CHEMISTRY

CLASSIFICATION AND NOMENCALATURE OF ORGANIC COMPOUNDS

1. Which one of the following is heterocyclic compound 11. The compound CH3COOCH2CH3 belongs to the
(1) Pyren (2) Thiophene class
(3) Phenol (4) Aniline (1) alkane (2) alkanones
2. Which one of the following compounds does not (3) alkyl alkanoate (4) alkanediol
contain OH gtoup 12. The correct name of CH3 CH2 CH2 is
(1) alcohol (2) carboxylic acid
C C CH
(3) aldehyde (4) phenol
(1) Hex–3–yn–5–ene (2) Hex–5–en–3–yne
3. What is the name of the following alkyl group
(3) Hex–3–yn–1–ene (4) Hex–1–en–3–yne
(CH3–)2 CH–
13. Which of the following compounds has isopropyl
(1) normal propyl (2) Isopropyl
group
(3) Sec. propyl (4) tert-propyl
(1) 2,2,3,3-tetramethyl pentane
4. Which group is always taken as a substituent in
(2) 2,2-dimethyl pentane
IUPAC nomenclature.
(3) 2,2,3-trimethyl pentane

LS
(1) – NH2 (2) – CN (4) 2-methyl pentane
(3) – NO2 (4) C O 14. When two halogen atoms are linked to same carbon

IA
5. The alkane which has only primary hydrogen atoms atom, the dihaloalkane is called
is (1) alkylidene halide (2) alkylene dihalide
(1) Pentane (2) Isopentane R (3) alkyl halide (4) alkane dihalide
TO
(3) Neopentane (4) 2, 2-dimethyl pentane 15. The IUPAC name of the compound CH3CONHBr
6. The IUPAC name of follwoing compound is is
U

CH2 = CH – CH (CH3)2 (1) 1-bromoacetamide

(2) ethanoyl bromide
T

(1) 3-methyl-1-butene
(2) 2-vinyl propane (3) N-bromoethanamide
JI

(3) 1-isopropyl ethylene (4) none of these

(4) 1, 1-dimethyl-2-propene
LA

16. The IUPAC name of C2H 5 O is :

7. The structure of 4-methyl-2-penten-1-ol is C O
(1) (CH3)2C = CHCH2CH2OH CH3 CH
A

(2) (CH3)2CHCH = CHCH2OH CH3

B

(3) CH3CH2CH = CHCH2OH

(1) ethoxy methanone
(4) CH3CHOHCH = C(CH3)2
(2) ethyl-2-methyl propanoate
8. The IUPAC name of Cl3CCH2CHO is : (3) ethoxy propanone
(1) Chloral (4) 2-methyl ethoxy propanone
(2) 3, 3, 3-trichloropropanal 17. The IUPAC name of (CH3)3 C – CH = CH2 is :
(3) 1, 1, 1-trichloropropanal
(1) 2,2-dimethyl but-1- ene
(4) 2, 2, 2-trichloropropanol
(2) 2,2-dimethyl pent-4-ene
9. The IUPAC name of the following compound is (3) 3,3-dimethyl but-1-ene
CH3 – CH2 – CH = CH – C  CH (4) Hex-l-ene
(1) Hex – yn –3–ene (2) Hex–5–yn–3-ene O OH
(3) Hex–3–en–yne (4) Hex–3–en–5–yne
18. The IUPAC name of CH3 C CH2 CH CHO
10. The formula of propanenitrile is
is
(1) CH 3CN (2) C 2H 5CN
(1) 5-oxo-4-hydroxy -2-pentanone
(3) C 3H 7CN (4) C 2H 5NC
(2) 4-hydroxy-5-al-2-pentanone
(3) 2-hydroxy-4-oxo pentanal
(4) 1-al-4-oxo-2-pentanal

CHEMISTRY CLASSES ANKUR SIR 7983744732

19. The IUPAC name of (3) 2-ethyl pentanol
CH3 (4) 3-ethyl butanol-1
CH3 CH2 CH C CH3 is
26. IUPAC name of compound OH is
CH3 C 4H 9 CH3
(1) 3, 4,4-trimethyl heptane
(1) 5-methyl hexanol
(2) 3,4,4-trimethyl octane
(2) 2-methyl hexanol
(3) 2-butyl-2-methyl -3- ethyl butane
(3) 2-methyl hen-3-enol
(4) 2-ethyl-3, 3-dimethyl heptane
(4) 4-methyl pent-2-enol
HO
O
20. The IUPAC name of compound is
27. The IUPAC name of N is
(1) 3, 4-dimethyl but-2-en-4-ol
(2) 3-methyl pent-2-en-4-01 (1) 2-oxo-1-N, N-dimethyl butanamine
(3) 3-methyl pent-3-en-2-ol (2) 3-keto-N-methyl pentanamine
(4) 1,2-ethyl-dimethyl-but-2-en-1-ol (3) N, N-dimethylbutanamide
21. Which of the following is an aromatic heterocyclic (4) N, N-dimethyl butanamine
compound 28. The IUPAC name of acrylonitrile is

