Lkpnn235a01 A03 CMS GN1 GN2 PH 1 Main

FIITJEE - JEE (Main)
Batch: LKPNN235A01, A03, CMS-GN1-SEC-A&J, LKITN235C01 (CMS-GN2)

(XI-ISC-PANINI-PINNACLE)
PHYSICS, CHEMISTRY & MATHEMATICS
JEE MAIN, 2025
PHASE – I
Date: 29.07.2023
Time Allotted: 3 Hour Maximum Marks: 300
 Do not open this Test Booklet until you are asked to do so.
 Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
Important Instructions
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR sheet before
attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each Section is further divided into Two Parts: Part-A & C in the OMR. Part-B of OMR to be left unused
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided for rough
work.
6. No candidate is allowed to carry any textual material, printed or written, bits of papers, clip boards, log tables, slide
rule, calculator, cellular phones, pagers and electronic devices ext. except the Admit Card inside the examination hall
/ room.
B. Filling of OMR Sheet:

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each character of your
Enrolment No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
4. Do not fold or make any stray marks on the Answer Sheet.
C. Marking Scheme for All Two Parts:

(i) Part-A (01–20) – Contains Twenty (20) multiple choice objective questions which have four (4) options each and only
one correct option. Each question carries +4 marks for correct answer and –1 mark for incorrect answer.
(ii) Part-C (01–05) contains Five (05) Numerical based questions with single digit integer as answer, ranging from 0 to 9
(both inclusive). Each question carries +4 marks for correct answer and –1 mark for incorrect answer.
Name of the Candidate (in Capital Letters) :_____________________________________
Enrolment Number :_________________________________________________________
Batch :________________________ Date of Examination : ________________________
FIITJEE Ltd., FIITJEE Kathauta Chauraha, Vinamra Khand, Gomti Nagar, Lucknow – 226010. Ph: 0522-2724960, 61. www.fiitjeelucknow.com
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LKPNN235A01-A03-CMS-GN1-(SEC-A&J)-LKITN235C01-(CMS-GN2)-PH-I-MAIN-2
USEFUL DATA
PHYSICS CHEMISTRY
2
Acceleration due to gravity : g = 10 m/s −1 −1
Gas Constant R = 8.314 J K mol
−34
Planck constant : h = 6.6 × 10 J − s = 0.0821 Lit atm
−19 −1 −1
Charge of electron : e = 1.6 × 10 C K mol
Mass of electron : me = 9.1 × 10
−31
kg
= 1.987 ≈ 2 Cal
−1 −1
−12 2 2 K mol
Permittivity of free space : ε 0 = 8.85 × 10 C /N −m
Avogadro’s Number Na = 6.023 × 1023
: ρwater = 10 kg / m
3 3
Density of water
−34
5 2 Planck’s constant h = 6.625 ×10 J .s
Atmospheric pressure : Pa = 10 N / m −27
Gas constant : R = 8.314 J = 6.625 ×10 erg .s
1 Faraday = 96500 coulomb
K −1 mol −1 1 calorie = 4.2 joule
−27
1 amu = 1.66 ×10 kg
−19
1 eV = 1.6 × 10 J
Atomic No: H = 1, He = 2, Li = 3, Be = 4, B = 5, C = 6, N = 7, O = 8, F = 9, Ne = 10, Na = 11,
Mg = 12, Si = 14, Al = 13, P = 15, S = 16, Cl = 17, Ar = 18, K = 19, Ca = 20,
Cr = 24, Mn = 25, Fe = 26, Co = 27, Ni = 28, Cu = 29, Zn = 30, As = 33, Br = 35,
Ag = 47, Sn = 50, I = 53, Xe = 54, Ba = 56, Pb = 82, U = 92.
Atomic masses: H = 1, He = 4, Li = 7, Be = 9, B = 11, C = 12, N = 14, O = 16, F = 19, Na = 23,

