Technowrap HT Hardener Part B 130320

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SAFETY DATA SHEET

according to Regulation (EU) 2015/830

Technowrap H.T. Hardener (Part B)


Page 1/6
Revision 1
Revision date 2020-03-13

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING


1.1 Product Identifier

Product Name Technowrap H.T. Hardener (Part B)

CAS Numbers 931-36-2 EC Number 213-235-5

Product Code W28-22B

1.1 Relevant identified uses of the substance or mixture and uses advised against

(SU3) Industrial uses: Uses of substances as such or in preparations at industrial sites; (PC7) Base metals and alloys. [PROC19] Hand-mixing
with intimate contact and only PPE available; [ERC8d] Wide dispersive outdoor use of processing aids in open systems.

1.2 Details of the supplier of the safety data sheet

Company Name ICR Integrity Ltd


Company Address Claymore Avenue, Aberdeen Energy Park, Bridge of Don, Aberdeen AB23 8BW

Telephone 01224 822822


Web www.icr-world.com
Email wtrops@icr-world.com

1.3 Emergency Contact

Name Ewan Robertson


Emergency Telephone 01224 822822
Emergency Email wtrops@icr-world.com

SECTION 2: HAZARD IDENTIFICATION


2.1 Classification of the substance or mixture
Classification and Precautionary Statements according to Regulation (EC) 1272/2008 CLP

Hazard Classification and Category


Acute toxicity, oral (4) H302 Harmful if swallowed.
Acute toxicity, dermal (4) H312 Harmful in contact with skin.
Skin corrosion (1) H314 Causes severe skin burns and eye damage.

2.2 Label Elements


GHS Pictograms Signal Word: DANGER

Precautionary Statements
Prevention: P260 Do not breathe mists.
P264 Wash exposed area with plenty of water and soap thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.

Response: P301+P3330+P331+312 IF SWALLOWED: Immediately seek medical advice. DO NOT INDUCE VOMITING.
P303+P361+P364+P353+P352 IF ON SKIN (or hair): Take off immediately all contaminated clothing and wash
before reuse. Rinse skin with water/shower.
P310: Immediately seek medical advice.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P391 Collect spillage.

Storage: P403+P233 Store in a well-ventilated place. Keep container tightly closed.


P405 Store locked up.

Disposal: P501 Dispose of contents and containers in accordance with local, regional and international regulations.
Technowrap H.T. Hardener (Part B)
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2.3 Other hazards
No data available.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS


3.1 Substances
Amounts specified are typical and do not represent a specification. Remaining components are proprietary, non-hazardous, and/or
present at amounts below reportable limits

Chemical Name CAS Number EC Number REACH Number Content Hazard Classification
2-Ethyl-4-methylimidazole 931-36-2 213-235-5 - 75-100% H302, H312, H314

3.2 Mixtures
Not applicable.

SECTION 4: FIRST AID MEASURES


4.1 Description of First Aid Measures

4.1.1 General information: No action should be taken involving any personal risk or without suitable training. If potential for exposure exist refer to
Section 8 for specific personal protective equipment. Show this SDS to medical professionals.

4.1.2 Following inhalation: If affected, remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration and seek
medical attention.

4.1.3 Following skin contact: Immediately remove contaminated clothing and shoes. Wash the affected area with plenty of soap and water until no
evidence of the chemical remains (at least 15-20 minutes). Launder clothing before reuse. Seek medical attention immediately.

4.1.4 Following eye contact: Immediately flush eyes with plenty of clean water for an extended time, not less than fifteen (15) minutes. Flush longer if
there is any indication of residual chemical in the eye. Ensure adequate flushing of the eyes by separating the eyelids with fingers and roll eyes in a
circular motion. Get medical attention immediately.

4.1.5 Following ingestion: Do not induce vomiting. Never give anything by mouth to an unconscious person. Rinse out the mouth with water. Seek
medical attention immediately.

4.1.6 Self-protection of the First Aider: First aider to adopt relevant PPE (see Section 8) if the hazard still exists.

4.2 Most important symptoms, both acute and delayed


Burns. Irritation. Pre-existing skin problems may be aggravated by prolonged or repeated contact. Persons with sensitive airways (e.g. asthmatics)
may react to vapours. See Section 11 for additional information.

4.3 Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

SECTION 5: FIREFIGHTING MEASURES


5.1 Extinguishing Media
Use an extinguishing agent suitable for the surrounding fire. Water spray, foam, carbon dioxide (CO2).

5.2 Special hazards arising from the substance or mixture


Product is not considered a fire hazard, but will burn if ignited. Closed container may rupture (due to build up in pressure) when exposed to extreme
heat. Irritating or toxic substances may be emitted upon burning, combustion or decomposition.

5.3 Advice for firefighters


Wear approved self-contained breathing apparatus (SCBA) in positive pressure mode with full face piece and full protective gear. Isolate the scene
by removing all persons from the incident area. No action should be taken involving any personal risk or without suitable training. See Section 9 for
additional information.

5.4 Additional information


No data available.

