11th Chemistry EM Unit Wise 6 Public Exam Question Papers English Medium PDF Download 1

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11TH CHEMISTRY PUBLIC QUESTIONS
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Unitwise
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S.MANIKANDAN.,M.Sc.,B.Ed.,
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S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401
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CONTENTS
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PUBLIC
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1 Preface 3
2 March 2019 4
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7 July-2022
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NNeett LESSON NAME

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Basic concepts of chemistry and 28
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calculation
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4 Hydrogen 34
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Alkali and Alkaline earth metals
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Gaseous state 36
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10 Chemical bonding 43
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Fundamentals of organic chemistry 45
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PREFACE aaddaassaa
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“Praise the lord”
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“Education is not the learning of facts,
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But the training of the mind to think”
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-Albert Einstein saa
“Education. P
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Respected Teachers/ Dear students
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This guide is based on the six government public 11THchemistry questions. This
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guide contains more than 200 questions .and 90 one marks. (question and answer)
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The purpose to get

marks.This guideis
You have any doubt of question and answer in this material contact
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your chemistry teacher or me
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God bless all
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All the best

S.MANIKANDAN.M.Sc., B.Ed.,
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NOTE:
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Government public question paper july2021 -jul22
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Interior page number
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N N t t Maximum marks : 70
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Time allowed : 2.30hours
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1.many of the organic compounds are inflammable because of Its :
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a) vander waal‟s force b) co-ordinate nature
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c) covalent nature
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d) ionic nature
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2.When Δng is negative in chemical equilibrium reaction then :
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a) CaC2 b) CO2 c) Ca d) Ca2O
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4.Splitting of spectral lines in an electric field is called :
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c) Zeeman effect d) shielding effect
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5.Which of the following species does not exert a resonance effect ?daa
a) C6H5NH2
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6.Match the following :

Compound uses
1)Chloro picrin i) detection of primary amine
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2)Methyl isocyanide
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3)Chlolro benzene
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iii) paint remover
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4)Meythylene chloride iv) soil sterilizer
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a) (1)- (iv), (2)-(iii) , (3)-(ii), (4)-(i)
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b) (1)- (iii), (2)-(iv) , (3)-(ii), (4)-(i)
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c) (1)- (i), (2)-(ii) , (3)-(iv), (4)-(iii)
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d) (1)- (iv), (2)-(i) , (3)-(ii), (4)-(iii)
7.use of hot air ballone in meteorological observatory is an application of :
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a) Kelvin‟s Law b) Brown‟s Law

c) Boyle‟s Law d) Newton‟s Law
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8.what is the pH of rain water ?
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a) 5.6 b) 4.6 c) 6.5 d) 7.5
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9. which compound is named as “blue john” among the following compounds ?
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c) CaH2
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d) CaF2
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10.The element with positive electron gain enthalpy is _____
a) Argon b) Fluorine
c) Hydrogen d) sodium
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11.which of the following molecule does not contain π bond ?
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a) CO2 b) H2O c) SO2 d) NO2
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12.which of the following compound has same percentage of carbon as that of
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c) propene
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b) ethane
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13.The SI unit of molar heat capacity is : ______
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c) KJ mol-1
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14.What percentage of solution of H2O2 is called as “100-volume‟ H2O2 ?
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d) π V=nRT
PART-II
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Answer any six of the following questions. Question no.24 is compulsory. 6 X 2 = 12
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16.State and explaine pauli‟s exclusion principle.
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17.Define valency
18.What are ideal gas ?
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19.State the third law of thermodynamics ?
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20.What is called bond length ? Name the techniques through which the length of a bond
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21.Describe the reaction involved in the detection of nitrogen in an organic compound by
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lassaigne method.
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22.How is alkane prepared from grignard reagent ?
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23.Define- acid rain
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24.Which is the suitable method for detection of nitrogen present in food and fertilizers?
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25.Calculate the equivalent mass of H2SO4

26.Explain diagonal relationship .
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27.How is Tritium prepared ?
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28.Define –Le-Chatelier principle.
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29.State the term “isotonic solution”
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31.Write note on Williamson‟s synthesis.
32.Explain why Ca(OH)2 is used in white washing .
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33.Give the structural formula for the following compounds.
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ii) Write any two different components you get during fractional distillation of
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coal tar at any two different temperatures.
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38.a) i) A compound having the empirical formula C6H6O has the vapour density
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ii) The simple aromatic hydrocarbon compound (A) reacts with bromine to
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Calculate the standard entropy change for the above reaction, given the
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ii) Identify the compound (A) and (B) www
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N Neett N Ne et t Maximum marks : 70

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JUNE-2019
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PART-I
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Note : i) Answer all the questions. .P Paa
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ii) choose thew ww w w
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1.The oxidation number of carbon in CH2F2 is ______
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a) +4 b) -4
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2.The energy of an electron in the third orbit of hydrogen atom is –E . The
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c) 2.1 d) 6.9
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4.The type of H-bonding present in orthonitro phenol and p-nitro phenol are ___respectively.
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b) Intra molecular H-bonding and inter molecular H-bonding
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d) Intra molecular H-bonding and intra molecular H-bonding

5.When CaC2 is heated in atmospheric nitrogen in an electric furnace, the
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6.When an ideal gas undergoes unrestrained expansion, no cooling occurs
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because the molecules ________
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c) do work equal to the loss in kinetic energy d) collide without loss of energy
7.Among the following statements, which one is /are correct ?
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ii)Refractive index is an example for intensive property
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iii) If the enthalpy change of a process is positive then the process is spontaneous
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8.If kb and kf for a reversible reaction are 0.8 x 10 and 1.6x 10 respectively
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a) 20 b) 0.2 x10-1 c) 0.05 d) 0.2
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9.Assertion : Mixture of carbon tetrachloride and chloroform show positive
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deviation from raoult‟s law
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Reason : In the mixture the inter molecular force of attraction between
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molecules of carbon tetrachloride and chloroform molecules.
a) Both assertion and reason are correct and reason is the correct explanation of
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b) Both assertion and reason are correct and reason is not the correct
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c) Both assertion and reason are false
d) Assertion is true , but reason is false ad
a a
d s
a aa
s
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10.Shape and hybridation of IF5 are :
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b) Trigonal bipyramidal sp3d
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lai
11.Which of the following is optically active ?
N Neett
a) 3-chlolro pentane
N Neettb) 2-chloro propane
l a
l i
a .i. l a
l i
a .i. l a
l i
a
sa
assaa aa aa
c) meso-tartaric acid d) glucose
ddaass d
12.Which of the following species is not electrophile in nature ?
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a) Cl+
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. Paa
b) BH3 c) H3O+
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. Paa d) +NO2
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13.______group is ortho para directing and deactivating group

a) amino b) methyl c) halogen d) aldehyde
14.The raw material for Rasching process is _______
Pa
N Neett
a) chloro benzene b) phenol
N Neett
c) benzene d) anisole
l a
l i
a .i.
15.________ cause kidney damage
l a
lai .i. l a
l i
a
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a) Cadmium , mercury b) Lead, Cadmium
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c) Freon, Fluoride d) copper, Cadmium

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Answer any six from the following questions.Q.no.24 is compulsory 6 X 2 = 12
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17.Write any two similarities between beryllium and aluminium .
N eett
18.What is inversion temperature ?
N N Neett
l a
l i
a .i. l a
lai.i. l
19.What is the effect of added inert gas on the rection at equilibrium ?a
l i
a
assaa aad aasaa
s
ad
a a
d s
a aa
s
20.Linear form carbon dioxide molecules has two polar bonds .yet the molecule has zero
d
.
dipole moment. Why ?
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w. P
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21.How do you detect the presence of nitrogen and sulphur together in anorganic compound?
22.What happens when acetylene undergoes ozonolysis ?
23.What is green chemistry ?
N N ett N N ett
24.Calculate the orbital angular momentum for d and f orbital.
e e
lalai.i. l a
l ai .i. Page 9 la
l i
a
assaa aa aa
dda a s s d aas s
PP a a
PP d
aa
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NN eett NN eett
lalai .i. any six from the following questions.lalQ.No.33
PART-III
a i .i. is compulsory 6 X 3 = 18 lalai
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Answer
d da ass
mole
ddaass
. P
. P
26.Ionisation potential of nitrogen is greater than that of oxygen . explain by .P.Pa
givinga
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appropriate reason.
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27.Among the alkali metal halides, which is covalent ? explain with reason.
28.Derive ideal gas equation.
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29.Define molar heat capacity. Give its unit.
N N N Neett
lalai.i. l a
l i
a .i. l a
l i
a
30.What is vapour pressure of a liquid ? what is relative lowering of vapour pressure ?
et
assaa a
very close boiling point.addas
a aa
s
ad
a a
d s
a aa
s
31.explain a suitable method for purifying and separating liquids present in a mixture having
. P
.P . P
. P
.N
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32.What is polymerisation ? explain the two types of polymerisation rection of acetylene .
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33.The bond length between all the four carbon atoms is same in 1,3-butadiene. Explain
lai
PART-IV
N Neett
Answer all the following questions.
N Neett 4 X 5 = 20
l a
l i
a .i. l a
l i
a .i. l a
l i
a
sa
assaa aa aa
34.a) i) What are auto redox rections ? give an example .
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. Paa (OR)
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. Paa
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b) i) Why hydrogen peroxide is stored in plastic containers, not in glass container ?

ii) Give the general electronic configuration of lanthanides and actinides.
Pa
N N ett N N ett
35.a) i) why blue colour appears during the dissolution of alkali metals in liquid ammonia ?
e e
l a
l i
a .i. l a
lai .i. l a
l i
ii) what is boyle‟s temperature ? what happens to real gases above and below the
a
assaa s aa saa
boyle‟s temperature ?
ddaa s ddaa s
aa aa
w.
(OR)
ww. P
. P w
w . P
. P
b) i) Derive the relation between kp and kc for a general homogeneous gaseous reaction.
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ii) How do you measure heat changes at constant pressure ?
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36.a) i) Draw the M.O diagram for oxygen molecule . calculate its bond order
and magnetic character.
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ii) Draw and explain the graph obtained by plotting solubility versus
N N
l a
l i
a .i. l a
lai.i.
temperature for calcium chloride .
l a
l i
a
assaa aaddaasaa
s (OR)
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a a
d s
a aa
s
w
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b) i) Write the IUPAC names for the following compounds :
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. P
w
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w w
w
(x) (Y) (Z)
N Neett N Neett
lalai.i. l a
l ai .i. 7708543401 Page 10 la l i
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assaa aa aa
S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY
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PP d
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ii) e
N N e t t the formal charge on carbon and oxygen N Neetfort the following
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l i
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structure
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a aa
s
aadda assaa
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.
about inductive
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ww .P.P
ww
ethane .
w
mean by conformation ? Explain about staggered
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b) i) Among the following compounds ,o-dichloro benzene and p-dichloro benzene ,
e e
lalai.i. l l ai .i.
which has higher melting point ? explain with reason .
a l a
l i
a
et
assaa s saa s saa
ii) Write notes on the adverse effect caused by ozone depletion.
aa d daa a ad da a
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. P . P
. P
.N
is 5.7 x w w w ww
38.a) i) calculate the uncertainty in the position of an electron, if the
ww
uncertainty
ww
in it velocity
10wms
5 -1
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ii) What is the mass of glucose (C H O ) in it one litre solution which is isotonic with
6 12 6
lai
6gl-1 of urea (NH2CONH2) ?
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ab)i.i)
i .An organic compound (A) of molecular formulaa i .i. C H O, on heating with conc.H SO lalai
l l a l l a
sa
assaa gives aacold dilute alkaline KMnO gives compound aa
2 6 2 4
compound (B) . (B) on treatingss s s
a ad daa with 4
a ad a
d a
w w . PP
(C) . Identify (A), (B) and (C) and explain the reactions.
. (A) reacts with chlorine to give compoundww . PP
. (B) .
ww with ammonia to give compound (C) which w w
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ii) A simple aromatic hydrocarbon

compound (B) wwreacts wwundergoes
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l a
l i
a .i. l a
lai .i. l a
l i
a
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ddaass ddaass
aa aa
w.
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w . P
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w
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N Neett N Neett
l a
l i
a .i. l a
lai.i. l a
l i
a
assaa aaddaasaa
s
ad
a a
d s
a aa
s
w
w .P. P w
w. P
. P
w
www w
www
N Neett N Neett
lalai.i. l a
l ai .i. 7708543401 Page 11 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
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wwww wwww
N Neett N Ne et t Maximum marks : 70

lalai .i.
l a
l i
a .i. l a
l i
a
assaa aa aa
Sep-2020
dda as s
PART-I
d a
d s
a s
. P
. Paa
Note : i) Answer all the questions. .P P a
. anda
ii) choose thew ww w ww
write the option code and the corresponding answer .
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four alternatives
1.The maximum number of electrons that can be accommodated in L orbit is
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a) 8 b) 2
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lalai.i. l a
l i
a .i.
2.The relative molecular mass of ethanol is ___
l a
l i
a
et
assaa a) 0.46g
aaddas
a aa
s
b) 4.6 g
3.Intra molecular hydrogen bonding is present in___
c) 460g
ad
a a
d s
a aa
s d) 46g
. P
.P . P
. P
.N
w
w
a) Ortho-nitro phenol b) Ice
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c) Water d) Hydrogen fluoride
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4.Ozone deplection will cause www
a) Global warning b) Forest fire c) Eutrophication d) Bio-magnification
lai
5.Among the following which is the path function ?
N Nee
a) Gtt b) U
N Neett c) H d) q
l a
l i
a .i. l a
l i
a .i. l a
l i
a
sa
assaa aa aa
6. match the following
1)Iodoform
ddaass
i) Fire extinguisher
ddaass
. P
. Paa
2)Carbon tetrachloride ii)Insecticide
. P
. Paa
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w
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3)CFC iii) Antiseptic

4)DDT iv)Refrigerants
a) (1)- (iii), (2)-(i) , (3)-(iv), (4)-(ii) b) (1)- (ii), (2)-(iv) , (3)-(i), (4)-(iii)
Pa
N Neett
c) (1)- (iii), (2)-(ii) , (3)-(iv), (4)-(i)
N Neettd) (1)- (i), (2)-(ii) , (3)-(iii), (4)-(iv)
l a
l i
a .i.
7.Cold dilute alkaline KMnO4 is known as
l a
lai .i. l a
l i
a
assaa s aa saa
a) Schiff”s reagent
ddaa s b) Fenton”s reagent
ddaa s
c) Tollen‟s reagent
aa aa
d) Baeyer‟s reagent
w.
ww. P
. P w
w .
8.osmotic pressure (π) of a solution is given by the relationP
. P
a) π RT=n w
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ww
c) π V=nRT d) None of these

9.n-propyl bromide on rection with alcoholic KOH gives
N eett
a) Butyl alcohol
N N Neett b) Propene
l a
l i
a .i.
c) Butene
l a
lai.i. l
d) Propyl alcohola
l i
a
assaa aad aasaa
s
10.Which of the following is incorrect statement ?
d ad
a a
d s
a aa
s
w
w .P. P
a) Equilibrium constant varies with temperature
w
w. P
. P
w
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b) For a system at equilibrium ,Q is always less than the equilibrium constant
c) Equilibrium can be attained from either side of the reaction
d) Presence of catalyst affects both the forward reaction and reverse reaction
N Neett
to the same extent.
N Neett
lalai.i. l a
l ai .i. 7708543401 Page 12 la l i
a
assaa aa aa
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N Neett N Neett
lala .i. l a
l i
a .i.
11.Assertion : Helium has the highest value of ionisation energy among all the
i l a
l i
a
assaa aa aa
elements known.
ddaass ddaass
Reason : Helium has the highest value of electron affinity among all the
. P
. P
elements known.aa .P.Paa
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w
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a) Both assertion and reason are false
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b) Both assertion and reason are true and the reason is correct explanation for
the assertion
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e N Neett
c) Both assertion and reason are true but the reason is not the correct
N
lalai.i. explanation for the assertion
l a
l i
a .i. l a
l i
a
et
assaa aaddas
a aa
s
d) Assertion is true and reason is false .
ad
a a
d s
a aa
s
. P
.P . P
. P
.N
12.Write the IUPACw w w w w
w
wwwname
a) 1-formyl propanol
of
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b) 1-hydroxy butanal
lai
c) 2-hydroxy butanal d) 3- hydroxy butanal
N Nee tt
13.Formula of Gypsum is
N Neet t.2H O
l a
l i
a .i.
a) CaSO4
l a
l i
a .i.
b)CaSO 4 2
l a
l i
a
sa
assaa 14.Gases s aa d) CaSO . H 0
s s aa
s
1
c) CaSO . H 0
4
2
2
aad da a 4 2
aad a
d a
. P
tent to behave ideally
w w P
. pressure b) High temperature andwHigh
only at
w
w . P
. P
w
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a) Low temperature and low pressure

c) High temperature wHigh
and
15.Which of the following is electron deficient ?
Pa
a) NH3
N Ne et t b) PH3 c) (CH3)2
N Neet t d) BH 3
l a
l i
a .
i . l a
lai .
i . l a
l i
a
assaa Answer any six from the following s a
s a s a
s a
PART-II
a ad da a 6 X2 =d
aa da a
w.
questions.Q.no.24 is compulsory. 12
16.Define basicity.Find the .
w w P
. P
basicity of ortho-phosphoric Acid.
w
w . P
. P
ww w
17.Write the exchange wreactions of Deuterium. ww ww
ww
18.state zeroth Law of Thermodynamics.

