TUGAS TERMODINAMIKA II

Nama : Annisa Farahiyah / 2104103010006

Laily Nuraida / 2104103010052
Miftahul Jannah / 2104103010078
Mata Kuliah : Termodinamika 2 Teknik Kimia
Dosen Pengampu : Dr. Ir. Syaubari, M.Sc

Problem 14.6
Use the method of equilibrium constants to verify the value of ɛ found as an answer in one of the
following:
a. Prob. 14.4
b. Prob. 14.5(a)
c. Prob. 14.5(b)
d. Prob. 14.5(c)
Solution
a. Prob. 14.4
First determine values for ∆ A , ∆ B , ∆ C ,dan ∆ D for the reaction:
H2(g) + CO2(g)  H2O(g) + CO(g)
T0 = 1000K
T = 2985,15K
The meaning of ∆ is indicated by: ∆=¿(H2O) + (CO) – (H2) – (CO2). Thus, from the heat-
capacity data of Table C.1:
∆ A=3,470+3,376−3.249−5,457=−1 , 86
−3 −3
∆ B=(1,450+0,557−0,422−1,045)×10 =0 , 54 × 10
−6
∆ C=(0+0−0−0)× 10 =0
5 5
∆ D=( 0,121+ (−0,031 )−0,083−(−1,157 ) )×10 =1,164 ×10

Value of ∆ H ° 298 and ∆ G ° 298 at 298,15 K for the hydration reaction are found from the heat
of formation datat of Table C.4:
∆ H ° 298 = -241,818 + (-110,525) - (-4,2) – (-393,509) = 40,366
∆ G ° 298 = -228,572 +-137,169 – 17,6 –(-394,359) = 11,018

For T = 1000 K, values of the integrals in Eq. (14.18) are;

IDCPH (298,15, 1000; -1,86, 0,54×10-3,0,1,164, ×10 5 ¿ = -780,879
IDCPS (298,15, 1000; -1,86, 0,54×10-3,0,1,164, ×10 5 ¿ = 0,004983

Substitution of values into Eq. (14.18) for a refenrence temperature of 298,15K gives:
 ∆ G ° 298 11,018−40,366 40,366 −780,879
= + + +0,004983=−0,7828
RT ( 8,314 )( 298 , 15 ) ( 8,314 ) ( 1000 ) 1000

Finally,
At 1000K: ln K = -0,7828 and K= 0,4571

b. Prob. 14.5(a)
First determine values for ∆ A , ∆ B , ∆ C ,dan ∆ D for the reaction:
H2(g) + CO2(g)  H2O(g) + CO(g)
T0 = 1100K
T = 2985,15K
The meaning of ∆ is indicated by: ∆=¿(H2O) + (CO) – (H2) – (CO2). Thus, from the heat-
capacity data of Table C.1:
∆ A=3,470+3,376−3.249−5,457=−1 , 86
−3 −3
∆ B=(1,450+0,557−0,422−1,045)×10 =0 , 54 × 10
−6
∆ C=(0+0−0−0)× 10 =0
5 5
∆ D=( 0,121+ (−0,031 )−0,083−(−1,157 ) )×10 =1,164 ×10

Value of ∆ H ° 298 and ∆ G ° 298 at 298,15 K for the hydration reaction are found from the heat of
formation datat of Table C.4:
∆ H ° 298 = -241,818 + (-110,525) - (-4,2) – (-393,509) = 40,366
∆ G ° 298 = -228,572 +-137,169 – 17,6 –(-394,359) = 11,018

For T = 1100 K, values of the integrals in Eq. (14.18) are;

IDCPH (298,15, 1100; -1,86, 0,54×10-3,0,1,164, ×10 5 ¿ = -898,547
IDCPS (298,15, 1100; -1,86, 0,54×10-3,0,1,164, ×10 5 ¿ = -0,00691

Substitution of values into Eq. (14.18) for a refenrence temperature of 298,15K gives:

