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Chemistry Study Book For Grade 9
Chemistry Study Book For Grade 9
Chemistry Study Book For Grade 9
2023/2024 Chemistry
Grade 9
Eslam Hamouda
+201091744480
Table of contents
Unit (1) Atomic structure ………………………………………………………………………………….. 3
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UNIT (1) ATOMIC STRUCTURE
• Describe the structure of the atom and its component parts
Atoms are the smallest particles of matter, that we cannot break
down further by chemical means.
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Protons, neutrons, and electrons
Atoms consist of a nucleus and a cloud of electrons that move around
the nucleus. The nucleus is itself a cluster of two kinds of particles,
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protons and neutrons.
All the particles in an atom are very light. So their mass is measured in
atomic mass units, rather than grams. Protons and electrons also have
an electric charge.
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Note
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• Define proton number and mass number
You can identify an atom by the number of protons in it.
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The number of protons in an atom is called its proton number.
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• Define isotopes
Isotopes are atoms of the same element, with different numbers
of neutrons.
Most elements have isotopes. For example calcium has six, magnesium
has three, iron has four, and chlorine has two.
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Relative atomic mass (Ar)
Atoms of an element are not always identical.
Some may have extra neutrons. Different atoms of the same element are
called isotopes. Chlorine has two isotopes:
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work out the relative atomic mass. This is the formula to use:
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• Describe the build-up of electrons in ‘shells’ and understand
the significance of the noble gas electronic structures
Electron shells:
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The electron shells for the first 20 elements:
Below are the electron shells for the first 20 elements of the
Periodic Table.
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The number of electrons increases by 1 each time. (It is the same as the
proton number.) The shells fill according to the rules above.
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• Use the valencies of elements and polyatomic ions to
construct formulae
• Use the symbols of the elements to write the formulae of more
complex compounds including those containing brackets
and/or polyatomic ions, for example sulfates, nitrates,
hydroxides, phosphates
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• Interpret the formula of a given compound from the relative
numbers of atoms present including formulae with brackets
and/or polyatomic ions, for example sulfates, nitrates,
hydroxides, phosphates
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• Write down the formula of a given compound from a model or
a diagrammatic representation including formulae with
brackets and/or polyatomic ions, for example sulfates, nitrates,
hydroxides, phosphates
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• Deduce the balanced equation for a chemical reaction, given
relevant information
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• Use, in a practical context, the following tests to identify some
gases.
• The period number tells you how many shells there are.
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• All the elements in a group have the same number of electrons in their
outer shells. So Group I elements have 1, Group II have 2, and so on.
• These outer-shell electrons are also called the valency electrons.
• The group number is the same as the number of outer-shell electrons,
except for Group 0.
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Group O, a special group:
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This stable arrangement of electrons has a very important result: it makes
the Group 0 elements unreactive.
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Formula from names of compounds
Sometimes the name of the compound gives information about the formula of that
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compound. Names of these compounds have prefixes that give the number of atoms
of certain elements in each molecule.
Names of compounds
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Tetra- Four
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Penta- Five
Hexa- Six
Example – Carbon monoxide contains one carbon atom joined to one oxygen atom,
so it has the formula CO.
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Valency
Valency is the combining power of an element. Elements in the same group of the
periodic table have the same valency. The valency of an element is related to how
many electrons are in the outer shell.
Valency table
Group number 1 2 3 4 5 6 7 8
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Valency 1 2 3 4 3 2 1 0
The noble gases have the valency 0 as they do not usually combine with other
elements.
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To write the chemical formula for a compound it is best to use the S.V.S.D.F system.
Step one: Write down the symbols of both the elements involved.
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Step two: Beneath each symbol, write its valency. Memorise the table above to help
you.
Step Four: If the valencies can be simplified, divide them both by the smaller of the
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two numbers. If one of the numbers is already one, then they cannot be divided and
simplified any further.
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Example 2: What is the formula for aluminium oxide?
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Example 3: What is the formula for carbon sulphide?
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Formulae of compounds containing group ions
Group ions contain two or more atoms and usually have a negative charge. The
formulae of these ions are given on page 4 of the data booklet. We can take the
number of charges on the ion as the valency of the ion.
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Formula and Roman Numerals
Roman NumeralNumber
I One
II Two
III Three
IV Four
V Five
VI Six
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Balanced Equations
A chemical equation is said to be balanced when there are the same number of the
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same type of every atom on both sides of the equation.
Balanced symbol equations show what happens to the different atoms in reactions.
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For example, copper and oxygen react together to make copper oxide.
Copper and oxygen are the reactants because they are on the left of the arrow.