SECTION 6: ACCIDENTAL RELEASE MEASURES


6.1 Personal precautions, protective equipment and emergency procedures

6.1.1 For non-emergency personnel


Keep unnecessary and unprotected personnel from entering. Ensure adequate ventilation/exhaust extraction .

6.1.2 For emergency responders


Use protective equipment as described in Section 8. Do not touch or walk through spilled material; spilled material may cause a slipping hazard.
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6.2 Environmental precautions
Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. Inform the relevant authorities if the product has caused
environmental pollution. See Section 12 for more details.

6.3 Methods and material for containment and cleaning up

6.3.1 For containment


Stop leak if without risk. Move containers from spill area. Contain by diking with sand, earth or other non-combustible material. Wear proper
personal protective clothing and equipment. Absorb spill with an inert material. Place into labelled, closed container; store in safe location to await
disposal. Change contaminated clothing and launder before reuse.

6.3.2 For cleaning up


Remove mechanically; cover the remainder with non-combustible absorbent material (e.g. sand, earth, vermiculite or diatomaceous earth).
Following absorption, transfer into properly labelled chemical waste containers. If necessary, repeat application of absorbent material until all liquid
has been removed from the surface. Wash the spill site with soap and water. Cover container and remove from work to a well-ventilated area.
Properly dispose of the waste material and any contaminated equipment (i.e., broom or brush) in accordance with existing hazardous waste
regulations.

6.3.3 Other information


Do not flush product into public sewer, water systems or surface waters.

6.4 References to other sections


See Section 1 for emergency contact and Section 13 for further disposal information.

SECTION 7: HANDLING AND STORAGE


7.1 Precautions for safe handling
As with any chemical product, use good laboratory/workplace procedures. Do not cut, puncture, or weld on or near the container. Use under well-
ventilated conditions. Wash thoroughly after handling this product. Always wash up before eating, smoking or using the facilities. Avoid eye and skin
contact. Avoid inhalation of aerosol, mist, spray, fume or vapor. Avoid drinking, tasting, swallowing or ingesting this product. Wash contaminated
clothing before reuse. Discard shoes contaminated with this product.

7.2 Conditions for safe storage, including any incompatibilities


Store in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10 for details), food and drink. Keep away from heat,
sparks and open flames. Store dry at 15-40°C, under well-ventilated conditions. Do not store in open, unlabelled or mislabelled containers. Keep
container closed when not in use.

7.3 Specific end use(s)


Employee education and training in the safe use and handling of this product are required. Employees and consumers should be warned of health
risks associated with product use. See Section 8 for additional information on hygiene measures.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION


8.1 Control parameters
No data available for the substance.

8.2 Exposure controls


Pictograms

8.2.1 Appropriate engineering controls


Always provide effective and, when necessary, local exhaust ventilation to draw spray, aerosol, fume mist and vapour away from workers to
prevent routine inhalation. Ventilation must be adequate to maintain concentrations below occupational exposure standards. When necessary,
use mechanical handling to reduce human contact with the materials.

8.2.2. Personal protective equipment

8.2.2.1 Eye and face protection


Safety glasses or goggles (EN 166) are required. Eyewash fountains and safety showers ae recommended in the work area.

8.2.2.2 Skin protection


Impervious, chemical-resistant nitrile gloves (EN374) should be worn. Impervious coveralls and safety footwear should be worn.

8.2.2.3 Respiratory protection


When risk assessment requires it, wear an faced-fitted approved respirator (e.g. an organic vapor respirator, a full-face air purifying respirator
for organic vapours, or a self-contained breathing apparatus whenever exposure to aerosol, mist, spray, fume or vapor exceed the applicable
exposure limit(s) of any chemical substance listed in this SDS . See risk assessment.
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8.2.2.4 Thermal hazards
None.

8.2.3 Environmental exposure limits


No data available.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES


9.1 Information on basic physical and chemical properties

Appearance Liquid
Colour Yellow amber
Odour Amine
Odour threshold Not available
pH 10.7 at 100g.L-1
Melting point/Freezing point 36-42 oC, 97-108 oC
Initial boiling point and boiling point range 270-276 oC,518-529 oC
Flash point >155 oC (Closed cup)
Evaporation rate Not available
Flammability (solid, gas) Not available
Upper/lower flammability or explosive limits LEL 1.5 vol%, UEL 13 vol%
Vapour pressure <1 mmHg at 25 oC
Vapour density Heavier than air
Specific gravity >1 (20 oC)
Solubility 180 g.L-1
Partition coefficient n-octanol/water 1.64 (Calculated)
Auto-ignition temperature 474 oC (887 oF)
Decomposition temperature Not available
Viscosity 5950 cP at 20 oC, 569 cP at 40 oC

9.2 Other Safety Information


No data available.

SECTION 10: STABILITY AND REACTIVITY


10.1 Reactivity
Exothermic reactions including polymerization may occur in contact with strong acids, strong bases, alcohols, strong oxidizing agents and
excessive heat.

10.2 Chemical stability


This product is stable.

10.3 Possibility of hazardous reactions


Hazardous polymerization will occur. This product will auto polymerize at very high temperatures .

10.4 Conditions to avoid


Excessive heat and ignition sources. Exposure to moisture.

