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Additives are chemicals blended into plastics to change their performance or appearance, making it

possible to alter the properties of plastics to better suit their intended applications. [31][32] Additives are
therefore one of the reasons why plastic is used so widely.[33] Plastics are composed of chains of
polymers. Many different chemicals are used as plastic additives. A randomly chosen plastic product
generally contains around 20 additives. The identities and concentrations of additives are generally
not listed on products.[2]
In the EU, over 400 additives are used in high volumes.[34][2] 5500 additives were found in a global
market analysis.[35] At a minimum all plastic contains some polymer stabilisers which permit them to
be melt-processed (moulded) without suffering polymer degradation. Other additives are optional
and can be added as required, with loadings varying significantly between applications. The amount
of additives contained in plastics varies depending on the additives’ function. For example, additives
in polyvinyl chloride (PVC) can constitute up to 80% of the total volume.[2] Pure unadulterated plastic
(barefoot resin) is never sold, even by the primary producers.

Leaching
Additives may be weakly bound to the polymers or react in the polymer matrix. Although additives
are blended into plastic they remain chemically distinct from it, and can gradually leach back out
during normal use, when in landfills, or following improper disposal in the environment. [36] Additives
may also degrade to form other toxic molecules. Plastic fragmentation into microplastics and
nanoplastics can allow chemical additives to move in the environment far from the point of use.
Once released, some additives and derivatives may persist in the environment and bioaccumulate in
organisms. They can have adverse effects on human health and biota. A recent review by the United
States Environmental Protection Agency (US EPA) revealed that out of 3,377 chemicals potentially
associated with plastic packaging and 906 likely associated with it, 68 were ranked by ECHA as
"highest for human health hazards" and 68 as "highest for environmental hazards". [2]

Recycling
Main article: Plastic recycling
As additives change the properties of plastics they have to be considered during recycling.
Presently, almost all recycling is performed by simply remelting and reforming used plastic into new
items. Additives present risks in recycled products, as they are difficult to remove. When plastic
products are recycled, it is highly likely that the additives will be integrated into the new products.
Waste plastic, even if it is all of the same polymer type, will contain varying types and amounts of
additives. Mixing these together can give a material with inconsistent properties, which can be
unappealing to industry. For example, mixing different coloured plastics with different plastic
colorants together can produce a discoloured or brown material and for this reason plastic is usually
sorted by both polymer type and color before recycling.[2]
Absence of transparency and reporting across the value chain often results in lack of knowledge
concerning the chemical profile of the final products. For example, products containing brominated
flame retardants have been incorporated into new plastic products. Flame retardants are a group of
chemicals used in electronic and electrical equipment, textiles, furniture and construction materials
which should not be present in food packaging or child care products. A recent study found
brominated dioxins as unintentional contaminants in toys made from recycled plastic electronic
waste that contained brominated flame retardants. Brominated dioxins have been found to exhibit
toxicity similar to that of chlorinated dioxins. They can have negative developmental effects and
negative effects on the nervous system and interfere with mechanisms of the endocrine system. [2]

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