Chemistry The Molecular Nature of Matter and Change 8th Edition Silberberg Test Bank

Chemistry The Molecular Nature of
Matter and Change 8th Edition

Silberberg Test Bank
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Chapter 8 Test Bank
Electron Configuration and Chemical Periodicity
1. “Each electron in an atom must have its own unique set of quantum numbers” is a statement of
A. the aufbau principle.
B. the Pauli exclusion principle.
C. Hund's rule.
D. the periodic law.
E. Heisenberg's principle.
Accessibility: Keyboard Navigation
Bloom's: 1. Remember
Difficulty: Easy
Gradable: automatic
Subtopic: Pauli Exclusion Principle
Topic: Electron Configuration
2. Energy states of atoms containing more than one electron arise from nucleus-electron and electron-electron interactions. Which
of the following statements correctly describes these effects?
A. Larger nuclear charge lowers energy, more electrons in an orbital lowers energy.
B. Larger nuclear charge lowers energy, more electrons in an orbital increases energy.
C. Smaller nuclear charge lowers energy, more electrons in an orbital lowers energy.
D. Smaller nuclear charge lowers energy, more electrons in an orbital increases energy.
E. None of these choices are correct.
Difficulty: Easy
Gradable: automatic
Subtopic: Energy-Level Splitting (Zeff and Shielding)
3. Which one of the following statements about orbital energies is incorrect?

A. In the hydrogen atom, the energy of an orbital depends only on the value of the quantum number n.
B. In many-electron atoms the energy of an orbital depends on both n and l.
C. Inner electrons shield outer electrons more effectively than do electrons in the same orbital.
D. The splitting of sublevels in many-electron atoms is explained in terms of the penetration effect.
E. The energy of a given orbital increases as the nuclear charge Z increases.
Difficulty: Medium
Gradable: automatic
4. The effective nuclear charge for an atom is less than the actual nuclear charge due to
A. shielding.
B. penetration.
C. paramagnetism.
D. electron-pair repulsion.
E. relativity.
Difficulty: Easy
Gradable: automatic
5. In many-electron atoms, which quantum numbers specify the energy of an electron?

A. n and l
B. n and ml
C. l and ml
D. n and ms
E. n, l, and ml
8-1
Copyright © 2018 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent
of McGraw-Hill Education.
Difficulty: Easy
Gradable: automatic
Subtopic: Quantum Numbers
Topic: Quantum Theory and Atomic Structure
6. Which of the following sublevels is filled last? 3d, 4s, 4p, 4d, 5s
A. 3d
B. 4s
C. 4p
D. 4d
E. 5s
Bloom's: 2. Understand
Difficulty: Medium
Gradable: automatic
Subtopic: Assigning Electrons to Atomic Orbitals (Aufbau Principle)
7. “Electrons added to atomic orbitals of the same energy will remain unpaired with parallel spins until the subshell is more than
half-filled” is a statement of
A. the aufbau principle.
B. Hund's rule.
C. the Pauli exclusion principle.
D. the periodic law.
E. the singularity rule.
Difficulty: Easy
Gradable: automatic
Subtopic: Hund's Rule
8. Which one of the following statements about atomic structure and quantum numbers is incorrect?
A. In a given atom, the maximum number of electrons having principal quantum number n = 3, is 18.
B. The number of orbitals in a given f subshell is 7.
C. For n = 4, the largest possible value of l is 3.
D. For n = 4, the largest possible value of ml is 2.
E. The following set of quantum numbers for a single orbital is not allowed: n = 3, l = 1, ml = –2.
Difficulty: Medium
Gradable: automatic
9. In a single atom, what is the maximum number of electrons which can have quantum number n = 4?
A. 16
B. 18
C. 32
D. 36
Difficulty: Medium
Gradable: automatic
10. Select the correct set of quantum numbers (n, l, ml, ms) for the highest energy electron in the ground state of potassium, K.
A. 4, 1, –1, ½
B. 4, 1, 0, ½
C. 4, 0, 1, ½
D. 4, 0, 0, ½
E. 4, 1, 1, ½
8-2
Bloom's: 3. Apply
Difficulty: Medium
Gradable: automatic
11. Select the correct set of quantum numbers (n, l, ml, ms) for the highest energy electron in the ground state of tin, Sn.
A. 5, 2, –1, ½
B. 5, 2, 0, ½
C. 5, 1, 2, ½
D. 5, 1, 0, ½
E. 5, 2, 1, ½
Bloom's: 3. Apply
Difficulty: Medium
Gradable: automatic
12. Select the correct set of quantum numbers (n, l, ml, ms) for the first electron removed in the formation of a cation for
strontium, Sr.
A. 5, 1 , 0, –½
B. 5, 1, 0, ½
C. 5, 0, 1, ½
D. 5, 1, 1, ½
E. 5, 0, 0, –½
Bloom's: 3. Apply
Difficulty: Medium
Gradable: automatic
13. Which of the following electron configurations is impossible?