10.5 Incompatible materials


Avoid strong amines, acids, acid chlorides and acid anhydrides.

10.6 Hazardous decomposition products


Carbon monoxide, carbon dioxide and oxides of nitrogen.

SECTION 11: TOXILOGICAL INFORMATION


11.1 Information on toxilogical effects
Likely routes of exposure: Skin and eye contact, inhalation and ingestion.

Acute Toxicity
Oral: Harmful if swallowed.

Dermal: Harmful in contact with skin. Causes chemical burns.

Inhalation: Harmful if inhaled. Exposure to vapours or mists may cause severe irritation and burns of the nose. Throat and respiratory tract.

Skin corrosion/irritation: Category 1.

Serious eye damage/eye irritation: No information available.

Specific Target Organ Toxicity (STOT), single exposure: No data available.


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Aspiration hazard: Category 1

Respiratory and skin sensitiser: No information available.

Germ cell mutagenicity: No data available.

Carcinogenicity: No data available.

Reproductive toxicity: No data available.

Specific Target Organ Toxicity (STOT), repeat exposure: No data available.

Medical conditions aggravated by overexposure: Additional information is not available.

11.2 Toxilogical Information


Toxicity Test Results: Not available for mixture. Results for components, when available:

Chemical Name LC50 Inhalation (Rat) LD50 Oral (Rat) LD50 Dermal (Rabbit)
2-Ethyl-4-methylimidazole Not available 731 mg.kg-1 >400 mg.kg-1

SECTION 12: ECOLOGICAL INFORMATION


12.1 Toxicity

Chemical Name Test Species Result


2-Ethyl-4-methylimidazole LC50 (96 hours) Fish >46-100 mg.L-1
EC50 (48 hours) Daphnia 300 mg.L-1
EC10 (96 hours) Bacteria 79 mg.L-1

12.2 Results of PBT and vPvB assessment


No data available.

12.3 Bioaccumulative potential

Chemical Name Log Pow BCF Potential


2-Ethyl-4-methylimidazole 1.64 Not available Not available

12.4 Mobility in soil


No data available.

12.5 Results of PBT and vPvB assessment


No data available.

12.6 Other adverse effects


No data available.

SECTION 13: DISPOSAL CONSIDERATIONS


13.1 Waste treatment methods

13.1.1 Product/Packaging disposal


The generation of waste should be avoided or minimized wherever possible. Dispose of waste in compliance with local regulations via licensed
waste disposal contractor. Container may retain residues. Containers should be completely emptied and safely stored until appropriately
reconditioned or disposed through licensed contractor in accordance with government regulation.

13.1.2 Waste treatment-relevant information


No data available.

13.1.3 Sewage disposal-relevant information


Do not discharge into sewer system.

13.1.4 Other disposal recommendations


Spill clean-up residues may still be subject to storage and disposal requirements.
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SECTION 14: TRANSPORT INFORMATION
Hazard Pictograms

14.1 UN Number
ADR/RID: 2735
IMDG: 2735
ICAO-TI/IATA-DGR: 2735
ADN: Not relevant

14.2 UN Proper shipping name


ADR/RID: Amines, liquid, Corrosive, N.O.S.
IMDG: Amines, liquid, Corrosive, N.O.S.
ICAO-TI/IATA-DGR: Amines, liquid, Corrosive, N.O.S.
ADN: Not relevant

14.3 Transport hazard class


ADR/RID: Class or Division 8
IMDG: Class or Division 8
ICAO-TI/IATA-DGR: Class or Division 8
ADN: Not relevant

14.4 Packing group


ADR/RID: III
IMDG: III
ICAO-TI/IATA-DGR: III
ADN: Not relevant

14.5 Environmental hazards


ADR/RID: Environmentally hazardous
IMDG: Environmentally hazardous
ICAO-TI/IATA-DGR: Environmentally hazardous
ADN: Not relevant

14.6 Special precautions for user


This substance is not a marine pollutant.

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
No information available.

SECTION 15: REGULATORY INFORMATION


15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

The information in this Safety Data Sheet is required pursuant to:


Registration, Evaluation, Authorisation and Restriction of Chemicals, Regulation (EC) No.1907/2006 (REACH)
Classification, Labelling and Packaging of Substances and Mixtures, Regulation (EC) No.1272/2008 (CLP)
European Inventory of Existing Chemical Substances (EINECS)
European List of Notified Chemical Substances (ELINCS)
New Format Required for Safety Data Sheets, Regulation (EC) No.2015/830
Waste Framework Directive 2008/98/EC
The Dangerous Substances and Explosive Atmospheres Regulations 2002 (DSEAR)
The Control of Substances Hazardous to Health Regulations 2002 (COSHH)
The Health and Safety at Work Act 1974 (HSWA)

SECTION 16: OTHER INFORMATION

Disclaimer: The data set forth in this sheet are based on information provided by the suppliers of the raw materials and chemicals used in the manufacture
of the aforementioned product. ICR Integrity Ltd makes no warranty with respect to the accuracy of the information provided by their suppliers, and
disclaims all liability of reliance thereof.

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