SET : C DATE : 25/06/2023

KEY & HINTS _ - ( - ) MAX.M.120

(PHYSICS & CHEMISTRY)

19. (A)

t1t 2
When both moves in same direction, t = =
+ t1 + t 2
t1 t2

20. (A)
21. (C)
22. (C)
23. (A)
24. (A)
25. (ACD)

26. (AC)

v AB = (3 − a) ˆi + (3 − b) ˆj (10,5)

vAB B
aAB = o
A
( 3 − a )  2 = 10 and ( 3 − b )  2 = 5 (0,0)

1
a = –2 and b =
2

27. (AD)
28. (ABCD)

u2 u2
h1 = sin2  and h2 = cos2 
2g 2g

u2
R= 2sin  cos 
g

u2 2gh1 2gh2
R= 2 , R = 4 h1h2
g 4 4

t1 2u sin  / g
= = tan 
t 2 2u sin ( 90 −  ) / g

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29. (ACD)
The body is at rest initially and again comes to rest at t = 1 second at position x = 1
Thus, firstly acceleration will be positive then negative
Thus, (  ) have to change the direction so that body may finally come to rest in the interval 0  t  1
If we plot v − t graph

1 2s
Now, .vmax t = s  Umax =
2 t
2 1
vmax = = 2m / s
1
Thus, maximum velocity = 2m / s
Now, just see the v − t diagram,

During AB   4m / s2
For ABE,
During BE   −4m / s2

During AC  = 4m / s2
For ACE
During CE  = −4m / s2

During AD   4m / s2
For ADF
During DE   −4m / s2

Thus,   4 , at some point or points in its path

30. (BC) a(m/s)2

1 v2 6
Area =  10  ( 6 + 4 ) =
2 2 4
v = 10 m/s
S(m)
1 v2 10 30
Area upto 30 m =  30  6 =
2 2
v 2 = 180
v max = 180  14

31. (45)
u2 sin2  u2 sin 2 45 1
H= and R = , = tan    = 45°
2g g 180 4
32. (05)
33. (01)
u 5 2 2
t= = = 1 sec.
g sin  10

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34. (45)
r = 3iˆ + 4ˆj , w = F.r = 21 + 24 = 45 J
35. (18)
We have, F = (12 – 2t)
dv
or, m = (12 − 2t ) , where m is the mass of the body
dt
dv  12 − 2t 
or, =
dt  m 
v t
1
 dv = (12 − 2t ) dt
0
m 0

12t − t 2
or, v =
m

or,
dx
=
(
12t − t 2 )
dt m
0 t

 dx =
1 1
m 0
( )
12t − t 2 dt, where t1 is required time.
0

1  2 t13 
or, 0 = 6t1 − 
m  3 

or, t1 – 18 = 0
t1 = 18s
36. (15)
Horizontal component of velocity of A is 10 cos 60° or 5 m/s which is equal to the velocity of B in
horizontal direction. They will collide at C if time of flight of both the particles are equal i.e.
tA = tB
2u sin  2h  1 
= h = gtB2 
g g  2 

2u2 sin2 
or h =
g
2
 3
2(10)  2

 2  = 15 m
10
37. (D)

hc 6.626  10−34  3  108

= w 0 + KE (but KE = 0);  = −19
= 3.1 × 10–7 m = 3100 Å.
 4  1.6  10
38. (A)
When l = 2
Volume of m = –2, –1, 0, 1, 2.

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39. (A)
Z
The velocity of an electron in the H–atom is given by Vn =  2.188  108 cm s–1.
n
For the first orbit of H–atom, Z = 1 and n = 1.
 V1 = 2.188  108 cm s–1.
For n = 2,

2.188  108 V2 1
V2 = cm s–1 ; =
2 V1 2

Thus, velocity is halved.

40. (C)
n(n − 1)
By nC formula ie. Total number of transitions = .
2 2
41. (A)

1 1 1 
= RHZ2  2 − 2  …. (i)
P 3  

1 1 1 
= RHZ2  2 − 2  ….(ii)
B 2  
Dividing (ii) by (i),
1
P 4 9
= = .
B 1 4
9
42. (A)
r1 = x

r4 = 16x ( r  n2)

h
also  = ……(i) (from de Broglie equation)
mv
nh
and mvr = ……(ii)
2
from (i) and (ii)
2r = n
2r
=
n
 Wavelength of electron in 3rd orbit.
2r3 2 16 x
3 = = = 8x.
n3 4

43. (BC)

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44. (ABC)

n2
rn = a0 
z

72 12
r7 − r1 = a0  − a0 
1 1

= a0 ( 49 − 1) = a0  48

62 12
r6 − r1 = a0  − a0 
1 1
= a0  35

52 12
r5 − r1 = a0  − a0  = a0  24
1 1
45. (AB)
46. (ACD)
47. (AB)
48. (BC)
n – l –1 = no. of radial nodes;
l = no. of angular nodes.
n – 1 = Total no. of nodes
n – l – 1 = l  n – 1 = 2l

49. (03)
50. (25)
51. (50)
Meq. of KMnO4 = 40 × 0.25 = 10
Meq. of CaO = 10
1
gm eq. of CaO = 10  10−3 =
100
1 56
Mass of CaO =  = 0.28 gm
100 2
0.28
% of CaO =  100 = 50%
0.56

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52. (99)

XO + K2Cr2O7 ⎯→ Cr3+ + XO−4 X2O3 + K2Cr2O7 ⎯→ Cr+3 + XO−4

Let the atomic weight of X be ‘a’ and weight of XO in the mixture be ‘x’ gm.

[ n–factors of XO and X2O3 are 5 and 8 respectively]

Equivalents of K2Cr2O7 consumed by the mixture = 0.015 × 6

x 2.18 − a
Equivalents of XO =  5 ; Equivalents of X2O3 = 8
a + 16 2a + 48

x 2.18 − x
 5 +  8 = 0.015 × 6 …(i)
a + 16 2a + 48

Since 1 mole of XO gives 1 mole XO−4 and 1 mole of X2O3 gives 2 moles of XO−4 ,

x 2(2.18 − x )
 + = 0.0187 …(ii)
a + 16 2a + 48
On solving (i) and (ii) we get a = 99
Atomic weight of X is 99.
53. (05)

1
5e− = +
2
1
5e− = −
2
54. (04)
Energy of incident photon should be higher than work function to slow photoelectric effect

6.62  10−34  3  108

Energy of photon = = 4.14 eV
300  10−9  1.6  10−19

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