∆ G ° 298 11,018−40,366 40,366 −898,547

= + + + (−0,00691 ) = -0,8311
RT ( 8,314 )( 298 , 15 ) ( 8,314 ) ( 11 00 ) 1 100

Finally,
At 1100K: ln K = -08311 and K= 0,4355

c. Prob. 14.5(c)
First determine values for ∆ A , ∆ B , ∆ C ,dan ∆ D for the reaction:
H2(g) + CO2(g)  H2O(g) + CO(g)
 T0 = 1000K
T = 2985,15K
The meaning of ∆ is indicated by: ∆=¿(H2O) + (CO) – (H2) – (CO2). Thus, from the heat-
capacity data of Table C.1:
∆ A=3,470+3,376−3.249−5,457=−1 , 86
−3 −3
∆ B=(1,450+0,557−0,422−1,045)×10 =0 , 54 × 10
−6
∆ C=(0+0−0−0)× 10 =0
5 5
∆ D=( 0,121+ (−0,031 )−0,083−(−1,157 ) ) ×10 =1,164 ×10

Value of ∆H°298 and ∆G°298 at 298,15 K for the hydration reaction are found from the
heat of formation datat of Table C.4:
∆H°298 = -241,818 + (-110,525) - (-4,2) – (-393,509) = 40,366
∆G°298 = -228,572 +-137,169 – 17,6 – (-394,359) = 11,018

For T = 1200 K, values of the integrals in Eq. (14.18) are;

IDCPH (298,15, 1200; -1,86, 0,54×10-3,0,1,164, ×10^5) = -1012,48
IDCPS (298,15, 1200; -1,86, 0,54×10-3,0,1,164, ×10^5) = -0,01451

Substitution of values into Eq. (14.18) for a refenrence temperature of 298,15K gives:
∆ G ° 298 11,018−40,366 40,366 −1012 , 48
= + + + (−0 , 01451 ) = -0,8660
RT ( 8,314 )( 298 , 15 ) ( 8,314 ) ( 12 00 ) 1 200

Finally,
At 1200K: ln K = -0,8660 and K= 0,42061

d. Prob. 14.5(c)
First determine values for ∆ A , ∆ B , ∆ C ,dan ∆ D for the reaction:
H2(g) + CO2(g)  H2O(g) + CO(g)
T0 = 1300K
T = 2985,15K
The meaning of ∆ is indicated by: ∆=¿(H2O) + (CO) – (H2) – (CO2). Thus, from the heat-
capacity data of Table C.1:
∆ A=3,470+3,376−3.249−5,457=−1 , 86
−3 −3
∆ B=(1,450+0,557−0,422−1,045)×10 =0 , 54 × 10
−6
∆ C=(0+0−0−0)× 10 =0
5 5
∆ D=( 0,121+ (−0,031 )−0,083−(−1,157 ) ) ×10 =1,164 ×10
Value of ∆ H ° 298 and ∆ G ° 298 at 298,15 K for the hydration reaction are found from the heat
of formation datat of Table C.4:
∆ H ° 298 = -241,818 + (-110,525) - (-4,2) – (-393,509) = 40,366
∆ G ° 298 = -228,572 +-137,169 – 17,6 –(-394,359) = 11,018

For T = 1300 K, values of the integrals in Eq. (14.18) are;

IDCPH (298,15, 1300; -1,86, 0,54×10-3,0,1,164, ×10 5 ¿ = -1122,27
IDCPS (298,15, 1300; -1,86, 0,54×10-3,0,1,164, ×10 5 ¿ = -0,01819

Substitution of values into Eq. (14.18) for a refenrence temperature of 298,15K gives:

∆ G ° 298 11,018−40,366 40,366 −1122, 27

= + + +(−0,01819) = -0,8895
RT ( 8,314 )( 298 , 15 ) ( 8,314 ) ( 13 00 ) 13 00

Finally,
At 1300K: ln K = -0,8895 and K= 0,41082