19.Explain homogeneous and heterogeneous equilibria.
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20.Write the shape and molecular geomentry for BF3
N N N Neett
l a
l i
a .i. l a
lai.i.
21.Which element exhibits maximum catenation and why ?
l a
l i
a
assaa aasaa
s
22.Write the no bond resonance structure shown by propene ?
aadd ad
a a
d s
a aa
s
.P P
23.Give the structure and uses of DDT .
w
w . w
w. P
. P
w
www w
www
24.In degenerate orbitals, why do the completely filled and half filled configurations are
more stable than the partially filled configurations ?
N Neett N Neett
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a
assaa aa aa
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PP d
aa
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NN eett Part-III ee
N N tt
lalai .i. : Answer any six questions. Question NO.33
l al i
a .i.is compulsory. 6 X 3 =18 l a
l i
a
assaa 25.State Heisenber‟s UncertaintyaPrinciple a a aa
Note
d da as s.
ddaass
P P a
26.Derive ionic radius using.pauling‟s
. method . .P.Paa
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w
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27.How do you convert para hydrogen into ortho hydrogen.
28.Distinguish between extensive and intensive property.
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29.Calculate the mole fraction of methanol and water when
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e N Neett
0.5 mole of methanol is mixed with 1.5 moles of water.
N
lalai.i. l a
l i
a .i.
30.What is hybridisation ? mention the type of hybridization found in CH4
l a
l i
a
et
assaa aaddas
a aa
s
31.Explain the different types of polymerisation in ethyne.
ad
a a
d s
a aa
s
32.What is green house effect ? Name the gases that cause green house effect .
. P
.P . P
. P
.N
w
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33.Explain geometrical isomerism in 2-butene.
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PART-IV
lai
Note : Answer all the questions . 5 X 5 = 25
N Neett N Neett
34. a) Calculate the empirical formula and molecular of a compound containing
l a
l i
a .i. l a
l i
a .i. l a
l i
a
sa
assaa aa aa
76.6% carbon,6.38% of hydrogen and rest oxygen. Its vapour density is 47.
ddaass (OR)
ddaass
. P
. Paa . P
. Paa
b) i) Calculate the total number of angular nodes and radial nodes present in
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3d and 4f orbitals.
ii) Explain why the electron affinity of Be and N is almost zero
Pa
N N ett N N ett
35.a) i) Write the laboratory method of preparation of hydrogen .
e e
l a
l i
a .i. l lai .i.
ii) Name the different methods of liquefaction of gases.
a l a
l i
a
assaa ssaa saa
s
(OR)
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adaa aaddaa
w.
b) i) How is bleaching powder prepared ?

ww. P
. P
ii)Write the uses of magnesium. w
w . P
. P
w
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iii)Write the mathematical formula for compressibility factor „Z‟
ww
36.a) i)Derive the relation between enthalpy ΔH and internal energy ΔU for an ideal gas.
N eett
ii) Define reaction quotient.
N N Neett
l a
l i
a .i. l a
lai.i.(OR)
l a
l i
a
assaa aaddaasaa
s
ad
a a
d s
a aa
s
b) i) Calculate the entropy change during the melting of one mole of ice into water at 0 0C
w
w P. P w
w. P
. P
and 1 atm pressure. Enthalpy of fusion of ice is 6008J mol-1
.
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ii) Write any four postulates of molecular orbital theory.
N Neett N Neett
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a
assaa aa aa
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PP d
aa
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NN eett N Neett
lalai .i. i)What is van‟t hoff factor „i‟ ? l a
l i
a .i. l a
l i
a
assaa ii) complete aa aa
37.a)
d a
d s
a s ddaass
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. Pa a .P.Paa
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2
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A) H C=CH + 2 H-Br
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B) CH3CHO
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l i
a .i. l a
l i
a
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assaa aaddas
a aa
s
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a a
d s
a aa
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w w
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tt
lai tt
D)
i N N e e (OR)
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l a l a
l a
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compound
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d s
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. to control environment pollution. www. . PPa a
w w w
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ii) Write any three strategies

(OR)
b) explain the mechanism involved in the elimination reaction of tertiary butyl chloride
Pa
N Neett
with alcoholic KOH.
N Neett
l a
l i
a .i. l a
lai .i. l a
l i
a
assaa ad
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aaddaasaa
s
w.
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ww. P
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w . P
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w
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N Neett N Neett
l a
l i
a .i. l a
lai.i. l a
l i
a
assaa aaddaasaa
s
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a a
d s
a aa
s
w
w .P. P w
w. P
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N Neett N Neett
lalai.i. l a
l ai .i. 7708543401 Page 15 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
N Ne ett N Neet t Maximum marks : 70

lalai .i.
l a
l i
a .i. l a
l i
a
assaa Note : i) Answer all the questions. aa aa
Sep-2021
ddaass
PART-I
d a
d s
a s
. P
. Paa .P P a
. anda
w ww
w code and the corresponding answer w
ii) choose the most appropriate
w ww
. ww 15 X 1 = 15
answer from the given four alternatives
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write the
1. Which one of the following of presents 180g of water ?
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N N e t5tmoles of water
b)e
lalai.i. c) 6.022 X 10 moles of water lalai.i. d) 90 moles of water
a) moles of water
180
l a
l i
a
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assaa 2.Which of the following compound(s) aa percentage of carbon same as that in aassaa
24
dda a ss dd
. P
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. P
. Paa
.N
ethylene (C H ) ?
2
w w
4
w
a) benzenew w b) propene w w w
w c) ethane wwwd) ethyne
3.Assertion ; permanent hardness of water is removed by treatment with washing soda
lai
Reasons : Washing soda reacts with soluble calcium and magnesium chloride and sulphate
N Neett e
in hard water to from insoluble carbonates.
N N ett
l a
l i
a .i.
a) Assertion is true but reason is false
l a
l i
a .i. l a
l i
a
sa
assaa aaddaasaa
s
aaddaassaa
b) Both assertion and reason are true and reason is the correct explanation of assertion
ww. P
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c) Both assertion ans reason are false
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w . P
. P
w
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da
d)Both assertion and reason are true but reason is the correct explanation of assertion.
4.Flame colour of potassium salts in bunsens burner
a) Lilac (violet ) b) crimson red c) Apple green d) yellow
Pa
N N ett
5. Formula of plaster of paris
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l a
l i
a .i.
a) 3CaSO4.H2O b) CaSO .2H O4 2
l
c)
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l ai .i.
2CaSO .2H 4 2
l
4
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l
1
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a
2
2
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aad d aas saa
aaddaasaa
s
w.
w w . P
directly proportional
P to the square root of its molecular weight
. to its density ww . P
. P
c) inversely w
b) directly proportional
www proportional to the square root of its molecular ww
wwweight
ww
d) directly proportional to its molecular weight

7. Heat of combustion is always :
N Neett
a) zero
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b) positive
l a
l i
a .i. l a
lai.i. l a
l i
a
assaa aa aa
c) either positive or negative d) negative
ddaass
8. For the following reversible rections at equilibrium A + B
d a
d s
a s C. If the concentration of
.P. Paa
the reactants A and B are doubled, then the equilibrium constant will :
. P
. Paa
w ww b) be doubled ww w
wwthewsame
a) be halved
c) remain
w
wwfourth
d) become one
9.The molality of a solution containing 1.8g of glucose dissolved in 250g of water is
N Neett
a) 0.02M b) 0.2M c) 0.04M
N Neett d) 0.01M
lalai.i. l a
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a
assaa aa aa
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PP d
aa
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N Neett N Neett
lala .i.
10.Match the following
i l a
l i
a .i. l a
l i
a
assaa aa aa
1) N2 molecule i) chemical bond
2) BF3 molecule
ddaass ddaass
ii) Trible covalent bond
3) HF molecule . P
. Paa .P.Paa
iii) Electron deficient molecule
www w w
w
4) NaCl
www www
iv) polar covalent bond
a) 1)- iii) , 2)- i) , 3)-iv) , 4)- ii) b) 1)-ii) , 2)- iv) , 3)-i) , 4)- iii)
c) 1)- i) , 2)- iv) , 3)- ii) , 4)- iii) d) 1)- ii) , 2)-iii) , 3)- iv) , 4)- i)
Neett N Neett
11.The structure of isobutyl group in organic compound
N
lalai.i. l a
l i
a .i. l a
l i
a
et
assaa a)
aaddas
a aa b)
s
ad
a a
d s
a aa
s
. P
.P . P
. P
.N
w w
w www
www www
lai
c) d)
N N ett
12.Which of the following is optically active ?
e N Neett
l a
l i
a .i. a) meso-tartaric acid
l a
l i
a .i. b) 3-chloropentane
l a
l i
a
sa
assaa saa
s ssaa
c) glucose d) 2-chloropropane
aaddaa
13.The geometrical shape of carbocation is
aaddaa
a) planar
ww. P
. P b) linear
w
w .
c) pyramidalP
. P d) tetrahedral
w
www w
www
da
14.An alkene is obtained by decarboxylation of sodium propionate.same alkene can be

prepared by :
a) reduction of 1-chloro propane b) catalytic hydrogenation of propene
Pa
N eett
c) reduction of bromo methane
N N eett
d) action of sodium metal on iodomethane
N
l a
l i
a .i. l a
lai .i.
15.Of the following compounds , which has the highest boiling point?
l a
l i
a
assaa a) t-butyl chloride
ad
adaassaa
aa daasaa
s
b) n-butyl chloride
d
w.
ww. P
. P
c) n-propyl chloride
. P P
d) Isobutyl chloride
w
w .
w
www w
www
PART-II
Answer any six from the following questions.Q.no.24 is compulsory. 6 X 2 = 12
ww
16.What is the empirical formula of the following ?
N Neet t
a) Fructose (C6H12O6) ii) Caffeine ( C H N O )
8 10
N Ne
4
ett2
l a
l i
a .i.
17.State Aufbau principle
l a
lai.i. l a
l i
a
assaa 18.How do you convert para hydrogen
a ad da as
intosaortho
a hydrogen ?
ad
a a
d s
a aa
s
w w. P
.
19.Give any two characteristicsPof gibbs free energy ?
w
w. P
. P
20.Define Hess‟swlaww
wofwconstant heat summation. w
www
21.What is the relation between KP and KC ? Give one example for which KP is equal
N Ne
to KC.
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lalai.i. l a
l ai .i. 7708543401 Page 17 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
N Neett N Neett
lala .i. short notes on Swarts reaction ? lalai.i.
22.What is molal depression constant ?
i l a
l i
a
assaa 24.Complete the following : aaddaassaa ssaa
23.Write
aaddaa
ww . P
. P w
w .P.P
a) CH -CH=CH
3
w
ww+wH 2 2
w
www
b) CH3MgCl + H2O
NN eett Part-III ee
N N tt
lalai.i. : Answer any six questions. Question NO.33
Note
l a
l i
a .i.is compulsory. 6 X 3 = 18 l a
l i
a
et
assaa 25. a as aa .
s
Distinguish between oxidation and reduction
a ad d a d
a a
d s
a aa
s
P P
26.Define electronegativity..State
. the trends in the variation of . P
.
electronegativityPin
.N
w w w w ww
www
group and period www
27.What are homogeneous and heterogeneous equilibria? Give example
l a
l i
a NN
29.Give
tt
lai
28.What are ideal solutions ? Give example
ee
.i. the shapes of molecules predicted by VSEPR
l a
l i
a N N eett
.i. theory l a
l i
a
sa
assaa a) BeCl b) NH c) HaaOddaassaa
2 3 2
aaddaassaa
w P
30.Give the general formula.for
w . Pthe following class of organic
w
compounds
w. P
. P
w w c) Alkynes wwww
da
a) Alkanes w b)wAlkenes
31.What is resonance ?
Pa
N e ett NN e ett
32.Suggest a simple chemical test to distinguish propane and propene
N
l a
l i
a .i. a certain automobile engine , the volume
33.Inside l a
lai .ofi.air in a cylinder is 0.375 dm ,
3
l a
l i
a
assaa when the pressure is 1.05atm a. When
a d da as s
the
agas
a is compressed to a volume of 0.125 dmaassaa
3
aadd
w.
ww
at the same temperature .
,.PP
What is the pressure of the compressed air ?w w . P
. P
w
www PART-IV www w
ww
Note : Answer all the questions . 5 X 5 = 25

34. a) i) What is exchange energy ?
N N e t t a note on principal quantum number NNeet t

e
l a
l i
a .i. ii) Write
l a
lai.i. l a
l i
a
assaa b) i) Define atomic radius. aaddaassa(OR) a
ad
a a
d s
a aa
s
w w .P. P w
w. P
. P
www w
ii) Explain diagonal relationship w
www
N Neett N Neett
lalai.i. l a
l ai .i. 7708543401 Page 18 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
N N e ett N Neett
lala .i. l a
l i
a .i.
35. a) Discuss the similarities between beryllium and aluminium
i l a
l i
a
assaa b) i) State the first law of thermodynamicsssaa s aa
s
(OR)
aad daa a d
a a
d a
ii) What are thew ww . PP
. for the spontaneity of a process? www. . PP
w w w
conditions
ww w
36. a) How will you determine the molar mass of a solute from osmotic pressure ?
(OR)
N N e ett N Neett
lalai.i.
b) i) Define Bond Order.
l a
l i
a .i. l a
l i
a
et
assaa 37. a)ii)i) What aa d aas
are the salient features of VB
d satheory
a ?
ad
a a
d s
a aa
s
. P
. P
What is meant by homologous series ?
. P
. P
.N
w w w www
www
ii) Give the structure for the following compounds .
www
1) 3-methylpentane
lai
2) 2-methylpropan-2-ol
N N e tt
e3) Propanone
N Neett
l a
l i
a .i. l a
l i
a .i. l a
l i
a
sa
assaa b) Explain the formation of Haa a a aa
(OR)
d da ass ddaass
. P2
P
molecule using MO-theory
. help to decide the aromatic character ofwaw . PPa
. ?a
ww ww w
ww
38. a) i) How does Huckel rule compound
da
ww
ii) Write the rection for conversion of acetylene to benzene.w
(OR)
Pa
NN e ett NNeett
l a
l i
a .i.with ammonia to from compound (C) of molecular
l a
lai .i. formula C H N. Compound
b) Simplest alkene (A) rects with HBr to form compound (B). Compound (B) reacts
l a
l i
a
assaa (C) undergoes carbylaminesatest. d
ada assaa 2 7
aaddaasaa
s
w.
ww . P
. P Identify (A), (B) and (C).
ww. P
. P
www w wwww
ww
N Neett N Neett
l a
l i
a .i. l a
lai.i. l a
l i
a
assaa aad aas aa
s
****************
d ad
a a
d s
a aa
s
w
w .P. P w
w. P
. P
w
www w
www
N Neett N Neett
lalai.i. l a
l ai .i. 7708543401 Page 19 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
N Neett N Nee t t Maximum marks : 70

