Sec: SR.

IIT_CO-SC PTA-18 Date: 03-01-21

Time: 3HRS 2016_P1 Max. Marks: 186
KEY SHEET

PHYSICS
1 A 2 B 3 C 4 A 5 B

6 AB 7 BD 8 ABCD 9 AC 10 AC

11 ACD 12 ABCD 13 BD 14 4 15 9

16 9 17 3 18 2

CHEMISTRY
19 B 20 C 21 A 22 A 23 C

24 ABCD 25 ABD 26 AC 27 ABD 28 AD

29 ABD 30 ABD 31 BCD 32 5 33 0

34 4 35 4 36 8

MATHEMATICS
37 D 38 B 39 D 40 C 41 C

42 D 43 ABCD 44 AB 45 AD 46 AD

47 AC 48 BCD 49 ABD 50 4 51 3

52 1 53 1 54 4

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SOLUTIONS
PHYSICS
1. Series of n identical ball, ball 1 collides with ball 2 with u, e

mu  mv1  mv2
eu  v2  v1
v2  v1
e
u
u
1  e   v2
2
u
v2  1  e 
2
1  e  1  e  u  1  e 
2
v
v3  1  e  2 
2 2 2 22
1  e 
n 1
u
vn  n 1
2
 n  n  1 
2

2. 1  2  3  ...  n  
2 2 3 2

 2 
m1 x1  m2 x2  ...  mn xn
X CM  .
m1  m2  ...  mn
3. Impulse = change in linear momentum

m cos  1  e 
 Ft  m  eu cos   u cos   or F 
t
4. Relative acceleration between the two is zero therefore the relative motion between the two is uniform relative
velocity of the two is (10+5) m/s or 15m/s in horizontal direction therefore the collision will take place after a
time
60
t  4s
15
Net linear momentum in horizontal direction of the two particle is zero therefore after collision the combined
mass will fall vertically downwards the desired distance fro A would be 40m.

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mg V
5. x0  , after the collision speed of combined mass is
k 2
2 2
1  v  1  mg   mg  6mg 2
 2m    k    2mg   so, V 
2 2 2  k   k  k
6. In collision horizontal component vx remains unchanged while the vertical component u y now

2u sin  2u y
T 
g g
T  uy
T1 3
 
T2 
u 2 sin 2  u y
2

H   u y2
2g 2g
H 1
 1  2
H2 e
u 2 sin 2 2 u x u y R 1
R   y 1 
g g R2 e
7. Fext  0  acom  0
8. m x 21 - 2m x 4 = m x 1 + 2m x v2
v2 = 6 m/s
e = -[ ]= = 0.2

J = m(v1 – u1) = m[21-1] = 20m N-s.

10. Along the string 10 cos 600  15  v ,

1
 vx  m/s for both 10kg and 5kg
3
In the direction perpendicular to string
10sin 600  5v y  v y  3 m/s
1
Velocity of 10kg  m/s ;
3
1 28
Velocity of 5kg  3   m/s
9 3

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11. In centre of mass frame (initially)
m M
vm  v0  v0  v0
M m M m
 M 
and vm    v0
M m
 Kinetic energy in centre of mass frame
2 2
1  m  1  m  1  mM  2
K .E.  m  v0   M  v0     v0
2 M  m  2  m M  2 M m
At maximum compression
m
v0  vM  vCOM  v0
M m
From energy conservation
1 2 1  m  1 2
mv0   M  m   v0   Kxmax
2 2 M  m  2
mM
 xmax  v0
 M  m k
At this moment
Velocity of m with respect to centre of mass = velocity of M with respect to centre of mass = 0
12. u cos   v cos  … (1)
v sin   eu sin 
eu sin   v sin  … (2)