Mg = 24, Si = 28, Al = 27, P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52,
Mn = 55, Fe = 56, Co= 59, Ni = 58.7, Cu = 63.5, Zn = 65.4, As = 75, Br = 80,
Ag = 108, Sn = 118.7, I = 127, Xe = 131, Ba = 137, Pb = 207, U = 238.
Section – I Physics
PART – A : (Single Correct Answer Type)
This part contains 20 Multiple Choice Questions. Each question has four options (A), (B), (C) and (D)
out of which ONLY ONE is correct.
1. A bird flies for 4 sec starts at t = 0 with a velocity of |t − 2| m/s in a straight line, where t = time in
seconds. It covers a distance of
(A) 2 m (B) 4 m
(C) 6 m (D) 8 m
2. A spring of weight W and force constant k is suspended in a horizontal

position by two light strings attached to its two ends. Each string makes θ θ
an angle θ with the vertical. The extension of the spring is (assume
spring doesn’t bend)
(A) (W/4k) tan θ (B) (W/2k)tan θ
(C) (W/4k)sin θ (D) 0
3. A person moves 30m north, then 40m east and then 50m south-west. His displacement from the
original position is nearly
5π 10π
(A) m (B) m
9 9
15π 20π
(C) m (D) m
9 9
4. What will be the angle between vectors, A = 3iˆ + 4ˆj + 5kˆ , B = 3iˆ + 4ˆj − 5kˆ
(A) π / 2 (B) cos-1 (3/7)
(C) zero (D) π
5. A ball is thrown vertically upwards with velocity 20 m/s from a tower of height 60 m. How long after
its release will the ball reach the ground? (Take g = 10 m/s2)
(A) 2 sec (B) 6 sec
(C) 4 sec (D) 8 sec
6. A ball is thrown upward under gravity only. After leaving the hand, acceleration of ball
(A) remains constant (B) increases
(C) decreases (D) is zero
7. A body of mass m is resting on an inclined plane which is making angle θ m

with the horizontal. The coefficient of friction between the block and plane is
µ. Then frictional force acting between the surfaces is
θ
(A) µ mg (B) µmg cos θ
(C) µ (mg sin θ - mg cos θ) (D) mg sin θ.
8. In the shown arrangement, in absence of friction 1 kg 2 kg

F=(12 )N
between the blocks and surface, the tension in the ideal
string connecting the blocks would be
(A) 4N (B) 2N
(C) 8 N (D) none of these
X Y
9. A block X slides down upon a frictionless fixed inclined plane
when released from the top of the inclined plane while another h
h
block falls freely from the same point then
θ
(A) block X will strike the ground first
(B) block Y will strike the ground first
(C) both block will strike the ground simultaneously.
(D) none.
10. You are pulling down a string to lift the block of mass 'm' with constant velocity.
Pulleys, string are massless. Value of m is 40 kg. Then value of F is
(A) 250 N (B) 400 N
(C) 200 N (D) none of the above F
m
11. If A,B,C represent unit vectors in each case, which vector combination(s) result in a unit vector ?
V C
V C
V B
(1) V B (2)
V A V A
B V B
(3) (4)
V
A
C A
V
V V
V C
(A) 1, 2, 3 (B) 1, 3
(C) 1, 2, 4 (D) 4
12. A man walking eastward at 5 m/s observes that wind is blowing from North
the north. On doubling his speed eastward, he observes that wind is
blowing from north-east. The velocity of the wind is
(A) v w = −5iˆ − 5ˆj m/s ĵ
West
î
East
(B) v = 5iˆ + 5ˆj m/s
w
(C) v w = 5iˆ − 5ˆj m/s

(D) v = −5iˆ + 5ˆj m/s
w South
13. A flexible chain of mass m hangs between two fixed points A and B at the same level. The
inclination of the chain with the horizontal at the two points of support is θ . The tension at the mid
point C of the chain is
mg mg
(A) (B)
tanθ 2 tanθ
(sin θ + cos θ)
(C) zero (D) mg
2
14. A particle has an initial velocity of 3iˆ + 4ˆj and an acceleration of 0.4iˆ + 0.3ˆj . Its speed after 10 s
is
(A) 10 units (B) 7 units
(C) 7√2 units (D) 8.5 units
15. A body moves along a path PQR from P to R shown as a dashed line in figure. When the particle
is at Q, its speed is decreasing. The acceleration of the particle at Q is best represented by the
2
R
Q
1
P 3
(A) 1 (B) 2
(C) 3 (D) 4
gx 2
16. The equation of a projectile is y = 3x– . The angle of projection is-
2
(A) 30º (B) 60º
(C) 45º (D) None
17. A car accelerates on a horizontal road due to the force exerted

