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FIITJEE

ALL INDIA TEST SERIES


JEE (Advanced)-2023
FULL TEST – IV
PAPER –2
TEST DATE: 08-02-2023

ANSWERS, HINTS & SOLUTIONS


Physics PART – I

Section – A

1. C
Sol. For upper portion:
 1 1.5  1
f1  2 (fa )   20  40 cm
2 1.5
1 1
1 1.2
 1
For lower portion, f1  2 (fa )
2
1
3
1.5  1
=  20 = –25 cm
1.5
1
2.5
 Object is at infinity, images will be form at focal points.
Hence the distance between two images will = 40 | 25 |  65 cm

2. B
R2  dB 
Sol. E  
2R1  dt 
 R2  dB 
e.m.f =   2R1
2 2R1  dt 
 2  dB 
= R  
2  dt 

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AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023 2

3. D
Sol. As  > 1
dT
for TV – 1 = constant 0
dv
and for T = KP – 1
dT
0
dP

4. A
0.8
Sol. y
3(x  2t)2  4
v = 2 m/s
A = 0.2 m

5. AC
Sol. AOB is zero potential surface F3
F1
+q –q
Induce charge = –q
F2
kq2 kq2
F 2 A
a2 2a2 O

–q +q

6. AC
 n(n 1) 
Sol. I1  r   Ix  nE where x external resistance
 2 
 n(n  1) 
Im  r   Ix  mnE
 2 
I1 + I2 + I3 + …….. + Im = I
n(m  1)E
2 V
 I 
n(n  1) x R
x r
2m

7. CD
dQ KA( T) KA[0  ( )] dQ KA
Sol.   ; 
dt x x dt x

8. ACD
Sol. y ( x, t) = –cos kx sin t
 2   2 
y(0.05, 0.05) = 4 cos  0.05  sin  0.005 
 0.4   0.2 
  
= 4 cos   sin    2 2 cm
4 2

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3 AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023

0.4
v  f  = 2 m/s
0.2
y
  A  cos (kx) cos ( t)
t
 2   2 1   2 
= 4   cos   cos  0.1
 0.2   0.4 15   0.2 
y
= 20  cm/sec = particle velocity
t

9. AC
A T
Sol. In SHM, time taken to move from x = 0 to x  is and time taken to move from
2 12
A T
extreme to x  is .
2 6
T
If =1  T = 12
12
T
If =1  T = 6.
6

10. ABC
GMm GMm GMm
Sol. Es  ; E1  ; E2 
R 2(2R) 2(3R)
3
E1  Es  mgR
4
mgR
E2  E1 
12

Section – B

11. 9
Sol. Path difference between rays reflected from upper and lower faces of layer = 2t cosr =
2 t (for normal incidence). But there is change in path of /2 of light at upper surface
due to reflection from denser medium. So actual path difference is 2 t – /2.


For constructive interference 2 t   n
2
(2n  1) 
t . For least thickness n = 0.
4

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AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023 4

 648
 tmin   nm = 90 nm
4 4  1.8

12. 5
mZ2 e4 mZ2e 4  1 1
Sol. En   , so hf   2 2  16

802n2h 2
8  0h  25 
mZ2e 4  9 
 f  
820h3  16  25 
Z 2 e 2m Z 2 e 4m
and frequency f4  
402n3h3 402 (4)3 h3
f 18
 = , so m = 5.
f4 25

13. 4
Sol. When the two spheres come in contact, they exert equal and opposite impulse.
 Fa dt  I1(0  1 ) …(i)

 Fb dt  I2 2 …(ii)
Finally 1a  2b …(iii)
2
a
I1( 0  1)  I2 1
b2
I10
1  = 4 rad/s.
a2
I1  2 I2
b

14. 5
Sol. Let the volume of the cylinder be V. When the cylinder is floating , upthrust = weight.
Hence,
3  4m
  V  g  mg  V 
4  3
Let the acceleration of the particle vessel be A (upwards). In the
reference frame of the vessel, the acceleration of the cylinder is
A/3.
A
 mg + mA – upthrust = m  
3
A
mg + mA – Vg = m  
3
where g = g + A = effective value of g for upthrust.
A
 mg + mA – V (g + A) = m  
3
4 2
 mg  m(g  A)  m A
3 3

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5 AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023

 g
A     upwards
 2
g 10
The acceleration of the vessel should be  = 5 ms–2 (downwards).
2 2

15. 6
Sol. Let the pressures in wide and narrow limbs be P1 and P2, respectively. If R1 and R2 be
the radii of meniscus in wide and narrow limb, pressure just below the meniscus of wide
2T 2T
tube = P1  and pressure just below the meniscus of narrow limb = P2  .
R1 R2
Therefore, difference of these pressures
 2T   2T 
 P1     P2  hg
 R1   R2 
Therefore, true pressure difference,
 1 1
P1  P2  h  g  2T   
 R2 R1 
For the water and glass surface, taking the angle of contact  to be zero, we have
r r
R1  1  r1 and R 2  2  r2 where r1 and r2 are radii of wide and narrow limbs,
cos  cos 
respectively.