From Equations (1) and (2), we can see that, tan   e tan 
Momentum or velocity changes only in vertical direction.
 Impulse  P

 m  u sin   eu sin    m 1  e  u sin 

v  v cos     v sin     u cos     eu sin  

2 2 2 2

 u 2  cos 2   e 2 sin 2    u 1  1  e 2  sin 2 

1 2
mv
Kf 2 v2
  2  cos 2   e 2 sin 2 
K i 1 mu 2 u
2
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  
13. Impulse =  p  m v f  vi  
  
 Impulse received by m = m  2 i  j  3 i  2 j   m 5 i  j
   
Impulse received by M = –(impulse received by m) = m 5 i  j  
14. Let velocity of I ball and II ball after collision be v1 and v2  v1  0.5  10
mv2  mv1  m  10  v2  v1  10
Solving equation (i) and (ii) v1  2.5 m/s, v2  7.5 m/s
Balls II after moving 10m collides with ball III elastically and stops. But ball I moves towards ball II. Time
taken for second collision between ball and ball 2 will be 4seconds.
15.
  
16.     
The impulse J  m v f  v f   i  3 j  4 i  j   3i  4 j 
       3i  4 j   3i  4 j   
2
The component of 4i  j along 3 i  4 j is   4 i  j 32  42


16
25

3 j  4 j 
16 16
or speed, u1   5  m/s
25 5
   
Component of i  3 j along 3 i  4 j is   i  3 j 3 i  4 j   3i  4 j 
  
  

9

3 i  4 j 


3 2
4 
2 2


25

95 9
or speed v1   m/s .
25 5
If u2 and v2 are the speed of floor before and after collision, then
v v   0   9 / 5   9
e   2 1    
 u2  u1   0  16 / 5  16
Thus, x  9 .
17. Using conservation of momentum in the direction of motion of colliding ball

mu  mv cos 300  mv cos 300 or u  3 v .

 v1  v2 
Coefficient of restitution e    ,
 u1  u2 
Where velocities of balls are along the line of collision.
e  
0  v  v  v 2
 .
 u cos 30  0  u cos 30 3 v  3 3
0 0

2
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18. Net external on the two blocks (whether they move with same retardation or not)
Fext   02  2  110   6 N
Fext
acm   2 m/s 2 .
2 1

CHEMISTRY
21. dSP 2 hybridisation03.
22. As ligand field strength increases, splitting energy increase and hence wave length devises.
Field strengths I   H 2O  en  CN 
4 4
23.  t    0   18000 = 8000 cm-1
9 9
24. A) Ni 2 can form inner orbital complexs [ Ni (CN ) 4 ]2
B) [ Fe( H 2O)6 ]3 has 5 unpaired electrons
Where as [ Fe(CN )6 ]3 has only one electron.
25. [ NiCl4 ]2  Sp3 , tetrahydral,paramagnetic
[ Ni (CN )4 ]2  dSp 2 , square planar, diamagnetic
26. [Cr ( H 2O)6 ]3  Sp3d 2
[Cr ( NH 3 )6 ]3  d 2 Sp3
27. C is wrong because O.S of metal ion is + 2
28. C is incorrect it does not show geometrical isomerism
29. For [ Fe(Cn)3 ]2

3d configuration is
It is low spin diamagnetic and it is [ M ( AA)3 ]n  type of complex. so exhibits optical isomerism but
not geometrical isomerism
30. the anti-pernicious anemia factor is cobalt complex
31. I, II – identical
I, II, IV - Trans III - Cis
32. Paramagnetic complex are
3 3 2 2
 Mn  CN   , V  CO   , Cr  H 2O   ,  Ni  NH 3   , Cu  NH 3   .
 6  6  6  6  4
33. Both contain one unpaired electron
34. It has three geometrical isomers in which one exists as enantiomer pairs, so total four forms
35. [ Fe( H 2O)6 ]3 is outer orbital complex with 5 unpaired electrons
[ Fe(CN )6 ]3 is inner orbital complex with no unpaired electrons
36. It has six geometrical isomers in which two exists as enantiomer pairs, so total eight forms

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MATHS
4n
37. tan 1
n  2n 2  2
4

