C0103. COBETCKMX COUMANMCTHMECKUX PECTYBAIK TOCY/APCTBEHHLIA KOMATET NO W3OBPETEHIMAM 4 OTKPBITHAM PU THT cece ONUCAHME UZOBPETEHUNA K ABTOPCKOMY CBUETENbCTBY ao» SU ay 1692641 Al (ns 8 01 J 37/02, 23/88 BUECOIOSHAR ATENTHD- TESAUEGSAS f (21) 4731280/04 (22) 18.08.89 (46) 23.11.91. Bion. Ne 43 (71) Fposnenckna HedraHoa uncTuTyT wm.akaa.M,),Muanvonuxosa 4 Uncrtyt ro- plow ucKonaenbix (72) H.©.Mereas, A.A.Kpwuxo,,B.Mupckua, A.V. Mexnymona, M.K.tOnuH u 5.5.Anmasoea (63) 66,097.3 (088.8) (56) TY-38-101-752-81 TY-38-101-806-80. (64) CNOCOB NOAYYEHMA KATAN3ATOPA ANIA TMAPOOMMCTKM YFOIbHBIX AMC- Tunnatos (67) Viaobperenne xacaerca KaranutmuecKon XMMiMM, B YaCTHOCTH nony4eHnA KaTanngaTopa Ana rMapoouNcTKu yronbHux ANCTHANATOB, YTO Moxer 6uTb HcnOnbsoBaHO @ npoMaRogcTRE MOTOpHLIx TonAHB, Liens ~ noBBUMIeHMe aKTHB Vso6perenue orHocurca x KaTanutwye- KOA xnMMM, KOHKpeTHO x cnocoBy nonyueHHA kaTanusatopa raqpooucrKu, u MOxeT ObITs vicnonksoBao NpM npowssogcTee MoTOpHHX Tonnme, nonyyaemuix npn rMaporenMsaynoH- Hon nepepaGorke yrnen. Npoayxra rmaporenuaaywn yrna conep- 2kaT ASOTHCTHIe OCHOBAHHA, CEpHHCTHE M KIC AOPOAHME CoeAMHEHHS (8 OCHOBHOM deHONL Ce-Ca), KoToptie HegonycTumis B roTOBLX TO Bapwx Toninnoax. Ueno nso6perenna aenserca nonyyenne KaTanmgaropa ¢ NOBHUIEHHOA aKTHBHOCTHIO No ‘AeasoTupoBaNmio uv oGecdeHonMBaHMIO NpoAyKros cxWKEHMR yrnA 3a CHET MCNOMBsO- Bahia B KavecTae MaTpHYN quoKcMga THTAKa 8 KonuuecTee 70-80 mac. % w ony¥enna MarT- HocTa KaranusaTopa npw AeasoTHposaHnn 1 o6echexonneanun npopyKTos oxWKeHMA yr- rns, Mpouecc seayr npeasapurensHum npiro- TOBneHeM MaTPM4M - QUOKCHAA THTaHA (conmecrao 70-80 mac. %), nonywaemoro np Twaponuse AS0%HOA conn cynedara Tarannna Wammonus. Nonyxentuit npoaykr ouastpyior, NpoMeaiOT, nponwTuBaior pacrsopamn co: neh monvGqena W HiKeNa W nOAYYEHHYIO Hie kent-monv6geHoeyio MaTpMuy CMeWMBSIOT C yeonvTom Tuna Y 6 KOGanbTOBOm gopme. B stom cnyyae creneHs aeasoruposanun y Tony¥ennoro Katanmaatopa 8 npouecce TMaporennaaymn npoaykToa cxMKeHHA yrnA coctasnset 77,3-76,7%, o6echenonusanna 100% npw crenenw o6eccepusanua Ha w3ee- THOM yposHe. Kpome Toro, KaTanusatop ume- eT nyu MHgeKc MpowHocTH ~ 3,3 Kr/MM ‘Avametpa rpanynis nporue 0,8-2,2 Kr/Mat H3- BeCTHOrO KaTanusaTopa. 2 Tabn. Hye FMAponugOM ABOAHOA COnM cyneara TH TaHuna W aMMOHMR, Msobperenne unniocrpupyior cneayiowne npwmepus Tpwmep 1. Ana nonyseaua marpaus va avoxcnaa TuTaHa npurorapnueaioT 1A pac- ‘Taopa cynbara THTaHina m aMMOHHAC conep- xanwem 60 r/n, KoTOpHA nogBepraWT rumponissy nyreM kunsweHMa ero 8 Konbe c O6paTHLM xonoAMAKHMKOM 8 NpoAOMKeHHe 5: 4, O6pasosaswmaca rent TIO2 (55 r) orpuinsT- POBWBaI0T, nPoMEBAIOT OT OTCYTCTENA aHHOH ‘$O4*" uw satem nponmTuieaiot cMeckIo conen RapamonuBqata ammonua 8,35 r (10 mac. % MoOs), nurpara muxens 10,8 r (4 mac.