lala .i.
i l a
l ai .i. l a
l i
a
assaa aPart-I
a aa
MAY-2022
d a
d as s d aa
d15 ss
. P
. Paa
Note : i) Answer all the questions. .P
15 Pa a
. and
X 1 =
ii) choose thew ww w w w
write the option code and the corresponding answer
www
four alternatives
Ne ett N Neett
1.Which of the following is aliphatic saturated hydrocarbon ?
N
lalai.i.
a) C9H18 b) C8H14
a i
a .i.
c) C8H18
l l d) All of the above
l a
l i
a
et
assaa 2.Equimolal aqueous solutions ofaNaCl
adda as saa
and KCl are prepared . If the freezing ad
a a
d s
a aa
s
. PP
the.freezing point of KCl solution is expected w . P
be . P
.N
point of NaCl is -2 cw
,w
0
tow
a) -1 C 0 w
wwwb) -2 C 0
c) 0 C 0
d) -4wwww 0
lai
3.The correct relative order of +I effect of alkyl groups is :
N Neett
a) -C(CH3)3 > -CH(CH3)2 > -CH2CH3 > -CH3
N Neett
l a
l i
a .i.
b) –CH3 l a
l i
a .i. l a
l i
a
sa
assaa aa aa
> -CH2CH3 > -CH(CH3)2 > -C(CH3)3
c) -CH2CH3 > -CH3
ddaass
> -C(CH3)3 > -CH(CH3)2
ddaass
. P
. Paa
d) –CH(CH3)2 > -C(CH3)3 > -CH2CH3 > -CH3
. P
. Paa
www w w
w
www www
da
4.7.5 g of a gas occupies a volume of 5.6 L at 00C and 1 atm pressure.The gas is
a) CO b) NO c) CO2 d) N2
5.Assertion : In monohaloarenes, electrophilic substitution occurs at ortho and para
Pa
N Neett positions
N Neett
l a
l i
a .i. l lai .i.
Reason : Halogen atom is a ring deactivator
a l a
l i
a
assaa ssaa saa
s
ad
adaa aaddaa
w.
b) Both assertion and reason are true and reason is the correct explation of
assertion ww. P
. P w
w . P
. P
w
www
c) Both assertion and reason are false w
www
ww
d) Both assertion and reason are true but reason is not the correct explanation
of assertion
N ee tt
6.The intensive property among the quantities below is :
N N Nee tt
l a
l i
a .i. l a
lai .i.
𝑚𝑎𝑠 𝑠
l a
l i
a
assaa 7. Which one of the following isaincorrect aa ? aa
a) Enthalpy b) mass c) d) volume
dd aas s 𝑣𝑜𝑙𝑢𝑚𝑒
d a
d s
a s
.P. P a statement
. P
. Paa
w w w w
a) Presence of catalyst affects both the forward reaction and reverse
w ww
reaction
w
w w
to the same extent.
w w
b) for a system at equilibrium Q is always less than the equilibrium constant
c) equilibrium constant varies with temperature
Neett N Neett
d) equilibrium can be attained from either side of the reaction
N
lalai.i. l a
l ai .i. 7708543401 Page 20 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
NNee tt N Neett
lalai .i. of following l a
l i
a .i. l a
l i
a
assaa 1) –NO aa aa
8.Match
i) propyl aa
dd ss ddaass
2) -OCH
2
. P
.
ii) P aa
Amino .P.Paa
3) -CH -CH -CH w
3
w
w w w
w
4) –NH
2
2
www iv) Nitro
iii)Methoxy
2 3
www
a) (1)- (iii), (2)-(ii) , (3)-(iv), (4)-(i) b) (1)- (iii), (2)-(iv) , (3)-(i), (4)-(ii)
ett
e
c) (1)- (iv), (2)-(iii) , (3)-(i), (4)-(ii)
N N eett
d) (1)- (ii), (2)-(i) , (3)-(iv), (4)-(iii)
N N
lalai.i. l a
l i
a .i.
9.Spodumene is the mineral source for which of the following alkali metal ?
l a
l i
a
et
assaa a) Lithium b) Sodium
aaddas
a aa
s c) Rubidium
10.Which of the following has highest hydration energy ? ad
a a
d s
a aa
s d) Potassium
. P
.P . P
. P
.N
a) BaCl2
w w
w
b) MgCl2 c) SrCl2
www d) CaCl2
www
11.Tritium nucleus contains : www
a) 1p+2n b) 1p+on c) 1p+1n d) 2p+1n
lai
12.Which one of the following is diamagnetic ?
N Neett
a) O22- b) O2+
N Neett
c) O2 d) None of these
l a
l i
a .i. l a
l i
a .i. l a
l i
a
sa
assaa aa aa
13.Splitting of spectral lines in an electric field is called :
a) Compton effect
ddaass b) Zeeman effect
ddaass
c) Stark effect
. P
. Paa . P
. Paa
d) Shielding effect
www w w
w
www www
da
14.A bottle of ammonia and a bottle of HCl connected through a long tube are opened
simultaneously at both ends. The white ammonium chloride ring will be first formed :
a) near the ammonia bottle b) at the centre of the tube
Pa
N Neett
c) throughout the length of the tube
N Neett
d) near the hydrogen chloride bottle
l a
l i
a .i. l a
lai .i. l a
l i
a
assaa aad da as saa
aaddaasaa
s
w.
15.
a) optical isomers w
w . P
. P d)ww . P
. P
wwww b) resonating structures c) conformers
w
www
tautomers
ww
Part-II
N Neett N Neett
Note : answer any six questions. Question No.24 is compulsory 6 X 2 = 12
l a
l i
a .i.
16.Define Gram equivalent mass
l a
lai.i. l a
l i
a
assaa saa s aa
17.Calculate the maximum number of electrons that can be accommodated in L shell
ddaa s d a
d a s
.P. Pa
18.Mention the three types of covalent hydrides .
a . P
. Paa
w
w
19.What are the condition for the spontaneity of a process
w w w
w
www
20.Explain sign convention of heat
www
21.Give a balanced chemical equation for the equilibrium reaction for which the
[𝑁𝐻3 ]4 [𝑂2 ]5
equilibrium constant is given by expression Kc =
N Neett N N ett
[𝑁𝑂]4 [𝐻2 𝑂]6
e
lalai.i. l a
l ai .i. 7708543401 Page 21 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
N Neett
22.Define the term “isotonic” solution
N Neett
lalai .i. l a
l i
a .i. l a
l i
a
assaa aa aa
23.How will you convert ethyl chloride to ethane ?
ddaas
24.Complete the following reactionss ddaass
. P
. Paa .P.Paa
www w w
w
www www
N N eet t PART-III
N Neett
lalai.i
Note. : Answer any six questions. Question
a
No.33
l l i
a .
i .
is compulsory 6X3=18
l a
l i
a
et
assaa 25.Calculate
i) CO ii) H SO aa dda s aa elements .
s
the oxidation number of underlined
a ad
a a
d s
a aa
s
2 2
.4
P
.P . P
. P
.N
w
26.Define electron affinity
w w www
wwofwpartial pressures.
27.State Dalton Law www
28.Write the formula to calculate the molar mass of a solute from realative lowering of
lai
vapour pressure values.
N Neett N Neett
29.Describe the formation of HF molecule by orbital overlap
l a
l i
a .i. l a
l i
a .i. l a
l i
a
sa
assaa aa aa
30.What is meant by optical isomerism ?
ddaass dd
31.Give any three differences between nucleophiles and electrophilesaass
. P
. Paa . P
. Paa
32.what happens when ethylene is passed through cold dilute alkaline potassium
www w w
w
www www
da
permanganate ?
33.The equilibnrium concentrations of NH3 and N2 and H2 are 1.8 x10-2M , 1.2x10-2M and
3x 10-2 M respectively. Calculate the equilibrium constant for the formation of NH3 from
Pa
N N ett
N2 and H2
e N Neett
l a
l i
a .i. l a
lai .i.
PART-IV
l a
l i
a
assaa Note : Answer all the questions.
ad
adaassaa
aaddaasaa
s 5 X 5 = 25
w.
34.a)i) How many orbitals are possible for n=4 ?

ww. P
. P w
w . P
. P
ii) Write the electronic configuration and orbital diagram for nitrogen ?
w
www (OR) w
www
ww
b) Describe the pauling method for the determination of ionic radius .

35.a) i) What are the reasons for the anomalous properties of Berylium ?
N eett N eett
ii) Give any three properties of beryllium that are different from other
N N
l a
l i
a .i. elements of the group l a
lai.i. l a
l i
a
assaa aaddaasaa
s (OR)
ad
a a
d s
a aa
s
w
w .P. P
b) Explain the characteristics of internal energy .
w
w. P
. P
w
www w
www
36.a) How will you determine the molar mass of solute from elevation of boiling point ?
(OR)
N N ett
b) Define i) Bond length ii)Bond angle iii)Bond enthalpy
e N Neett
lalai.i. l a
l ai .i. 7708543401 Page 22 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
N Neett N Neett
lala .i. l a
l i
a .i.
37.a) How will you determine the ionic character in covalent bond using electronegativity
i l a
l i
a
assaa aa aa
values ?
ddaass (OR)
ddaass
. P
. Paa
b) Give the IUPAC names of the following compounds . .P.Paa
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w
www www
N Nett
e N Neett
lalai.i. l a
l i
a .i. l a
l i
a
et
assaa aaddas
a aa
s
ad
a a
d s
a aa
s
. P
.P . P
. P
.N
w
w w w www
V ) CH =w
2w
CH – CH = CH 2 www
tt
lai tt
38.a) How will you prepare the following compounds from benzene ?
i N
.i. Nee
i) nitrobenzene
i N
.i. Nee
ii) benzene sulphonic acid iii) BHC
i
l a
l a l a
l a l a
l a
sa
assaa aa aa
(OR)
ddaass ddaass
b) Simplest alkene (A) reacts with HCl to form compounds (B) .compounds (B) reacts with
. P
. Paa . P
. Paa
www w w
ammonia to form compound (C) of molecular formula C2H7N. compounds (C) undergoes
w
www www
da
carbylamines test. Identify (A),(B) and (C)

Pa
N Neett e
*********
N N ett
l a
l i
a .i. l a
lai .i. l a
l i
a
assaa ad
adaassaa
aaddaasaa
s
w.
ww. P
. P w
w . P
. P
w
www w
www
ww
N Neett N Neett
l a
l i
a .i. l a
lai.i. l a
l i
a
assaa aaddaasaa
s
ad
a a
d s
a aa
s
w
w .P. P w
w. P
. P
w
www w
www
N Neett N Neett
lalai.i. l a
l ai .i. 7708543401 Page 23 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
N Neett N Nee t t Maximum marks : 70

lala .i.
i l a
l ai .i. l a
l i
a
assaa aPart-I
a aa
July-2022
d daas s ddaass
. P
. Paa
Note : i) Answer all the questions. .P Pa a
. and
ii) choose thew w w w w w
write the option code and the corresponding answer
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four alternatives
CHOOSE THE BEST ANSWER 15 X 1 = 15
N Nett
e N Ne ett
lalai.i. l a
l i
a .i.
1. Total number of electrons present in 1.7 g of ammonia is :
l a
l i
a
et
assaa a) 6.022 X 10 c)ssaa ssaa
6.022𝑋 10 22 6.022𝑋 10 24 6.022𝑋 10 23
23
b)
a ad
1.7
d a a 1.7
d)
1.7
aaddaa
. P
.
2. The total number of orbitals P
associated with the principle quantum .
number P
. Pn=3
.N
w w w w w ww
a) 9
wwb) 8 c) 5 d) 7
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lai
3.Tritium is a ______ emitter
a) α
N Neett b) β c) γ
N Neett d) none of these
l a
l i
a .i. l a
l i
a .i.
4._________ is used in devising photoelectric cells.
l a
l i
a
sa
assaa a) Lithium b) Sodium
aaddaasaa
s c) Potassium
5. Aming the following the least thermally stable is : aaddaas
d) Caesium
saa
a) K2CO3 ww. P
. P
b) Na2CO3 c) BaCO3 w
w . P
. P
d) Li2CO3
w
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www
da
6.If temperature and volume of an ideal gas is increased to twice its values, the initial
pressure P becomes :
a) 4P b) 2P c) P d) 3P
Pa
N Neett N Neett
7.The amount of heat exchanged with the surrounding at constant pressure is
l a
l i
a .i. l a
lai .i. l a
l i
a
assaa aa aa
given by the quantity :
a) ΔE b) ΔH
ddaass c) ΔS d) ΔG
ddaass
aa aa
w.
ww. P
. P w
w . P
. P
8.If X is the fraction of PCl5 dissociated at equilibrium in the reaction
PCl5 w
www PCl3 + Cl2 w
www
ww
Then atarting with 0.5 mole of PCl5 , the total number of moles of reactants and products at
equilibrium is ;
N Neett
a) 0.5-X b) X+ 0.5
N Neett
c) 2X+0.5 d) X+1
l a
l i
a .i. l a
lai.i. l a
l i
9.Which one of the following binary liquid mixtures exhibit positive deviation
a
assaa from Raoult‟s law ?
a) Acetone + Chloroform
aaddaasaa
s
ad
a
b) Water + Nitric acida
d s
a aa
s
c) HCl + Water w
w .P. P w
w. P
.
d) Ethanol +Water P
w
www w
www
10.The ratio of number of sigma ( ) and pi ( π) bonds in 2-butynal is :
8 5 8 9
a) b) c) d)
N Neett
3 3 2
N Neett 2
lalai.i. l a
l ai .i. 7708543401 Page 24 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
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N Neett N Neett
lalai .i. l a
l i
a .i. l a
l i
a
assaa 11.The IUPAC name of the com,pound
aadda s
a aa
s
aaddaassaa
w w . P
. P w
w .P.P
w
www Is
w
www
a) 2-ethylbut-2-enoic acid b) 3-ethylbut-3-enoic acid
c) 3-ethylbut-2-enoic acid d) 2-ethylbut-3-enoic acid
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lala .i.
12.Match the following
i l a
l i
a .i. l a
l i
a
et
assaa aa aa
1) -NH2 i) Sulpho-
2) -CN
ddas
a s ii) Formyl -
d a
d s
a s
3) -SO3H . P
.Paa iii) Amino - . P
. Paa
.N
w w
w www
4) -CHO
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a) 1)- i) , 2)- ii) , 3)- iii), 4)- iv)
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b) 1)- iv), 2)- iii) , 3)- ii) , 4)- i)
lai
c) 1)- iii) , 2)- iv), 3)- i) , 4)- ii) d) 1)- iii), 2)- i) , 3)- iv), 4)- ii)
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13.-I effect is not shown by
N N N Neett
l a
l i
a .i.
a) -CH2CH3 b) -F
l a
l i
a .i.
c) -Cl d) -NO2
l a
l i
a
sa
assaa aadd asaa
s
14. Identify the compound (A) in the following reaction :
a aaddaassaa
ww. P
. P w
w . P
. P
w
www w
www
da
Pa
N Neett N Ne ett
l a
l i
a .i. l a
l ai .i. l a
l i
a
aaddaasaa
s
w.
ww . P
.
15. Assertion : Increasing orderPof boiling points of halo alkanes are
ww . P
. P
ww
CH w w< CH Cl < CHCl < CCl www
Cl
3 2 2 3 4
w
ww
Reason : The boiling points of halo alkanes increase with increase in the
number of halogen atoms
a)
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Assertion is true but reason is false
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l a
l i
a
b).i. l a
lai.i. l a
l i
a
both assertion and reason are true and reason is the correct xplanation of
assaa c) assertion
aaddaasaa
s
ad
a a
d s
a aa
s
.P P
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w
w . w
w. P
. P
d)
w
www w
www
both assertion and reason are true and reason is not the correct explanation
of assertion
N Neett N Neett
lalai.i. l a
l ai .i. 7708543401 Page 25 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
N Neett N Neett
lalai .i. l a
l i
a .i. l a
l i
a
assaa Answer the following any six questions aa aa
PART-II
d da ass s
6 X 2 = 12aa
dd s
.
16.What is meant by limiting PP a a
. principle
reagents ? .P.Pa a
w w w w w
w
www
17.State Heisenberg”s uncertainty
18.Give an example for ionic hydride and covalent hydride.
www
19.What is path function ? Give two examples .
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e
20.Define reaction quotient
N N N Neett
lalai.i. l a
l i
a .i. l a
l i
a
21.50g of tab water contains 20 mg of dissolved solids. What is the TDS val;ue in ppm?
et
assaa aadd s
a aa
s
22.How will you prepare ethane by Kolbe”s electrolytic method ?
a ad
a a
d s
a aa
s
23.Mention any two methods of preparation of haloalkanes from alcohols.
. P
.P . P
. P
.N
w w
w www
24.If an automobile engine burns petrol at a temperature of 1089 K and if the surrounding
www www
temperature is 294 K , calculate its maximum possible efficiency .
PART-III
lai
Answer the following any six questions 6 X 3 = 18
N Neett N Neett
25.calculate the empirical formula of a compound containing 76.6% carbon, 6.38%,
l a
l i
a .i. l a
l i
a .i. l a
l i
a
sa
assaa aa aa
hydrogen and rest of oxygen.
ddaass
26.compare the ionisation energy of beryllium and boron
ddaass
. P
. Paa
27.Distinguish between diffusion and effusion.
. P
. Paa
www w w
w
wwwH + S www
da
28.At particular temperature Kc = 4X 10-2 for the reaction

1
H2S(g) 2(g) 2(g)
2
Calculate Kc for each of the following reactions.
Pa
N eett
i) 2H2S(g)
N 2H2(g) + S2(g)
N Neett
l a
l i
a .iii). 3H S 3
l a
lai .i. l a
l i
a
assaa 29.What are the conditions whenaaad atends
a to behavelike an ideal solution? aassaa
3H + S
2 (g)
d
2(g)
aa ss 2
2(g)
dd
solution
aa
w.
30.Describe fajan‟s Rule .P. P . P

. P
w ww w ww
wwonwhyper conjugation
31.Write short notes www
ww
32.Explain Brich reduction