 1 1  1 1 
P1  P2  h  g  2T     0.2  103  9.8  2  72  10 3    4
 3 
r r
 2 1  7.2  10 1.44  10 
= 1.96 × 103 – 0.10 × 103 = 1.86 × 103 N/m2 = 1860 N/m2
 N = 6.

16. 8
q
Sol. J = E =
20r 3

q + – –
I= +
 J 2xdx  0  + –
0
+ –
q + – –
V   IR + –
20 a +

 R = 0.50
2a
 n = 8.

17. 4
2C1C2  C2C3  C3C1 7
Sol. Ceq  
C1  C2  2C3 5

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AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023 6

Where C1 = 1, C2 = 2, C3 = 1
4

3 4
2 4 4
B A
8
6
4 8

20
Req = 6
 = RC = 8.4
 n = 4.
18. 2
Sol. Component of acceleration along incline is g sin 
and effective acceleration along groove is a = sin 
cos .
h
From figure   OB
sin 
OA is the groove making an angle  = 45° with AB
on the inclined surface.
OB
From figure,  cos 
OA
h
or OA 
sin  cos 
Since acceleration along groove is constant, we
1
may use equation s  at 2 .
2
 k = 2.

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7 AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023

Chemistry PART – II

Section – A

19. C
Sol. O
Intermediate is
COOH
Which loses CO2 on heating (-keto acid)
20. B
Sol. M absorbs some heat energy and prevents decomposition of O3
21. C
Sol. Tf  4Ti
Tf v
S  nC V ln  nRln f
Ti v1
3R v
0  n ln 4  n.Rln f
2 v1
3 v
log4  log i
2 vf
vi
43 /2 
vf
8v f  v i
Tf Pi
0  S  nCp ln  nR.ln
Ti Pf
Pf
45/ 2 
Pi
32Pi  Pf

22. D
Sol. At ¼ th and 3/4 th neutralization points the solution is buffer solution. Upon substitution
we can get the ans.
23. ACD
Sol. - O
O
H3C O O O-

O CH3
Br
Br -
O

H3C +
O O

Br

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AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023 8

24. AC
Sol. Azeotropic mixture has fixed composition.

25. ABC
Sol. Rate = k[X][Y]0  2  10-8 = k[0.1] [0.1]0  k = 2  10–7s–1

26. ABC
Sol. CaC2  2H2O  Ca  OH2  C2H2
Mg3N2  6H2O  3 Mg  OH2  2NH3
Na2S  2H2O  2NaOH  H2S
KNO3  H2O  No reaction

27. ABCD
Sol. Cl
Ph Ph
Cl 2 Ph

Cl

Cl-

dichloroproduct

28. BCD
Sol. The geometrical isomers of (B) are
NH2 NH2 NH2
O
CH2 CH2 CH2
Pt C O O C
O C Pt C O
CH2
O O O
H2 N
Cis trans
The geometrical isomers of (C) are
Cl Cl Cl (C2H5)3P Cl Cl
Pt Pt Pt Pt
(C2H5)3 P Cl P (C2H5)3 Cl Cl P (C2H5)3

Cis trans
The geometrical isomers of (D) are

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9 AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023

2- 2-
NH 3 NH 3

NH3 CN NC CN

Fe Fe

CN CN NC CN

CN NH3

Cis trans

Section – B

29. 6
NO 2
N
Sol. Compound (Z) is
N N
O 2N NO 2

30. 4
Sol. (4n + 2)e– rule

31. 3
Sol. 5C2H5 – 5e–
2 CO – 4e–
Mo – 6e–
Mo – Mo – 3e–

32. 3
Na Fe CN NO 
Sol. S 2  HCl  2
 H2S 
NaOH
5 
 Na 4 Fe(CN)5 NOS 

33. 5
25  10 3  g  16  10 3  g 
Sol. 
250 250  x18
X=5
34. 4
Sol. O O

O O

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AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023 10

35. 4
Sol. (1) ala-phe-leu-gly
(2) ala-phe-gly-leu
(3) ala-leu-phe-gly
(4) ala-leu-gly-phe

36. 3
Sol. It exists in two geometrical isomeric forms in which trans isomer is optically active.

