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Colloid 1
Colloid 1
COLLOIDS
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Types of colloids
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1) Lyophilic colloids
• Colloidal particles interact to an appreciable extent with
the molecules of the dispersion medium (solvent loving).
• Obtained spontaneously by dissolving the material in the
solvent ( due to the high affinity)
•Hydrophilic colloids
•Solvent: water
Types of lyophilic •Example: acacia, insulin, gelatin
colloids;
(According to type of
solvent) •Lipophilic colloids
•Solvent: non- aqueous, organic
•Example: polystyrene
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2) Lyophobic colloids
✓Colloidal particles have very little or no attraction for the
dispersion medium (solvent hating).
✓Colloidal particles: inorganic particles (e.g. gold, silver, sulfur….)
dispersed in water.
✓These colloids are easily precipitated on the addition of small
amounts of electrolytes, by heating or by shaking
✓Addition of small amount of lyophilic or lyophobic colloid to a
lyophobic colloid of opposite charge make the latter more sensitive
to coagulation by electrolytes
✓Addition of excess lyophilic sol to a lyophobic sol (less
precipitation of lyophobic by electrolyte)
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3) Association colloids:
• Certain molecules or ions termed
amphiphile (surface active agent SAA) are
characterized by two distinct regions of
opposing solution affinities within the
same molecules or ions.
➢ Amphiphiles may be
1. Anionic (e.g., Na. lauryl sulfate)
2. Cationic (e.g., cetyl triethylammonium bromide)
3. Nonionic (e.g., polyoxyethylene lauryl ether)
4. Ampholytic (zwitterionic) e.g., dimethyl dodecyl
ammoniom propane sulfonate.
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Preparation of colloids
✓Lyophilic sols and association colloidal sols are usually
prepared by dissolving the dispersed phase in water.
✓While lyophobic colloids were prepared by :
Dispersion methods, in which coarse particles are reduced in
size, and condensation methods, in which materials of
subcolloidal dimensions are caused to aggregate into particles
within the colloidal size range.
A. Condensation process:
1) Change of solvent 2) Double decomposition
3) Reduction 4) Oxidation
B. Dispersion methods:
1) Ultrasonic generator 2) Electric arc.
3) Colloid mill. 4) peptization
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3) Colloidal mill:
• Material sheared between 2 rapidly rotating close
plates (in opposite directions).
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