A. 1s22s22p63s23p4
B. 1s22s22p53s13p4
C. 1s22s22p63s23p63d104s2
D. 1s22s22p63s33p4
E. 1s12s22p63s23p4
Difficulty: Medium
Gradable: automatic
14. Select the correct electron configuration for sulfur (Z = 16).

A. 1s21p62s22p6
B. 1s22s22p83s23p4
C. 1s22s22p83s23p2
D. 1s22s22p63s23p4
E. 1s22s22p63s23d4
Bloom's: 3. Apply
Difficulty: Easy
Gradable: automatic
15. Select the correct electron configuration for Cu (Z = 29).

A. [Ar]4s23d9
B. [Ar]4s13d10
C. [Ar]4s24p63d3
D. [Ar]4s24d9
8-3
E. [Ar]5s24d9
Bloom's: 3. Apply
Difficulty: Hard
Gradable: automatic
16. Select the correct electron configuration for Te (Z = 52).

A. [Kr]5s25p64d8
B. [Kr]5s25d105p4
C. [Kr]5s24d105p6
D. [Kr]5s24f14
E. [Kr]5s24d105p4
Bloom's: 3. Apply
Difficulty: Medium
Gradable: automatic
17. The electronic structure 1s22s22p63s23p64s23d8 refers to the ground state of

A. Kr.
B. Ni.
C. Fe.
D. Pd.
Bloom's: 3. Apply
Difficulty: Medium
Gradable: automatic
18. In the ground state of an atom of silver (Ag), how many electrons will there be with the quantum number l = 1? (The n, ml,
and ms quantum numbers may have any appropriate values.)
A. 9
B. 12
C. 18
D. 24
E. 36
Bloom's: 3. Apply
Difficulty: Hard
Gradable: automatic
19. An atom of element number 33 (As) is in its ground electronic state. Which one of the following sets quantum numbers could
not apply to any of its electrons?
A. n = 2 l = 1 ml = –1 ms = +½
B. n = 3 l = 0 ml = 0 ms = –½
C. n = 3 l = 2 ml = –2 ms = –½
D. n = 4 l = 0 ml = 0 ms = –½
E. n = 4 l = 2 ml = 1 ms = +½
Bloom's: 3. Apply
Difficulty: Hard
Gradable: automatic
20. How many valence electrons are there in an atom with the electron configuration [noble gas]ns2(n –1)d10np3?
A. 2
B. 3
8-4
C. 5
D. 10
E. 15
Difficulty: Medium
Gradable: automatic
21. How many valence electrons are there in an atom with the electron configuration [noble gas]ns2(n – 1)d8?
A. 2
B. 6
C. 8
D. 10
Difficulty: Medium
Gradable: automatic
22. Which of the following electron configurations represents the ground state of an element?
A. [Ne]3s13p1
B. [He]2s12p3
C. [Ne]3s23p23d1
D. [Ne]3s23p33d1
E. [Ne]3s23p3
Bloom's: 3. Apply
Difficulty: Medium
Gradable: automatic
23. Which of the following sets of elements have the [noble gas]ns2np2 valence electron configuration?
A. O, S, Se, Te, Po
B. N, P, As, Sb, Bi
C. F, Cl, Br, I, At
D. C, Si, Ge, Sn, Pb
E. Ti, Zr, Hf
Bloom's: 3. Apply
Difficulty: Easy
Gradable: automatic
24. In the electron configuration [Ar]4s23d104p4, which are valence electrons?

