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CE 14 Study Guide Lesson 6
CE 14 Study Guide Lesson 6
PORTLAND CEMENT CONCRETE 600 B.C – Greeks discovered a natural substance that
History of Cement could create concrete when mixed with lime.
• Cement, though not in the refined form found 200 B.C - Romans had perfected building with concrete.
today, has been employed in a variety of ways
since the dawn of human civilization. 1824 - Joseph Aspdin created Portland Cement.
18th Century
• James Parker – a British clergyman and cement
Properties and Composition of Concrete
maker who produced one of the late-eighteenth
There are Four Basic Ingredients Within the Concrete
centuries pioneering new cements which is the
Material Mix:
Roman Cement.
1. Binding Material
- It is the main element of a concrete material
19th Century
mix. Cement is the most commonly used
• Frenchman Louis Vicat – laid the groundwork binding material.
for the chemical composition of Portland cement. 2. Aggregates
• Joseph Aspdin – brought Portland Cement to the - Sand is a fine mixture. Gravel or crushed
market in England. stone is the coarse mixture in most mixes.
• William Aspdin – developed the modern Aggregates occupy about 60-80% of the
Portland Cement volume of concrete.
• Rosendale Cement - was discovered in New 3. Water
York. Though its rigidity first made it fairly - Water is required to with chemicals react with
popular, market demand quickly fell due to its the cement (hydration) and to supply
lengthy curing period. workability with the concrete. the pH of
• Catskill Aqueduct – a developed blend of mixing water should e between 6 and 8.5.
Rosendale and Portland Cement, both are durable 4. Admixture
and required less curing time. - It includes all materials other than cement.
• Rosendale – Portland Cement – now often used
for highway or bridge construction. Manufacturing of Cement
The Common Raw Cement Materials
History of Concrete • Limestone (Calcium)
• Concrete is the most used building material in the • Sand and Clay
world. • Shale
• Some of the world's most famous structures may • Fly Ash
never have been built or may not have withstand
• Mill Scale
the test of time without concrete.
• Bauxite
Concrete has several advantages that make it a unique
building material: The 6 Stages of Cement Manufacturing
Stage 1: Raw Material Extraction / Quarry
• Sustainability
1. The ore rocks are quarried and crushed into
• Versatility
smaller pieces of about 6 inches.
• Resiliency
2. Secondary crushers or hammer mills then reduce
6500 B.C – First concrete like buildings were made. them to an even smaller size of 3 inches.
3000 B.C - Egyptians use mud mixed with straw to create 3. The ingredients are prepared for pyro processing.
adobe-like building material. China used a form of cement
created with sticky rice. Stage 2: Grinding, Proportioning, and Blending
1. The crushed raw ingredients are made ready for
700 B.C - Bedouins discovered cement that hardens the cement-making process in the kiln by
underwater.
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combining them with additives and grinding important property of cement, compressive
them to ensure a fine homogenous mixture. strength.
2. The composition of cement is proportioned here 2. Triethanolamine (used at 0.1 wt.%), are added as
depending on the desired properties of the grinding aids to avoid powder agglomeration.
cement. Generally, limestone is 80%, and the 3. Other additives sometimes used are ethylene
remaining 20% is clay. glycol, oleic acid, and dodecyl- benzene
sulphonate.
3. Heavy wheel-type rollers and rotating tables
blend the raw mix and then the roller crushes it to Stage 6: Packing and Shipping
a fine powder to be stored in silos and fed to the
1. Cement is conveyed from grinding mills to silos
kiln.
(large storage tanks) where it is packed in 20-40
kg bags.
Stage 3: Pre – Heating Raw Material
2. Product is shipped in bulk quantities by trucks,
1. A pre-heating chamber is made up of a series of trains, or ships, and only a small amount is packed
cyclones that use hot gases from the kiln to reduce for customers who need small quantities.
energy usage and make the cement-making
process more environmentally friendly.
Physical Properties and Chemical Composition of
Cement
The Principal Stage of the Cement Production Process Chemical Composition of Cement
1. Tricalcium Silicate
Stage 4: Kiln Phase
- Hardens rapidly and is largely responsible for
• Clinker is produced from the raw mix through a initial set and early strength.
series of chemical reactions between calcium and 2. Dicalcium Silicate
silicon dioxide compounds. - Hardens slowly and its effect on strength
increases occurs at ages beyond one week.
Sequence:
3. Tricalcium Aluminate
1. The evaporation of free water. - It contributes to strength development in the
2. Evolution of combined water in the argillaceous first few days.
components. - First compound to hydrate.