LS
(1) 2-propene-1-nitrile (2) 2-propene-2-nitrile
(1) (2) (3) propane-nitrile (4) none of these

IA
O O 29. The correct IUPAC name of (C6H5–)4 is
(1) neophenyl
R (2) quarternary phenyl
TO
(3) (4)
(3) 3,3-diphenyl dodecane
N (4) tetraphenyl methane
U

H 30. CH3 CH C CH3 has the IUPAC name

T

22. The IUPAC name of compound O

(1) -cyclopropyl-2-butanone
JI

O = CH – CH2 – CH2 – CH2 – CH2 is

(2) 3-cyclopropyl butan-2-one
LA

COOH (3) 2-cyclopropyl-3-butanone

(1) 5-carboxy -1-pentanal (4) None of these
(2) 5-oxopentanoic acid
A

(3) 5-aldo pentanoic acid 31. has IUPAC name

O
B

(4) none of these (1) 3-methyl hept-6-en-2-one

23. The IUPAC name of the keto form of phenol is (2) 5-methyl hept-2-en-6-one
(1) cyclohex-2, 4-dien-1-one (3) 4-allyl-3-methyl butan-2-one
(2) cyclohex-1, 3-dien-1-one (4) 4-methyl-hept-1-en-2-one
(3) cyclohex-3, 4-dien-1-one 32. The name of enol form of ethanal will be
(4) none of these (1) Allyl alcohol (2) Carbinol
(3) vinyl alcohol (4) methyl carbinol
24. The IUPAC name for is 33. According to IUPAC system the compound
O OCH3
(1) 3-ethyl-methoxy pentan-2-one COOH
(2) methyl-4-keto-3-ethyl butyl ether HOOC CH2 C CH2 COOH can be named as
(3) methyl-2-ethyl butanoate
OH
(4) None of these
(1) 2-hydroxy propan-1, 2, 3-tricarboxylic acid
25. IUPAC name of the compound (C2H5)2 CHCH2OH
is (2) 2-hydroxy-2-carboxy pentanedioic acid
(3) 2-hydroxy-2-carboxy pentanedioic
(1) 2-ethyl butan-1-O1
(4) Citric acid
(2) 2-methyl pentan-1-O1

CHEMISTRY CLASSES ANKUR SIR 7983744732

34. The IUPAC name of isoprene is 42. The IUPAC name of the compound
(1) 2-methyl but-1, 3-diene CH3 C CH CH2 COOH is
(2) 3-methyl but-1, 3-diene
(3) 3-chloro but-1, 3-diene OH
(4) none of these (1) Hydroxy pentanoic acid
(2) 4-hydroxy-3-pentanoic acid
35. The IUPAC name of compound
(3) 4-hydroxy-4-pentanoic acid
Cl – CH CH2 – CH2 – Cl is (4) 4-hydroxy-4-methyl-ene pentanoic acid
CH3 43. The compound which contains all the four 1o, 2o, 3o
and 4o carbon atoms is
(1) 1-1-chloro ethyl-4-chloro ethyl cyclohexane
(2) 1-(1-chloroethyl)-4-(2-chloro ethyl) cyclohexane (1) 2, 3-dimethyl pentane
(3) Dichloro ethyl cyclohexane (2) 3-ethyl-2, 2-dimethyl pentane
(4) 1, 4-dichloro ethyl cyclo-hexane (3) 2, 3, 4-trimethyl pentane
(4) 3, 3-dimethyl pentane
36. The IUPAC name of propargyl alcohol is
44. The IUPAC name for the compound
(1) Prop-2-yn-1-ol (2) But-1-yn-2-ol
(3) But-2-yn-1-ol (4) none of these O OH

is
NH2

LS
37. The correct name of the structure is O
(1) 3-carboxamido pent-3-enx-1-oic acid
(1) 2-(31-methyl cyclopentyl) cyclobutane (2) 3-carboxa-midyl pent-3-en-1-oic acid

IA
(2) 1-cyclobutyl-3-methyl cyclopentane (3) 3-carbomoyl pent 3-en-1-oic acid
(3) 1-methyl cyclopentyl cyclopentane (4) 3-carbomoylpent-2-en-1-oic acid
(4) none of these R
TO
38. The IUPAC name of 45. The correct IUPAC name for the structure

(H2C = CH)2 CHCH2CH = CH–CH3 is (1) Prop-1, 2-diyne (2) Prop-1, 2-diene
(3) Prop-1, 3-diyne (4) None of these
U

(1) 2-ethanyl-1, 4-heptadiene

(2) 1, 1-bis-(vinyl) pent-3-ene O
T

(3) 3-ethanyl-1, 5-heptadiene

46. The IUPAC name of terpene camphor is
JI

(4) None
LA

39. The IUPAC name for the compound is (1) 1, 5, 4-trimethyl bicyclo [2.2.0] hept-1-one
O (2) 1, 7, 7-trimethyl bicyclo [2.2.1] hept-1-one
(1) Spiro [2.3] oxaheptane (3) 1, 6, 6-trimethyl bicyclo [2.2.1] heptanone-1
A

