SECTION-A

Choice Questions (MCQ) type questions, carrying

Queston No.1to 16 are Multiple (16x1=16)
1mark each.
1

1. Which of the following is dependent on temperature?

(b) Molarity
(a) Molality
(d) Weight percentage
(c) Mole fraction
could be produced when l mole of carbon is
2. Calculate the amount of cartbon dioxide that
burnt in air.

(b) 12g
(a) 22 g
(d) 88 g
(c) 44 g

maximum number of electrons in a subshell is given by the expression :

3. The
(b) 2+1
(a) 48+2

(d) None of these

(c) 2n
distinguished by
4. Two electrons occupying the same orbital are
Principal quantum number (b) Azimuthal quantum number
(a)

(c) Magnetic quantum number (d) Spin quantum number

in
5. Which of the following series of transitions in the spectrum of hydrogen atom fall
visible region. Amole
Lyman series (b) Balmer series
(a)
Paschen series (d) Brackett series
(c)
 Na. of pages - 24

of 5s*
6. In the long form of the periodic table, the valence shell electronic configuration
Sp corresponds to the element present in :
(b) Group 16 and period 5
(a) Group 16 and period6
(d) Group 17 and period 5
(c) Group 17 and period 6
1
7. Be is isoelectronic with which of the following ion?

(a) (b) Ca

Lit (d) Mg
1
8. Which of the following has largest size?

(a) Na (b) Mg

(d) Mg
Which of the following molecules does not have hydrogen bonding? 1
9

(a) NH3 H,0

(c) CH4 (d) HF

10. Which of the following is paramagnetic? 1

(a) H2 (b) N,

(c) F2 ( O,
11. The oxidation number of the underlined atom is PO ion : 1

(a) +3 +5

(c) +7 (d)

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12.
What is the change in oxidation number of ion in the following reaction?

Fe,0, +3CO,, 2F, +3C0,)

(a) +1 to 0 (b) +2 to 0

(c) +2 to +3 (d) +3 to 0

For questions 13 to 16, two statements are given one labelled as Assertion (A) and
from
the other labelled as Reason (R), Select the correct answer to these questions

the codes (a), (b), (c) and (d) as given below :

the corrcct
(a) Both ASsertion (A) and Reason (R) are true and Reason (R) is

explanation of the Assertion (A).

(b) Both Assertion (A) and Reason (R) are true, but Reason (R) is not the correct

explanation of the Assertion (A).

(c) Assertion (A)is true, but Reason (R) is false.

(d) Assertion (A) is false, but Reason (R) is true.

13. Assertion (A): Combustion of 16 gof methane gives 18g of water.

Reason (R) : In the combustion of methane, water is one of the products.

14. Assertion (A):The last electron in potassium atom enters into 4s orbital, not 3d orbital. 1

Reason (R) : (n +) rule is followed for determining the subshell of lowest energy state.

15. Assertion (A):lonic radius of C! is smaller than CL. 1

Reason (R): Effective nuclear charge of Cr is lower than C..

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 l6. Assertion (A): It is impossible to determine the exact
position ard momentum of
electron simultaneousty.
Reason (R):The path of an electron in an atom is clearty defined

SECTION-B
The following questions (17 to 21) are very short answer type questions carrying 2
marks each. One question have internal choice only.
17. If the velocity of the electroa in Bor's first orbit is 2.19 x 10 ms. Calculate the
de-Broglie wavelengths associated with it. (h = 6.63 x 10 s, mass of elecron =
9.1x1031 kg)
OR

Calculate the energy required for the process:

He, ’He +e

The ionization energy for the H-atom in the ground state is 2.18 x 10J atom
18. (a) Define electron gain enthalpy.
(b) Mention one similarity in the behaviour of Be and AL to stow that the sho
diagonal relationship.
19. Identify the substance oxidized, reduced. oxidizing agent and reducing agent for the
following reaction :

Pb, +PbO +2H_SO ’2PbSO -2H,0,

20. In three moles of ethane (C,H,), calculate the following :

(a) Number of moles of carbon atoms.

(b) Number of molecules of ethane.

X-CHE MISTRY-M
 MIN TEDA (M)
If 16.3 g of NaHCO, is added to
21. solutionof acetic acid weighing 10.0 g.
Residue was
found to weugh 18.0 g. Determine the mass of CO; formcd.

NaHCO, +CH,COOH ’ CH,COONa +H,0 +CO,

Which law is obeyed in this case?

SECTION-C
This section contains 7 short answer type questions. Each question carries 3 marks,
having one internal choice.

22. A compound contains 4.07% hydrogen, 24.27% carbon and 71.65% chlorine. Its molar
mass is 98.96 g. What are its empirical and molecular formulas? (Atomic mass of
C=12g,H =lg, Cl=35.5g) 3

23. (a) How many subshells are associated withn=4?

(b) How many electrons will be present in the subshells having m, value of for
2
n=4.

(c) Write the electronic configuration of Cu ion (z= 29) 3

24. (a) Draw the shape of d orbital.

(b A 100W bulb emits monochromatic light of wavelength 400 nm. Calculate the
number of photons enmitted per second by the bulb. 3

(h=6.63 x 10 Js)

25. (a) Write the general outer electronic configuration of d-block elements.
(b) Use the periodic table to identify the following:
(i) Agroup whose elements show valence 2 and 6.