 (n  1)2  (n  1) 2 
= tan 1  2 
 1  (n  1) (n  1) 
2

= tan 1 (n  1)2  tan 1 (n  1)2

38. f ( x)  cot 1 ( x)  tan 1 x  sec1 x
   cot 1 x  tan 1 x  sec1 x
   sec 1 x
2
39. Domain of x is [1, 2)
as sin 1[ x]  1  [ x]  1
[ x]  1,0,1
    1   1  1 
40. x  cos ec  tan 1  cos  cot 1       x  cos ec  tan   
  
 1 a   2a 
2 2
   
 x  3  a2
    1   1  1 
y  sec  cot 1  sin  tan 1       y  sec  cot   
    1 a
2
  2a
2

   
y  3  a2
x  y
41. By graph no.of solutions is 3

o  2

42. x  2  4, y    3
43. sin 1 x    ,sin 1 y    ,sin 1 z   
2 2 2
 x  1, y  1, z  1

44. Domain of f(x) is +1 and -1

1
45. Adding given equations, we get y = 1, x 
2
Let f (x)   sin 1 x    cos 1 x 
2 2
46.

  sin 1 x  cos 1 x   2sin 1 x cos 1 x

2

2  
  2sin 1 x   sin 1 x 
4 2 

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    2
 2  sin 1 x   sin 1 x  
2

 2 8
 
2

 2  sin 1 x    2  
 4 16 
 
Now,   sin 1 x 
2 2
3  
   sin 1 x  
4 2 4
  9 2
2

 0   sin 1 x   
 4 16
  9 2
2

 0  2  sin 1 x   
 4 8
 2  1   2 52
2

   sin x    
8  4 8 4
47. We have
1  n  10n  21.6  
2
cot  
   6
n  10n  21.6 
  cot
 6
 n  10n  21.6   3
2

 n 2  10n  25  21.6  25   3
  n  5   3  3.4
2

  3  3.4  n  5  3  3.4
 5 3  3.4  n  5  3  3.4
Since 3  5.5 nearly, 3  3.4  8.9  2.9
 2.1  n  7.9
 n  3, 4, 5, 6, 7

48. f (x)  0  sin cot 1 (x  1)  cos  tan 1 x 

1 1
 sin sin 1  cos cos 1
1   x  1 1 x2
2

1 1
   1  x 2  2  x 2  2x
1   x  1 1 x
2 2

 x  1/ 2, so f (x)  0 for x  1/ 2

a  cos tan 1 sin cot 1 x  cos tan 1 sin  where x  cot .

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1 1
 cos tan 1  cos  where tan  
1 x2 1 x2

1 x2 1 x2 1 5
   a  2
2
 forx  1/ 2
1 x2  2 x 2 9
1
1 x2


and b  cos 2 cos 1 x  sin 1 x   cos  cos 1 x   / 2 

 b   sin  cos 1 x    1  x 2
49. tan 1 x  tan 1 x for all x  R  tan tan 1 x  x
sin 1 x  sin 1 x for all x  1  sin sin 1 x  x
cot 1 x  cot 1 x for all x  cot cot 1 x  x
tan x  tan x for all x  C is wrong
50. cos1  cos 1 1  0, cot1  cot 1 1  1
sin1  sin 1 1  1, sec1  sec1 1  0
tan1  tan 1 1  0, cos ec1  cos ec 11  1
(sec 1 x  cos ec 1 x)3  3sec 1 x cos ec 1 x  sec 1 x  cos ec 1 x 
53. 7
 
3

 
2
 3
   7
3

  3sec1 x cos ec 1 x     sec1 x   or sec1 x 
8 2 8 2
 x  1
1   10 1   3r  2   (3r  1) 
10
3
54.  tan  2    tan 
 9r  3r  1  r 1

r 1  1  (3r  2)(3r  1) 
10
  tan 1 (3r  2)  tan 1 (3r  1)
r 1

 tan 1 32  tan 1 2
 13 
 cot 1    m  13, n  6
6
2m  n 32
  4
8 8

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