33.Give an example for each of the following type of organic compounds
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i) Non-benzonoid aromatic compound
N N N Neett
l a
l i
a .i.
ii) Aromatic heterocyclic compound
l a
lai.i. l a
l i
a
assaa iii) carbocyclic compound
aaddaasaa
s
ad
a a
d s
a aa
s
w
w .P. P w
w. P
. P
w
www w
www
N Neett N Neett
lalai.i. l a
l ai .i. 7708543401 Page 26 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
N N e ett N Neett
lalai .i. l a
l i
a .i. l a
l i
a
assaa ANSWER ALL THE QUESTIONS aa aa
PART-IV
d da as s s
5 X 5 = 25 aa
dd s
. P
.
34. a) i) Describe about magnetic Paa
quantum number ? .P.Paa
w w w w w
w
www www
2+ 3+
ii) Give the electronic configuration of Mn and Cr
(OR)
b) i) What are f-block elements ?
N Nett
e N Neett
ii) State the trends in the variation of electronegativity in group and periods
lalai.i. l a
l i
a .i.
35. a) Discuss the similarities between lithium and magnesium
l a
l i
a
et
assaa aaddas
a aa
s
b) i) Define entropy .Give its unit.
(OR)
ad
a a
d s
a aa
s
. P
.P . P
. P
.N
w w
w www
ii) List any three characteristics of gibbs free energy.
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36. a) Derive KC and KP for synthesis of ammonia
lai
(OR)
N Nee tt N Nee tt
b) Discuss the formation of C2 molecule using MO theory
l a
l i
a .i. l a
l i
a .i. l a
l i
a
sa
assaa 37. a) mention the shape of the following
a a ddaas aa
s
aaddaassaa
w w . P P
.PCl iv) SF v) IF
molecules based on VSPER
.
theory
ww P
. P
www w w
www
da
i) BF ii) BrF
3 iii)
3 5 6 7
(OR)
b) Describe any two types of constitutional isomers.
Pa
N Neett N Neett
l a
l i
a .i. l a
lai .i. l a
l i
38. a) An organic compound (A) C2H4 decolourises bromine water. (A) on reaction with
a
assaa ssaa saa
s
chloride gives (B) . (A) reacts with HBr to give (C) . identify (A), (B) and (C) explain
ad
adaa aaddaa
w.
the reactions.
ww. P
. P (OR) w
w . P
. P
w
www w
www
b) Starting from CH3MgI , how will you prepare the following ?
ww
i) Acetaldehyde ii) Acetone iii) Methane
N Neett N eett
****************
N
l a
l i
a .i. l a
lai.i. l a
l i
a
assaa aaddaasaa
s
ad
a a
d s
a aa
s
w
w .P. P w
w. P
. P
w
www w
www
N Neett N Neett
lalai.i. l a
l ai .i. 7708543401 Page 27 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
N Neett N Neett
lalai .i. l a
l i
a .i. l a
l i
a
assaa aaddaassaa
aaddaassaa
ww. P
. P w
w .P.P
w
www w
www
N Nett
e N Neett
lalai.i. l a
l i
a .i. l a
l i
a
et
assaa aaddas
a aa
s
ad
a a
d s
a aa
s
. P
.P . P
. P
.N
w w
w www
www www
l a
l i
a N
.i. Neett
lai l a
l i
a NNeett
.i.QUESTIONS l a
l i
a
sa
UNITWISE PUBLIC
assaa aaddaasaa
s
aaddaassaa
ww. P
. P w
w . P
. P
w
www w
www
da
Pa
N Neett N Neett
l a
l i
a .i. l a
lai .i. l a
l i
a
assaa ad
adaassaa
aaddaasaa
s
w.
ww. P
. P w
w . P
. P
w
www w
www
ww
N Neett N Neett
l a
l i
a .i. l a
lai.i. l a
l i
a
assaa aaddaasaa
s
ad
a a
d s
a aa
s
w
w .P. P w
w. P
. P
w
www w
www
N Neett N Neett
lalai.i. l a
l ai .i. 7708543401 Page 28 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
NNeett NNeett
lalai .i. Concepts Of ChemistrylalaAnd i .i. Chemical Calculations lalai
assaa aa aa
1.Basic
ddaass dd aass
. P
. Paa . P
.P a a
ONE MARKS ;- ww w w w w
wwwcompound has same percentage of carbonwwas w
1.which of the following that of ethylene
(C2H4) ? (mar 19)
N Nett
a) benzene
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b) ethane
lalai.i. c) propene
l a
l i
a .i. d) ethyne
l a
l i
a
et
assaa aa aa
2.The oxidation number of carbon in CH2F2 is ______ (jun19)
a) +4 ddas
a s b) -4 d a
d s
a s
. P
.Paa . P
. Paa
.N
c) 0
w w
w d)+2
www
www
3.The relative molecular mass of ethanol is ___ (sep20)
www
a) 0.46g b) 4.6 g
lai
c) 460g d) 46g
NNe tt
e NNeett
l a
l a .i. a) l a
l i
a .i. b) 5 moles of water
4. Which one of the following of presents 180g of water ? (sep21)
i l a
l i
a
sa
6.022 X 10 24
assaa c) 6.022 X 10 moles ofaawater ssaa s aa

s
moles of water
180
24
dda a d) 90 moles of water aa d a
d a
5.Which of the followingww . P
. P
compound(s) ww
has/have percentage of carbon same . P P
as.that in
ww wwww
da
ethylene (C H )w
2 ?w
4(sep21)
a) benzene b) propene c) ethane d) ethyne
6. Total number of electrons present in 1.7 g of ammonia is : (jul22)
Pa
N Neett 6.022𝑋 10 22
N Ne et t d) 6.022𝑋 10 24 6.022𝑋 10 23
l a
l i
a .i.
a) 6.022 X 1023 b)
1.7
l a
lai .i. c)
1.7
l a
l i
a 1.7
assaa a addaas aa
s
aaddaasaa
s
w.
2&3&5 MARKS :-
w
1.Calculate the equivalentw . P
massP
. of H SO (mar 19).(ipn : 9) w
w . P
. P
w w of oxygen in H O (mar 19). (ipn : w
wwnumber
2. calculate oxidation
2 4
ww
21)
w
ww
2 2
3.A compound having the empirical formula C6H6O has the vapour density 47. Find its
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molecular formula. (mar 19).(b/b-42) (ipn : 247)
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l a
l i
a .i. do you understand by the term mole ? l(jun19)(b/b-27)
alai.i. l a
l i
a
assaa 5.What are auto redox rections ?agive aa aa
4.What (ipn : 6)
ddaass d a
d s
a s
.P P a an example .(jun19) (ipn : 23)
. of ortho-phosphoric Acid.(sep20) www. . P
P aa
ww w
6.Define basicity.Find thewbasicity
w
w w + ww
Basicity is no. of moles of ionisable H ions present in 1 mole of the acid
ortho-phosphoric Acid H3PO4 H3PO4 basicity = 3 eq mol-1
N Neett N Neett
lalai.i. l a
l ai .i. 7708543401 Page 29 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
N Ne ett NNeett
lala .carbon,6.38%
. l a
l a .i. density is 47. (sep20) (b/b-42) lalai
7.Calculate the empirical formula and molecular of a compound containing 76.6%
i i i
assaa (ipn : 247) ss aa ssaa
of hydrogen and rest oxygen. Its vapour
a ad d aa aad daa
w w. PP
. of the following ? (sep21)(b/b-38) www. .P P
w
8.What is the empirical
w ww formula
w w w
a) Fructose (C H O )
6 12 6 ii) Caffeine ( C H N O )
8 10 4 2
9. Distinguish between oxidation and reduction . (sep21) (b/b-30)

N N eett N Neett
lalai.i. l l i
a .i.
10..Define Gram equivalent mass (May22) (b/b-28) (ipn :8)
a l a
l i
a
et
assaa 11.Calculate aas saa elements . (May22)
the oxidation number of underlined
ii) H SO P aad d ad
a a
d s
a aa
s
i) CO
. .P . P
. P
.N
2
w w w 2 4
www
i) CO 2 www www
lai
x+2(o) = 0
N Neet tx + 2(-2) = 0 N Neett

l a
l i
a .i. l a
l i
a .i. l a
l i
a
sa
assaa saa s aa
x-4 = 0
ddaa s ddaa s
x = +4 aa aa
w w . P
. P w
w . P
. P
w
wwwof carbon is +4 w
www
da
oxidation number
ii) H2SO4
Pa
N Neett 2(H)+x +4(o) = 0

N Neett
l a
l i
a .i. l a
lai .i. l a
l i
a
assaa aa aa
2(+1)+x +4(-2) = 0
d aass d aass
2+x -8a=
a 0d aa d
w.
w w. P P
.x-6 = 0 w
w . P
. P
wwww w
www
ww
x =+6
e tt
e
oxidation number of sulfur is +6
NN N N e tt
e
l a
l i
a .i. is meant by limiting reagents ? (jul22)lal(ipn
ai.i:.17) l a
l i
a
assaa 13.calculate the empirical formulaaaofddaacompound
assaa containing 76.6% carbon, 6.38%, aa
12.What
ddaass
hydrogen and rest ofw . PP
. (jul22) (b/b-42) (ipn : 247) . P
. Paa
w w
oxygen.
w ww
www www
N Neett N Neett
lalai.i. l a
l ai .i. 7708543401 Page 30 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
N N eet t 2.Quantum Mechanical N Nee

Modelt t Of Atom
lalai .i. l a
l i
a .i. l a
l i
a
assaa ONE MARKS ;- a ad da a s saa
aaddaassaa
w w . P P
in.an electric field is called _____ (mar 19) w
w .P.P
ww w
1.Splitting of spectral lines
a) Compton weffect b) stark effect www w
c) Zeeman effect d) shielding effect
2.The energy of an electron in the third orbit of hydrogen atom is –E . The energy of an
NN e ett N Neett
lalai.i.a) -3E
electron in the first orbit will be _____ (jun19)
l a
l i
a .i. l a
l i
a
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assaa 3.The maximum number of electrons aa aa
𝐸 𝐸
b) -
3
d da a s s c) -
9
d) -9E
d a
d s
a s
. P
.2Pa a . P
. Paa
that can be accommodated in L orbit is _____(sep20)
.N
w w w w w w
a) 8
www
4.Splitting of spectral
c) 4
ww
lines in an electric field is called : (May22) w
b) d) 6
lai
a) Compton effect b) Zeeman effect
N Neett
c) Stark effect
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l a
l i
a .i. l a
l i
a .i. l a
l i
5. The total number of orbitals associated with the principle quantum number n=3 (jul22)
a
sa
assaa a) 9
2&3&5 MARKS :-
b) 8
aaddaasaa
s c) 5
aaddaassaa d) 7
ww. P
. P w
w . P
. P
1.state and explaine pauli‟s exclusion principle. (mar 19).(b/b-31) (ipn :52 )
w
www w
www
da
2. Write the de-broglie equation. (mar 19). (ipn : 40 )

3. Define orbital.What are the n and l values for 3px and 4dx2-y2 electron ? (jun19)
(b/b-32) (ipn : 44,257 )
Pa
N eett N eett
4. calculate the uncertainty in the position of an electron, if the uncertainty in its velocity is
N N
l a
l i
a .i. l a
lai .i.
5.7 x 105 ms-1 (jun19) (ipn : 43,252 )EY :2 l a
l i
a
assaa aad aassaa
aaddaasaa
s
5.Calculate the orbital angular momentum for d and f orbital. ( jun19) (compulsory 2 mark)
d
w.
Angular momentum = 𝑙(𝑙

ww . P
.
+ P
1)
ℎ
w
w . P
. P
orbital angular w w
ww forl =d2
momentum
2𝜋
w
www
ww
ℎ
= 2(2 + 1)
N Neett N Neett
2𝜋
l a
l i
a .i. = 6
l
ℎ
a
la
2𝜋i.i. l a
l i
a
assaa orbital angular momentum for=af al=3
d a
d assaa
ℎ
ad
a a
d s
a aa
s
ww .P. P 3(3 + 1)
2𝜋
w
w. P
. P
w
www = 12
ℎ
2𝜋
w
www
ℎ
=2 3
2𝜋
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ℎ
N Neett
lalai.i. 2𝜋
l a
l ai .i. 7708543401 Page 31 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
N Neett N Neett
lala .i. l a
l i
a .i.
6.In degenerate orbitals, why do the completely filled and half filled configurations are more
i l a
l i
a
assaa aa aa
stable than the partially filled configurations ? (sep20) (compulsory 2 mark)
dd a as s d aass
dother
. PP a
The stability of exactly half-filled a
.This can be explained using symmetry w
orbitals in degenerate orbitals is stronger .P P a
. of
than a
that of
w w w w w
www
partially filled configurations.
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exchange energy . half and completely-filled subshells become more stable because of the
symmetrical distriburion of electron.
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e
Reason :-
N N N Neett
lalai.i. i)
l a
l i
a .i.
Symmetrical distribution of electron in orbital
l a
l i
a
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assaa ii) Exchange energy
aadda as saa
a ad da as s aa
. PP
. Principle . (sep20) (ipn : 42 ) www. . P
P
.N
ww
7.State Heisenber‟s Uncertainty
w
w of angular nodes and radial nodes present
wwnumber
8.Calculate the total wwwin 3d and 4f orbitals.
(sep20) (b/b-28) (ipn : 257 )
lai
9.What is exchange energy ? (sep21) (ipn :56 )
N Neett N
10.State Aufbau principle (sep21) (ipn : 52 )
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l a
l i
a .i. l a
l i
a .i. l a
l i
a
sa
assaa aa aa
11.Write a note on principal quantum number (sep21) (ipn : 44 )
ddaass ddaass
12.Calculate the maximum number of electrons that can be accommodated in L
shell(May22)
. P
. Paa . P
. Paa
www w w
w
www www
da
The maximum number of electrons that can be accommodated in a given

shell is 2n2.
L shell is n = 2
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N Neett
l a
l i
a .i. =8
l a
lai .i. l a
l i
a
assaa ssaa saa
s
maximum number of electrons that can be accommodated in L shell = 8
ad
adaa aaddaa
w.
13.How many orbitals are possible for n=4 ? (May22) (b/b-27)(ipn : 256 )
ww. P
. P w
w . P
. P
14. Write the electronic configuration and orbital diagram for nitrogen ? (May22) (ipn :54 )
w
www w
www
15.State Heisenberg”s uncertainty principle (jul22) (ipn : 42 )
ww
16. Describe about magnetic quantum number ? (jul22) (ipn : 45 )

17.Give the electronic configuration of Mn2+ and Cr3+ (jul22) (b/b : 39 )
N Neett N Neett
l a
l i
a .i. Mn 1s 2s 2p 3s 3p 4s 3daa
2+ 2 2
l l i
6.i. 2 6 0
l a
l
5
i
a
assaa Cr 1s 2s 2p 3s a
3+
aa
2
dd a
3pssaa3d
4s 2 6 2 6
ad
a a
d s
a aa
s
0 3
ww. P
. P w
w. P
. P
w
www w
www
N Neett N Neett
lalai.i. l a
l ai .i. 7708543401 Page 32 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
N N eet t 3.Periodic ClassificationNOf Neett