(ii) A metal which can form a predominantly stable covalent halide of the
formula MX (X= halogen)

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 its
26/ Write the molecular orbital configuration of N,. Caleulate its bond order and predict
3
magnetic behaviour.
3
2
According to VSEPR theory draw the shape of the following molecules:

(i) SF4
(ii) BrFs
(ii) H, 0
OR

(a) What is the hybridization of carbon atoms in benzene (C&H,)?

does not exist?
(b) Use molecular orbital theory toexplain why the He, molecule
3
(c) Write the Lewis structure of the nitrite ion (NO, ).

28. (a) Write a short note on disproportionation reaction'.

Balance the following redox reaction in acidic medium: 3
(b)
MnO, +Fe* ’ Mn + Fe

SECTION-D

The following questions are case study based questions. Read the case carefully and
answer the questions that follow:

29. Ionization Enthalpy

A quantitative measure of the tendency of an element to lose electron is given by its

ionization enthalpy. The first ionization enthalpy for an element Xis the enthalpy change
(AH) for the reaction depicted in the equation given below:
Xyg) ’ Xe +e

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 MID-TERM EX AMIN
The ionization enthalpy is expressed in units of kJ
mol". Energy is always required to
remove electrons from an atom and
hence ionization enthalpies are always
positive.
The first ionization enthalpies of
elements of the second period are plotted in Fig.l and
AH of alkali metals are
plotted in Fig.2

2500 550
mot'
4,H/kJ LI(520)
A,H/LJ
mor Ne
2000 500 Na(496)
(2080),
F

1500 N (1681) 450

(1402)
Be
c (1314) 400 K Rb(403)
1000 (899) l086) (419)
Cs(374)
500 (520) (Bo1) 350L0
2 4 6
10 20 30 40 50 B0
60

Fig.1 Fig.2

Answer the following questions: 1+1+2

(a) Which element is more metallic : Li kor Cs and why?

(b) Which has low ionization enthalpy: Na or Na" and why?

(c) Explain why :

) Be has higher AH, B?

(ii) Ohas lower AH, than N?

OR

Vh
O02X (o-4

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lo-3
() From above graphs, which elenent is :

() the most reactive metal

() the elenent which can form a stable binary halide of the formula MX,

(X-halogen)
Polarity of bonds

The existence of a hundred percent ionic or covalent bond represents an ideal situation.

In rrality no bond or a compound is cither completely covalent or ionic. When covalent

bond is formed between two similar atonms, the shared pair of electrons is equally
attracted by the two atoms. As a result, electron pair is situated exactly between the two
identical nuclei. The bond so formed is called non-polar covalent bond. Contrary to this
in case of heteronuclear molecular, the shared electron pair between the two atoms gets

displaced more towards more electronegative element. The resultant covalent bond is a
polar covalent bond. As a result of polarization, the molecule possesses the dipole

moment. Mathematically, it is expressed as follows:

Dipole moment (1) =Charge (q) xdistance of separation (d)

Answer the following questions: 1+1+2

(a) Draw the shape of H,0 molecule showing bond dipoles on it.

OR

Give an example of non-polar molecule.

(b) Which is more polar :C oTor HF?

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 Give reasons :
(c) bond is
more dipole moment than NF,, although N-F
(i) NH, molecule has
more polar than N-H bond.
dipole moment although B-F bonds are polar.
(1) BF,molecule has zero
SECTION-E
5
multiplicity.
(a) Define Hund's rule of maximum
31.
1.9eV. Calculate the threshold wavelength.
Caesium atom is
(b) The work function for
= 1.6 x 10J
[Given : h= 6.63 x 10* Js, leV
principle is significant only for motion of microscopic
(c) Heisenberg's uncertainty
Justify :
objects and is negligible for the macroscopic objects.
(h =6.63 x 10 Js, M, =9.1 x 10 kgl

OR

(a) Account for the following :

(i) Bohr's orbit are called stationary states.

(ii) A moving cricket ball cannot have wave character.

(b) An ion with mass number 56 contains 3 units of positive charge and 30.4% more
neutrons than electrons. Assign the symbol to this ion.

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 (c) Which atoms are indicated by the following configuration?
[Ar] 3d' 4s?
(i) [Ne] 3s 3p' (ii)

32 (a) Give reasons for the following :

(i) Hydrogen fluoride gas exist as dimer

than bond.
(ii) G bond is stronger
107".
(11i) Bond angle of NH, is
5
draw the shape of SF6.
(d) On the basis of hydrogen, explain and
hybuciatonOR

(a) Draw resonating structures of NO, ion.

following reaction:
(b) Describe the change in hybridization of the Al atom in the

AC., + C ’ ACI;
Boiling point of NH3 is higher than PH,. Why?

(d) Which of the following wll have higher value of the property mentioned? Give
reason:

LiF,CAE, (Ionic character)

(i) 0, E (Bond order)

33. (a) State law of multiple proportion.

(b) How are 0.5 mol Na,C0, and 0.5M Na,C0,
(C) 50.0 kg of N/e) and 10.0 kg of H,0 are mixed to produce NH,. Calculate the
NH3g) formed. Identify the limiting reagent in the production of NH; in this
situation.

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 OR

(a) Define mole fraction.

which the mole fraction of

(b) Calculate molarity of a solution of ethanol in water in

ethanol is 0.040 (density of water = 1gm L)

present in 2.0034?
(c) How many significant figures are
sulphate (Na,SO4).
(d) Calculate the mass percent of sodium present in Sodium

Given : Atomic mass of Na=23 g, S=32 g, O= 16g]

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