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Chapter 02 - Fuel, Lubricating Oil, Cooling Water
Chapter 02 - Fuel, Lubricating Oil, Cooling Water
02
Fuel, lubricating oil, cooling water
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W200
02.1.Fuel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
02.1.1.General . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
02.1.2.Fuel specifications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
02.2.Lubricating oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
02.2.1.Minimum fresh oil characteristics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
02.2.2.Approved lube oils . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
02.2.2.1.Engine oils . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
02.2.2.2.Oil for air starter . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
02.2.2.3.Oils for Woodward speed governors UG-8 and UG-A . . . . . . . . . . . . . . . . . . . . . . . . . . 7
02.3.Cooling water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
02.3.1.General . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
02.3.2.List of approved products . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
02.3.3.Product use . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14
02.3.4.Product references . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
02.3.5.Raw water quality . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
02.3.6.Water treatment product checking . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16
02.3.6.1.Laboratories addresses . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16
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Diesel Engines
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W200 Fuel, Lubricating Oil, Cooling Water 02.
Brand Name
Gali ETG 10
BP Energol HLP 32
Elf Olna, Visga 32
TotalFinaElf Total Equivis ZS 32
Fina Hydrau HV 32
Esso Nuto HP 32, Oleo Fluid HM 32
ExxonMobil
Mobil DTE 13M
Motul Rubric 32
Shell Tellus
Brand Name
BP Vanellus D1 5W40
Elf Excellium 5W40
TotalFinaElf Total Quartz 9000 5W40
Fina First 5W40
Esso Ultron Diesel 5W40
ExxonMobil
Mobil Delvac 1, Mobil 1 5W40
Castrol Syntruck 5W40
Shell Helix Diesel Ultra 5W40
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W200 Fuel, Lubricating Oil, Cooling Water 02.
Alkalinity / Acidity
If the lubricant alkalinity becomes too high, the life duration of
some components prone to acid corrosion (e.g. CuPb bearings) can
be shortened, viscosity can increase and the accumulation of
varnish and deposits can lead to pistons and segments wear. Corro-
sive wear is more commonly associated with combustion and oxida-
tion products results from the attack of sulphuric acids or organic
acids on iron surfaces.
Alkalinity is brought by the detergent additives to neutralise acid
combustion products. In diesel applications, sulphuric acid, formed
by oxidation of the sulphur content of the fuel, is one of the major
compounds.
Measuring the Base Number (or BN) allows the control of the lubri-
cant’s alkalinity and its determination is of prime importance for
diesel engines. The BN is measured in mg KOH / g of oil. The
method described by ASTM D2896 is generally used.
Oxidation / Nitration
After contact with oxygen from air and high temperatures, hydro-
carbons are oxidised and transformed or polymerised in long oxy-
genated hydrocarbons chains. Furthermore, oxidation intermediate
products can react with the nitrogen oxides, formed during the com-
bustion and contained in the blow by gas, to build very corrosive
nitro-oxygenated hydrocarbons.
Oil degradation by oxidation can be very harmful because it
leads to :
• the corrosive wear of metal surfaces by corrosive and
volatil acids
• viscosity increase by oil polymerisation
• engine deposits of sludge and varnish
• filter plugging by sludge.
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02. Fuel, Lubricating Oil, Cooling Water W200
Insolubles
The word “insolubles” describes all the products which are
non-soluble with the lubricating oil. They are mainly carbonaceous
materials like soot, dust and wear particles and organic oxidation
products.
Usually two solvents are used : n-pentane and toluene. The first
solvent coagulates all the insoluble components whereas only oxi-
dation products are soluble in the second one.The difference of
mass between n-pentane and toluene insolubles gives a good indica-
tion of the oil oxidation level used. Sometimes the insoluble oil con-
tent can be measured by filtration on a membrane.
For diesel engines the insoluble content is higher than that of natu-
ral gas engines, mainly because the amount of insoluble combustion
residue is greater when burning liquid fuel.
Insolubles lead to engine deposits of sludge and varnish but they
can also, to a certain extent, help to lubricate hot parts like valves
and valve seats.
Flash Point
It is the minimal temperature at which a product’s vapour can be
momentarily ignited by a flame. Two methods are generally used in
parallel depending if the oil is confined in an open or a closed cup :
ASTM D 92 Cleveland Open Cup method (preferred for engine oils)
and D 93 Pensky-Martens Closed Tester method.
The flash point is only measured for diesel engine oils because it is a
very good indication of fuel dilution problems and it can confirm
viscosity loss results.
Water content
The presence of water in lubricant can lead to sludge formation by
hydrocarbons hydrolysis, oil emulsion, additives demixtion... It can
also lead to seize by lack of lubricity.
The presence of water in oil may be an indication of leakage of
coolant on cylinder heads, liners seals or oil cooler, cracks on liner
or head, sump condensation problems and low temperature opera-
tion.
Coolant leakage is generally proved by detection of mineral salts
like sodium, bore, potassium, silicon... coming from the coolant for-
mulation even if certain of these elements are part of the initial fresh
oil. Sometimes the presence of water is not detected because it is
evaporated or decanted at the bottom of the sump. In that case,
coolant leakage can be suspected by the presence of the above men-
tioned salts or by glycol products detection.
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Note : For the products to be mixed, more the mixture ratio is higher,
worse is the water cooling performance.
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Unit Method
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