducted as these steels
to homogenise the steel by diffusion [5,6]. It has been are demanded by the automotive industry to reduce
reported that central segregation enhances the yield and the weight and fuel consumption of vehicles without
ultimate strength of the steel, but affects in a negative affecting safety uses.
CONTACT Rafael Colás colas.rafael@gmail.com Facultad de Ingeniería Mecánica y Eléctrica, Universidad Autónoma de Nuevo León, 66455 San
Nicolás de los Garza, México
Figure 1. LOM images of steels A and B at their centre (C) and close to the surface of the strip (S) at different magnifications. The
rolling direction and a cuboid particle towards the centre of steel B are indicated.
Each curve was fit to equations of the power type The values of strain and stress corresponding to the
proposed by Hollomon [28]: yield and UTS for each testing condition are indicated
in their corresponding curve; two points are associ-
σ = k · εn (1) ated to yielding in steel B, Figure 5, due to the Lüders
effect that is observed in the stress–strain curves, the
where σ is the stress, ε the strain, and n and k are the
first one corresponds to what is called the lower yield
straining exponent and coefficient that are obtained by
point, whereas the second one is plotted where proper
fitting the plastic deformation region, Figures 7 and
homogeneous deformation starts (ε l ); Lüders effect is
8. Each experimental curve was also fit to exponential
associated in carbon steels to the interaction of intersti-
relationship proposed by Voce [29]:
tial atoms and dislocations and is known as strain aging
σ = σo + (σs − σo ) exp(−Cε) (2) [30,31]. Figures 5 and 6 show the straight lines that are
obtained by fitting stress–strain data in a double log-
where σ s is the saturation or steady state stress, σ o arithm plot to obtain the parameters of Equation (1).
the yield strength and C a coefficient determined from The strain domain for these adjustments was that from
the experimental data. The dashed curves adjusted to yielding to UTS in the case of steel A and from the start
Equations (1) and (2) are shown together with the of homogeneous deformation (ε l ) to UTS in the case of
experimental ones. steel B.
330 F. A. PÉREZ-GONZÁLEZ ET AL.
Figure 2. SEM images of steels A and B at their centre (C) and close to the surface of the strip (S). The constituents indicated
correspond to ferrite (F), bainite (B) and martensite (M); the rolling direction is indicated.
The value of the hardening rate (dσ /dε) is plotted the required characteristics, although the carbon con-
as a function of the stress for each experimental con- tent is kept well below that of the peritectic reaction
dition, Figure 9. This relationship yields to curves that [24,25], Table 1. Steel A contains higher amounts of Cr
exhibit a continuous decrease in hardening rate as the and Mo to enhance the transformation of austenite into
stress increases; a straight line in the dσ /dε – σ relation- bainite and martensite on cooling. Ti is added to Steel
ship was adjusted as the curve approaches Considère’s B to promote the formation of TiN; the amount of both
criterion expressed by dσ /dε = σ [31]. The slope of elements is such that will promote precipitation of TiN
this straight line is equal to parameter C in Equation (2), in the melt before the formation of δ-ferrite. Figure 10
the strength at which dσ /dε = 0 is the saturation stress shows the transformations that would occur during
σ s , which is indicated by small arrows in Figure 9. solidification due to the chemistry of the steels. These
The values for yield stress (σ y ), ultimate tensile transformations were predicted by a thermodynamic
strength (σ u ), uniform elongation strain (ε u ), strain to and kinetics-based software [20]; the simulation was
the end of Lüders effect (ε l , only for steel B), elonga- ended at 1400°C. The critical temperatures for the reac-
tion (l) and reduction in area (RA) to fracture, as well tions taking place during solidification are summarised
as those for n, k, σ o , σ s , and C are shown in Table 3. in Table 4.
It should be mentioned that n and ε u should be equal Start of precipitation of TiN was predicted at 1481.0
for a material that fulfils Hollomon’s equation (1), in and 1530.8°C for steels A and B, respectively, which fall
agreement with Considère’s criterion [32]. within the range computed from the solubility products
given by equations of the type:
Figure 3. Images from steels A and B in regions close to the surface (S) and centre (C) of the strips. The analyses put in evidence the
presence of ferrite, martensite and carbides. The rolling direction (RD) is indicated.
Table 2. Microstructural constituents measured by SEM and a function of the cooling rate, identified as Fs , Ps and
EBSD. Bs , respectively, and at which the transformation to
Steel Location Constituent SEM EBSD pearlite and bainite finish, Pf and Bf , respectively. The
A Centre F 0.60 0.756 CCT diagrams for both compositions are shown in
B 0.30 – Figure 11. The critical temperatures (A1 , A3 and Ms )
M 0.10 0.179
C – 0.064 are shown in this figure and in Table 5. The greater
Surface F 0.70 0.705 content in alloying elements in steel A promotes the
B 0.25 –
M 0.05 0.164 shifts of curves corresponding to Fs , Ps , Bs , Pf and
C – 0.053 Bf to higher times and would result in delaying the
B Centre F 0.25 0.571 occurrence of such microstructures. The CCT diagram
B 0.70 –
M 0.05 0.125 was calculated using a finish rolling temperature of
C – 0.303 900°C and an austenite grain size of 20 μm, which were
Surface F 0.24 0.665
B 0.68 – the values predicted by modelling hot rolling of steel
M 0.08 0.158 [16,21,22]. The cooling curves at the surface and cen-
C – 0.177
tre of a 3.6 mm strip are shown in Figure 11. These
Note: Ferrite (F), Bainite (B), Martensite (M), Carbides (C).