lalai .i. l a
l i
a .i. Elements
l a
l i
a
assaa ONE MARKS ;- a ad a
d s
a aa
s
aaddaassaa
w w . PP .
. gain enthalpy is _____ (mar 19)www.PP
www
1.The element with positive
a) Argon w
electron
b) Fluorine www
c) Hydrogen d) sodium
2.The effective nuclear charge experienced by the d1 electron in the given electronic
N Nett
e N Neett
configuration, (1s)2 (2s,2p)8 (3s,3p)8 (3d)1 (4s)2 is : (jun19)
lalai.i. l a
l i
a .i. l a
l i
a
et
assaa aa aa
a) 4 b) 3 c) 2.1 d) 6.9
ddas
a s d a
d s
a s
3.Assertion : Helium has the highest value of ionisation energy among all the elements
. P
.Paa . P
. Paa
.N
known.
w w
w www
www www
Reason : Helium has the highest value of electron affinity among all the elements known.
(sep20)
lai
a) Both assertion and reason are false
N Neett N Neett
b) Both assertion and reason are true and the reason is correct explanation for the
l a
l i
a .i. assertion
l a
l i
a .i. l a
l i
a
sa
assaa aaddaasaa
s
aaddaassaa
c) Both assertion and reason are true but the reason is not the correct explanation for
ww. P
the assertion
. P w
w . P
. P
w
d) Assertion is true and reason is false .
www w
www
da
2&3&5 MARKS :-
1.Explain diagonal relationship (mar 19) (b/b-41) (ipn : 90)
Pa
N N e ett N N e
2.State and explain Dobereiner”s “triad” (mar 19) (ipn :69 )
ett
l a
l i
a .i. potential of nitrogen is greater thanlalthatai .iof. oxygen . explain by giving l a
l i
a
assaa appropriate reason. ( jun19)(b/b-44i) aa: 85 ) aa
3.Ionisation
dda as s dd aa ss
aa (ipn
a a
w.
ww .
4.Give the general electronic P P
.configuration of lanthanides and actinides. (ww . PP
. (b/b-36)
jun19)
(ipn :78 ) w ww w wwww
ww
5.Derive ionic radius using pauling‟s method . (sep20) (b/b-39) (ipn : 83)
N e ett N ee tt
6. Explain why the electron affinity of Be and N is almost zero(sep20) (ipn : 86)
N N
l a
l i
a .i. electronegativity. State the trends in the
l a
lai.i. of electronegativity in l a
l i
a
assaa group and period (sep21) (b/b-47) aa aa
7.Define variation
d d aa s s d a
d s
a s
.P Pa a (ipn :87,88 )
. (ipn : 79 ) . P
. P aa
w w w w
8.Define atomic radius. (sep21)
ww w w
w w
9.Explain diagonal relationship (sep21) (ipn : 90 )
ww
10.Define electron affinity (May22) (ipn : 86 )
N Neett N Neett
lalai.i. l a
l ai .i. 7708543401 Page 33 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
NN eett N N eett
lala .i. are f-block elements ? (jul22) (ipn : 78lala)i.i.
11.Describe the pauling method for determination of ionic radius . (May22) (ipn : 83 )
i l a
l i
a
assaa 13. State the trends in the variationaadofdaelectronegativity
assaa in group and periods (jul22)aaddaassaa
12.What
w w.P. P ww.P
.P
w ww
(b/b-47) (ipn :87,88
w )
w
w ww
14. define valency (mar 19) (ipn :88 )
15.How will you determine the ionic character in covalent bond using electronegativity
N N e t t? (May22)
e N N e ett
lalai.i. values
l a
l i
a .i. l a
l i
a
et
assaa bonds ssacharacter
a in various A – B polar covalentaassaa
δ- δ+
a a da a
Pauling estimated the percentage of ionic
d ad
a d
. P
.P
from known (X –X ) values and has derived the following
. P
. P
.N
w
A
w wB
www
conclusions : www www
(i) When (XA–XB) = 1.7, the amount of ionic character in Aδ- – Bδ+ bond is 50%
l a
l i
a NN
.i50%
tt
. covalent. lai l a
l i
a N
.i. N ett
and that of covalent character is also 50%. Thus A-B bond is 50% ionic and
e e e
l a
l i
a
sa
assaa (ii) When (X –X ) < 1.7, the amount
A B
aadda
ofas saacharacter in A – B bond is less aassaa
ionic δ- δ+
aadd
w w. P
. P
than 50% and that of covalent character is more than 50%. Thus A –
wwB. P
. P
δ- δ+
w
www covalent and hence is represented as A–B. www w
da
bond is predominantly
(iii) When (XA–XB) > 1.7, the amount of ionic character in Aδ- – Bδ+ bond is
Pa
NN ett N N e tt
more than 50% and that of covalent character is less than 50%. Hence Aδ- –
e e
l a
l i
a .iB. bond is predominantly ionic and hencelaislairepresented
δ+ .i. –
as A B +
l a
l i
a
assaa aa dda assaa
aaddaasaa
s
w.
w
16.compare the ionisationw . PP
. of beryllium and boron (jul22) (ipnw
energy .
)w.
: 85w P
P
wwww www
ww
N Neett N Neett
l a
l i
a .i. l a
lai.i. l a
l i
a
assaa aaddaasaa
s
ad
a a
d s
a aa
s
w
w .P. P w
w. P
. P
w
www w
www
N Neett N Neett
lalai.i. l a
l ai .i. 7708543401 Page 34 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
N Ne ett 4.Hydrogen N Neett

lalai .i. l a
l i
a .i. l a
l i
a
assaa ONE MARKS ;-
1.What percentage of solution ofa
Had a assaa
Odis called as “100-volume‟ H O ? (mar 19)aa ddaassaa
w w . P
. P 2 2 2 2
ww .P.P
a) 15%
c) 20% w ww w b) 50%
d) 30% ww ww
2.The type of H-bonding present in orthonitro phenol and p-nitro phenol are ______
Respectively. (jun19)
N Nett
e N Neett
a) Inter molecular H-bonding and intra molecular H-bonding
lalai.i. l l i
a .i.
b) Intra molecular H-bonding and inter molecular H-bonding
a l a
l i
a
et
assaa s aa s aa
c) Intra molecular H-bonding and no H-bonding
ddaa s d a
d
d) Intra molecular H-bonding and intra molecular H-bonding a s
. P
.Paa . P
. Paa
3.Intra molecular hydrogen bonding is present in________ (sep20)
.N
w w
w www
c) Waterwww
a) Ortho-nitro phenol
www b) Ice
d) Hydrogen fluoride
4.Assertion ; permanent hardness of water is removed by treatment with washing soda
lai
Reasons : Washing soda reacts with soluble calcium and magnesium chloride and sulphate
N Neett N Neett
l a
l i
a .i. l a
l i
a .i.
in hard water to form insoluble carbonates. (sep21)
l a
l i
a
sa
assaa aa aa
ddaass ddaass
b) Both assertion and reason are true and reason is the correct explanation of assertion
. P
. Paa
c) Both assertion ans reason are false . P
. Paa
www w w
w
www www
da
d)Both assertion and reason are true but reason is the correct explanation of assertion
5.Tritium nucleus contains : (May22)
a) 1p+2n b) 1p+on
Pa
c) 1p+1n d) 2p+1n
N Neett
6.Tritium is a ______ emitter(jul22)
N Neett
l a
l i
a .i. a) α b) β l a
lai .i. c) γ l a
l i
a
assaa aa aa
d) none of these
2&3&5 MARKS :-
ddaass ddaass
aa aa
w.
ww. P
. P
1.How is Tritium prepared ? (mar 19)(ipn : 104 )
w
w . P
. P
w
www
2. complete the following equation (ipn : 111 )
Na2O2 + ?  Na2SO4+ H2O2 (mar 19) w
www
ww
3.What is syn gas ? How it is prepared ? ( jun19) (ipn :103 )

4.Why hydrogen peroxide is stored in plastic bottle containers not in glass container ?
eett
(jun 19) (ipn : 112 )
N N N Neett
l a
l i
a .i. l lai.i.
5.Write the exchange reactions of Deuterium. (sep20) (ipn : 105 )
a l a
l i
a
assaa saa
s s aa
s
6.How do you convert para hydrogen into ortho hydrogen. (sep20) (ipn : 102 )
aaddaa ad a
d a
7.Write the laboratory method of preparation of hydrogen . (sep20) (ipn : 103 )
a
w
w .P. P w
w. P
. P
8.How do you convert para hydrogen into ortho hydrogen ? (sep21) (ipn : 102 )
w
www w
www
9.Mention the three types of covalent hydrides . (May22) (ipn : 113 )
10.Give an example for ionic hydride and covalent hydride. (jul22) (ipn : 113 )
N Neett N Neett
lalai.i. l a
l ai .i. 7708543401 Page 35 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
N Neett 5.Alkali And Alkaline N Neet t Metals

Earth
lalai .i. l a
l ai .i. l a
l i
a
assaa ONE MARKS ;- aa ddaassaa
aa ddaassaa
w w . P P
. CO
1.Find A in the following reaction CaO + 3C A + CO
w w .P.
(marP19)
a) CaC
2. which compound
w
wwisw b) c) Ca
named as “blue john” among the followingw
2 2 w
ww ? (mar 19)
d) Ca
compounds
O 2
a) Ca3(PO4)2 b) CaO c) CaH2 d) CaF2

3.When CaC2 is heated in atmospheric nitrogen in an electric furnace, the compound formed
N ett
e
is __________ (jun19)
N N Nee tt
lalai.i. a) Ca(CN)2 b) CaNCN
l a
l ai .i.
c) CaC2N2 d) CaNC2
l a
l i
a
et
assaa a
4.Formula of Gypsum is ________ (sep20)
a d
a d assaa
a addaassaa
b).P P
. in bunsens burner (sep21) . P
. P
1
.N
a) CaSO CaSO .2H O c) CaSO . H 0 d) CaSO . H 0
4
www w 4 2 4
2
w
2
w w w 4 2
w
a) Lilac (violet )
w
5.Flame colour of potassium salts
b) crimson red c) Apple green
w
wd) yellow
lai
6. Formula of plaster of paris (sep21)
N eett
a) 3CaSO4.H2O
N b) CaSO .2H O c) 2CaSOe
N N e t t O d) CaSO . H O
.2H
𝟏
l a
l i
a .i. 4 2
l a
l ai .ifollowing
. 4 2 4
𝟐
2
l a
l i
a
sa
assaa 8.Which aac) Rubidium aa
7.Spodumene is the mineral source for which of the alkali metal ? (May22)
a) Lithium b) Sodium aa
d d ss d) Potassium aa
dd ss
. P
. Paa
of the following has highest hydration energy ? (May22)
. P
. Paa
w w w wd) ww
wwinwdevising photoelectric cells. (jul22) www
da
a) BaCl 2 b) MgCl 2 c) SrCl

2 CaCl 2
9._________ is used
a) Lithium b) Sodium c) Potassium d) Caesium
10. Among the following the least thermally stable is : (jul22)
Pa
N Neett
a) K2CO3 b) Na2CO3
N Neett
c) BaCO3 d) Li2CO3
l a
l i
a .i. l a
lai .i. l a
l i
a
assaa aa aa
2&3&5 MARKS :-
d aass
1.Explain why Ca(OH)2 is used in white washing . (mar 19) (ipn : 145 )
d ddaass
aa aa
w.
. P P
2.Among the alkaline earth metals BeO is insoluble in
ww . w
w . P
. P
w
www w
water but other oxides are soluble .why ? (mar 19) (ipn : 142 )
www
3.Write any two similarities between beryllium and aluminium ( jun19). (ipn : 140 )
ww
4.Among the alkali metal halides, which is covalent ? explain with reason. ( jun19)(ipn:130)
5.why blue colour appears during the dissolution of alkali metals in liquid ammonia
eett
(jun19) (ipn : 130 )
N N N Neett
l a
l i
a .i. l lai.i.
6.How is bleaching powder prepared ? (sep20) (ipn :145 )
a l a
l i
a
assaa saa s aa
7.Write the uses of magnesium. (sep20) (ipn : 141)
ddaa s d a
d a s
8. Discuss the similarities between beryllium and aluminium (sep21) (ipn : 140 )
.P. Paa . P
. Paa
9. What are the reasons for the anomalous properties of Berylium ? (May22) (ipn : 139)
w w
w w w
w
www www
10. Give any three properties of beryllium that are different from other elements of the
group (May22) (ipn : 139 )
11. Discuss the similarities between lithium and magnesium (jul22) (ipn :129 )
N Neett N Neett
lalai.i. l a
l ai .i. 7708543401 Page 36 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
N N eett 6.Gaseous N N
State ee tt
lalai .i. l a
l i
a .i. l a
l i
a
assaa ONE MARKS ;-
aadd aa s aa
s
aaddaassaa
ww . P
. P
1.use of hot air ballone in meteorological observatory is an (mar 19)
w
w .P.P
www
application of________
a) Kelvin‟swLaw b) Brown‟s Law wwww
c) Boyle’s Law d) Newton‟s Law
2.When an ideal gas undergoes unrestrained expansion, no cooling occurs because the
ett
e
molecules ________ (jun19)
N N N Neett
lalai.i. l a
l i
a .i.
a) are above the inversion temperature
a i
b) exert no attraction force on each other
l l a
et
assaa s aa
s s aa
s
c) do work equal to the loss in kinetic energy d) collide without loss of energy
aaddaa
3.Gases tent to behave ideally only at _____ (sep20)
ad
a a
d a
. P
.P . P
. P
.N
a) Low temperature and low pressure b) High temperature and High pressure
w w
w www
www
c) High temperature and low pressure
4. Rate of diffusion of a gas is : (sep21) www
d) Low temperature and High pressure
a) directly proportional to the square root of its molecular weight
lai
b) directly proportional to its density
N eett N eett
c) inversely proportional to the square root of its molecular weight
N N
l a
l i
a .i. l a
l i
a .i.
d) directly proportional to its molecular weight
l a
l i
a
sa
assaa a) CO aadd a
b) NO
saa
s c) CO2 aaddaassaa
5.7.5 g of a gas occupies a volume of 5.6 L at 00C and 1 atm pressure .The gas is (May22)
a d) N2O
ww. P
. P w
w . P
. P
6.A bottle ao ammonia and a bottle of HCl connected through a long tube are opened
w
www w
www
da
simultaneously at both ends. The white ammonium chloride ring will be first formed :
(May22)
a) near the ammonia bottle b) at the centre of the tube
Pa
N Neett
c) throughout the length of the tube
N Neett d) near the hydrogen chloride bottle
l a
l i
a .i. l a
lai .i. l a
l i
7.If temperature and volume of an ideal gas is increased to twice its values, the initial
a
assaa aa aa
pressure P becomes : (jul22)
a) 4P
d aass
b) 2P
d c) P
ddaass d) 3P
aa aa
w.
2&3&5 MARKS :-
ww. P
. P w
w . P
. P
w
www
1.what are ideal gas ? (mar 19) (ipn : 169 )
2. State Diffusion law. (mar 19) (ipn : 168 ) w
www
ww
3.What is inversion temperature ? ( jun19) (ipn : 175)

4.Derive ideal gas equation. ( jun19) (ipn : 165 )
N N ett N N ett
5.what is boyle‟s temperature ? .what happens to real gases above and below the boyle‟s
e e
l a
l i
a .i.
temperature ? ( jun19) (ipn : 171 )
l a
lai.i. l a
l i
a
assaa aa aa
6.Write the mathematical formula for compressibility factor „Z‟ (sep20) (ipn : 169 )
ddaass d a
d s
a s
7. Name the different methods of liquefaction of gases. (sep20) (ipn : 175 )
.P. Paa . P
. Paa
8.Inside a certain automobile engine , the volume of air in a cylinder is 0.375 dm3 ,
w w
w w w
w
www www
when the pressure is 1.05atm . When the gas is compressed to a volume of 0.125 dm3
at the same temperature , What is the pressure of the compressed air ? (sep21)
(ipn :162-268) (compulsory 3 mark)
9.State Dalton Law of partial pressures. (May22) (ipn : 166 )
Neett N Neett
10.Distinguish between diffusion and effusion. (jul22) (ipn : 168 )
N
lalai.i. l a
l ai .i. 7708543401 Page 37 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
N N eett N Neett
lalai .i. 7.Thermodynamics
l a
l i
a .i. l a
l i
a
assaa ONE MARKS ;- aad d a a ssaa
aaddaassaa
ww . P
. P w
w .P.P
-1
a) JK mol
w
www b) KJ mol
1.The SI unit of molar heat
-1
capacity is : ______ (mar 19)
-1
c) Kj mol -1w
wwwd) cm
2.Among the following statements, which one is /are correct ? (jun19)
i) During cyclic process the amount of heat absorbed by the surrounding is equal to
N Nett
e work done on the surrounding
N Neett
lalai.i. l a i
a .i.
ii)Refractive index is an example for intensive property
l l a
l i
a
et
assaa aadd s
a aa
s
ad
a d s
a aa
s
iii) If the enthalpy change of a process is positive then the process is spontaneous
a a
iv) The entropy of an isolated system increases during spontaneous process
. P
.P . P
. P
.N
w w
w
a) (i), (ii), (iii) b) (i), (iv)
ww
c) (ii), (iv)
w
d) (ii) only
a) G www b) U www
3.Among the following which is the path function ? (sep20)
c) H d) q
lai
4. Heat of combustion is always : (sep21)
N Neett a) zero
N Neett b) positive
l a
l i
a .i. l l i
c) either positive or negative
a a .i. d) negative
l a
l i
a
sa
assaa saa
s ssaa
5.The intensive property among the quantities below is : (May22)
a) Enthalpy
aaddaa
b) mass c)
𝒎𝒂𝒔𝒔
aaddaa d) volume
ww. P
. P w
w . P
𝒗𝒐𝒍𝒖𝒎𝒆
. P
6.The amount of heat exchanged with the surrounding at constant pressure is given by the
w
www w
www
da
quantity : (jul22)
a) ΔE b) ΔH c) ΔS d) ΔG
Pa
NN e ett NNee tt
l a
l i
a .i. the third law of thermodynamics (mar 19)
2&3&5 MARKS :-
l a
lai .i. (ipn : 218 ) l a
l i
a
assaa 2.calculate the entropy change during ssaa s aa
s
1.state b/b-42
aad da a
the melting of one mole of ice into water ata
0ad a
c.d
a
w.
enthalpy of fusionw w w . PP
.6008 J mol . (mar 19) (ipn : 213 ) www. . P P
w w w
of ice is -1
w w w
ww
3.C + O  CO Calculate the standard entropy change for the above reaction, given
(s) 2(g) 2(g)
the standard entropies of CO2(g), C(s), O2(g) are 213.6,5.740 and 205 jk-1 respectively.
N Ne ett N Ne et t (mar19) (ipn : 212 )
l a
l i
a .i. l a
la i.i. l a
l i
a
assaa 4.Define a s
a s
molar heat capacity. Give its unit.
5. How do you measure heat P aa d d
a( ajun19) b/b-34(ipn : 201 )
ad
a a
d s
a aa
s
w w . . P
changes at constant pressure ? ( jun19) (ipn :
w .
204
w P
. P
)
ww
6.state zeroth Law ww
of Thermodynamics. (sep20) (ipn :195 ) www w
7.Distinguish between extensive and intensive property. (sep20) (ipn : 189 )
N Neett N Neett
lalai.i. l a
l ai .i. 7708543401 Page 38 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
NN ee tt NNe ett
lalai .i. the relation between enthalpy ΔH andlainternal
l i
a .i. energy ΔU for an l a
l i
a
assaa ideal gas. (sep20) (ipn : 197 a)addaassaa s aa
s
8.Derive
aa dd aa
ww . PP
. during the melting of one mole of icew w w. PP
. at 0 c and
w w w
9. Calculate the entropy
w change
-1
w w w
into water 0
1 atm pressure. Enthalpy of fusion of ice is 6008J mol (sep20) (ipn : 213 )
10.Define Hess‟s law of constant heat summation. (sep21) (ipn : 207 )
N N ee tt N Neett
lalai.i. l l ai .i.
11.Give any two characteristics of gibbs free energy ? (sep21) (b/b-52)
a l a
l i
a
et
assaa 12. State the first law of thermodynamicss
aa dda a saa (ipn : 195 )
(sep21)
ad
a a
d s
a aa
s
.
13. What are the conditions for P
.Pthe spontaneity of a process? (sep21) (ipn :
.
215P
. P
)
.N
w w w w w w
www for the spontaneity of a process (May22)ww
14.What are the condition (ipnw: 215 )
15.Explain sign convention of heat (May22) (ipn : 192 )
l a
l i
a NN
17.What
ett
lai
.i. is path function ? Give two examplesl.al(jul22)
ai NN ett
16. Explain the characteristics of internal energy . (May22) (ipn : 191 )
e e
.i. (ipn : 191 ) l a
l i
a
sa
assaa 18.If an automobile engine burnsapetrol
ad a
d a aa
atss a
temperature
dda a
of 1089 K and if the surrounding
aa
ssaa
w w . P
. P
temperature is 294 K , calculate its maximum possible efficiency .
ww
(jul22) . P
. P
w
www 2 mark) www w
da
(ipn : 211 ) (compulsory