(A) by the engine of the car (B) by the driver of the car
(C) due to the earth’s gravity (D) by the road
18. A block of mass m is placed on smooth triangular block as shown in the figure. The triangular
block is moving horizontally with uniform speed 2 3 m/s. The acceleration of block of mass m
with respect to the triangular block is
(A) 5 m/s2 (B) 8 m/s2

(C) 4 m/s2 (D) 6 m/s2
19. A racing motor boat speeds up in a straight line in a lake, from a (m/s2)
rest. Referring to the acceleration displacement graph for
speeding boat, find speed of the motor boat when it has
maximum acceleration 8
(A) 64 m/s (B) 32 m/s
(C) 8 m/s (D) 4 m/s
S(m)
O 8 16
20. An observer is moving with acceleration a1 and an object of mass m is

moving with acceleration a2. The pseudo force observed by observer on a1
object of mass m will be :
(A) m (a1 – a2) ( − î) (B) m (a2 + a1) ( − î)
a2
(C) m a1 ( − î) (D) ma2 ( − î)
y
PART – C : (Single digit integer)

This part contains 5 questions. The answer to each question is a single digit integer ranging from 0 to 9
(both inclusive).
1. Block A and B have masses of 2 kg and 3 kg respectively. The ground is 3 kg

2 kg
smooth. P is an external force of 10 N. Find the force exerted by B on A in P = 10 N B
Newton. kg A
2. A particle is projected from point A perpendicular to inclined plane with a velocity 50 m/s as
shown in the figure. Particle strikes a vertical plane perpendicularly at point B. Find the time taken
by particle in going form point A to point B.
3. ( 2 3
)
x-coordinate of a particle moving along this axis is x = 2 + t + 2t . Here x is in meter and t is in
seconds. Find velocity of particle in m/s at t = 1 sec.
4. A uniform rope of length l lies on a table with horizontal surface. If the co-efficient of friction is
0.25, then the maximum length l1 of the part of this rope which can over hang from the edge of the
table without sliding down .find ratio l/ l1.
5. A stationary man observes that the rain is falling vertically downward. When he starts running
horizontally with a velocity of 2 3 km/h he observes that the rains is falling at an angle 600 with
the vertical. The actual velocity of rain is…………. Km/h.
Section – II Chemistry
1. The hydrated salt Na2CO3. xH2O undergoes 63% loss in mass on heating and become
anhydrous. The value of x is
(A) 10 (B) 12
(C) 8 (D) 18
2. How many maximum number of orbitals are associated with the orbit of hydrogen atom, which
energy is -0.85 eV?
(A) 9 (B) 16
(C) 25 (D) 4
o
3. A radiation of wavelength 1000 A was absorbed by hydrogen atom in ground state and the
electron was excited. On de-excitation to ground state two photons are emitted. If the wavelength
o
of one photon is 6000 A , what will be the wavelength of the other photon?
o o
(A) 1200 A (B) 5000 A
o o
(C) 4000 A (D) 2400 A
4. The radius of first orbit of hydrogen atom is identical to the radius of

(A) third orbit of He+ (B) second orbit of Be3+
(C) fourth orbit of Li2+ (D) fourth orbit of He+
5. Which of the following atom contains maximum number of unpaired electrons in ground state?
(A) O (B) P
(C) Br (D) Xe
6. Out of following molecules of ABx type (where A = central atom), which one has at least one BAB
bond angle as 90°
(A) ClF3 (B) SF4
(C) IF5 (D) PCl5
7. If 1 g of H2(g) reacts with 1 g of Cl2(g) in a closed container, then how many grams of HCl will be
produced during the reaction?
(A) 1.028 g (B) 2.076 g
(C) 3.114 g (D) None of these
8. The molality of 1 litre solution of 93% H2SO4 (w/v) having density 1.84 g/mL is
(A) 10.43 (B) 1.043
(C) 0.1043 (D) None of these
9. What is the group number of the least reactive elements of the periodic table?
(A) Group – 1 (B) Group – 17
(C) Group – 18 (D) Group – 12
10. The empirical formula of a compound is CH2. Which cannot be the molecular mass of the
corresponding compound?
(A) 84 (B) 70
(C) 56 (D) 48
11. What forms solid bicarbonates?

