Anode: Source of «© a4 -Y¥e Cathode: Sink for © 4 tNe = Tupac; LAG —> Left Anode Oxidation (sor) Anede; Zn(s) ——9 Zn2t + ge& a zeit =? ay) (oxde) Frat | zn = - Oey (SRP) Cathode! Cu? * (ag) + VF —— cu ls) Feaaryeas Oo ( Redn) (sep) Cupar? = 7 O-3ey (sor) Overall vent Zo ts) + Cu** (aq) ——+ Zn3* (ay) + Cuts), not ot e® involved in the van (nm) =2> cell potential / EMF of ce? 4 Standard conditions * Calculation of The potential difference between Cett_potentiats ( £° 4,) the two half cells ie cathode ond anode.Een = & + . =o . tt Zn |zn* Cutt|cy = OREN t OBRY = tly Eve = SRP (cathode) — SRP (anede) | & - = ight : “Righ ot = Beatiea — Baaapzy 2 e8ty> Foe) = hy “ce = SOP (anode) — SOP (cathode) pee eee Eset) eS ° In| Zn? 7 - & Vz Cul Cy* FO O#EY - ~ORQy 2 IN Reaction Guotien? (Q) 3 Zn (8) + Cu®t (ag) ——— Cu (s) + Zn? tlaq). = Representation of galvanic cell: Tupac: Anode \| Coth ode t sat bridge: Anede Gheuld be written in terme sf Onidation andCothede in term: of reduction + Daniel cell? Za] Za™* || cal | Gu (s) © (aq) fey &) Species in different phaser mut be Separated by single verHeal Line bd = specie in same phase can be Separated — by comma 8 Als) + 8° (aq) ——> A®* (aq) + 80s), Anode is made up ot Platinum Cathode is made up of graphite. SEE MIS) ated] AP CaP) |] Bt Cay) | BE), Cgre. Nerst Equation ¢ Ecey —? Calculated Ecell < At any ther condition 4 Using Nernst eqn: ¢ = Ecell @an be calowated iF Fvcel is Knnon: [ae = Sa° + RT ANG F2 Faraday const: 3 Fee = Even -_ RT ge, Fz 96500C~- Faraday tonst - is charge prac en ene mole # &2.303RT 2 0-053. Ji foamia es boaeit F = = 965000 eeu = Eten = ees. = at ACs) + tty) —— “op Dp o-tm r07 8 . Ovorm Eg ett 2 -Sy Een 2? SRP (cathede) — SRP (an ode) : ° a ne Betia — Etta = S¥ — 1¥ © 4y¥ Qo? = Ecen ot 298K. Anode: (a = =—— ad + oe) x2 cotnode (87+ + 2e®@ ——> B.)x3 + on 4 gett ——4 20°F + 38 (0) (s) cag) oy) n= & = [a] * = (et ten! Ca")? ten? Ecet = Evcett ~_0:059_ tog 8 = 4y- en6 2 aN OOH é > Fv + o-ol¥ > 4qeoy = For spon galvanie cet; at = —ve — Ecell = tye Eceu = tre grrer'e <= = Ecem = —ve —9 — electrolyte cet. Slee energy —a chem 4 cnerpy. Bate =