curves were obtained from a heat transfer model devel-
oped to compute the temperature distribution within
β are equilibrium coefficients. Table 5 shows the tem- steel strips that are being cooled within a run-out table
peratures calculated from the chemical composition of [17]; the cooling time in the run-out table was set as
the steel using the coefficients reported by different 30 s; coiling was predicted to occur at 593°C. These
authors [33–36]. results confirm the microscopical observations shown
The transformation of the strips during the run- in Figures 1–3 and in Table 2 in the sense that both steels
out table cooling was simulated with the aid of the will transform into a mixed microstructure made of fer-
software mentioned above [20] feeding their composi- rite, bainite and martensite; the highest alloying content
tions. The software predicts the temperatures at which of steel A will result in a higher amount of martensite in
transformation to ferrite, pearlite and bainite start as comparison with steel B, as it is presented in Table 2. No
332 F. A. PÉREZ-GONZÁLEZ ET AL.
Figure 4. SE images of samples of steels A and B at their centre (C) and close to the surface (S) together with EDX area analyses that
show the absence of central segregation.
Figure 5. Stress–strain curves from samples from steel A cut Figure 6. Stress–strain curves from samples from steel B cut
and tested at 0 (a), 45 (b) and 90° (c) with respect to the rolling and tested at 0 (a), 45 (b) and 90° (c) with respect to the rolling
direction (full lines); the dotted curves correspond to their fitting direction (full lines); the dotted curves correspond to their fitting
to equations (1) and (2). to equations (1) and (2). The end of Lüders strain is indicated as
εl .
Figure 8. Double logarithm plot of the stress–strain values to Figure 10. Solidification reactions for A and B steels as pre-
obtain the n and k parameters of equation (1) for steel B. The dicted by the thermodynamic and kinetics-based software.
end of Lüders strain is indicated as ε l .
Table 5. Temperatures for start of precipitation of TiN for steels the samples tested in the transverse direction to rolling
A and B. (90°). Figure 17 shows that yielding occurs at a lower
Coefficients in Equqation (3) Steel stress in steel A in comparison to the other material,
Authors α β A B but its strengthening to the UTS value is much higher.
Turkdogan [32] 15,790 5.40 1414.9 1632.4 Figure 18 compares the values of the strain and stress to
Kunze [33] 17,640 6.17 1469.3 1674.7 the point of maximum load of the steels studied in this
Cui et al. [34]
Capurro and Cicutti [35]
16,586
17,040
5.90
6.40
1410.1
1372.6
1614.6
1561.8
work (A and B) with unpublished results of steel sam-
ples obtained from sheets obtained from conventional,
thick, slabs, it can be appreciated that the data points
follow a similar behaviour.
Figures 5 and 6 show the experimental stress–strain
curves for both steels and their fitting to constitu-
tive equations of the power and exponential type.
Figure 5 shows that fitting the data to power relation-
ship, Equation (1), does only agree within a short strain
domain, whereas that to exponential type (2) agrees
over the yielding to UTS straining domain. Moreover,
Equation (2) has been justified in terms of the changes
that take over dislocation arrangement as a result of the
equilibrium between the dislocations being created to
sustain the plastic deformation and their annihilation
by restoration mechanisms [38–40] and has been used
in analyses of plastic deformation in complex multi-
Figure 11. Continuous cooling transformation for steels A and
B and the computed temperatures at the centre and surface of phase steels [41–43]. Use of power type of equation (1)
the strip using the model described elsewhere [16]. has been criticised by their limitations in covering the
full range of plastic strain and that they predict infinite
strength [44]. In some cases, the stress–strain curve has
been fitted into various segments, each with different
values for parameters k and n [45,46]. Figure 6 shows
that both types of equations fit with accuracy the exper-
imental data once the Lüders strain has been surpassed.
The proximity of the values of exponent n and that for
the strain to the UTS in this steel confirm the fitting
of this material to power type equations. In all cases,
the fittings to either equation between the yield point
and the end of Lüders strain are underestimated. The
biggest divergence occurs in the case of Equation (2),
as parameter σ o is lower than the yield strength (σ y ),
Table 3. Such difference may point to the strengthening
that results in steel B due to the amount of nitrogen and
Figure 12. EDX spectrum of a TiN particle found towards the carbon in solution, rather than combined with titanium
centre of strip B. or other alloying elements.
Figure 13. TiN precipitates in samples from steels A (a and b) and B (c and d) close to the centre (a and c) or surface (b and d) of the
strips. The straight lines connect the closest neighbours.
Figure 14. Particle area distribution of TiN precipitates found in Figure 15. Temperatures for the precipitation of TiN as a func-
steels A and B. tion of their contents as calculated with the coefficients pro-
posed by Turkdogan [31]. The points corresponding to steels A
and B are shown. The solidification temperature of 1538° for iron
is indicated [23].
Disclosure statement
No potential conflict of interest was reported by the author(s).
ORCID
Rafael Colás http://orcid.org/0000-0001-6017-7244
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