%.NIO}. Pacrsopennux 8 500 Mn saw. BnpononxeHne 244 npw 20-25°C. Fene nocne storo orduneT- MAS ov Iv LVvVOZAOl3 1692641 4 PoBLiBaloT, CMewHBaiOT Cc 4,1 r yeonmTa CoY (6 mac. % weonta), neperapaior e crynke 0,5 4 W rpaHynupyWoT BraxHyIo Macey B nepdopy- PoBaHHeIX broponnactosLx nnactunax. Tab- neTKH B naacTHHax NoAcyUIEaIOT Ha BOSAYKe, a sate 5 4 5 cyummeHom wrady np 105- 110°C u npoxanueaior 8 mydene npu 450°C 5 4. TlonyenHeit Katanusatop Tak xe, KaK 4 waBecTHue KaTanMaaTOpHL, NCMUTHBAIOT pA TMAPOONMCTKE B NPOTOYHOA ycraHoRKe C Obb- eMom peakropa 0,8-2 n ppaKyui yroneoro auctunnsa H.K, ~ 400 np 400°, aasnennu 8 Mila, oBkemHom ckopocra nogayn coipea 14, uMpkynaynu Bogopora 800 n H2/n chipes. Crenens oGeccepmsanin rmaporennaara npoaykros oxmxeHMR yrna 82.3%, aeaaorH- posanna 74,2%, oGecheHonmsannn 100% w Tanpmposanus HenpenensHLX coeAMHeHMT 75%. Tpwmep 2, Matpmuy quoKcuga turana, NpuroTosnennyio no npumepy 1, nponuTbipa- ‘oT cMecbIO Cone napamonnigata ammouun 8,4 r(12,5 mac.% MoOg), Hutpata Huxens 10,8 (mac. % NiO}, pacreopentinx 8 50010 sons, 8 NpogonxeHme 244 npu 20-25°C, Tent no- “che Toro OTuAbTPOBEBAIOT , CMeWMBAIOT C 4,14 r yeonmra (7,5 mac. % yeonura) unepeme- wimeaior 8 crynke 0,5 4. Tpanynsymo anaxwor maccH. cywKy Npokanky Beayt no npumepy 1. Crenens oGeccepueanna ruaporennaara Apozykros exwxenua yin 843%, aeaaoru- powatna 75,0%, oGecoenonneanna 97.0% Twapmposauua HenpenenbHux coeaunenna 72.2%. Tipmmep 3. Marpnuy anoxcnga TuTaHa, NpurorosneHHyio no npaMepy 1, nponuruisa~ tor cmeckio Cone napamonnBgara ammonia 10,1 r (15 mac. % MoOs), nurrpara wuxena 13 7 (6 mac.% NiO), pacrsopennwx 8 500 mn Boat, Bnpogomxenne 24 4 npu 20-25°C, Pent nocne s¥oro orintrpoawieaior, cmewmBaioT ¢ 4,95 r eonura (9 mac.% yeonura) u nepemewmeaior a crynke 05.4, Tparynaywio snaxkHom maccti, cyuiKy 1 npoxanky Beayt no npumepy 1. 15 20 25 30 35 40 45 Crenens oGeccepusanna runporennaata MPOAYKTOS CxWKeHIA yrna B86 %, neasoTupORA- Hua 77%, oBecdenonnsanna 98% w raapupo- BaHun HenpenenbHbsx coequHeHU 74.7%. B ra6n. 1 npeactasnen ycnosna cuntesa Rony4eHHisx no npmmepam 1-3 obpasyos kaTanusatopos; 8 Ta6n, 2 ~ peaynurara uc- RUTaHMA KaTanisaTopoB, MonyYeHHeX npen- Raraemun W MaBeCTHEM CnocobaMn, Tow conepxxannn marpuus 8 KaTannsaTo- pe MeHee 70% ymentwaerca neazornpyio- laa oBecenonneaioujaa cnoco6HocTH Ao Renwunlt mene 75 90% cooreercraenHo, Tipw yoennuenwn conepxanua Marpuuti ~ Awoxcuaa Turana couue 80% npaxruvecku He APOWCXOAUT MsMeHeHKA KaTanMTHNECKUX cBoncrs. Npmmevenve 8 KaNecTse Marui