3. Calcination of the calcium carbonate (CaCO3) to - It is less desirable component due to high heat
calcium oxide (CaO). and reactiveness with soil and water
4. The reaction of CaO with silica to form dicalcium
containing moderate-to-high sulfate
silicate.
concentrations.
5. The reaction of CaO with the aluminum and iron-
4. Tetracalcium Aluminoferrite
bearing constituents forms the liquid phase.
6. Formation of the clinker nodules. - It allows lower clinkering temperature.
7. Evaporation of volatile constituents (e. g., - Contributes very little to strength even
sodium, potassium, chlorides, and sulfates). though it hydrates very rapidly.
8. The reaction of excess CaO with dicalcium
silicate forms tricalcium silicate. Physical Properties of Cement
Physical qualities distinguish different cement mixtures
used in building. Some critical parameters influence
Stage 5: Cooling and Final Grinding cement quality. Good cement's physical qualities are
determined by:
The clinker is rapidly cooled down from 2000°C to
1. Fineness of Cement – The size if the particles of
100°C-200°C by passing air over it.
cement.
1. Gypsum added to and ground with clinker
regulates the setting time and gives the most 2. Soundness of Cement – The ability of cement to
not shrink upon hardening.
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Le Chatelier Test – Tests the expansion of 6. Heat of Hydration - The reaction that occurs
cement due to lime. when water is introduced to cement is known as
Standard Autoclave Test: AASHTO T107 and hydration.
ASTM C151. - Hydration generates heat, which can affect
the quality of the cement and also be
3. Consistency of Cement – The ability of cement beneficial in maintaining curing temperature
pastes to follow its consistency. during cold weather.
Vicat Test - When heat generation is high, especially in
large structures, it may cause undesired
4. Strength of Cement stress.
a. Compressive Strength – The test specimen is ✓ ASTM C186: Heat of Hydration of
taken and subjected to a compressive load Hydraulic Cement
until failure.
✓ AASHTO T106 and ASTM C109: 7. Loss of Ignition - Improper and prolonged
Compressive Strength of Hydraulic storage or adulteration during transport or
Cement Mortars (Using 50 mm or 2 transfer may lead to pre-hydration and
in Cube Specimens). carbonation, both of which might be indicated by
✓ ASTM C349: Compressive Strength increased loss of ignition.
of Hydraulic Cement Mortars (Using ✓ AASHTO T105 and ASTM C114:
Portions of Prisms Broken Flexure). Chemical Analysis of Hydraulic
b. Tensile Strength Cement
c. Flexural Strength – Measures tensile strength
in bending. 8. Bulk Density – Cement has a varying range of
ASTM C348: Flexural Strength of Hydraulic density depending on the cement composition
Cement Mortars percentage. The density of cement may be
anywhere from 62 to 78 pounds per cubic foot.
5. Setting Time of Cement
Factors That Affect the Setting Time of Cement: 9. Specific Gravity (Relative Density)
- Fitness of Cement - Specific gravity is generally used in mixture
- Cement – Water Ratio proportioning calculations.
- Chemical Content - Portland cement has a specific gravity of
- Admixtures 3.15, but other types of cement (for example,
Initial Set: When the paste begins to stiffen Portland-blast-furnace-slag and Portland-
noticeably (typically occurs within 30-45 pozzolan cement) may have specific gravities
minutes). of about 2.90.
Final Set: When the cement hardens, being able AASHTO T133 and ASTM C188: Density
to sustain some load (occurs below 10 hours). of Hydraulic Cement
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when it sets slowly, valuable construction time is Types of Portland Cement ASTM C150
lost. 1. ASTM TYPE I (Normal) - used where the
• Heat of Hydration - The heat generated from the concrete will not be subjected to sulfate attack
chemical reaction between water and cement. from soil or water or be exposed to severe
weathering conditions.
Types of Portland Cements and Corresponding
Application – ASTM 2. ASTM TYPE II (Moderate Heat or Modified)
Two Different Types of Cement - used to where resistance to moderate sulfate
1. Hydraulic Cement attack is important, areas wherein sulfate
- It hardens due to the addition of water. concentration in ground water is higher than
- Hydraulic Cement is mainly made up of normal.
silicates and oxides:
o Belite (2CaO·SiO2)
o Alite (3CaO·SiO2) 3. ASTM TYPE III (High Early Strength) – used
o Tricalcium aluminate/ Celite where an early strength gain is important and heat
(3CaO·Al2O3) generation is not a critical factor.
o Brownmillerite
(4CaO·Al2O3·Fe2O3) 4. ASTM TYPE IV (Low Heat) - used where the
- The ingredients are processed in the kiln in rate and amount of heat generated must be
cement plants. The complete chemistry of minimized.
the reactions is still a subject of research.