(A) Fe (B) Na
(C) Ca (D) Pb
12. Choose the s-block element from the following

(A) 1s2 , 2s2 , 2p6 , 3s2 , 3p6 , 3d10 , 4s1 . (B) 1s2 , 2s2 , 2p6 , 3s2 , 3p 6 , 3d9 , 4s1 .
(C) 1s2 , 2s2 , 2p6 , 3s2 , 3p6 , 4s1 . (D) all of the above
13. A molecule having trigonal bipyramidal geometry and sp3d hybridization d orbitals involved in
hybridization is
(A) dxy (B) dyz
(C) d x 2 − y2 (D) d z2
14. Insulin has 3.4% sulphur. Minimum molecular weight of Insulin is

(A) 94.176 (B) 1884
(C) 941.176 (D) 976
15. What mass percentage of oxygen is present in magnesium oxide?

(A) 60% (B) 40%
(C) 20% (D) 80%
16. The correct order of decreasing X-O-X bond angle is (X = H, F or Cl)

(A) H2O > Cl2O > F2O (B) Cl2O > H2O > F2O
(C) F2O > Cl2O > H2O (D) F2O > H2O > Cl2O
17. The percentage ionic character of a single bond having 1.275 Å as its length and 1.03 D its dipole
moment will be
(A) 8.63% (B) 6.83%
(C) 3.68% (D) 16.83%
18. Among LiCl, BeCl2, BCl3 and CCl4, the covalent character follows the order
(A) LiCl < BeCl2 > BCl3 > CCl4 (B) LiCl > BeCl2 < BCl3 < CCl4
(C) LiCl < BeCl2 < BCl3 < CCl4 (D) LiCl > BeCl2 > BCl3 > CCl4
19. The correct order of penetrating power of 3s, 3p and 3d electrons are in the order:
(A) 3d > 3p > 3s (B) 3s > 3p > 3d
(C) 3s > 3d > 3p (D) 3d > 3s > 3p
20. The first (IE1) and second (IE2) ionisation energies (kJ mol–1) of a few elements are shown
below:
IE1 IE2
(P) 2372 5251
(Q) 520 7300
(R) 900 1760
(S) 1680 3380
Which of the above elements is likely to be a noble gas?
(A) (P) (B) (Q)
(C) (R) (D) (S)

(both inclusive).
1. How many maximum number of electrons in an atom can have the following set of quantum
numbers?
n + ℓ = 4, m = 0 and s = ±½
o
2. The S-F bond length of an isolated SF6 molecule is 2.828 A . What is the distance of separation
o
between two adjacent fluorine atoms in SF6 in A unit?
3. When hydrogen atoms are exposed with certain radiation of a particular frequency, the maximum
number of spectral lines obtained in the emission spectra is 15. The uppermost energy level (n)
to which the e − is excited is
4. Based on VSEPR theory, number of 90o F – Br – F bonds in BrF5 is
5. Total number of sigma bonds in C2H4 is ……..
Section – III Mathematics

2 3
1. The number of integral values of x satisfying

( x − 2 )( 2x − 3 ) ( x − 6 ) < 0 is
4
( x + 5)
(A) 0 (B) 1
(C) 2 (D) 3
sin2 3x
2. The value of lim is:
x →0 x2
(A) 3 (B) 6
(C) 9 (D) 1
3. If A = tan 6° tan 42° and B = cot 66° cot 78°, then

1
(A) A = 2B (B) A = B
3
(C) A = B (D) 3A = 2B
The solutions of the inequation 2 x + 3 x − 9 ≤ 0 are given by :