A. all of the electrons after the [Ar]
B. only the 4s2 electrons
C. only the 3d10 electrons
D. only the 4p4 electrons
E. both the 4s2 and the 4p4 electrons
Difficulty: Easy
Gradable: automatic
25. Which of the following electron configurations is correct for the excited state of an element?
A. [He]2s22p5
B. [Ne]3s23p1
8-5
C. [Ar]4s14p1
D. [Kr]5s24d7
E. [He]1p1
Bloom's: 3. Apply
Difficulty: Medium
Gradable: automatic
26. Which of the following electron configurations is not possible for an atom in an excited state?
A. 1s22s22p63s23p63d104s14p1
B. 1s22s22p63s13p5
C. 1s22s22p63s23p23d2
D. 1s22s22p63s23p63d104s2
E. 1s22s22p63s23p63d104s14p3
Difficulty: Medium
Gradable: automatic
27. Which of the following fourth-period elements has the smallest atomic radius?
A. K
B. Ti
C. Cu
D. Ge
E. Kr
Difficulty: Easy
Gradable: automatic
Subtopic: Trends in Physical Properties (Atomic Radius, Ionization Energy, Ionic Radius, Electron Affinity)
Topic: Chemical Periodicity
28. Which of the following elements has the largest atomic size?
A. S
B. Ca
C. Ba
D. Po
E. Rn
Difficulty: Medium
Gradable: automatic
29. Which of the following elements has the smallest atomic size?
A. Na
B. Ar
C. K
D. Ca
E. Kr
Difficulty: Medium
Gradable: automatic
30. Which of the following elements has the smallest atomic radius?
A. Li
B. Ne
8-6
C. Rb
D. Sr
E. Xe
Difficulty: Medium
Gradable: automatic
31. Which of the following elements has the greatest atomic radius?
A. Li
B. Ne
C. Rb
D. Sr
E. Xe
Difficulty: Medium
Gradable: automatic
32. Which one of the following equations correctly represents the process relating to the ionization energy of X?
A. X(s) → X+(g) + e–
B. X2(g) → X+(g) + X–(g)
C. X(g) + e– → X–(g)
D. X–(g) → X(g) + e–
E. X(g) → X+(g) + e–
Difficulty: Hard
Gradable: automatic
33. Which of the following elements has the largest first ionization energy?
A. Na
B. Cl
C. Ca
D. Te
E. Br
Difficulty: Medium
Gradable: automatic
34. Which of the following elements has the smallest first ionization energy?
A. Rb
B. Mg
C. I
D. As
E. F
Difficulty: Medium
Gradable: automatic
35. When comparing the successive ionization energies of an element, an unusually big increase in ionization energy is seen
when
A. the first valence electron is removed.
8-7
B. the second valence electron is removed.
C. the eighth electron of is removed.
D. the first core electron is removed.
E. the last valence electron is removed.
Difficulty: Medium
Gradable: automatic
36. Identify the element of Period 2 which has the following successive ionization energies, in kJ/mol.
IE1, 1314 IE2, 3389 IE3, 5298 IE4, 7471
IE5, 10992 IE6, 13329 IE7, 71345 IE8, 84087
A. Li
B. B
C. O
D. Ne
Bloom's: 3. Apply
Difficulty: Medium
Gradable: automatic
37. Which of the following elements has the largest second ionization energy (IE2)?
A. Li
B. B
C. O
D. F
E. Na
Bloom's: 3. Apply
Difficulty: Hard
Gradable: automatic
38. Elements with the highest first ionization energies are found in the ___________ region of the periodic table.
A. lower left
B. upper left
C. center
D. lower right
E. upper right
Difficulty: Easy
Gradable: automatic
39. Which one of the following equations correctly represents the process involved in the electron affinity of X?
A. X(g) → X+(g) + e–
B. X+(g) → X+(aq)
C. X+(g) + e– → X(g)
D. X(g) + e– → X–(g)
E. X+(g) + Y–(g) → XY(s)
Difficulty: Hard
Gradable: automatic
8-8
40. Select the element with the most negative electron affinity (i.e., accepts an electron most readily).
A. H
B. Li
C. C
D. F
E. Ne
Difficulty: Medium
Gradable: automatic
41. Which of the following has the most negative electron affinity?
A. H
B. Li
C. Na
D. K
E. Rb
Difficulty: Medium
Gradable: automatic
42. Elements with ________________ first ionization energies and ___________ electron affinities generally form cations.
A. low; very negative
B. high; positive or slightly negative
C. low; positive or slightly negative
D. high; very negative
Difficulty: Hard
Gradable: automatic
43. Elements with _______________ first ionization energies and ___________ electron affinities generally form anions.
A. low; very negative
B. high; positive or slightly negative
C. low; positive or slightly negative
D. high; very negative
Difficulty: Hard
Gradable: automatic
44. Select the element with the greatest metallic character.

