MSDS

Material Safety Data Sheets

Date: Jun.29.2023 Report No.: H23062927060110

Section 1 - Product and Company Identification

Product Identification: phosphorus white; phosphorus yellow

Company Name: ADAMA LTD.

Company Address: No. 93, Beijing East Road, Lianhe Street, Shashi District, Jingzhou, Hubei Province

Tel : -

Email: -

Identified uses: Industrial and scientific research uses.

Remark:The MSDS is prepared based on the information provided by client.

Hengwei Testing Technology(Huizhou) Co., Ltd.

HengWei Testing Technology (Huizhou)Co., Ltd.

ADD：No.6, Songlin Road, Zhongkai High-tech Zone, Huizhou, Guangdong Province (Plant C) A
E-mail: info@ctbv-test.com；Tel：0752-2326 891
 MSDS
Material Safety Data Sheets
Date: Jun.29.2023 Report No.: H23062927060110
Page 1 of 6
Section 2 –Hazard identification
Emergency Overview: Spontaneous combustion on exposure to air, fatal if swallowed, fatal if inhaled, causes
severe skin burns and eye damage
GHS Classification
Self-igniting solids, category 1;
Acute toxicity-oral, category 2;
Acute toxicity - inhalation, category 2;
Skin corrosion/irritation, Category 1A;
Severe eye damage/eye irritation, category 1;
Hazardous to the aquatic environment - acute hazard, category 1
GHS labeling elements, including precautionary statements
Hazard type pictogram:

Signal word: Danger

Hazard statement: Spontaneous combustion on exposure to air, fatal if swallowed, fatal if inhaled, causes severe
skin burns and eye damage, very toxic to aquatic organisms
Precautionary statements
Precautionary measures: Keep away from heat sources, sparks, open flames, and hot surfaces. Smoking is
prohibited. No contact with air. Avoid contact with eyes, skin, and wash thoroughly after operation. No eating,
drinking or smoking in the workplace. Avoid breathing dust and vapor. Operate only outdoors or in well
ventilated areas. Wear respiratory protective equipment. Wear protective gloves, protective clothing, protective
glasses and face shield. Prohibit discharge into the environment
Incident response: In case of fire, use misted water to extinguish the fire. Wipe off particles from skin, immerse
contact area in cold water, wrap with wet bandages. If inhaled: Move the patient to fresh air, rest, and maintain
a position conducive to breathing. Skin (or hair) contact: Remove all contaminated clothing immediately. Rinse
skin with water and shower. Contaminated clothing must be washed before reuse. Eye contact: Carefully flush
with water for several minutes. If contact lenses are worn and can be easily removed, remove contact lenses and
continue rinsing. Ingestion: Rinse mouth. Do not induce vomiting. Call a poison control center or seek medical
attention immediately. Collect the spill
Safe storage: Store in a well-ventilated place. Keep containers airtight. Keep under lock and key
Disposal: This product and its contents, containers are disposed of according to national and local regulations
Physical and chemical hazards: spontaneous combustion in contact with air
Health hazards: Acute inhalation poisoning manifests as respiratory irritation, headache, dizziness, general
weakness, vomiting, bradycardia, epigastric pain, jaundice, and hepatomegaly.
HengWei Testing Technology (Huizhou)Co., Ltd.
ADD：No.6, Songlin Road, Zhongkai High-tech Zone, Huizhou, Guangdong Province (Plant C) A
E-mail: info@ctbv-test.com；Tel：0752-2326 891
 MSDS
Material Safety Data Sheets
Date: Jun.29.2023 Report No.: H23062927060110
Page 2 of 6
In severe cases, acute liver necrosis and toxic pulmonary edema appear. Oral poisoning develops oral erosion,
acute gastroenteritis, and even esophageal and gastric perforation. Liver and kidney damage occurs after several
days. In severe cases, liver and kidney failure occurs. This product can cause skin burns, phosphorus absorption
through the burned skin causes poisoning, toxic liver disease, kidney damage, acute hemolysis, etc. in severe
cases, resulting in death.
Chronic poisoning neurasthenia syndrome, digestive disorders, toxic liver disease. Causes skeletal damage,
especially in the mandible, with necrosis of the mandible and atrophy of the alveoli at a later stage.
Environmental hazard Very toxic to aquatic organisms
Section 3 – Composition/Information on Ingredients
Substance/mixture Substance
Chemical Name:
Chemical Formula Concentration(%) CAS NO.
phosphorus white; phosphorus yellow ≥99.5 12185-10-7
Section 4 –First-aid measures
Inhalation : Get out of the scene quickly to fresh air. Keep airway open. If breathing is difficult, give oxygen
infusion. If breathing and heartbeat stop, perform CPR immediately. seek medical attention
Skin contact: Remove contaminated clothing and rinse immediately with plenty of running water. Followed by
the application of 2% to 3% silver nitrate to extinguish phosphorus fire. Also use 1% copper sulfate solution to
rinse. Seek medical attention. Forbid the use of oily dressings
Eye contact: Immediately separate eyelids and rinse thoroughly with plenty of running water or saline for 10 to
15 min.
Ingestion: Immediately drink 0.2% copper sulfate and then stimulate the pharynx with fingers to induce
vomiting of gluten can be repeated several times until the vomit is free of garlic taste. After that, take 10ml of
0.2% copper sulfate solution orally every 10 minutes for 3 times. Then give 25% magnesium sulfate or sodium
sulfate solution orally to induce diarrhea. Do not drink vegetable oil and milk. Seek medical attention
Advice for those who protect the rescuer: use personal protective equipment as needed
Special advice to doctors: treat the symptoms
Section 5 - Fire Fighting Measures
Extinguishing agent Extinguish with foggy water
Special hazard: White phosphorus can spontaneously combust and cause combustion and explosion when in
contact with air. The spontaneous combustion point in moist air is lower than that in dry air. Explosion occurs
when mixed with oxidizing agents such as chlorates. Its fragments and debris on contact with dry skin will
catch fire and can cause severe skin burns. Burning to generate harmful phosphorus oxide