19.Define entropy .Give its unit. (jul22) (ipn : 210,211 )
Pa
Neett N Neett
20. List any three characteristics of gibbs free energy. (jul22) (b/b-52)
N
l a
l i
a .i. l a
lai .i. l a
l i
a
assaa ad
adaassaa
aaddaasaa
s
w.
ww. P
. P w
w . P
. P
w
www w
www
ww
N Neett N Neett
l a
l i
a .i. l a
lai.i. l a
l i
a
assaa aaddaasaa
s
ad
a a
d s
a aa
s
w
w .P. P w
w. P
. P
w
www w
www
N Neett N Neett
lalai.i. l a
l ai .i. 7708543401 Page 39 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
N N eet t 8.Physical And Chemical N Neett

Equilibrium
lalai .i. l a
l ai .i. l a
l i
a
assaa ONE MARKS ;-
aad daa s saa
aaddaassaa
w w P
P
1.When Δng is negative in chemical
.
K.=1/K
equilibrium reaction then (mar 19)
w
w
-ve .PP
K. > K
a) K <K
2.If k and k for w
b
p
f aw
c
w b)
reversible
p c c) K =K (RT)
-5
p c
w
w reaction are 0.8 x 10 and 1.6x 10 respectively
www ,the value of
d)
-4
p c
equilibrium constant is _______ (jun19)

a) 20 b) 0.2 x10-1 c) 0.05 d) 0.2
Nett
e N Neett
3.Which of the following is incorrect statement ? (sep20)
N
lalai.i. l a
l i
a .i.
a) Equilibrium constant varies with temperature
l a
l i
a
et
assaa s aa
s s aa
s
b) For a system at equilibrium ,Q is always less than the equilibrium constant
aaddaa ad
a
c) Equilibrium can be attained from either side of the reaction a
d a
. P
.P . P
. P
.N
d) Presence of catalyst affects both the forward reaction and reverse reaction to the same
w w
w www
extent.
www www
4. For the following reversible rections at equilibrium A + B C. If the
lai
concentration of the reactants A and B are doubled, then the equilibrium constant will :
(sep21)
N Neett a) be halved
N Neett b) be doubled
l a
l i
a .i. c) remain the same
l a
l i
a .i. l
d) become one fourtha
l i
a
sa
assaa aasaa
s
5. Which one of the following is incorrect statement ?(may22)
aadd aaddaassaa
ww P
. P w
w . P
. P
a) Presence of catalyst affects both the forward reaction and reverse reaction
.
w
www w
www
da
to the same extent.

b) for a system at equilibrium Q is always less than the equilibrium constant
c) equilibrium constant varies with temperature
Pa
d) equilibrium can be attained from either side of the reaction

N Neett N Neett
l a
l i
a .i. l a
lai .i.
6.If X is the fraction of PCl5 dissociated at equilibrium in the reaction
l a
l i
a
assaa aa aa
PCl5 PCl3 + Cl2
ddaass d aass
Then Starting with 0.5 mole of PCl5 , the total number of moles of reactants and products
d
aa aa
w.
. P P
at equilibrium is ; (jul22)
ww . w
w . P
. P
a) 0.5-X
w w w
w b) X+ 0.5
w
w w
w
c) 2X+0.5 d) X+1
ww
2&3&5 MARKS :-
1.Define –Le-Chatelier principle. (mar 19) b/b-32(ipn : 16 )
NNee tt N N eett
l a
l i
a .i. the balanced chemical equation for thelalai.i. K =
2.Write
[𝐶𝑎𝑂 (𝑆) ][𝐶𝑂2(𝑔) ]
(mar 19) (ipn : 8 )
l a
l i
a
assaa aa aa
c
[𝐶𝑎𝐶𝑂 3(𝑔) ]
CaCO add a as s d da ass

. P3
P a CaO + CO
.inert gas on the rection at equilibrium ? w . P
.
2
Paa
w w ww
3.What is the effect of added
w ww
(jun19)b/b-38(ipn :19 )
ww ww
4.Derive the relation between kp and kc for a general homogeneous gaseous reaction.
(jun19)b/b-39 (ipn :6 )
N Neett N Neett
lalai.i. l a
l ai .i. 7708543401 Page 40 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
N Ne tt
e N Neett
lalai .Define
i . reaction quotient. (sep20) (ipn : 11 )lalai.i.
5.Explain homogeneous and heterogeneous equilibria. (sep20) (ipn : 5 )
l a
l i
a
assaa 7.What is the relation between Kaaand s saa ssaa
6.
d da a a a ddaa
(sep21)w w w . PP
. :7) P C
ww P.P
K ? Give one example for which K is equal
. P
to K .C
w w w
b/b- 28(ipn
w ww w
8.What are homogeneous and heterogeneous equilibria? Give example (sep21) (ipn :5 )
9.Give a balanced chemical equation for the equilibrium reaction for which the equilibrium
NN e ett N Neett
lalai.iconstant
. is given by expression Kc = lalai.i.(May22) b/b-37 (ipn : 295)
[𝑁𝐻3 ]4 [𝑂2 ]5
l a
l i
a
et
assaa aa aa
[𝑁𝑂]4 [𝐻2 𝑂]6
ddaass d a
d s
a s
. P Paa . P Paa
6H .O .
.N
4NO w
+w w w
w
www
2 4NH + 5O
wwww 3 2
lai
10.The equilibnrium concentrations of NH3 and N2 and H2 are 1.8 x10-2M , 1.2x10-2M and
N Ne ett N Neett
3x 10-2 M respectively. Calculate the equilibrium constant for the formation of NH3 from
l a
l i
a .iN. and H (May22) (ipn :15 ) (compulsory l a
l i
a .mark)
i . l a
l i
a
sa
assaa 11.Define reaction quotient (jul22)aad(ipndaa:s11)saa ssaa
3
2 2
a add aa
ww . PP
. = 4X 10 for the reaction (jul22) (b/b-44 w
w . PP
. : 295)
w
www w
www
da
-2
12.At particular temperature K c ) (ipn
1
H2S(g) H2(g) + S2(g)
2
Pa
N N eett N Ne
Calculate Kc for each of the following reactions.
ett
l a
l i
a .i.i) 2H S 2H +S
l a
lai .i. l a
l i
a
assaa ii) 3H S aa a a
2 (g) 2(g) 2(g)
d a
+d S ass 3
ddaass
aa aa
w.
3H
2 (g)
KP w
13. Derive KC and w w . P
. P
2(g)
2
2(g)
synthesis of ammonia (jul22) (ipn : 14 ) ww

w . P
. P
www for
www
ww
N Neett N Neett
l a
l i
a .i. l a
lai.i. l a
l i
a
assaa aaddaasaa
s
ad
a a
d s
a aa
s
w
w .P. P w
w. P
. P
w
www w
www
N Neett N Neett
lalai.i. l a
l ai .i. 7708543401 Page 41 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
N Neett 9.SolutionsN Ne ett

lalai .i. l a
l i
a .i. l a
l i
a
assaa ONE MARKS ;-
aad
1.osmotic pressure ( π) of a solution d
is
a assaa
given by the relation __ (mar 19) aadd a s
a aa
s
a) π rt=n ww . P
. P b) V= π nRT w
w .P.P
w
c) π= n RTw ww d) π V=nRTww ww
2.Assertion : Mixture of carbon tetrachloride and chloroform show positive deviation from
raoult‟s law
Nett
e N Neett
Reason : In the mixture the inter molecular force of attraction between chloroform and
N
lalai.i. l a
l i
a .i. l a
l i
carbon tetrachloride is weaker than those between molecules of carbon
a
et
assaa s aa s aa
tetrachloride and chloroform molecules. (jun19)
ddaa s d a
d a s
a) Both assertion and reason are correct and reason is the correct explanation of
assertion
. P
.Paa . P
. Paa
.N
w w
w www
www www
b) Both assertion and reason are correct and reason is not the correct explaination for
assertion
lai
d) Assertion is true , but reason is false
N e ett N Neett
3.osmotic pressure (π) of a solution is given by the relation (sep20)
N
l a
l i
a .i.a) π RT=n l a
l ai .ib). π= n RT l a
l i
a
sa
assaa 4.Thec) molality
π V=nRT
aa dda as aa d) None of these
s
1.8g of glucose dissolved in 250g of wateraa dda assaa
ww . P
. P
of a solution containing
ww . P
. P is (sep21)
ww w w
da
a) 0.02M b) 0.2M c) 0.04M d) 0.01M

wwsolutions of NaCl and KCl are prepared . If the
5.Equimolal aqueous wwfreezing point of NaCl
is -20c , the freezing point of KCl solution is expected to be (May22)
a) -10C b) -20C
Pa
N Neett
c) 00C
N Neett d) -40C
l a
l i
a .i. l a
lai .i. l a
l i
a
6.Which one of the following binary liquid mixtures exhibit positive deviation from Raoult‟s
assaa law ? (jul22)
ad
adaassaa
aaddaasaa
s
w.
ww P
. P
a) Acetone + Chloroform
. w
w . P
. P
b) Water + Nitric acid
c) HCl + Water
w
www w
www
d) Ethanol +Water
ww
2&3&5 MARKS :-
NN e tt N N ett
1.State the term “isotonic solution” (mar 19)(b/b-37) (ipn : 56)
e e
2.i.
i .i. 19) (ipn : 40)
. and HCl do not obey Hentry‟s law. Whylala?i(mar i
l a
l a NH
l a
l a
assaa 3.What is vapour pressure of a liquid aais relative lowering of vapour aa
3
dda
?as s
what
dd aas s
. P
. Paa . P
. Paa
ww
pressure ?(jun19) (b/b-32
w
)
w ww
4.What is the masswwof w wwiswisotonic with 6gl-
glucose (C H O ) in it one litre solution which
6 12 6
1 of urea (NH2CONH2) ? ( jun19) (ipn : 57,299)ey-13
N Neett N Neett
lalai.i. l a
l ai .i. 7708543401 Page 42 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
N N ee tt NN e e tt
lalai .Draw
i . and explain the graph obtained by plotting
l a
l i
a .isolubility
. versus temperature for calcium lalai
assaa chloride . ( jun19) (ipn : 37) aaddaassaa ssaa
5.
aadda a
6.Calculate the molew w w . P P .P P
.of methanol and water when 0.5 mole ofwmethanol
ww . is mixed
w w w
fraction
w
w w
with 1.5 moles of water. (ipn : 33) (SEP20)
7.What is van‟t hoff factor „i‟ ? (sep20) (ipn : 58)
N N eett N N eett
lalai.i. l l ai .i.
8.What is molal depression constant ? (sep21) (ipn : 54)
a l a
l i
a
et
assaa 9.What aas
are ideal solutions ? Give example
a ad d saa (ipn :46 )
(sep21)
ad
a a
d s
a aa
s
10.How will you determine the
. P
.Pmolar mass of a solute from osmotic
.
pressure P
.
? P
.N
w
) w
w w w ww
(sep21)(ipn:56w
w www
11.Define the term “isotonic” solution . (May22) b/b-37(ipn :56 )
l a
l i
a NN ett
.ivapour lai N
. pressure values. (May22) (ipn : 50 l)alai.i. N ett
12.Write the formula to calculate the molar mass of a solute from realative lowering of
e e
l a
l i
a
sa
assaa 13. How will you determine the molar
aad daas s
massaofasolute from elevation of boiling point ? aassaa
a d
a d
ww . P
. P (May22)
w w
(ipn. P
.
:53P)
w
w 20 mg of dissolved solids. What is theww w wval;ue in ppm?
da
wwcontains
14.50g of tab water TDS
(jul22) (ipn :34 )
Pa
Neett N Neett
15.What are the conditions when a solution tends to be have like an ideal solution?
N
l a
l i
a .i. l a
lai .i. (jul22) (ipn : 46 ) l a
l i
a
assaa ad
adaassaa
aaddaasaa
s
w.
ww. P
. P w w . P
. P
w
www wwww
ww
N Neett N Neett
l a
l i
a .i. l a
lai.i. l a
l i
a
assaa aaddaasaa
s
ad
a a
d s
a aa
s
w
w .P. P w
w. P
. P
w
www w
www
N Neett N Neett
lalai.i. l a
l ai .i. 7708543401 Page 43 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
N Neett 10.Chemical N eett

Bonding
N
lalai .i. l a
l ai .i. l a
l i
a
assaa ONE MARKS ;-
a
1.which of the following moleculeadda
does
as saa
not contain π bond ? (mar 19) aaddaassaa
ww. P
. P ww.P.P
a) CO
c) SO2 w
2
ww w b) H O
d) NO2
2
w ww w
2.Shape and hybridation of IF are : (jun19)
5
a) Trigonal bipyramidal sp3d2 b) Trigonal bipyramidal sp3d
N Nett
e c) Square pyramidal sp3d2
NNe tt
d) Octahedral, sp3d2
e
lalai.i.
3.Match the following (sep21)
l a
l ai .i. bond l a
l i
a
et
assaa s aaii) Trible covalent bond
s s aa
s
1) N2 molecule i) chemical
2) BF3 molecule
aaddaa ad
a a
d a
. P
.P . P
. P
.N
3) HF molecule
w w
w iii) Electron deficient
w w
molecule
w
4) NaCl www www
iv) polar covalent bond
a) 1)- iii) , 2)- i) , 3)-iv) , 4)- ii) b) 1)-ii) , 2)- iv) , 3)-i) , 4)- iii)
lai
c) 1)- i) , 2)- iv) , 3)- ii) , 4)- iii) d) 1)- ii) , 2)-iii) , 3)- iv) , 4)- i)
NN eett N Ne ett
l a
l i
a .i. one of the following is diamagnetic ?l(May22)
4.Which
al i
a .i. l a
l i
a
sa
assaa s s aa b) O ssaa
2- +
a) O
c) O
2
aaddaa d) None of these

2
aaddaa
2
w w .
5.The ratio of number of sigmaP
. P
( ) and pi ( π) bonds in 2-butynal is :
w w.
(jul22)P. P
w
wwb)w www
da
d) w
𝟖 5 8 9
a) c)
𝟑 3 2 2
Pa
NNee tt
2&3&5 MARKS :-
NN eett
l a
l ai .i. is called bond length ? name the techniques
l a
lai .ithrough
. which the length of a bond can lalai
assaa be determined . (mar 19) ( ipna;a76) aa aa
1.what
dda ass ddaass
aa
w.
2. Write the structure of ww . P