A. Li
B. Ca
C. Al
D. Pb
E. Cs
Difficulty: Medium
Gradable: automatic
8-9
45. Select the element with the least metallic character.
A. Sn
B. Sr
C. Tl
D. Ge
E. Ga
Difficulty: Medium
Gradable: automatic
46. Metallic behavior is generally associated with

A. elements with very negative electron affinities.
B. elements with low ionization energies.
C. elements with small atomic radii.
D. elements with unpaired electrons.
E. elements with partially filled p orbitals.
Difficulty: Medium
Gradable: automatic
47. The most acidic oxides are formed from elements found in the _________________ region of the periodic table.
A. upper right
B. upper left
C. center
D. lower right
E. lower left
Difficulty: Easy
Gradable: automatic
Subtopic: Trends in Chemical Reactivity
48. The most basic oxides are formed from elements found in the __________________ region of the periodic table.
A. upper right
B. upper left
C. center
D. lower right
E. lower left
Difficulty: Easy
Gradable: automatic
49. Select the most acidic compound from the following.

A. SO2
B. Al2O3
C. CaO
D. PbO
E. H2O
Difficulty: Medium
Gradable: automatic
8-10
50. Select the most basic compound from the following.
A. Bi2O3
B. SiO2
C. Cs2O
D. Na2O
E. H2O
Difficulty: Medium
Gradable: automatic
51. Which of the following elements will form a cation with a +2 charge?
A. Si
B. Sr
C. Ga
D. Cs
E. S
Difficulty: Easy
Gradable: automatic
Subtopic: Molecules and Ions
Topic: Components of Matter
52. Which of the following ions will be most likely to form when selenium ionizes?
A. Se6+
B. Se4+
C. Se2+
D. Se2–
E. Se4–
Difficulty: Easy
Gradable: automatic
Subtopic: Molecules and Ions
Topic: Components of Matter
53. Which of the following atoms will be diamagnetic?

A. Cr
B. Ru
C. Fe
D. Pt
E. Cd
Bloom's: 3. Apply
Difficulty: Medium
Gradable: automatic
Subtopic: Diamagnetism and Paramagnetism
54. Which of the following elements is paramagnetic?

A. Kr
B. Zn
C. Sr
D. V
E. Ar
Bloom's: 3. Apply
Difficulty: Medium
Gradable: automatic
8-11
55. Select the paramagnetic ion.
A. Cu+
B. Ag+
C. Fe3+
D. Cd2+
E. Ca2+
Bloom's: 3. Apply
Difficulty: Hard
Gradable: automatic
56. Select the diamagnetic ion.

A. Cu2+
B. Ni2+
C. Cr3+
D. Sc3+
E. Cr2+
Bloom's: 3. Apply
Difficulty: Hard
Gradable: automatic
57. Consider the set of isoelectronic atoms and ions A2–, B–, C, D+, and E2+. Which arrangement of relative radii is correct?
A. A2– > B– > C > D+ > E2+
B. E2+ > D+ > C > B– > A2–
C. A2– > B– > C < D+ < E2+
D. A2– < B– < C > D+ > E2+
Difficulty: Medium
Gradable: automatic
58. What is the correct order of decreasing size of the following ions?
A. P3– > Cl– > K+ > Ca2+
B. Ca2+ > K+ > Cl– > P3–
C. K+ > Cl– > Ca2+ > P3–
D. K+ > Cl– > P3– > Ca2+
Difficulty: Medium
Gradable: automatic
59. In Mendeleev's version of the periodic table, the elements were arranged in order of increasing atomic number.
FALSE
Difficulty: Easy
Gradable: automatic
Subtopic: Development of the Periodic Table
60. Moseley's measurements of nuclear charges of the elements provided the basis for arranging the elements of the periodic table
in order of increasing atomic number.
TRUE
8-12
Difficulty: Medium
Gradable: automatic
Subtopic: Development of the Periodic Table
61. According to the exclusion principle, two is the maximum number of electrons in an atom which can share the same four
quantum numbers.
FALSE
Difficulty: Easy
Gradable: automatic
Subtopic: Pauli Exclusion Principle
62. The difference in energies between the 1s and 2s orbitals is due to the penetration effect.
FALSE
Difficulty: Medium
Gradable: automatic
63. In neutral atoms, the 3d orbitals have higher energy than the 4s orbitals.
TRUE
Difficulty: Easy
Gradable: automatic
64. Hund's rule is used to predict the electron configuration of atoms in excited states.
FALSE
Difficulty: Easy
Gradable: automatic
Subtopic: Hund's Rule
65. Elements in which the outermost electron has the same principal quantum number n, show similar chemical properties.
FALSE
Difficulty: Medium
Gradable: automatic
66. The maximum number of electrons in an atom with the same value of n is 2n2.
TRUE
Difficulty: Medium
Gradable: automatic
67. Elements in the same period of the periodic table have similar valence shell electron configurations.
FALSE
8-13
Difficulty: Easy
Gradable: automatic
68. Atomic size decreases across a period due to an increase in the effective nuclear charge, Zeff.
TRUE
Difficulty: Easy
Gradable: automatic
69. First ionization energies of neutral atoms may be positive or negative.