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If we just replace the words shown above by the correct chemical formulae, we will
get an unbalanced equation, as shown here:
Cu + O2 → CuO
Notice that there are unequal numbers of each type of atom on the left-hand side
compared with the right-hand side. To make things equal, you need to adjust the
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number of units of some of the substances until you get equal numbers of each type
of atom on both sides.
2Cu + O2 → 2CuO
You can see that now there are two copper atoms and two oxygen atoms on each
side. This matches what happens in the reaction.
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Two atoms of copper react with two atoms of oxygen to form two molecules of
copper oxide.
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To balance equations on your own, follow these simple rules:
Step 1: Check that all the formulae in the equation are correct.
Step 3: Balancing is adding BIG numbers. You cannot change any of the small
numbers in a chemical formula. If balancing is required, put the number in front of
the substance.
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Step 4: Check each element again and repeat step 3 again if needed.
Example:
This equation is unbalanced. There are four carbon atoms on the left hand side and
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only one on the right. To balance the carbon, add a big “4” in front of the carbon
dioxide.
Next, to balance the hydrogen. We have 8 atoms of hydrogen on the left hand side in
C4H8 and only 2 on the right hand side. To balance the hydrogen atoms, add a big
"4" in front of H2O.
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We’re not finished yet. Now that the carbon and hydrogen have been balanced, we
only have to balance the oxygen. We have 2 atoms of oxygen on the left, but in total
on the right (taking into account what we have balanced already) we have 12 oxygen
atoms. This can be balanced by adding a big “6” in front of the diatomic oxygen
molecule on the left hand side.
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Ions and neutral atoms:
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When an atom of Sodium is neutral it is written that way (Na) with no charge above
the symbol.
As we know Sodium atom to become stable it loses one electron to form a positive
ion with the formula (Na+) with a positive charge on top of the symbol
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When an atom of Oxygen is neutral it is written that way (O) with no charge above
the symbol.
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As we know Oxygen atom to become stable it gains two electron to form a negative
ion with the formula (O-2) with two negative charge on top of the symbol
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Radicals
What is a Radical (Poly atomic ion)?
A radical is a group of atoms of elements, e.g., sulphate radical [SO42-]. Some
radicals and their chemical symbols are listed below.
Valency Radical
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Hydroxide (OH1-)
Monovalent
Nitrate (NO31-)
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Carbonate (CO32-)
Divalent
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Sulphate (SO42-)
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• Use models or diagrams to show the difference between
single atoms, elements (as having only one type of atom) and
molecules (as being a small number of atoms chemically
joined)
Elements can be either single atoms like (Na) or molecules of the same
atoms like (Cl2 – O2 – N2)
Compounds are always in the form of molecules Like (CO2 – CH4 H2O)
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• Gases: hydrogen (using lighted splint) oxygen (using a
glowing splint).
You have a sample of gas. You think you know what it is, but you’re not
sure. So you need to do a test. Below are some tests for common gases.
Each is based on particular properties of the gas, including its appearance,
and sometimes its smell.
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UNIT (2) METALS AND REACTIVITY
• Describe metallic bonding
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In metals, the atoms are packed tightly together in a regular lattice.
The tight packing allows outer electrons to separate from their atoms.
The result is a lattice of ions in a ‘sea’ of electrons that are free to move.
Look at copper:
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The copper ions are held together
by their attraction to the free
electrons between them.
The strong forces of attraction
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are called metallic bonds .
The metallic bond is the attraction between metal ions and free
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Electrons (Delocalised electrons)
Delocalised electrons
The electrons that move freely in the
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Explaining some key properties of metals
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slide over each other. This diagram represents any metal lattice:
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The layers can slide without breaking the metallic bond, because the
electrons are free to move too.
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3. Metals are good conductors of heat.
That is because the free electrons take in heat
energy, which makes them move faster. They
quickly transfer the heat through the metal
structure:
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because it is cheaper.
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• Explain why metals are often used in the form of alloys
• Identify representations of alloys from diagrams of structure
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the gold-coloured alloy called brass.
When this solidifies, it is hard, strong,
and shiny. It is used
for door locks, keys, knobs, and
musical instruments such as trumpets.
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Turning a metal into an alloy changes its properties, and makes it more
useful.
It is not only strength that changes: other properties will change too.
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For example the alloy may be more resistant to corrosion than the original
metal was.
You can add more than one substance. You can try out different amounts
of different substances, to design an alloy with exactly the properties that
you need.
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• Describe some uses of metals related to their physical and
chemical properties
Properties dictate uses
Examples of some metals and their properties and how these properties
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• Investigate the general physical and chemical properties of
metals
1. They are strong. If you press on them, or drop them, or try to tear
them, they won’t break – and it is hard to cut them.
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2. They are malleable. They can be hammered into shape without
breaking.
3. They are ductile: they can be drawn out into wires.
4. They are sonorous: they make a ringing noise when you strike them.
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5. They are shiny when polished.