. P
following compounds. (mar 19) ( ipn ; 82,83w
)w
. P
. P
ww w w the
www w
ww
A) NH 3 B) BF 3
3.Both C2H2 and CO2 have the same structure. Explain why. (MAR19)
NN eett
 C2H2 and CO2 has sp hybridisation linear structure NN eett
l a
l i
a .i. The linear structure of ethyne and that oflalcarbon
ai.i. dioxide is explained on the basis of lalai
assaa hybridisation. aad da as saa
a add a asaa
s
w w .P P w . P
. when both the carbon atoms undergowspwhybrisation P
. and
 Ethyne molecule
ww ww is formed
ww w
have two unhybridised orbitals (2py and 2px)
N Neett N Neett
lalai.i. l a
l ai .i. 7708543401 Page 44 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
NN e ett N N e ett
lalai .idipole
. moment. Why ? ( jun19) b/b-40 ( ipnla;la80i.i.)
4.Linear form carbon dioxide molecules has two polar bonds .yet the molecule has zero
l a
l i
a
assaa 5.Draw the M.O diagram for oxygen aad da s
a aa
s
aad daassaa
ww . PP
. ; 100 ) w w .P.P
molecule . calculate its bond order and magnetic
w ww
character. ( jun19)
w ( ipn
w w ww
6.Calculate the formal charge on carbon and oxygen for the following structure
NN e ett ( jun19) ( ipn : 72)

N N e ett
lalai.i. the shape and molecular geomentry forlalBFai.i.(sep20) ( ipn : 91 ) l a
l i
a
et
assaa 8.What is hybridisation ? mentionaatheddatype
assofaahybridization found in CH (sep20)a(aipn aa
7.Write 3
d da a ss
: 92 )
.ofPP .P P
4
. .
.N
ww w w
9.Write any four postulates molecular orbital theory. (sep20) ( ipn : 97)w
ww w
ww w w
10.Give the shapes of molecules predicted by VSEPR theory (sep21) ( ipn :82,83,83 )
t t
lai tt
a) BeCl2 b) NH c) H O
i NNee 3 2
.i. Bond Order. (sep21) ( ipn : 76 ) lalai.i. N N e e i

l a
l a l a
l a
sa
assaa 12.What are the salient features ofaaVB aa? (sep21) ( ipn : 86 ) aa
11.Define
dda ass ddaass

13.Explain the formationw . PP
theory
H. molecule using MO-theory (sep21) ( ipn :w .
).PPaa
w w
of
ww?w(sep21) ( ipn :78 ) w
www w
99
da
14.What is resonance
15.Describe the formation of HF molecule by orbital overlap. (May22) ( ipn :88 )
Pa
NNee tt NN e ett
16.Define i) Bond length ii)Bond angle iii)Bond enthalpy . (May22) ( ipn : 76,77)
l a
l i
a .i. fajan‟s Rule (jul22) ( ipn : 81 ) lalai.i. l a
l i
a
assaa 18. Discuss the formation of C molecules aa saa
17.Describe
dda a s ddaa s
aa using MO theory (jul22) ( ipn : 100 ) aa
w.
of w
19.mention the shapew w . P
. P 2
w w . P
. P
w w w the
w w ww
following molecules based on VSPER theory (jul22)
ww
i) BF ii) BrF iii) PCl iv) SF v) IF ( ipn : 82,83,83,84,84 )

3 3 5 6 7
N Neett N Neett
l a
l i
a .i. l a
lai.i. l a
l i
a
assaa aaddaasaa
s
ad
a a
d s
a aa
s
w
w .P. P w
w. P
. P
w
www w
www
N Neett N Neett
lalai.i. l a
l ai .i. 7708543401 Page 45 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
N Ne et t 11.Fundamentals Of Organic N Neet t Chemistry

lalai .i. l a
l ai .i. l a
l i
a
assaa ONE MARKS ;-
aa dd a as aa
s
a a ddaassaa
ww
a) vander waal‟s force P
1.many of the organic compounds
. . P are
b) co-ordinate nature ww.P.P
inflammable because of Its_______ (mar 19)
c) covalentww w w
nature d) ionic nature w www
2.Which of the following is optically active ? (jun19)
a) 3-chlolro pentane b) 2-chloro propane
N Ne ett
c) meso-tartaric acid
N eett
d) glucose
N
lalai.i. l a
l ai .i. l a
l i
a
et
assaa 3.Write the IUPAC name of aaddaassaa (sep20)
ad
a a
d s
a aa
s
. P
.P . P
. P
.N
w w
a) 1-formyl propanol
w b) 1-hydroxy butanal
w w
w
c) 2-hydroxy
ww group in organic compound (sep21) www
4.The structure ofw
butanal
isobutyl
d) 3- hydroxyl butanal
l a
l i
a N
.i. Neett
a)
lai l a
l i
a N
.i. Neettb)
l a
l i
a
sa
assaa aaddaasaa
s
aaddaassaa
w w. P
. P w
w . P
. P
w
wwwis optically active ? (sep21) w
www
da
c) d)
5.Which of the following
a) meso-tartaric acid b) 3-chloropentane
Pa
c) glucose d) 2-chloropropane
N Neett N Neett
l a
l a .i. l a
lai .i.
6.Which of the following is aliphatic saturated hydrocarbon ? (May22)
i l a
l i
a
assaa aa aa
a) C9H18 b) C8H14 c) C8H18 d) All of the above
7.match of following (May22)
ddaass ddaass
aa aa
w.
1) –NO2
ww. P
. P i) propyl
w
w . P
. P
2)-OCH3
3)-CH2-CH2-CH3 w
www
ii) Amino
iii)Methoxy w
www
ww
4) –NH2 iv) Nitro

a) (1)- (iii), (2)-(ii) , (3)-(iv), (4)-(i) b) (1)- (iii), (2)-(iv) , (3)-(i), (4)-(ii)
eett
c) (1)- (iv), (2)-(iii) , (3)-(i), (4)-(ii)
N N eett
d) (1)- (ii), (2)-(i) , (3)-(iv), (4)-(iii)
N N
l a
l i
a .i. l a
lai.i. l a
l i
a
assaa 8. aaddaass aa (May22)
ad
a a
d s
a aa
s
a) optical isomers w
w .P. P b) resonating structures w w . P
. P
c) conformers wwww d)tautomers wwww
N Neett N Neett
lalai.i. l a
l ai .i. 7708543401 Page 46 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
N Neett N Neett
lala .i.
9.The IUPAC name of the compound (jul22)
i l a
l i
a .i. l a
l i
a
assaa aaddaassaa
Is aaddaassaa
w w .
a) 2-ethylbut-2-enoic acid P
. P b) 3-ethylbut-3-enoic acid
w
w .P.P
w
www
c) 3-ethylbut-2-enoic acid d) 2-ethylbut-3-enoic
wwww
acid
10.Match the following (jul22)
1) -NH2 i) Sulpho-
ett
e
2) -CN
N N eett
ii) Formyl -
N N
lalai.i.
3) -SO3H
l a
l i
a .i.
iii) Amino -
l a
l i
a
et
assaa 4) -CHO
aaddas
a aa
s
a) 1)- i) , 2)- ii), 3)- iii , 4)- iv)
iv) Cyano -
ad
a a
d s
a aa
s
b) 1)- iv , 2)- iii) , 3)- ii) , 4)- i)
. P
.P . P
. P
.N
w
w
c) 1)- iii), 2)- iv), 3)- i) , 4)- ii)
w ww
d) 1)- iii), 2)- i) , 3)- iv) , 4)- ii)
w
2&3&5 MARKS :- www www
1.Describe the reaction involved in the detection of nitrogen in an organic compound by
lai
lassaigne method. (mar 19) (ipn : 138)
N eett N eett
2.which is the suitable method for detection of nitrogen present in food and fertilizers?
N N
l a
l i
a .i. l a
l i
a .i. l a
l i
a
sa
(compulsory 2 mark) (mar 19) (ipn :147 )
assaa aad aasaa
s
aaddaassaa
This method is carried much more easily than the Dumas method. It is used largely in the
d
ww. P
. P w
w . P
. P
analysis of foods and fertilizers. Kjeldahls method is based on the fact that when an organic
w
www w
www
da
compound containing nitrogen is heated with Conc. H2SO4, the nitrogen in it is

quantitatively converted to ammonium sulphate.
3.Give the structural formula for the following compounds. (mar 19) (compulsory 3 mark)
Pa
N Neett
a)m-dinitrobenzene b)p-dichlorobenzene
N Nee tt
c)1,3,5,Tri-methyl Benzene
l a
l i
a .i. l a
lai .i. l a
l i
a
assaa aa ddaassaa
aaddaasaa
s
w.
ww . PP .
. for the following compounds (marw19)ww. P
P
a) www w
4.Identify the cis and trans isomers
b) www
ww
N Neett N Neett
l a
l i
a .i. l a
lai.i. l a
l i
a
assaa 5.Write the IUPAC names for theaafollowingacompounds.
a aa
TRANS CIS
d daas s (mar 19)
d a
d s
a s
.P. P . P
. Paa
w ww w w
w
www www
(A) (B)
N Neet t 2-methyl butane

N Neet t2,2-dimethyl propane
lalai.i. l a
l ai .
i . 7708543401 Page 47 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
N Neett N Neett
lala .i. l a
l i
a .i.
6. Write any two different components you get during fractional distillation of coal tar at any
i l a
l i
a
assaa aa aa
two different temperatures. (mar 19)
ddaass
S.NO Name of the fraction Temperature range ddaass
Name of the components
. P
. Paa .P.Paa
1
ww
Crude tight oil
w 350-443k
w w
w Benzene, toluene,xylene
2
3
www
Middle oil
Heavy oil
443-503k
503-543k
www Phenol,naphthalene
Napththalene,cresol
4 Green oil 543-633k Antharacene
N5
Ne ett Pitch Alone 633k
N Ne ett residue
lalai.i. l a
l i
a .i. l a
l i
a
et
assaa 7.How aad d aas saaand sulphur together in an organic aassaa
do you detect the presence of nitrogen
a a dd
. PP . PP
. purifying and separating liquids presentwinwawmixture
compounds ? ( jun19) (ipn : 139)
. having
.N
w w w
w ( jun19) (ipn : 150) (fractional distillation
www
8.explain a suitable method for
wwpoint.
very close boiling )
lai
9. Write the IUPAC names for the following compounds : ( jun19)
N Neett N Neett
l a
l i
a
(x).i. (Y)
l a
l i
a .i. (Y)
l a
l i
a
sa
assaa 5-oxohexanoic acid aa a ass
4-chloro
dd
apent-2-yne
a 2-ethoxy propaness
aad da a aa
w w . PP .
. in 2-butene. (sep20) (ipn :135 ) (compulsory
ww PP
. 3 mark)
w
www of a solid organic compound by crystallization
www w
da
10.Explain geometrical isomerism

11. Explain the purification
method (sep20) (ipn : 149 )
Pa
N N ett N N ett
12.Give the general formula for the following class of organic compounds (sep21)
e e
l a
l i
a .i.
a) Alkanes b) Alkenes c) Alkynes
l a
lai .i. l a
l i
a
assaa C H n 2n+2 CH n 2n
aa
CH
d dan
as saa
2n-2
aaddaasaa
s
w.
ww . P
.
13.What is meant by homologousP series ? (sep21) (ipn : 112)
w
w . P
. P
w
wwforwthe following compounds . (sep21) www
14.Give the structure w
ww
1) 3-methylpentane
2) 2-methylpropan-2-ol
N Neett
3) Propanone
N Neett
l a
l i
a .i.
3-methylpentane
l a
lai.i.
2-methylpropan-2-ol Propanone
l a
l i
a
assaa aaddaasaa
s
aaddaasaa
s
w
w .P. P w
w . P
. P
w
www w
www
N Neett N Neett
lalai.i. l a
l ai .i. 7708543401 Page 48 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
N Neett N Neett
lala .i. l a
l i
a .i.
15.What is meant by optical isomerism ? (May22) (ipn : 137 )
i l a
l i
a
assaa aa aa
16.Give the IUPAC names of the following compounds . (May22)
ddaass ddaass
. P
. Paa .P.Paa
www w w
w
www www
2-bromo-3-methylbutane
methoxymethane
N Nett
e N Neett
lalai.i. l a
l i
a .i. 2-hydroxybutanal
l a
l i
a
et
assaa aaddas
a aa
s
ad
a a
d s
a aa
s
. P
.P . P
. P
.N
w w
w www
www www
4-chloropent-2-yne
lai
v) CH2 = CH – CH = CH2 1,3-butadiene
N Neett N Neett
l a
l i
a .i. l a
l i
a .i.
17.Which element exhibits maximum catenation and why ? (ipn : 110)
l a
l i
a
sa
assaa aa aa
18.Give an example for each of the following type of organic compounds (jul22)
(compulsory 3 mark)
ddaass ddaass
. P
. Paa
i) Non-benzonoid aromatic compound
. P
. Paa
www w w
w
www www
da
azulene
Pa
N N ett
ii) Aromatic heterocyclic compound
e N Neett
l a
l i
a .i. l a
lai .i. l a
l i
a
assaa aa ddaassaa
aaddaasaa
s
w.
w w . P
. P w
w . P
. P
www w w
www
ww
iii) carbocyclic compound
N Neett N Ne ett
l a
l i
a .i. l a
lai.i. l a
l i
a
assaa cyclopropane
a ad da as aa
s
ad
a a
d s
a aa
s
ww
19. Describe any two types .P P
of. constitutional isomers. (jul22) (ipn : 132) w
w. P
. P
wwww www w
N Neett N Neett
lalai.i. l a
l ai .i. 7708543401 Page 49 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
N Neet t 12.Basic Concepts Of Organic N Neet t Reactions

lalai .i. l a
l ai .i. l a
l i
a
assaa ONE MARKS ;- a d
a a
d as saa
aad a
d s
a aa
s
w w . PP
. does not exert a resonance effect ? w w w .P.P
w w ww
1.Which of the following species
w+
w w
(mar 19)
a) C H NH6 5 b) C H NH
2 c) C H OH
6 5 3 d) C H Cl
6 5 6 5
2.Which of the following species is not electrophile in nature ? (jun19)

N Ne ett N N eett
lalai.i. a) Cl +
b) BH c)
l a
l
3
ai
H .
i .
O d) NO3
+
l a
l i
a
+
2
et
assaa 3.Whicha) ofNHthe following is electron
aad a as saa? (sep20)
deficient
d ad
a a
d s
a aa
s
. P
.
b)PPH c) (CH ) d)
. P
.
BH P
.N
3
w ww
wof carbocation is (sep21)
3
www 3 2 3
4.The geometricalw
wshape www
a) planar b) linear c) pyramidal d) tetrahedral
l a
l i
a N Nee tt
lai NN eett
5.The correct relative order of +I effect of alkyl groups is : (May22)
.ia). -C(CH ) >-CH(CH ) >-CH CH >-CHlalaib).i.–CH >-CH CH >-CH(CH ) >-C(CH ) lalai
sa
assaa c) -CH CH >-CH >-C(CHa)ad aa) d) –CH(CH ) >-C(CH ) >-CH CH >-CH aa
3 3 3 2 2 3 3 3 2 3 3 2 3 3
daass
>-CH(CH
ddaass
2 3
. P
. P
3 3 3 3 2
. P
. Paa
3 2 3 3 2 3 3
w w
6.-I effect is not shown by (jul22)
w w w w
ww b) -F wwwd) -NO
da
a) -CH CH w
2 3 c) -Cl 2
2&3&5 MARKS :-
Pa
Neett NN e tt
e
1. Explain with example the positive mesometric effect. (mar 19) ( ipn : 169 )
N
l a
l i
a
2. .What
i . are nucleophiles and electrophiles ? give
l a
lai .i. example each (mar 19) ( ipn : 164 ) lalai
one
assaa a adda as saa
a ad daasaa
s
w.
3. w w . P
. P w w
(mar 19) . P P
( .ipn : 174 )
wwww wwww
ww
N Neett NNe ett