2
4.
3 3
(A) −3 ≤ x ≤ − (B) −3 ≤ x ≤
2 2
3
(C) ≤ x≤3 (D) none of these
2
5. If α ⋅ β are the roots of a quadratic equation x2 − 3x + 5 = 0, then the equation whose roots are
( α2 − 3α + 7) and (β2 − 3β + 7 ) is:

(A) x 2 + 4x + 1 = 0 (B) x 2 − 4x + 4 = 0
(C) x 2 − 4x − 1 = 0 (D) x 2 + 2x + 3 = 0
3π
6. If π < 2θ < , then 2 + 2 + 2 cos 4θ is equal to
2
(A) −2 cos θ (B) −2 sin θ
(C) 2 cos θ (D) 2 sin θ
dy π
7. If y = sin3 x + sin2 x + sin x + 1, then the value of at x = is:
dx 2
(A) 4 (B) 3
(C) -1 (D) 0
p q
8. If tan α = and tan β = , then the angle ( α + β ) is equal to
q p
π π
(A) (B)
3 2
π
(C) (D) none of these
6
9. ( 2 + 3 ) sin θ + 2 cos θ lies between

(A) − 3 and 3 (
(B) − 2 + ) (
3 and 2 + 3 )
(C) − 2 +( ) (
5 and 2 + 5 ) (D) none of these
(x − 1)(x − 2)2 (x + 4)
10. Solution set of ≥0
(x + 2)(x − 3)
(A) ( −∞, −4] ∪ ( −2,1] ∪ {2} ∪ (3, ∞ ) (B) ( −4,2] ∪ [1,2] ∪ (3, ∞ )
(C) ( −∞, −4] ∪ {2} ∪ (3, ∞ ) (D) None of these
11. The value of 2 sin12° − sin 72° is:
(A)
5 1− 3( ) (B)
1− 5
4 θ
(C)
(
3 1− 5 ) (D)
(
3 1− 5 )
2 4
12. If the equation x2 – 3xk + 2e2ln k – 1 = 0 has real roots such that the product of root is 7, then the
value of k is
(A) ±1 (B) ±2
(C) ±3 (D) None of these
13. If both the roots of the quadratic equation x 2 − 2kx + k 2 + k − 5 = 0 are less than 5, then k lies in
the interval
(A) (−∞, 4 ) (B) [4, 5]
(C) (5, 6] (D) (6, ∞ )
π 5π 7π
14. The value of sin sin sin is
18 18 18
1 1
(A) (B)
8 2
1 1
(C) (D)
4 16
15. If sinθ and cosθ are the roots of the equation ax2 + bx + c = 0, then
(A) (a − c)2 = b2 − c2 (B) (a − c)2 = b2 + c2
(C) (a + c)2 = b2 − c2 (D) (a + c)2 = b2 + c2
16. If α, β are the roots of the equation ax2 + bx + c = 0, then the roots of the equation cx2 + bx + a =
0, are
(A) −α, −β (B) α, −β
1 1 1
(C) α, (D) ,
β α β
17. |x + 1| + |x − 2| > 3
(A) (−∞, −1) ∪ (2, ∞) (B) (2, ∞)
(C) (−1, 2) (D) none of these
18. Solution set for the inequality log 1 x − 3 > 0 is

2
(A) [3, ∞) (B) (2, 3)∪(3, 4)

(C) [2, 3) ∪(3, 4] (D) (2, 4)
 (x )
2
19. + 2x dx =
0
(A) 4/3 (B) 32/3
(C) 6 (D) 20/3
( log5 x )
2
20. If + log5 x < 2, then x belongs to the interval
 1  1 1 
(A)  ,5 (B) 5, 
 25   5
(C) (1, ∞ ) (D) none of these

