8) Acidih aluhsls

Jhe
Vacide chaaetu
0-H bond
natuu
Hhepla
An e linding
inciaes e 0-H bord

aeuas
Jhis ollascs aleuases a plours
aleshol
Jhe did sungh
R-CH, OH > CHOH)R C - o H
R

Phenola .
) Aidihy
he
C- alon benzene Ag
uhith att
Duu t his

be tve
Auctu
10-H

Zhe fonisahon of an al eokol anda phenol aku pau

produeng altozide and phenouide ions
the

R-o-H R- Þ: +H1

+ H.

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 Date
Pace
13

dn akoide ion ), the -vc ion the -ve chasge is locats

on oxy gen. shile bhenonide fon, the charge 4
delocalised.
Jhe de localsahon Chavge maks phenonide Ton
andfavouus he onid aloo phanol.

b) Estucahon
Aleohsls and Phne ls ek uo cas bory ke avds, a d
chlarides and Qcid anty ludes tofpam c e
H Ae ocoR' +H0
Esti

aud anhyode
Penidrng
AM/-0H + 2'cou
Aid ahlonde
C-0 bon ds in Aleohe
elavagebelbdes
Alwhak set eih hydogen haleg to foun. alkyl halides.

R-0H + H X tH, o

C14y CH, OH HU

6) Rn Jhes phoneus t halides

halides y
uh PAasfhoaus tihalides. alty
Pro

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 Dare

14

Dehydaatbn
Aiahels undeugo olehydrahon o foamn alkens
(on H so4 oA Hz Po4)
tabng Aunina

CAz CH;-OH SO4,

r°2 hyl alrehel ihene

CH; - .CHs - C=cH

prapylene
pachyl alehcl

3 CH3
H3c -C- (H
355k
OH

Lobuylene
Mechenism
ehars Alcohdl.
Steb I: toamahon
brolonaad aliohct

H-c-c-0-H +Ht Fast

H H T
H

Elha nol
baolonabd alehol
ion
loamahon caubo -calion:
the
Aatt
stowet sap and hen ce he
Jhe axn

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 wiScanned
th
ChlosPysi
o di un PCC heat qu0d hyde Ade
KCHO OHRCH
eldetyoe tsclabon
he
used medum
is anhyaous îa
acid arbony
lit Aldehyde °Altohol
R-c0 OH
PCH;
Oxdn,
casbony
b'e
Qcid
he
dingq Defen
het /° On
ogenahon deky known also
T H
dobon C-H and 0-H af
aleavage
Qn
aah bond double C-0
thefoamabon invdhves
xdahon d
Ehene
H H
elminehon Ehene foanahon
H,o +
-c-c H
H
H H
15
Page,
 DCC
CHz-CH = CH- cl, o
Aldeiyde

keton e

hlher the vab dehyageaahon aluy

Oye

blace and en alolehyde on ke tone is foamed.

CH
RcHo
573*

A(dehyde
2- CH - 2'
673E
Ke 5ne

CHz CHz

CHz -C= (H, + H,o

CH3 Alkene
3° Aleshol
Paatan tene.
Ryn of Phensls
Aomati aubsthhon
a) Nihehion.
i) Nihahon uith dil 4ND,
mizllu Orttio and paa
iho phendks

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 Pcçe 9
14

NO
+

N P:nibophonol.
O-niko phenol
Nitahon uih Conc ANOZ þhenol is Convevlad to.
4 6-hi niko phendl (piciic aud)

NO NO
Conc HND3

NO, , 4,6- tiniho þhenol : (picric acid)

b) Halogenahon
When the an is cau'ed Dut in sotven ti loo
Such cHlg CS and at low érnas
ono - baomo phenols eamed.
OH
Be
+

1 Mino Major
Ba
0-baomophenol
p- baoo phenl

)When Phendl is tiatid uih BADmie wau 6

Ba BA
+

phenol

, 4,b) bi baomo phenol

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 Page

48
2) Kol bes Aea chon
Pherpxide ion qenuatd
NaDH us MOAe Actve than phend, it undugoy

Oadho hydioNy benzoie acid is fomed

ONa

NaH ( 0OH

O-hydiony benz oie atid

(Sal cycl'e ocid)

-X"3| Reinen - Tieman Rea chon

Cn treahng bhenol with chloofoam. in Jhe_presene 4
Na DH, a £ cho is înlhodueet at sttho pohhon
berzene ang: Jhis RTAXn.

CHgtag Naol, CHU CHO CHO

Driumediaa Saliayclalde hece

Rea chon 9-shend7 wnlh Zinc dlst
Phendt is eonvetit to Benzene
tuahng wih Zine lugt

+ Zn + ZnD

benzene
 Note:
Ua thepeSeue o alt, phe wols ae
dank coloubuod ufxted coataiulug nuino
ComeiÊally lupo9rtant alcohols

+IE s poocuced by destuctive distttok ofw0od.

Zn0-(pO3
200-300 Qhm CH,OH.
513-673K

foreperte

Note
lugex tou of eyeu a swall qusntyof metha hol an Gule
bidnes and asge quanted caue deat.
Vses

|owwerral Poupaasto

he susa is nslasses ,sughane as ust such as

useue enze avertase

SUse gluose fsuctose.
(Suga).
24naSe
> 2,Hot
ehal
glucose
(o)

Ahe pw ducto of ettauoL

epaation o l i e

enzyuAe a d auaesobi ouclBtou.

praseuce
Cagbon dioxle Co) is aleied dusiug deantatbu.

Note:
ahebtted oce te perceuta
alohol fored exceeds 47.
oKÃ dïses ethauoL to ethaoe a l nkeh destoys the
taltes of alcoolE dks.

Psroper tieA
Elhs uol s coloualess e d au wo pofsoo
Eoilu pofut 35) K

Vses
mnte canbon opouns
The
 classMate
Date
Page

Appaie te) 5 elhauol ie ale

IoO alcool s alled obsouk alool