5. ASTM TYPE V (Sulfate Resisting) – used
2. Non – Hydraulic Cement where the soil or groundwater contains high
- Hardened by carbonation with the carbon sulfate concentrations, and the structure would be
present in the air, so it cannot be used exposed to severe sulfate attack.
underwater.
- It is produced through the following steps 6. Air – Entraining Portland Cements (ASTM
(Lime Cycle) C175) – TYPE IA, TYPE IIA, TYPE IIIA: these
o Calcination: Lime is produced from cements provide the concrete with improved
limestone at over 825°C for about 10 resistance to freeze-thaw action to scaling caused
hours. (CaCO3 → CaO + CO2) by chemicals and salts used for ice and snow
o Slaking: Calcium oxide is mixed removal.
with water to make slaked lime.
(CaO + H2O → Ca (OH)2) 7. White Portland Cement (ASTM C150 &
o Setting: Water is completely C175) – It is recommended wherever white or
evaporated. colored concrete or mortar is desired. This white
o The cement is exposed to dry air, and cement allows more accurate colors.
it hardens after time-consuming
reactions. (Ca (OH)2 + CO2 → 8. Portland Blast – Furnace Slag Cements –
CaCO3+ H2O) Granulated blast-furnace slag of selected quality
is interground with Portland cement.
The most commonly used type of cement is hydraulic o TYPE IS & TYPE IS – A (ASTM
cement (Hardens When Water is Added) – Portland C595)
Cement or Portland Cement Blends. o These cements can be used in general
• It is suitable for wet climates and can be used concrete construction when the specific
underwater. properties of other types are not required.
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9. Portland – Pozzolan Cements (-IP, IP – A, P, transform a stiff concrete mix into one that flows
and P – A) – Where the A denoting air-entraining freely into the forms.
additives as specified in ASTM C595. - They are used either to facilitate placement of
o These cements are used principally for concrete under difficult circumstances or to
large hydraulic structures sucks as bridge reduce the water content of a concrete mix to
piers and dams. increase its strength.
10. Masonry Cements (TYPE I & TYPE II – 4. Accelerating Admixtures – cause concrete to
ASTM C91) – Contain Portland cement, air - cure more rapidly, and retarding admixtures slow
entraining additives and other materials selected its curing to allow more time for working with the
for their ability to impart physical properties to wet concrete.
the masonry mortars.
5. Workability Agents - improve the plasticity of
Different Admixtures in Concrete wet concrete to make it easier to place in forms
What is an Admixture? and finish.
• Defined as any material other than cement, - They include pozzolans and air- entraining
aggregate, and water added to a concrete mix and admixtures, along with certain fly ashes and
used to modify basic concrete designs organic compounds.
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Water Standards to produce concrete, and the agitating of the
What is the Purpose of the Standard? already-mixed concrete.
• This is to ensure that the water is reasonably free
from such impurities as suspended solids, organic Methods of Concrete Mixing
matter and dissolved salts, which may adversely 1. Transit Mix Trucks
affect the properties of the concrete, especially - Mobile concrete production system
the setting, hardening, strength, durability, pit sometimes referred to as a concrete mobile.
value, etc. - Bins on the truck carry coarse and fine
• Water shall be tested in an approved Laboratory aggregates and cement, while tanks carry
for its use in preparing concrete. water and admixtures.
• The pH value of water for making cement - The system produces concrete on-site to
concrete should be between 6 to 8.5. required specifications; for larger projects the
bins and tanks are reloaded at the jobsite.
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and delivered to the jobsite in a transit 1. Place the cylinder and beam mold in a leveled,
mixer operating at agitating speeds. rigid, and free of vibrations and disturbance
b. Transit – Mixed Concrete – is surface.
completely mixed in the truck. The 2. Fill in the molds in 3 layers and 25 roddings per
ingredients are batched, water is added, layer, hit 10 - 15 times with rubber mallet.
and the concrete is mixed in the drum 3. Consolidate the layer of concrete as necessary for
mounted on a truck. the mold’s diameter after pouring it into the mold.
c. Shrink – Mixed Concrete – is a 4. Flatten the concrete mixture using a trowel.
combination of central mix and transit 5. Put the cylinder and beam mold in a suitable
mix, with mixing requirements split location for the curing procedure for at least 48
between the central plant and the transit hours.
truck.
