SAINIK SCHOOL SATARA

HOLIDAY HOMEWORK
Class 11 - Chemistry

1. The number of grams of oxygen in 0.10 mol of Na2CO3. 10H2O is

a) 20.8 g b) 18 g

c) 10 g d) 12.8 g
2. SI unit of density is:

a) kg m-2 b) kg m-3

c) kg m3 d) kg -1m3

3. 27°C in Kelvin is

a) 227 K b) 246.15 K

c) 300.15 K d) 127.15 K
4. The molar mass of AgNO3 in g/mol is:

a) 159.9 b) 169.9

c) 179.9 d) 189.9
5. The molar mass of CaCO3 is:

a) 120 u b) 70g

c) 100 g /mol d) 90 amu

6. The density of 3 M solution of NaCl is 1.25gmL-1. Calculate molality of the solution?

a) 0.79 m b) 2.09 m

c) 2.79 m d) 1.79 m
7. 30 microliters is the same as:

a) 0.0003 liters b) 3000000 liters

c) 0.03 mL d) 0.003 mL
8. The number of moles of solute present in 1 kg of a solvent is called________.

a) Molarity (M) b) ppm

c) Normality( N ) d) Molality (m)

9. A person is suffering with fever with a high temperature of 104°F. What will be his body temperature in°C?

a) 41°C b) 38°C

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 c) 40°C d) 39°C
10. Avogadro constant is

a) the number of electrons in 1 mol b) the number of protons in 1 mol

c) the number of atoms in 1 mol d) the number of molecules in one mole of a

gas
11. According to Bohr’s theory the frequency of radiation absorbed or emitted when transition occurs between two
stationary states that differ in energy by ΔE, is given by

a) ΔE =
1

hν
b) ΔE = 2hν

c) ΔE = 2

hν
d) ΔE = hν

12. Correct expression for all series of lines in the hydrogen spectrum is (n1 = 1, 2 , 3...) and n2 = n1 + 1, n1 + 2, ...,

and ν̄ is the wave number)

a) 1 1 b) 1 1
ν̄ = 109, 677 ( − ) ν̄ = 109, 677 ( − )
3 2 4 2
n n n n
1 2 1 2

c) ν̄ = 109, 777 (
1
−
1
)
d) ν̄ = 109, 737 (
1
−
1
)
2 3 2 2
n n n n
1 2 1 2

13. What will be the Electronic configuration of the element having atomic number 24?

a) 1s2 2s2 2p6 3s2 3p6 3d4 4s1 4p1 b) 1s2 2s2 2p3 3s2 3p6 3d5 4s1 4p3

c) 1s2 2s2 2p6 3s2 3p6 3d5 4s1 d) 1s2 2s2 2p6 3s2 3p3 3d5 4s1 4p3

14. Purpose of a mass spectrometer is to

a) determine the mass of an atom b) determine the charge of a particle

c) provide data for data loggers d) determine the particles

15. Cathode rays are discharged under one of the following conditions:

a) when a certain type of gas is used b) at very low pressure and high voltage

c) when a certain type of electrode is used d) only when the rays become negatively
charged
16. When an electron from an excited hydrogen atom undergoes the transition from energy level n = 4 to n = 2, the
emission of radiations will give rise to:

a) Lyman series b) Balmer series

c) Brackett series d) Paschen series

17. Calculate the wavelength (in nanometer) associated with a proton moving at 1.0 × 103 ms-1 (Mass of proton =

1.67 × 10-27 kg and h = 6.63 × 10-34 Js)

a) 0.40 nm b) 0.032 nm

c) 14.0 nm d) 2.5 nm
18. Among the following pairs of orbitals 2s and 3s, 4d and 4f, 3d and 3p, the orbitals that will experience the larger
effective nuclear charge will be:

a) 2s, 4d and 3d respectively b) 2s, 4d and 3p respectively

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 c) 2s, 4f and 3d respectively d) 3s, 4f and 3d respectively
19. Radio frequency region of the electromagnetic spectrum is used for broadcasting. It is

a) Around 10 Hz6
b) Around 10 15
Hz

c) Around 10 13
Hz d) Around 10 10
Hz
20. If nucleon and proton number of manganese is 24 and 12 respectively, number of electrons and protons will be

a) 12,12 b) 36,12

c) 24,24 d) 12,24
21. Paper chromatography is an example of ________.