HengWei Testing Technology (Huizhou)Co., Ltd.

ADD：No.6, Songlin Road, Zhongkai High-tech Zone, Huizhou, Guangdong Province (Plant C) A
E-mail: info@ctbv-test.com；Tel：0752-2326 891
 MSDS
Material Safety Data Sheets
Date: Jun.29.2023 Report No.: H23062927060110
Page 3 of 6
Firefighting precautions and protective measures: firefighters must wear full-body acid and alkali-resistant
firefighting suits, wearing air breathing apparatus to extinguish the fire. Move the container from the fire to an
open area if possible. Spray water to keep the fire container cool until the end of the fire
Section 6 –Accidental release measures
Worker protective measures, protective equipment and emergency disposal procedures: Eliminate all ignition
sources. Isolate the spill contaminated area and restrict access. Recommend emergency response personnel to
wear dust masks, anti-static, anti-corrosion, anti-toxic clothing, and rubber gloves. Prohibit contact with or
crossing the spill. Access to ruptured containers and spills is strictly prohibited until appropriate protective
clothing is worn. Cut off the source of the spill if possible
Environmental protection measures: prevent spills from entering bodies of water, sewers, basements or
confined spaces
The method of sheltering and removing spilled chemicals and the disposal materials used: Small spills: Cover
with water, sand or soil, and keep in metal containers and in water. Large amount of spill: Construct a dike or
dig a pit and cover it with moist sand and soil.
Section 7 –Handling and storage
Operating precautions: operate airtight and provide adequate local exhaust air. Operation is mechanized and
automated as much as possible. Operators must be specially trained and strictly follow the operating procedures.
It is recommended that the operator wears a self-absorbing filtering gas mask (full face mask), rubberized gas-
proof clothing and rubber gloves to keep away from fire and heat sources. Smoking is strictly prohibited in the
workplace. Use explosion-proof ventilation system and equipment. Avoid contact with oxidizers, acids and
halogens. Handle lightly to prevent damage to packaging and containers. Equip with appropriate variety and
quantity of fire-fighting equipment and leak emergency handling equipment. Emptying the container may leave
harmful substances
Storage precautions: It should be kept in water and must be submerged underwater to isolate the air. Stored in a
cool, well-ventilated special storage room. The temperature of the storage room should be kept above 1℃.
Keep away from fire and heat source. It should be stored separately from oxidizers, acids, halogens and edible
chemicals, and should not be mixed. Use explosion-proof lighting and ventilation facilities. Prohibit the use of
spark-prone machinery and tools. The storage area should be equipped with suitable materials to shelter leaks.
Section 8 –Exposure controls/personal protection
Occupational exposure limits:
China PC-TWA:0.050.05mg/m3;PC-STEL:0.1mg/
USA (ACGIH) TLV0.1mg/m3
Biological exposure limits: No standard has been established
Monitoring method: Toxic substances in air measurement method: Absorbent collection - gas chromatography
method Biological monitoring test method: No standard set
HengWei Testing Technology (Huizhou)Co., Ltd.
ADD：No.6, Songlin Road, Zhongkai High-tech Zone, Huizhou, Guangdong Province (Plant C) A
E-mail: info@ctbv-test.com；Tel：0752-2326 891
 MSDS
Material Safety Data Sheets
Date: Jun.29.2023 Report No.: H23062927060110
Page 4 of 6
Engineering control: tightly enclose and provide adequate local exhaust air. Provide safety showers and
eyewash equipment
Individual protective equipment:
Respiratory protection: Filtered gas masks (full face masks) should be worn when exposure to toxins is possible
Eye protection: Protection has been made in respiratory protection
Skin and body protection: Wear insulated gas-protective clothing
Hand protection: Wear rubber gloves
Section 9 –Physical and chemical properties
Appearance: Solid
Color: Colorless to yellow
Odour: Garlic odor
Ignition temperature : Not available
pH-value : Not available
Change in condition
Melting point/Freezing point : 280.5℃
Initial boiling point and boiling range : 44.1℃
Flash point : Not available
Flammability (solid, gas): Not available
Auto-ignition temperature: 30℃
Decomposition temperature : Not available
Self-igniting : Product is not selfigniting.
Explosive properties: Product does not present an explosion hazard.
Explosion limits
Lower: Not available
Upper: Not available
Oxidising properties: Not available
Vapour pressure : Not available
Density : 1.88
Relative density: Not available
Vapour density: Not available
Evaporation rate: Not available
Solubility in / Miscibility with water: Insoluble in water
Partition coefficient: n-octanol/water : Not available
Viscosity Dynamic: Not available
Kinematic : Not available