FALSE
Difficulty: Medium
Gradable: automatic
70. Bigger atoms generally have smaller ionization energies.

TRUE
Difficulty: Medium
Gradable: automatic
71. Electron affinities of neutral atoms may be positive or negative.

TRUE
Difficulty: Medium
Gradable: automatic
72. Electron affinities become increasingly positive toward the right hand end of a period.
FALSE
Difficulty: Easy
Gradable: automatic
73. A negative electron affinity implies that the atom repels an approaching electron.
FALSE
Difficulty: Medium
Gradable: automatic
74. In moving down a group in the periodic table, the oxides of the elements become more acidic in nature.
FALSE
Difficulty: Easy
Gradable: automatic
8-14
75. In forming ions of the first series of transition metals, the 4s electrons are lost before the 3d electrons.
TRUE
Difficulty: Medium
Gradable: automatic
Subtopic: Electron Configurations of Cations and Anions
76. Which one of the following oxides does not react with water to form acid solutions?
A. CO2
B. SO3
C. BaO
D. NO2
E. Cl2O7
Difficulty: Easy
Gradable: automatic
77. Consider the element with the electron configuration: [Rn]7s25f7. How would you classify this element?
A. a representative element
B. a transition metal
C. a nonmetal
D. an actinide element
E. a noble gas
Difficulty: Medium
Gradable: automatic
Category # of Questions
Accessibility: Keyboard Navigation 77
Bloom's: 1. Remember 26
Bloom's: 2. Understand 33
Bloom's: 3. Apply 18
Difficulty: Easy 23
Difficulty: Hard 10
Difficulty: Medium 44
Gradable: automatic 77
Subtopic: Assigning Electrons to Atomic Orbitals (Aufbau Principle) 15
Subtopic: Development of the Periodic Table 2
Subtopic: Diamagnetism and Paramagnetism 4
Subtopic: Electron Configurations of Cations and Anions 1
Subtopic: Energy-Level Splitting (Zeff and Shielding) 4
Subtopic: Hund's Rule 2
Subtopic: Molecules and Ions 2
Subtopic: Pauli Exclusion Principle 2
Subtopic: Quantum Numbers 9
Subtopic: Trends in Chemical Reactivity 8
Subtopic: Trends in Physical Properties (Atomic Radius, Ionization Energy, Ionic Radius, Electron Affinity) 28
Topic: Chemical Periodicity 42
Topic: Components of Matter 2
Topic: Electron Configuration 24
Topic: Quantum Theory and Atomic Structure 9
8-15

Chemistry The Molecular Nature of Matter and Change 8th Edition Silberberg Test Bank

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Chemistry The Molecular Nature of Matter and Change 8th Edition Silberberg Test Bank

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Chemistry The Molecular Nature of

Matter and Change 8th Edition

3. Which one of the following statements about orbital energies is incorrect?

5. In many-electron atoms, which quantum numbers specify the energy of an electron?

13. Which of the following electron configurations is impossible?

14. Select the correct electron configuration for sulfur (Z = 16).

15. Select the correct electron configuration for Cu (Z = 29).

16. Select the correct electron configuration for Te (Z = 52).

17. The electronic structure 1s22s22p63s23p64s23d8 refers to the ground state of

24. In the electron configuration [Ar]4s23d104p4, which are valence electrons?

44. Select the element with the greatest metallic character.

46. Metallic behavior is generally associated with

49. Select the most acidic compound from the following.

53. Which of the following atoms will be diamagnetic?

54. Which of the following elements is paramagnetic?

56. Select the diamagnetic ion.

69. First ionization energies of neutral atoms may be positive or negative.

70. Bigger atoms generally have smaller ionization energies.

71. Electron affinities of neutral atoms may be positive or negative.

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