l a
l ai .i. Amide
l a
lai .i. acid
carboxylic
l a
l i
a
assaa 4.The bond length between all theaafour
dda as saaatoms is same in 1,3-butadiene. Explainaassaa
carbon
ad
a d
ww .
(compulsory 3 mark)P. P ( jun19) ( ipn :
w
168
w
). P
. P
1,3-butadiene is w
aww w molecule with four overlapping p-orbital
conjugated w
wwwon adjacent
atoms,and a electrons are delocalised over four atoms. This shortens the bond length of
Neett N Neett
central c bond thus, the bond length between all the four-c- atoms are same in 1,3-butadiene
N
lalai.i. l a
l ai .i. 7708543401 Page 50 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
NNeett NN eett
lalai .i. the no bond resonance structure shownlabylaipropene
.i. (sep20) ( ipn : 170 )
5. explain about inductive effect . ( jun19) ( ipn : 166 )
l a
l i
a
assaa 7.Give any three differences between s aa
s ss aa
6.Write
aad da a a ad
:d
aa
( ipnw ww. . PP w w. P
. P
nucleophiles and electrophiles. (May22) ( ipn 164 )
8. complete
ww :w
173,173,173,173 )
www w
N Nett
e A)
N N ett
(sep20)
e
lalai.i. l a
l i
a .i. l a
l i
a
et
assaa a d
a da s
a aa
s
ad
a a
d s
a aa
s
.
B) H C=CHP
.P+ H-Br
. P
. P
.N
w w ww
2 2
www
ww
C) CH CHO 3
www
l a
l i
a N
.i. Neett
lai l a
l i
a N
.i. Ne ett
l a
l i
a
sa
assaa a d
a da as saa
aaddaassaa
D) w w . P
. P w
w . P
. P
ww w
w
da
ww
9.Write short notes on hyper conjugation (jul22) ( ipn : 170 )
w
w
Pa
N Neett N Neett
l a
l i
a .i. l a
lai .i. l a
l i
a
assaa ad
adaassaa
aaddaasaa
s
w.
ww. P
. P w
w . P
. P
w
www w
www
ww
N Neett N Neett
l a
l i
a .i. l a
lai.i. l a
l i
a
assaa aaddaasaa
s
ad
a a
d s
a aa
s
w
w .P. P w
w. P
. P
w
www w
www
N Neett N Neett
lalai.i. l a
l ai .i. 7708543401 Page 51 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
NN eett 13.Hydrocrbons N Neett

lalai .i. MARKS ;- l a
l i
a .i. l a
l i
a
assaa 1.______group is ortho para directing aa aa
ONE
dd aas s ddaass
. P
. Paa and deactivating group (jun19)
.P.Paa
a) aminow w b) methyl w w
www w
c) halogen
wwww
d) aldehyde
2.Cold dilute alkaline KMnO4 is known as ______ (sep20)
N Nee t ta) Schiff”s reagent N Ne etb)t Fenton”s reagent

lalai.i. l a
l i
a .i. l a
l i
a
et
assaa c) Tollen‟s reagent
a a dda assaa d) Baeyer’s reagent
ad
a a
d s
a aa
s
. P
.P . P
. P
.N
3.n-propyl bromide on rection with alcoholic KOH gives (sep20)
w w w w ww
a) Butylwww alcohol www
b) Propene
lai
c) Butene d) Propyl alcohol
N e ett N e ett
4.An alkene is obtained by decarboxylation of sodium propionate.same alkene can be
N N
l a
l i
a .i.prepared by : (sep21) l a
l i
a .i. l a
l i
a
sa
assaa a) reduction of 1-chloro propane aadda as aa
sb) catalytic hydrogenation of propeneadd
a a s
a aa
s
. P
. P
wwmethane d) action of sodium metalww onww . P
. P
ww
da
c) reduction of bromo iodomethane

w w
5. Identify the compound (A) in the following reaction : (jul22)
ww
Pa
N Neett N Neett
l a
l i
a .i. l a
lai .i. l a
l i
a
assaa ad
adaassaa
aaddaasaa
s
w.
ww. P
. P w
w . P
. P
w
www w
www
ww
NNeett N Neett
l a
l i
a .i. MARKS :-
2&3&5
l a
lai.i. l a
l i
a
assaa 1.How will you get the followingaproducts
ad daa ssaa the given reactants ? (mar 19) aassaa
with
ad
a d

ww
A)Acetylene Benzene .P. P
(ipn :204 )
ww . P
. P
B)Phenolw ww (ipn : 210 )
wBenzene
 www w
C)Benzene Tolune (ipn : 210 )
N Neett N Neett
lalai.i. l a
l ai .i. 7708543401 Page 52 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
N Neett NN eett
lalai .icompound
. l a
l a .i. Identify (A) , (B) and (C).(MAR19) lalai
2.The simple aromatic hydrocarbon compound (A) reacts with bromine to give (B).
i
assaa s aa
s ssaa
(A) reacts with Raney Ni and gives (C).
aadda a aaddaa
w w . P
. P ww . P
.P
www w www w
N Nett
e N Neett
lalai.i. l a
l i
a .i. l a
l i
a
et
assaa aaddas
a aa
s
ad
a a
d s
a aa
s
. P
.P . P
. P
.N
w w
w www
www www
l a
l i
a .
i N
. Nee
S.NOt t COMPOUNDS
lai
FORMULA ee
l a
l i
a .
iN. N tt NAME
l a
l i
a
sa
assaa 1 A
aaddaasaCaH
s 6 Benzene
6
aaddaassaa
2 B
w
w . P
. P C H -Br 6
ww . P
.
bromobenzene
5 P
w
wwCw w w
da
3 CH 6 wwcyclohexane
12
Pa
NNee tt N N eett
l a
l i
a .i. is polymerisation ? explain the two types
l a
la i .ipolymerisation
3.What happens when acetylene undergoes ozonolysis ? ( jun19) (ipn : 203 )
. l a
l i
a
assaa ssaa s aa
s
4.What of rection of acetylene .
aa d da a aad:d
a a
w.
5. What do you meanw w w . P

. P w w . PP
( jun19) (ipn 204 )
. in ethane .
www by conformation ? Explain about staggered
www w
conformation
ww
( jun19) (ipn : 187 )

6. An organic compound (A) of molecular formula C2H6O, on heating with conc.H2SO4
N Neett N Neett
l a
l i
a .i. l a
lai.i. l a
l i
gives compound (B) . (B) on treating with cold dilute alkaline KMnO4 gives compound
a
assaa . Identify (A), (B) and (C) and aexplain
ad da as s
theareactions.(JUN19)
a
ad
a a
d s
a aa
s
w w . P
. P w
w. P
. P
wwww w
www
N Neett N Neett
lalai.i. l a
l ai .i. 7708543401 Page 53 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
N Neett N Neett
lalai .i. l a
l i
a .i. l a
l i
a
assaa aaddaassaa
aaddaassaa
ww. P
. P w
w .P.P
w
www w
www
N Neet
S.NOt COMPOUNDS FORMULA et t
N N e NAME
lalai.i. l a
l i
a .
i . l a
l i
a
et
assaa s aa s aa
1 A C H OH Ethanol
ddaa s 2 5
d a
d a s
2 B
. P
.Paa CH = CH Ethene
. P
. Paa
.N
2 2
w w
w w ww
3 wwCw HO-CH -CH -OH www
Ethane-1,2-diol
2 2
l a
l i
a N
.write
i eett
lai N
. Brich reduction . (sep20) (ipn : 215 ) lalai.i. Neett
7.Explain the different types of polymerisation in ethyne. (sep20) (ipn : 204 )
N l a
l i
a
sa
assaa 9.Complete the following : (sep21)aad(compulsory
aa 2 mark) aa
8.
da ass ddaass
. P
. P . P
. Paa
w w w w w
w
ww+wH www
da
a) CH -CH=CH
3 2 2 CH -CH -CH 3 2 3
Propane
Pa
N Neett N Neett
l a
l i
a .i.
b) CH3MgCl + H2O
l lai .i.
CH4 + Mg(OH)Cl
a l a
l i
a
methane
a add aasaa
s
w.
ww . P P .
.test to distinguish propane and propenew(sep21)
ww P P
.(b/b-39 )
www w
10.Suggest a simple chemical
www
ww
11.How does Huckel rule help to decide the aromatic character of a compound?
N Neet t N Neet t (sep21)(ipn : 205 )
l a
l i
a .
i .
12.Write the rection for conversion of acetylene
l a
lto
a i.i.
benzene. (sep21) (ipn : 210 )
l a
l i
a
assaa 13.How will you convert ethyl chloride
aa dd atoss
a aa ? (May22)
ethane
aa ddaasaa
s
ww .P. P
Zn/HCl [H]
w w. P
. P
CH -CH -Cl
3 www
2
w CH -CH + HClw ww w
3 3
ethyl chloride ethane
N Neett N Neett
lalai.i. l a
l ai .i. 7708543401 Page 54 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
N N e ett N Neett
lalai .permanganate
i . l a
l i
a .i.
14.what happens when ethylene is passed through cold dilute alkaline potassium
l a
l i
a
assaa 15. How will you prepare the following s saa s aa
s
? (May22) (ipn : 198 )
a ad daa a ad a
d a
ww. P
. P compounds from benzene ? (May22)
ww . PP
. )
w w w
w w w
(ipn
w w: 211,212,215
i)nitrobenzene ii)benzene sulphuric acid iii)BHC
16.How will you prepare ethane by Kolbe”s electrolytic method ? (jul22) (ipn :201 )
N Ne e tt N N e e tt
lalai.i.
17.Explain Brich reduction (jul22) (ipn : 215 )
l a
l ai .i. l a
l i
a
et
assaa 18. Anchloride a add a ass
organic compound (A) C2H4 decolourisesaa bromine water. (A) on reaction withaassaa
a add
. P
.P
gives (B) . (A) reacts with HBr to give (C) . identify (A), (B)
.
and P
. P
(C) explain
.N
w w w w w w w
ww
the reactions. (jul22) www
l a
l i
a N
.i. Neett
lai l a
l i
a N
.i. Neett
l a
l i
a
sa
assaa aaddaasaa
s
aaddaassaa
ww. P
. P w
w . P
. P
w
www w
www
da
Pa
N Nee
S.NOt t COMPOUNDS FORMULA ee
N N tt NAME
l a
l i
a .
i . l a
lai .
i . l a
l i
a
assaa 1 A
ad
adaas
CHaa= CH
s 2 Ethene
2
aaddaasaa
s
w.
2 B
w
w . P
. P Cl-CH -CH -Cl 2 . P
. P
1,2-dichloroethane
2
w w
3
w
wwCw CH -CH -Br 3 ww
2
ww
bromoethane
ww
N Neett N Neett
l a
l i
a .i. l a
lai.i. l a
l i
a
assaa aaddaasaa
s
ad
a a
d s
a aa
s
w
w .P. P w
w. P
. P
w
www w
www
N Neett N Neett
lalai.i. l a
l ai .i. 7708543401 Page 55 la l i
a
assaa aa aa
dda a s s d aass
PP a a
PP d
aa
ww.. w
w ..
wwww wwww
NN eet t 14.Haloalkanes And Haloarenes N Neett

lalai .i. MARKS ;- l a
l i
a .i. l a
l i
a
assaa 1.match the following (mar 19) aaddaassaa ssaa
ONE
aaddaa
Compound
ww . P
.
usesP w
w .P.P
w
1)Chloro picrin
ww wi) detection of primary amine w
w w
w
2)Methyl isocyanide ii) DDT
3)Chlolro benzene iii) paint remover
N ett
e
4)Meythylene chlorine iv) soil sterilizer
N N Neett
lalai.i. l a
l i
a .i.
a) (1)- (iv), (2)-(iii) , (3)-(ii), (4)-(i)
l a
l i
a
b) (1)- (iii), (2)-(iv) , (3)-(ii), (4)-(i)
et
assaa as
a aa
s
c) (1)- (i), (2)-(ii) , (3)-(iv), (4)-(iii)
aadd aa a
d s
a aa
s
d) (1)- (iv), (2)-(i) , (3)-(ii), (4)-(iii)
d
PP
2.The raw material for rasching process is _______ (jun19)
. . . P
. P
.N
w w
w www
www www
a) chloro benzene b) phenol c) benzene d) anisole
3. match the following (sep20)
1)Iodoform i) Fire extinguisher
tt
lai tt
2)Carbon tetrachloride ii)Insecticide
i N
.i. Nee 3)CFC
i N
.i. Nee
iii) Antiseptic
i
l a
l a l a
l a l a
l a
sa
assaa aa aa
4)DDT iv)Refrigerants
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d) (1)- (i), (2)-(ii) , (3)-(iii), (4)-(iv)
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4.Of the following compounds , which has the highest boiling point? (sep21)
a) t-butyl chloride b) n-butyl chloride
c) n-propyl chloride d) Isobutyl chloride
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5.Assertion : In monohaloarenes, electrophilic substitution occurs at ortho and para positions
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6. Assertion : Increasing order of boiling points of halo alkanes are
N Neett N Neett
l a
l i
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CH3Cl < CH2Cl2 < CHCl3 < CCl4
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2&3&5 MARKS :-
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4.Give the structure and uses of DDT . (sep20) (ipn : 250 )
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alcoholic KOH. (sep20) (ipn : 237 )
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w w . P
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ammonia to form compound (C) of molecular formula C2H7N compounds (C) undergoes
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carbylamines test. Identify (A),(B) and (C). (May22)
aadd ad
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w
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lalai.i. l a
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lalai.i. 3 C CH3-CH2-NH2
l a
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a a ddaass aa
. PP
. to give compound (C) which undergoes . P P
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compound
w w (B) .
ww(A),w(B) and (C) and explain the rteactions. (jun19)
compound (B) reacts
reaction. Identify
with ammonia
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FORMULA NAME
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aa Benzene aa
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B C H -Cl 6
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chlorobenzene
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3 C C6H5-NH2 aniline
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l a
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lai.i. l a
l i
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11.Mention any two methods of preparation of haloalkanes from alcohols. (jul22)
assaa aaddaasaa
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d s
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i) Acetaldehyde ii) Acetone iii) Methane w
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N Neett N Neett
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N Nee tt 15.Environmental N Neett

Chemistry
lalai .i. l a
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a) Cadmium , mercury b) Lead, Cadmium
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c) Freon, Fluoride
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d) copper, Cadmium
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3.Ozone deplection will cause (sep20)
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“Life is nothing without chemistry
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comments S.MANIKANDAN.M.Sc.B.Ed.,
N Neett PG ASST. IN CHEMISTRY

N Neett
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Mob :7708543401 mail a
la: .yazimani@gmail.com
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YOUR HINTS
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lalai.i. l a
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11TH CHEMISTRY PUBLIC QUESTIONS

N Neett June-2019 N Neett

11TH CHEMISTRY PUBLIC QUESTIONS

NNeett LESSON NAME

3 Periodic classification of elements w

11TH CHEMISTRY PUBLIC QUESTIONS

The purpose to get

All the best

11TH CHEMISTRY PUBLIC QUESTIONS

a) vander waal‟s force b) co-ordinate nature

6.Match the following :

a) Kelvin‟s Law b) Brown‟s Law

11TH CHEMISTRY PUBLIC QUESTIONS

25.Calculate the equivalent mass of H2SO4

11TH CHEMISTRY PUBLIC QUESTIONS

N N e ett Na2O2 + ?  Na2SO4+ H2O2

37. a) i) Write the IUPAC names for the following compounds.

11TH CHEMISTRY PUBLIC QUESTIONS

lalai.i. b) i) C(s) + O2(g)  CO2(g)

11TH CHEMISTRY PUBLIC QUESTIONS

N Neett N Ne et t Maximum marks : 70

d) Intra molecular H-bonding and intra molecular H-bonding

i) During cyclic process the amount of heat absorbed by the surrounding is

11TH CHEMISTRY PUBLIC QUESTIONS

13.______group is ortho para directing and deactivating group

c) Freon, Fluoride d) copper, Cadmium

16.What is syn gas ? How it is prepared ?

11TH CHEMISTRY PUBLIC QUESTIONS

b) i) Why hydrogen peroxide is stored in plastic containers, not in glass container ?

11TH CHEMISTRY PUBLIC QUESTIONS

ii) A simple aromatic hydrocarbon

11TH CHEMISTRY PUBLIC QUESTIONS

N Neett N Ne et t Maximum marks : 70

1.The maximum number of electrons that can be accommodated in L orbit is

3)CFC iii) Antiseptic

c) π V=nRT d) None of these

11TH CHEMISTRY PUBLIC QUESTIONS

a) Low temperature and low pressure

18.state zeroth Law of Thermodynamics.

11TH CHEMISTRY PUBLIC QUESTIONS

b) i) How is bleaching powder prepared ?

11TH CHEMISTRY PUBLIC QUESTIONS

ii) Write any three strategies

11TH CHEMISTRY PUBLIC QUESTIONS

N Ne ett N Neet t Maximum marks : 70

1. Which one of the following of presents 180g of water ?

assaa 6. Rate ofa)diffusion of a gas is :

d) directly proportional to its molecular weight

11TH CHEMISTRY PUBLIC QUESTIONS

14.An alkene is obtained by decarboxylation of sodium propionate.same alkene can be

16.What is the empirical formula of the following ?

11TH CHEMISTRY PUBLIC QUESTIONS

Note : Answer all the questions . 5 X 5 = 25

N N e t t a note on principal quantum number NNeet t

11TH CHEMISTRY PUBLIC QUESTIONS

11TH CHEMISTRY PUBLIC QUESTIONS

N Neett N Nee t t Maximum marks : 70

11TH CHEMISTRY PUBLIC QUESTIONS

11TH CHEMISTRY PUBLIC QUESTIONS

34.a)i) How many orbitals are possible for n=4 ?

b) Describe the pauling method for the determination of ionic radius .

11TH CHEMISTRY PUBLIC QUESTIONS