6. They are good conductors of electricity and heat.
7. They have high melting and boiling points. (They are all solid at room
temperature, except mercury.)
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8. They have high density – they feel ‘heavy’. (Look at the blue panel.)
4. For the metals in the numbered groups, the charge on the ion is the
same as the group number. But the transition elements have variable
valency: they can form ions with different charges. For example CuI
and Cu2I.
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1 The reaction of metals with water
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Note the order of reactivity, based on the reaction with water.
And note that only the first three metals in the list produce hydroxides.
The others produce insoluble oxides, if they react at all.
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2 The reaction of metals with hydrochloric acid
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Hydrogen is displaced
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UNIT (3) RATES OF CHEMICAL
REACTION
• Carry out practical activities and interpret data that
illustrate the effect of temperature, simple catalysts
and particle size on the rates of chemical reactions.
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In general, to find the rate of a reaction, you should measure:
the amount of a reactant used up per unit of time or the amount of
a product produced per unit of time.
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A reaction that produces a gas
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The volume of gas in the syringe is noted at intervals – for example
every half a minute. How will you know when the reaction is complete?
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temperature. The rate will change - but the amount of product you
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1 By changing concentration
Here you will see how rate changes with the concentration of a reactant.
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2 By changing temperature
Here you will see how rate changes with the temperature of the
reactants.
The method Dilute hydrochloric acid and sodium thiosulfate solution
react to give a fine yellow precipitate of sulfur. You can follow the rate of
the reaction like this:
1. Mark a cross on a piece of paper.
2. Place a beaker containing sodium thiosulfate
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solution on top of the paper, so that you can see the
cross through it, from above.
3. Quickly add hydrochloric acid, start a clock at the
same time, and measure the temperature of the
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mixture.
4. The cross grows fainter as the precipitate forms.
Stop the clock the moment you can no longer see the cross. Note
the time.
5. Now repeat steps 1 – 4 several times, changing only the
temperature.
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You do this by heating the sodium thiosulfate solution to different
temperatures, before adding the acid.
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The cross disappears when enough sulfur has formed to hide it.
This took 200 seconds at 20 °C, but only 50 seconds at 40 °C.
So the reaction is four times faster at 40 °C than at 20 °C.
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3 By changing surface area
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The rate can be measured using the apparatus on the
right.
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The method Place the marble in the flask and add the acid. Quickly plug
the flask with cotton wool to stop any liquid splashing out. Then weigh it,
starting the clock at the same time. Note the mass at regular intervals
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until the reaction is complete.
Carbon dioxide is a heavy gas. It escapes through the cotton wool,
which means that the flask gets lighter as the reaction proceeds. So by
weighing the flask at regular intervals, you can follow the rate of
reaction.
The experiment is repeated twice. Everything is kept exactly the same
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each time, except the surface area of the marble chips.
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4 Catalysts
What is a catalyst?
You saw that a reaction can be speeded up by increasing the
temperature,
or the concentration of a reactant, or the surface area of a solid reactant.
There is another way to increase the rate of some reactions: use a
catalyst.
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A catalyst is a substance that speeds up a chemical reaction, but
remains chemically unchanged itself.
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Hydrogen peroxide is a colourless liquid that breaks down very slowly to
water and oxygen:
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You can show how a catalyst affects the reaction, like this:
1. Pour some hydrogen peroxide into three measuring cylinders. The
first one is the control.
2. Add manganese(IV) oxide to the second, and raw liver to the third.
3. Now use a glowing wooden splint to test the cylinders for oxygen.
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The splint will burst into flame if there is enough oxygen present.
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UNIT (4) ACIDS AND ALKALI
• Investigate the use of the pH meter
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• Investigate the characteristic properties of acids and Alkalis:
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UNIT (5) CARBON CHEMISTRY
Carbon Chemistry
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Carbon has 4 Valence electrons, so it makes Four bonds
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Both Carbon and Hydrogen combine together to form several molecules
called Organic compounds
Hydrocarbons:
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Those are compounds that are made of hydrogen and carbon only.
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For these families, the name of the organic compound tells you:
which family it belongs to
how many carbon atoms are in it.
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• Know that methane and ethane are examples of
hydrocarbons
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containing up to four carbon atoms per molecule
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of burning, and the substitution reactions of alkanes
with chlorine am
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• Describe the manufacture of alkenes and of hydrogen
by cracking
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• Distinguish between saturated and unsaturated
hydrocarbons:
– from molecular or displayed formulae
– by reaction with aqueous bromine
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• Describe the formation of poly(ethene) as an example of
addition polymerisation of monomer units
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units, considered as monomers, joined together by condensation
polymerisation
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• Describe chromatography as a separation technique and describe how it
could be useful in separating and identifying the products of hydrolysis
of carbohydrates
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• Describe the fermentation of simple sugars to produce ethanol (and
carbon dioxide) (learners will not be expected to give the molecular
formulae of sugars)
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There are two types of polymerization (Making a polymer)
1- Addition polymerisation
2- Condensation polymerisation
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Plastics are non-biodegradable
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• They link with each other with an ester linkage by eliminating water molecule,
which means it is a condensation reaction.