a) column chromatography b) adsorption chromatography

c) partition chromatography d) thin-layer chromatography

22. Heterolysis of carbon - bromine bond gives ________.

a) two free radicals b) one carbocation ion and one carbanion

c) two carbocations d) two carbanions

23. Delocalisation of σ electrons of C - H bond of an alkyl group directly attached to an atom of unsaturated system
or to an atom with an unshared p orbital is called:

a) Electromeric effect b) Hyperconjugation

c) Inductive effect d) Resonance effect

24. Correct IUPAC name for H 3C - CH - CH - C H3 is ________.
| |

C2 H5 C2 H5

a) 2, 3-diethylbutane b) 2 - sec-butylbutane

c) 2 - ethyl-3-methylpentane d) 3, 4 - Dimethylhexane
25. Refining of petroleum involves the process of

a) Steam distillation b) Simple distillation

c) Distillation under reduced pressure d) Fractional distillation

26. The organic compound given below is one of the four options given below. Choose the most appropriate one.

a) aromatic heteroyclic compound b) benzenoid compound

c) aliphatic heterocyclic compound d) alicyclic compound

27. Straight or branched chain compounds, for example, the below ones are called
CH3 O

| ||

C H3 C H3 C H3 - CH - C H3 C H3 - C - H

a) closed chain compounds b) aliphatic cyclic compounds

c) alicyclic compounds d) aliphatic compounds

28. The IUPAC name of the compound is:

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 CH3 − C H − CHO
|
C H
2 5

a) 2-ethylpropanal b) 3-methyl isobutyraldehyde

c) butan-2-aldehyde d) 2-methylbutanal
29. In Carius method of estimation of halogen, 0.15 g of an organic compound gave 0.12 g of AgBr. Find out the
percentage of bromine in the compound.

a) 41. 5% b) 41. 06 %

c) 24 % d) 34.04%

30. How many metamers are possible for pentan-1-al?

a) Two b) Four

c) Three d) Zero
31. The IUPAC name of the compound
CH2 = CH - CH(CH3)2 is

a) 2-vinylpropane b) 1-isopropylethylene

c) 3-methyl-1-butene d) 1,1-dimethyl-2-propene
32. Electrophilic addition reactions proceed in two steps. The first step involves the addition of an electrophile.
Name the type of intermediate formed in the first step of the following addition reaction.

H3C—HC = CH2 + H+→ ?

a) 2° Carbocation b) 1° Carbocation

c) 2° Carbanion d) 1° Carbanion
33. The following compounds are called:

a) benzenoid compounds b) Alicyclic compounds

c) aromatic hetrocyclic compounds. d) aliphatic heteroyclic compounds

34. Which one is the use of chromatography?

a) In purification b) All of these

c) To test purity d) In separation

35. Correct IUPAC name of 2-ethylpropane will be:

a) 2-methylbutane b) 2-ethylbutane

c) Isobutane d) None of these

36. Two volatile compounds A and B differ in their boiling points by 25 K. The process which is most suitable for
their separation is ________.

a) re-crystallization b) simple distillation

c) distillation under reduced pressure d) fractional distillation

37. The IUPAC name for the following compound is:

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 a) 2, 5-dimethyl-6-oxo-hex-3-enoic acid b) 2, 5-dimethyl-5-carboxy-hex-3-enal

c) 2, 5-dimethyl-6-carboxy-hex-3-enal d) 6-formyl-2-methyl-hex-3-enoic acid

38. Nucleophile is a species that should have:

a) capacity to accept electrons b) a pair of electrons to donate

c) positive charge d) electron deficiency

39. The CORRECT statement regarding electrophile is:
i. Electrophile is a negatively charged species and can form a bond by accepting a pair of electrons from a
nucleophile.
ii. Electrophile is a negatively charged species and can form a bond by accepting a pair of electrons from
another electrophile.
iii. Electrophiles are generally neutral species and can form a bond by accepting a pair of electrons from a
nucleophile.
iv. Electrophile can be either neutral or positively charged species and can form a bond by accepting a pair of
electrons from a nucleophile.