(2) Spiro [2.4] oxaheptane (4) None of these

B

(3) 4-oxa spiro[2.4] heptane

47. Which of the following is pyrolidine?
(4) none of these
CN
O (1) (2)
40. The IUPAC name for is N N
O H
(1) 4-oxa-3-keto-2-cyano hexane
(2) 3-keto-4-oxa-2-hexanenitrile (3) (4)
(3) Ethyl-2-cyano propanoate N N
(4) none of these H H
41. The IUPAC name of structure
O O
48. The IUPAC name for the structure will be
is
O
(1) Butanoic propanoic anhydride (1) 2, 7, 7-trimethyl bicyclo [3.1.1] hept-2-ene
(2) 3, 5-diketo-4-oxa-octane (2) 2, 6, 6-trimethyl bicyclo [3.1.1] hept-2-ene
(3) Propanoic-anhydride (3) 1, 7, 7-trimethyl bicyclo [2.2.1] heptane
(4) 4, 6-diketo-5-oxa octane (4) 1, 6, 6-trimethyl bicyclo [2.2.1] heptane

CHEMISTRY CLASSES ANKUR SIR 7983744732

49. Oxetane is O
(1) Oxacyclobutane (2) 1,3-epoxy propane
(3) CH3 O S (4) CH3– S –
(3) Both (1) & (2) (4) none of these
O
50. is named as (IUPAC) 59. The IUPAC name of isoprene is
(1) Vinyl acetylene (2) 1-butene-3-yne (1) 1, 3-butadiene
(3) 1-butyne-3-yne (4) (2) & (3) both (2) 2-methyl-1, 3-butadiene
51. The IUPAC name of crotyl chloride is (3) 2-methyl-1-butene
(1) 1-chloro-1-butene (4) 3-methyl-1-butene
(2) 1-chloro-2-butene
(3) 2-chloro-2-butene 60. Which of the following molecule is planar
(4) 3-chloro-2-2butene (1) Ethane (2) Methane
52. Select the molecule which has three pi-bond (3) Ethyne (4) Benzene
(1) CH  CH 61. The number of  electrons in anthracene is
(2) CH2 = CH – CH = CH – CHO
(3) CH3 – CH = CH – COOH (1) 10 (2) 12
(4) CH3CH = CH2 (3) 14 (4) 8
53. Number of 2o H atom in isobutane is 62. Which of the following alkanes has neither secondary

LS
(1) 1 (2) 9 nor tertiary hydrogens?
(3) 4 (4) none of these
(1) isobutane (2) isopentane

IA
54. IUPAC name of DDT is
(3) pentane (4) neopentane
(1) Dichlorodiphenyl trichloro ethane
(2) Dichlorodiphenyl trichlorobenzene R 63. In which of the following compounds, carbon uses
TO
(3) Dichlorodiphenyl trichloro propane sp3-hybid orbitals only for bonding?
(4) 1, 1, 1-trichloro-2, 2-bis-(p-chlorophenyl) ethane
(1) H–COOH (2) CH 3CHO
55. C – C bond length is minimum is
U

(3) (CH 3–) 3COH (4) (NH2) 2CO

(1) C 6H 6 (2) C 2H 4
T

(3) C 2H 2 (4) C 2H 6 64. An aromatic molecule will

56. C–H bond length is minimum is (1) have 4n  electrons
JI

(1) C 2H 6 (2) C 2H 4 (2) have (4n + 2)  electrons

LA

(3) C 2H 2 (4) C 6H 6 (3) be planar

57. The hybridization of carbon atoms in C–C single bond (4) both (2) & (3)
of H2C = CH – CH = CH2 is :
A

(1) sp3 – sp3 (2) sp2 – sp3 65. The number of sigma and pi bonds in but-1-en-3-yne
B

(3) sp2 – sp2 (4) sp3 – sp are respectively

58. Which of the following groups is mesyl group (1) 3 and 2 (2) 5 and 2
O (3) 3 and 3 (4) 7 and 3

(1) CH3 S (2) CH3 – SO3 –

O



CHEMISTRY CLASSES ANKUR SIR 7983744732

 CHEMISTRY
CLASSIFICATION AND NOMENCALATURE OF ORGANIC COMPOUNDS

1. (2) 14. (1) 27. (3) 40. (3) 53. (4)

2. (2) 15. (3) 28. (4) 41. (1) 54. (4)
3. (2) 16. (2) 29. (1) 42. (2) 55. (2)
4. (3) 17. (1) 30. (2) 43. (2) 56. (3)
5. (3) 18. (3) 31. (1) 44. (3) 57. (3)
6. (1) 19. (2) 32. (2) 45. (4) 58. (1)
7. (2) 20. (3) 33. (1) 46. (4) 59. (2)
8. (2) 21. (1) 34. (1) 47. (3) 60. (4)
9. (3) 22. (4) 35. (2) 48. (2) 61. (4)
10. (2) 23. (1) 36. (1) 49. (3) 62. (3)
11. (3) 24. (3) 37. (2) 50. (2) 63. (4)
12. (4) 25. (1) 38. (3) 51. (2) 64. (1)
13. (4) 26. (4) 39. (3) 52. (2) 65. (3)

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CHEMISTRY CLASSES ANKUR SIR 7983744732