Slump Test
Slump test is used to check if an appropriate amount of
The Standards
water has been added to the concrete mix.
To produce quality concrete, the batching and measuring
1. Put a slump cone on a flat surface and then
of ingredients must be done accurately:
dampen the apparatus.
• Concrete mixing equipment loads should not
2. Mark the layers at a distance of 155.58 mm and
exceed rated capacities.
66.68 mm from the slump cone’s base.
• Interior of the mixing drum should be
3. Place a suitable amount of the sample from the
periodically checked for worn blades and
concrete mix into the test slump cone.
hardened concrete buildup
4. Rod the concrete inside by 25 times using the
• All weighing equipment should be checked
tamping rod.
periodically and adjustments made when
5. Add another layer of concrete and repeat previous
required.
step until 3rd layer is rod 25 times.
• Admixture equipment should be checked daily. 6. Remove the mold, then raise the mold in 5 – 10
seconds and measure the slump if within 6 mm.
Creation of Beam and Cylindrical Concrete Samples
Methods and Standards Cylindrical and Beam Compressive Strength Test:
Concrete Beam Samples Procedures and Standards
• Flexural strength specimens shall be beams of • Compressive strength is the measured maximum
concrete cast and hardened in the horizontal resistance to axial loading, expressed as force
position. per unit of cross-sectional area in pounds per
• The length shall be at least 50 mm greater than square inch.
three times the depth as tested. • Compressive strength is measured by breaking
• The ratio of width to depth as molded shall not cylindrical concrete specimens in a compression-
exceed 1.5. testing machine.
• Compressive strength is calculated from the
Concrete Cylinder Samples failure load divided by the cross-sectional area
• Compressive or splitting tensile strength resisting the load and reported in units of pound-
specimens shall be cylinders cast and allowed to force per square inch (psi) or megapascals
set in an upright position. (MPa).
• Acceptance testing for specified compressive
strength, cylinders shall be 150 by 300 mm or 100 2 Point vs 3 Point Beam Sample Test
by 200 mm.
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Schmidt Rebound Hammer: Procedures, Standards, 5. The 10 readings are averaged, and any reading
and Testing: ASTM C805 that differs by more than 6 from the average is
Rebound Hammer discarded; then average the remaining values.
• The device is used to estimate in-place strength, a
relationship between strength and rebound 6. If more than 2 readings differ from the average by
number needs to be established for the specific more than 6, discard all 10 readings and repeat the
concrete mixture design of interest. test.
Concrete Pump
• The concrete pump transports plastic concrete
• The device consists of a plunger rod and an through a pipeline system from the ready – mix
internal spring-loaded steel hammer and a truck to the point of placement without changing
latching mechanism. the basic characteristics of the concrete mix.
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Pumpable Mix • The purpose of a construction joint is to allow for
• The pump lines are lubricated with a concrete mix some horizontal movement, while being rigid
that contains no coarse aggregate. against rotational and vertical movement.
• The amount of mortar used will depend on the
length of the run. A cubic yard of mortar will Importance and Quality Points of the Use of Concrete
lubricate approximately 1000 ft of pipe. Vibrator
• Vibrators may either be immersion or external
Conveyor Belts form mounted systems powered by air or
• It is used by the concrete industry to move plastic electricity.
concrete for several years. • The contractor must determine a vibrator pattern
• The volume of concrete transported by a and the amplitude and frequency of vibration, as
conveyor is determined by the belt width, well as the depth of the vibrator into the concrete,
conveyor speed, angle of incline or decline, and to ensure good consolidation.
the properties of the concrete mix itself, such as • The revibrated concrete exhibits a higher strength
aggregate size and shape, mix proportions, and and less settlement cracking, and the effects of
slump. internal bleeding are reduced.
• The conveying system must be properly designed
with enough power to start and stop with fully Self – Compacting Concretes (SCC)
loaded belts during placement delays. • These are made with viscosity – modifying
admixtures and / or new – generation
superplasticizers and aggregate to and ratios of
about 1 to 1, plus additional fines.
• Self – Compacting concrete is widely used in the
precast industry and has virtually eliminated the
use of Vibration equipment.