a) Option (iv) b) Option (ii)

c) Option (i) d) Option (iii)

40. In a column chromatographic separation of a sample consisting of components A, B and C, if component C
elutes out first while A elutes out last. This means C is ________ while A is ________.

a) weakly adsorbed, strongly adsorbed b) moderately adsorbed, strongly adsorbed

c) strongly adsorbed, weakly adsorbed d) moderately adsorbed, weakly adsorbed

41. Which of the following is less reactive than benzene towards electrophilic substitution reactions?

a) Bromobenzene b) Nitrobenzene

c) Aniline d) Chlorobenzene
42. The number of possible conformational isomers of ethane is ________.

a) infinite b) zero

c) one d) two
43. Which of the following conformations of butane is most stable?

a) Skew b) Eclipsed

c) Gauche d) Anti
44. The increasing order of reduction of alkyl halides with zinc and dilute HCl is

a) R–Cl < R–Br < R–I b) R–I < R–Br < R–Cl

c) R–Br < R–I < R–Cl d) R–Cl < R–I < R–Br
45. Halogenation of alkanes is a:

a) Rearrangement reaction b) Elimination reaction

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 c) Addition reaction d) Substitution reaction
46. The synthesis of 3-octyne is achieved by subsequent stepwise reactions of sodium amide with an alkyne, and a
bromoalkane. The bromoalkane and the other alkyne respectively are:

a) BrCH2CH2CH3 and b) BrCH2CH2CH2CH2CH3 and

C H3 C H2 C H2 C ≡ CH C H3 C ≡ CH

c) BrCH2CH2CH2CH3 and d) BrCH2CH2CH2CH2CH3 and

C H3 C H2 C ≡ CH C H3 C H2 C ≡ CH

47. The peroxide effect in anti-Markovnikov's addition of HBr to unsymmetrical alkenes involves

a) homolytic fission of the double bond b) a free radical mechanism.

c) heterolytic fission of the double bond d) an ionic mechanism

48. Which of these fuels given below is not a hydrocarbon?
A. Hydrogen
B. LNG
C. LPG
D. CNG

a) C b) B

c) D d) A
49. Total number of isomers having molecular formula C4H8:

a) 2 b) 4

c) 6 d) 3
50. n-Propylbromide on treatment with ethanolic KOH is:

a) Propene b) Propanal

c) Propane d) Propyne
51. Saturated hydrocarbons contain

a) double bonds b) triple bonds

c) ionic bonds d) single bonds

52. In Friedel-Crafts alkylation reaction, when benzene is treated with an alkyl halide in the presence of a catalyst,
alkylbenzene is formed. The catalyst used is:

a) Anhydrous aluminium chloride b) Palladium

c) H3PO4 d) Silver

53. A molecule of benzene has:

a) 6σ and 3π bonds b) 12σ and 3π bonds

c) 6σ and 9π bonds d) 9σ and 3π bonds

54. Boiling point of alkanes are:

a) is independent of branching. b) decreases with increase in molecular mass.

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 c) is independent of molecular mass. d) increases with increase in molecular mass.
55. The carbon atoms of benzene are:

a) sp3 - hybridised b) sp - hybridised

c) sp2 - hybridised d) non-hybridised

56. In the Wurtz reaction method of preparation of alkanes, the stoichiometric coefficient of Sodium is ________.

a) 5 b) 3

c) 2 d) 1
57. The general formula for alkenes is:

a) CnH2n b) CnH2n+1

c) CnH2n+3 d) CnH2n+1

58. Ozonolysis of an organic compound gives formaldehyde as one of the products. This confirms the presence of:

a) a vinyl group b) two ethylenic double bonds

c) an isopropyl group d) an acetylenic triple bond

59. What product is obtained by heating ethylidene chloride with alcoholic KOH?

a) Ethyne b) Methane

c) Ethene d) Ethane
60. Stereoisomeric alkenes due to the different arrangement of atoms or groups in space are referred to as:

a) Constitutional isomers b) Position isomers

c) Chain isomers d) Geometric isomers

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