GUIDED REVISION ENTHUSIAST & LEADER

Target : JEE(Main + Advanced) - 2019 COURSE

INORGANIC CHEMISTRY
GUIDED REVISION PLAN-SCORE ADVANCED
Question Bank # 10 [Topic : Allotropes]

SINGLE CORRECT
1. Which of the following molecule has tetrahedral geometry :-
(A) S8 (B) P4 (C) S6 (D) Graphite
2. Which of the following crystalline allotrope is present in given arrangement of atoms -

(A) Graphite (B) Black phosphorus

(C) Rhombic sulphur (D) Red phosphorus
3. White phosphorus produces the following products on reaction with conc. NaOH
(A) NaH2PO2 + PH3 (B) NaH2PO4 + PH3
(C) Na2HPO3 + PH3 (D) None of these
4. The soldiers of Napolean army while at Alps during freezing winter suffered a serious problem as regards
to the tin buttons of their uniforms. White Metallic tin buttons get converted to grey powder. This transfor-
mation is related to:-
(A) An interaction with water vapour contained in humid air
(B) A change in crystalline structure of tin
(C) A change in the partial pressure of O2 in air
(D) An interaction with N2 of air at low temperature
5. Graphite is a soft solid lubricant extremely difficult to melt. The reason for this anomalous behaviour is that
graphite :
(A) Has molecules of variable molecular masses like polymers
(B) Has carbon atoms arranged in large plated of rings of strongly bonded carbon atoms with
weak interplate bonds
(C) Is a non crystalline substance
(D) Is an allotropic form of diamond
6. Which of the following statements regarding sulphur is incorrect ?
(A) At 600°C the gas mainly consists of S2 molceules
(B) The oxidation state of sulphur is never less than +4 in its compounds
(C) S2 molecule is paramagnetic
(D) The vapour at 200°C consists mostly of S8 rings
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 GUIDED REVISION ENTHUSIAST & LEADER
Target : JEE(Main + Advanced) - 2019 COURSE
PARAGRAPH TYPE
Paragraph for Q.7 to Q.9

D H2O
Acidic gas (A) + Yellowish green gas (B) (C) (D) + (E)

NaOH

(F) + (G)

(i) D and E are both acids while F and G both are salts.
D
(ii) F(solid) + conc. H2SO4 + K2Cr2O7 (s) ¾¾ ® reddish brown vapour which is passed into NaOH
solution to give yellow solution.
Filtered
(iii) Solution of (G) + CaCl2 White residue insoluble in dil. mineral acid
7. The gas (B) is
(A) SO2 (B) CO2 (C) CO (D) Cl2
8. The compound (C) is -
(A) COCl2 (B) SOCl2 (C) SO2Cl2 (D) CSCl2
9. The hybridisation state of central atom of the compound present in reddish brown vapour is-
(A) sp3 (B) sp3d (C) d3s (D) sp2
ONE OR MORE THAN ONE CORRECT
10. Select CORRECT statement (s) -
(A) White phosphorus produces PH3 with NaOH conc.
(B) SCN¯ is a pseudohalide ion
(C) He is mixed with O2 for scuba-divers
(D) Standard Hypo solution is used for iodine titrations
11. Select CORRECT statement about ozone -
(A) It is a allotrope of oxygen (B) It reduce the fluidity of Hg
(C) It is diamagnetic gas (D) It’s bleaching action is
permanent
12. The percentage of p-character in the orbitals forming P–P bonds in P4 is
(A) 25 (B) 33 (C) 50 (D) 75
13. The reaction of white phosphorus with aqueous NaOH gives phosphine along with another phosphorus
containing compound. The reaction type ; the oxidation states of phosphorus in phosphine and the other
product are respectively
(A) redox reaction ; –3 and –5
(B) redox reaction ; +3 and +5
(C) disproportionation reaction ; –3 and +1
(D) disproportionation reaction ; –3 and +3
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 GUIDED REVISION ENTHUSIAST & LEADER
Target : JEE(Main + Advanced) - 2019 COURSE

14. With respect to graphite and diamond, which of the statement(s) given below is (are) CORRECT ?
(A) Graphite is harder than diamond.
(B) Graphite has higher electrical conductivity than diamond.
(C) Graphite has higher thermal conductivity than diamond.
(D) Graphite has higher C – C bond order than diamond.
15. Which of the following is thermodynamicaly most stable allotrope of corresponding element.
(A) Rhombic sulphur (B) Black phosphorous
(C) Monoclinic sulphur (D) White phosphorous
16. Engel's sulphur have
(A) S8 molecules (B) S6 molecules
(C) Two lone pair on each sulphur (D) Chair conformation
17. Which of the following undergo disproportionation with conc. NaOH.
(A) Rhombic sulphur (B) White phosphorous
(C) Zinc (D) Aluminium
18. Allotropic form of phosphorous which show phosphresence
(A) White phosphorous (B) Black phosphorous
(C) Red phosphorous (D) All of the above
MATCH THE COLUMN
19. Column-I Column-II
(Allotropic form) (Physical apperance)
(A) Graphite (P) Solid
(B) a-sulphur (Q) Yellow coloured

(C) ( 4—
—P )n (R) Red coloured

(D) b-sulphur (S) Slippery solid

(T) Needle shaped crystal

Integer (Single Digit)

20. Find the total number of allotropes contain discrete molecules held together by London forces :-

Diamond , Graphite , Fullerene , White phosphorus , Rhombic sulphur , Black phosphorus

21. Find number of reagents which produce CO2 when reacted with carbon :
dil. H2SO4, conc. H2SO4, dil. HNO3, conc. HNO3, conc. NaOH, Lime water,

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 GUIDED REVISION ENTHUSIAST & LEADER
Target : JEE(Main + Advanced) - 2019 COURSE
Integer (Multiple Digit)

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7 8 9
4 5 6
1 2 3
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22. Find the number of hexogonal rings in C84 fullerene.
23. Find the sum of number of pentagon (x) , number of hexagon (y) & number of C–C linkage (Z) in
fullerene (C60)
24. Find the number of hexagonal ring in fullerene (C80).
25. Find the sum of number of pentagonal rings in C40,C60, C80.

ANSWER-KEY
Guided revision plan -score advance-Question Bank (10)
Topic : Allotropes
SINGLE CORRECT
1. Ans. (B) 2. Ans. (B) 3. Ans. (A) 4. Ans. (B) 5. Ans. (B) 6. Ans. (B)7.
Ans. (D) 8. Ans. (C) 9. Ans. (C) 10. Ans. (A,B,C,D) 11. Ans. (A, B, C, D)
12. Ans. (D) 13. Ans. (C) 14. Ans. (B,D) 15. Ans. (A, B) 16. Ans. (B, C, D)
17. Ans. (A, B) 18. Ans. (A) 19. Ans. (A) ® P, S ; (B) ® P, Q ; (C) ® P, R ; (D) ® P, T)
20. Ans. (3) 21. Ans. (2) 22. Ans.(32) 23. Ans (122) 24. Ans. (30)
25. Ans. (36)
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