(both inclusive).
a21 + b21 + a17 + b17

1. If a and b are roots of the equation x 2 − 7x − 1 = 0, and the value of =λ,
a19 + b19
λ
then the value of is:
17
1
dy
2. If y = x 2 + x 2 , then at x = 1 is n. Find the value of 2n.
dx
3. The value of tan9° − tan 27° − tan 63° + tan 81o is:
2
4. The sum of the real roots of the equation x − 2 + x − 2 − 2 = 0 is
5. If one root of equation x 2 + px + q = 0 be the square of other then p 3 + q 2 + q = kpq where k is
FIITJEE - JEE (Main)

Batch: LKPNN235A01, A03, CMS-GN1-SEC-A&J, LKITN235C01 (CMS-GN2)
(XI-ISC-PANINI-PINNACLE)
PHYSICS, CHEMISTRY & MATHEMATICS

JEE MAIN, 2025
PHASE – I
Date: 29.07.2023
ANSWERS
PHYSICS
PART – A
1. B 2. B 3. D 4. A
5. B 6. A 7. D 8. A
9. B 10. C 11. B 12. C
13. B 14. C 15. C 16. B
17. D 18. A 19. C 20. C
PART – C
1. 6 2. 4 3. 8 4. 5
5. 6
CHEMISTRY
PART – A
1. A 2. B 3. A 4. B
5. B 6. D 7. A 8. A
9. C 10. D 11. B 12. C
13. D 14. C 15. B 16. B
17. D 18. C 19. B 20. A
PART – C
1. 4 2. 4 3. 6 4. 0
5. 5
MATHEMATICS
PART – A
1. D 2. C 3. C 4. B
5. B 6. D 7. D 8. B
9. D 10. A 11. D 12. D
13. A 14. A 15. D 16. D
17. A 18. B 19. D 20. A
PART – C
1. 3 2. 5 3. 4 4. 4
5. 3

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FIITJEE - JEE (Main)

Batch: LKPNN235A01, A03, CMS-GN1-SEC-A&J, LKITN235C01 (CMS-GN2)

B. Filling of OMR Sheet:

C. Marking Scheme for All Two Parts:

Name of the Candidate (in Capital Letters) :_____________________________________

Enrolment Number :_________________________________________________________

Batch :________________________ Date of Examination : ________________________

Atomic masses: H = 1, He = 4, Li = 7, Be = 9, B = 11, C = 12, N = 14, O = 16, F = 19, Na = 23,

2. A spring of weight W and force constant k is suspended in a horizontal

7. A body of mass m is resting on an inclined plane which is making angle θ m

8. In the shown arrangement, in absence of friction 1 kg 2 kg

(C) v w = 5iˆ − 5ˆj m/s

17. A car accelerates on a horizontal road due to the force exerted

(A) 5 m/s2 (B) 8 m/s2

20. An observer is moving with acceleration a1 and an object of mass m is

PART – C : (Single digit integer)

1. Block A and B have masses of 2 kg and 3 kg respectively. The ground is 3 kg

4. The radius of first orbit of hydrogen atom is identical to the radius of

11. What forms solid bicarbonates?

12. Choose the s-block element from the following

14. Insulin has 3.4% sulphur. Minimum molecular weight of Insulin is

15. What mass percentage of oxygen is present in magnesium oxide?

16. The correct order of decreasing X-O-X bond angle is (X = H, F or Cl)

PART – C : (Single digit integer)

5. Total number of sigma bonds in C2H4 is ……..

Section – III Mathematics

1. The number of integral values of x satisfying

3. If A = tan 6° tan 42° and B = cot 66° cot 78°, then

The solutions of the inequation 2 x + 3 x − 9 ≤ 0 are given by :

( α2 − 3α + 7) and (β2 − 3β + 7 ) is:

9. ( 2 + 3 ) sin θ + 2 cos θ lies between

11. The value of 2 sin12° − sin 72° is:

18. Solution set for the inequality log 1 x − 3 > 0 is

(A) [3, ∞) (B) (2, 3)∪(3, 4)

PART – C : (Single digit integer)

a21 + b21 + a17 + b17

5. If one root of equation x 2 + px + q = 0 be the square of other then p 3 + q 2 + q = kpq where k is

FIITJEE - JEE (Main)

PHYSICS, CHEMISTRY & MATHEMATICS

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