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UNIT (6) Analytical Chem.
Testing for ions in the lab
Time for detective work!
You have an unknown salt, and you want to find out what it is. Remember CAP! !
This unit gives some tests you can do. But first, note these points: Cations Are Positive.
Positive ions are also called cations. Negative ions are called anions.
In each test, either a precipitate forms or a gas you can test.
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Cation Test If the cation is present Ionic equation for the reaction
copper(II) Add dilute sodium hydroxide A pale blue precipitate forms. Cu 21 (aq) 1 2OH 2 (aq) Cu(OH)2 (s)
Cu21 or ammonia solution.
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But it dissolves on adding more The precipitate dissolves again in excess
ammonia, giving a deep blue ammonia solution
solution.
iron(II) Add dilute sodium hydroxide A pale green precipitate forms. Fe 21 (aq) 1 2OH 2 (aq) Fe(OH)2 (s)
Fe21 or ammonia solution.
iron(III)
Fe31
zinc
Zn21
Add dilute sodium hydroxide
or ammonia solution.
Zn(OH)2 (s)
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Tests for anions
Halide ions (Cl 2, I 2)
To a small amount of the solution, add an equal volume of dilute
nitric acid. Then add silver nitrate solution.
Silver halides are insoluble. So if halide ions are present a precipitate
will form. The colour tells you which one. Look at this table:
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white chloride ions, Cl 2 Ag 1 (aq) 1 Cl 2 (aq) AgCl (s)
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AgCl dissolves. But AgI does not dissolve.
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The Periodic Table of Elements
Group
1 2 13 14 15 16 17 18
1 2
H He
hydrogen helium
Key 1.0 4.0
3 4 atomic number 5 6 7 8 9 10
Li Be atomic symbol B C N O F Ne
lithium beryllium name boron carbon nitrogen oxygen fluorine neon
6.9 9.0 relative atomic mass 10.8 12.0 14.0 16.0 19.0 20.2
11 12 13 14 15 16 17 18
Na Mg Al Si P S Cl Ar
sodium magnesium aluminium silicon phosphorus sulfur chlorine argon
23.0 24.3 3 4 5 6 7 8 9 10 11 12 27.0 28.1 31.0 32.1 35.5 39.9
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
potassium calcium scandium titanium vanadium chromium manganese iron cobalt nickel copper zinc gallium germanium arsenic selenium bromine krypton
39.1 40.1 45.0 47.9 50.9 52.0 54.9 55.8 58.9 58.7 63.5 65.4 69.7 72.6 74.9 79.0 79.9 83.8
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
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Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
rubidium strontium yttrium zirconium niobium molybdenum technetium ruthenium rhodium palladium silver cadmium indium tin antimony tellurium iodine xenon
85.5 87.6 88.9 91.2 92.9 95.9 – 101.1 102.9 106.4 107.9 112.4 114.8 118.7 121.8 127.6 126.9 131.3
55 56 57–71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
lanthanoids
Cs Ba Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
caesium barium hafnium tantalum tungsten rhenium osmium iridium platinum gold mercury thallium lead bismuth polonium astatine radon
132.9 137.3 178.5 180.9 183.8 186.2 190.2 192.2 195.1 197.0 200.6 204.4 207.2 209.0 – – –
87 88 89–103 104 105 106 107 108 109 110 111 112 114 116
actinoids
Fr Ra Rf Db Sg Bh Hs Mt Ds Rg Cn Fl Lv
francium radium rutherfordium dubnium seaborgium bohrium hassium meitnerium darmstadtium roentgenium copernicium flerovium livermorium
– – – – – – – – – – – – –
57 58 59 60 61 62 63 64 65 66 67 68 69 70 71
lanthanoids La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
lanthanum cerium praseodymium neodymium promethium samarium europium gadolinium terbium dysprosium holmium erbium thulium ytterbium lutetium
138.9 140.1 140.9 144.4 – 150.4 152.0 157.3 158.9 162.5 164.9 167.3 168.9 173.1 175.0
89 90 91 92 93 94 95 96 97 98 99 100 101 102 103
actinoids Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
actinium thorium protactinium uranium neptunium plutonium americium curium berkelium californium einsteinium fermium mendelevium nobelium lawrencium
– 232.0 231.0 238.0 – – – – – – – – – – –