KaTa- mugaTopa qMoKcMRa TuTaha, nony¥eHHoro Fugponngom AeoRHOA conn cynu@ara THTaHH- nau aMMonna, oecnewnoaer 8 ranporenusa- Te NPOAYKTOB CXMKEHMA yraa cTeneHE Aeagotuporanna 77,3-76,7%, oGecdexonu- Bana 100% npu crenenn obeccepusanun Ha YPOBHE He Hike HSBeCTHEIX OBpas\yoR KaTaNH 3aTopa Mw npesuiwenua ee Ha 45%. Kpome Toro, Kataniaarop, nonywennuin Apeanaraemuim cnoco6om, umeer HHAeKc AposocTn, aHauMTenbHO NpesHWAIOWINA MH ‘eke nposHocth, kaTanugaTopoa, nony¥eHHLUX wanecTHUMM cnocoBamn (3,3 rHa 1 mM ana Merpa rpanynus porns 0,8-2,2 xr), Dopmyna usobperenus Cnoco6 nonywenna Katanusatopa ana FuApOOWMCTKM yronbHBKx ANCTUANATOB, BKmIO~ WaIOWMA NonyYeHMe MATH, dunETPaUWNO, NpomBiBKy ee, NocneayioMylo NponuTKy pac- ‘Teopamu cone MonnBnexa u HuKens, cMewe- HMe HuKeALMOnHOAeHOBOA MaTpHUM C Yeonurom Tuna Y¥ B KOGanbTOBOA GopMe, OT - Aw4awwnac# Tem, 470, c YeNIO RonyweHua KaTansaTopa C NOBLUEHHOM aK- TUBHOCTEIO No AeasoTHpoBAHnIo K OBecHeHo- AuBaHuio NpoAyKTOS OxWKEHKA yrnn, B KavecTae MaTpMUM McnONBayioT AMOKtMA THTa- Ha B xonmectse 70-80 mac.% 4 nonyuenne MaTpHust OcyulecTanaioT rMaponusoM ‘ABOr- HOM conn Cynbata THTaHuna H aMMoHMA,Yenoswa cmnresa 1692641 TaGnuuat 1 3 Conepaanve marpuyu TIO2, mac. % 80 5 70 Copepanne MoOs, mac. % 10 12,5 5 |Coneoxanne NiO, mac. % 4 5 6 Coepxanve yeonuta CoY, mac. % 6 7S 9 Crenens neasormposanns, mac. % 7713 1 76,7 Crenens oGeccepweanis, mac. % 86,1 86 85 Crenetb oGecpenonneannn, mac. % 100 100 98 [Crenens rmapupopaua, mac. % 75.25 75 743 Ta6anua 2 Tloxaaarenn Karanussrop nonywennia 10 ananory |nporormny|conocrasu- as npomuur|npeanarae- TK-35. |TKR-202 —|rensiuia o6-lnenHoA TIO2 |Momy cnoco- paseu 13 AB0%| by HOA conn cyne| Jara neranr naw anmo- His [Dopma rpanyn Yepenxn | “Tabnerkn | TaGnerxm | Tabnerkn | TaGnernn Hacwinian anorHocrs. xr/n! 0,8-0,95 08 0,805 0.88 0.89 Conepxanue, %: ‘oxciia Kobansra (I!) - 04 0,64 04 - oxema Hinkens (lI) 70-85 5.0 5.0 5.0 50 ‘TpmoKcua MonuBgena | 18,0-19,5 13,0 13,0 13,0 125 OkcHA aniomnnns 15-72 816 0,0 0.0 0.0 OrHocurensHas axrue-| Hocts, % no o6eccepusaHino 78 80 86,2 85.8 86.3, AeasoTuposaninio 36 48 115 772 713 oGecdeHonneanmio a aT 100 - 100 TMApMpoBaniio Henpe- AenbHuXx coeauHeHna 80 86 86 86 86,2 Conepmanne ueonuta, r Her | Hedgopmy] 7.5 15 75 pyerca sinexc npownocrn, xr Ha 1 MM anamerpa rpaHynus 18 22 | 34 08 33 Coctasurens B.Tennaxoza Pepaxrop T.MisaHoea ‘Texpea M.Moprenran Koppextop H.Kopons 3axas 4031 Tupax Noanuchoe BHVIVTIM Focynapcreennoro xommrera no uso6perennam m orcpuraam npn TKHT CCCP 113035, Mock: 35, Paywcxan Ha6., 4/5 Nponssoncreenno-nanarenscKua KoMBuHar “| Tent", r. 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