HengWei Testing Technology (Huizhou)Co., Ltd.

ADD：No.6, Songlin Road, Zhongkai High-tech Zone, Huizhou, Guangdong Province (Plant C) A
E-mail: info@ctbv-test.com；Tel：0752-2326 891
 MSDS
Material Safety Data Sheets
Date: Jun.29.2023 Report No.: H23062927060110
Page 5 of 6
Section 10 –Stability and reactivity
Stability: stable
Hazardous reactions: contact with strong oxidizers, halogens, chlorates and other forbidden substances, there is a risk
of fire and explosion
Conditions to avoid contact: Air
Prohibited substances: strong oxidizers, acids, halogens, sulfur, chlorates, etc.
Dangerous decomposition products: meaningless
Section 11 –Toxicological information
Acute toxicity
Oral: LD50: 3.03mg./kg (rat orally); 4.82mg/kg (mouse orally)
Inhalation: no data available
Dermal: no data available
Skin corrosion/irritation
no data available
Serious eye damage/irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
no data available
Reproductive toxicity
no data available
STOT-single exposure
no data available
STOT-repeated exposure
no data available
Aspiration hazard
no data available
Section 12 –Ecological information
Toxicity
Toxicity to fish: LC50：＜0.1mg/L(96h)
Toxicity to daphnia and other aquatic invertebrates: no data available
Toxicity to algae: no data available
Toxicity to microorganisms: no data available

HengWei Testing Technology (Huizhou)Co., Ltd.

ADD：No.6, Songlin Road, Zhongkai High-tech Zone, Huizhou, Guangdong Province (Plant C) A
E-mail: info@ctbv-test.com；Tel：0752-2326 891
 MSDS
Material Safety Data Sheets
Date: Jun.29.2023 Report No.: H23062927060110
Page 6 of 6
Persistence and degradability: no data available
Bioaccumulative potential: no data available
Mobility in soil: no data available
Section 13 –Disposal considerations
Waste chemicals: Dispose of in accordance with relevant national and local regulations, or contact the factory or
manufacturer to determine the disposal method.
Contaminated packaging: Return container to manufacturer or dispose of in accordance with national or local
regulations
Disposal Notes: Please refer to relevant national and local regulations before disposal
Section 14 –Transport information
UN-Number
ADR/RID/ADN, IMDG, IATA : 1381 (dry, or immersed in water or solution); 2447 (molten)
UN proper shipping name
ADR/RID/ADN, IMDG, IATA : White phosphorus (dry, or immersed in water or solution); molten white phosphorus
(molten)
Transport hazard class(es)
ADR/RID/ADN, IMDG, IATA : 4.2,6.1 (dry, or immersed in water or solution); 4.2,6.1 (molten)
Packing group
ADR/RID/ADN, IMDG, IATA : I
Environmental hazards
Marine pollutant: Yes
Section 15 –Regulatory information
Regulatory information: ISO 11014-2009 Safety data sheets for chemical products - Contents and sequence of parts.
Regulation (EC) No. 1272/2008 Classification, labelling and packaging of substances and mixtures.
Section 16 – Other information
16.1 Release record
Date of issue / Date of revision : 2023.06.29
16.2 DISCLAIMER OF LIABILITY
The information in this SDS was obtained from sources which we believe are reliable.However,the information
is provided without any warranty, express or implied,regarding its correctness.The conditions or methods of
handling,storge,use or disposal of the product are beyond our control and may be beyondour knowledge.For
this and other reason,we do not assume responsibility and expressly disclaim liability for loss,damage or
expense arising out of or in any way connected with the handling,storage,use or disposal of the product.This
SDS was prepared and is to be used only for this product.If the product is used as a component in another,this
SDS information may not be applicable.

HengWei Testing Technology (Huizhou)Co., Ltd.

ADD：No.6, Songlin Road, Zhongkai High-tech Zone, Huizhou, Guangdong Province (Plant C) A
E-mail: info@ctbv-test.com；Tel：0752-2326 891