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• Methods used to prevent moisture loss may Shrinkage and Creep Properties of Concrete
include the use of waterproof papers, plastic film,
Creep – It is the effect due to which concrete undergoes
and liquid curing compounds which form a
continuous deformation under sustained loading applied
membrane and the leaving of forms in place. for a considerable time.
• The additional water methods are by ponding,
sprinkling, and using wet coverings such as
burlap, sand, and straw.
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• Creep strain develops gradually with time. Creep Effects
1. Creep Primary
(i) We can infer from the figure that when the
time is tending to infinity, creep would be - The primary effects are independent of the
approaching a limiting value. boundary conditions of the structure and can
be calculated based on the formulations given
(ii) Hence, after several years, the rate of change in various design codes.
of creep is quite small.
2. Creep Secondary
(iii) Due to this reason around 50 percent of the - The secondary effects are dependent on the
final creep develops in the first 2–3 months boundary conditions of the structure.
and about 90 percent develops after 2–3
years. Common Field Problems
1. Bleeding
Factors Affecting Creep - It occurs when the excess water comes to the
surface of the concrete due to the settlement
1. Concrete Mix
of heavier components like aggregates,
- Creep is inversely proportional to the
cement.
characteristic strength of concrete.
Prevention:
- So, for a specific stress level, creep would be
more in lower strength concrete. - Strictly maintaining water to cement ratio.
- Adding sand of finer particles.
2. Aggregate - Supplementary cementitious materials to
- An increase in aggregate content or the incase water absorption.
maximum aggregate size reduces creep. - Adding air entertaining mixtures.
4. Environment
- Creep increases as the relative humidity
decreases.
5. Surface Area
- Creep is greater in thin members with large
surface-area-to-volume ratios, such as slabs.
- However, the dependence of creep on relative
humidity and the size and shape of the
specimen decreases as the concrete strength 2. Segregation
increases. - The cement paste comes to the top while the
aggregates settle down at the bottom of the
6. Ambient Temperature concrete.
- A rise in temperature increases the Prevention:
deformability of the cement paste and - Using the recommended proportion of
accelerates drying, and thus increases creep. cement and water.
- Avoiding over – vibration or compaction of
7. Age of Concrete and Loading
concrete.
- Concrete loaded at an early age undergoes
- Adhering to the advised concrete mixing
creep more than concrete loaded at a later
guidelines, like mixing at a speed.
age.
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- Avoiding dropping concrete from long 4. Plastic Shrinkage Cracking
heights. - It Occurs when there is an excessive and
rapid loss of water from concrete before it has
even set.
Prevention:
- Avoiding overmixing of the concrete.
- Providing sunshades around the concrete in
hot weather.
- Placing or constructing temporary walls to
block or reduce wind velocity.
- Placing concrete either early in the morning
or in the late afternoon to avoid hot
temperatures.
3. Scaling
- The surface layer of concrete gets
deteriorated by getting peeled or by breaking
off.
Prevention:
- Using air trained concrete.
- Not performing finishing steps till the water
is present on the surface.
- Not using deicing salts, such as calcium,
magnesium, or sodium chloride.
- Properly curing the concrete with the use of
liquid membrane curing compound or by 5. Laitance
covering the surface of freshly placed slab - The consequence of the problems of
with wet burlap and polyethene sheets or a segregation and bleeding leads to laitance in
non-woven geotextile. the concrete.
- Protecting the concrete surface during harsh Prevention:
weather conditions. - Using water-reducing admixtures in
concrete.
- Not doing the finishing steps till the water has
evaporated from the surface.
- Removing clay, silt, dust content before
mixing concrete.
- Using well – graded aggregates in the
concrete mixture.
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6. Dusting • Type 1P is sold under “Eagle
- It refers to the formation of a loose powdery Cement Advance” brand and is
layer on the surface of the concrete. used for general construction
Prevention: applications such as floorings
- Maintaining perfect water – cement ratio. and plastering as well as the
- Using dust – free aggregates. production of concrete products
- Giving the concrete proper time to cure or like hollow blocks, culverts,
dry. and concrete pipes.
- Using searers to make concrete dusting
proof. 2. Republic Cement & Building Materials, Inc.
- Republic is acknowledge in the industry as
the leader in bulk cement for reliable
consistency and predictability.
- Republic provides high – quality cement for
the Filipino builder’s versatility, ease, and
sustainable use.
- Batangas, Bulacan, Danao City, Iligan City
(Republic Cement Iligan, Inc.), Rizal
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- CEMEX is one of the most popular brads of
Portable Cement in the Philippines
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