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11 AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023

Mathematics PART – III

Section – A

37. A
Sol. Since for two square matrices A & B the trace of AB – BA is zero.
a b 
 let AB  BA   
 c a 
 (AB – BA)2 = k I2
where k = a2 + bc
and odd power of AB – BA is equal to a multiple of this matrix.
i.e. odd power it can not be equal to I2
 ‘n’ is even.

38. B
Sol. A2B2 = rB4
B2A2 = rB4
 A2B2 = B2A2
& rB2A = rAB2 = A3
Multiplying pAB + qBA = In on the right and then on the let by B, we obtain
pAB2 + qBAB = B
pBAB + qB2A = B
also we have B2A = AB2
on subtraction (p – q) (AB2 – BAB) = 0
if p  q then AB2 = BAB
 (p + q) AB2 = (p + q) B2A = B
 (p + q) A2B2 = AB
& (p + q)B2A2 = BA
 AB = BA
which is a contradiction
p=q

39. A
dy  cos3x x3
Sol. Integrating the given differential equation, we have   ex   C1 but
dx 3 3
 1  1
y1  0   1 so 1     1  C1  C1  .
3  3
 sin 3x x4 1
Again integrating, we get y   ex   x  C2
9 12 3
 sin 3x x4 1
but y  0   0 so 0  0  1  C 2  C2  1 . Thus y   ex   x 1
9 12 3

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AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023 12

40. B
Sol. Let the radius of the circle is equal to 1. Set the origin at B with BA the positive x – semi

axis and t the y – axis. If BOM  , then BP  PM  tan . In triangle PQM, PQ
2
   
tan  tan 2   1 sin  
 2 . So the coordinates of Q are ,tan    ,
 .
sin   sin  2   1  cos  1  cos  
 
The x and y coordinates are related as follows:
2
 sin   1  cos2  1  cos  1
   2
 2  1.
 1  cos   1  cos   1  cos  1  cos 
2
Hence the locus of Q is the parabola y  2x  1.

M
N

A O B

41. BC
 0 1  2
Sol. 4a  2    2
 2  2

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13 AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023

42. BCD
Sol. Put  a  r cos ,2  r sin   to equn. of ellipse
a 2  r 2 cos2   2ar cos 

9
2 2
4  r sin   4r sin 
 1 0
4
4a2

4 cos2   9 sin2 
Put  a  r cos ,2  r sin   to equation xy  0
a2
 PA PD   9
cos2  sin2 

9 4

 2a  r 2 sin  cos    a sin   2 cos   r  0


2a
 PB PC  
sin  cos 
PA .PD  PB.PC
4a 2 2a
 
4 cos2   9 sin2  sin  .cos 
4 cot   9 tan 
a
2
 a  49 6
 a   ,  6   6,  

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AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023 14

43. CD
Sol. If  is a multiple of , then I     0 . Otherwise, use the substitution
x  cos   t sin  . The indefinite integral becomes
sin  dx dt
 1  2x cos   x2  1  t 2  art tan t  C .

 1  cos    1  cos  
 I     arctan    arc tan  ,
 sin    sin  
 
where the angles are to be taken between  and . But
2 2
1  cos  1  cos 
  1.
sin  sin 

Hence the difference between these angles is  . Notice that the sign of the integral is
2
 
the same as the sign of  . Hence I     if    2k,  2k  1   and  if
2 2
    2k  1 ,  2k  2    for some integer k.

44. AD
Sol. k1u  k 2 v  0 ……….(i)
k1u  k 2 v  0 ………..(ii)
 equations of bisectors of the angles formed by lines (i) and (ii) are
k1u  k 2 v
2 2
 ak1  bk 2    k1b  ak 2 
  k1u  k 2 v 

2 2
 k1a  bk 2   k1b  ak 2 
 k1u  k 2 v    k1u  k 2v  ………..(iii)
(i) by taking positive sign in (iii), we get
k1u  k 2 v  k1u  k 2 v
2k 2 v  0  v0
(ii) by taking negative sign in (iii), we get
u0

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15 AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023

45. BD
3
 1
 x  1 x 
Sol. After we bring the function into the form f  x  
  , let x  1  s
1 x
x3  1  3
x
3
 s  1  1  3s  6s over the domain ,  2  2,  . Setting the
2
h s  3
s  3s  1 s3  3s  1
   
3 2
first derivative equal to zero yields the equation 3  s  1 s  3s  2  0 .  
The roots are s = 1 (double root) and s  1  3 . Of these, only s  1  3 lies in the
domain of the function.
We compute
3
lim h  s   1, h  2   1, h  2   9, h 1  3 
x 
  2 3
.

46. AC
Sol.
R(z + iz)

Q(iz)

P (z)

Section – B

47. 3
Sol. Equation of the chord of contact of a point P  3 sec , 2 tan   on the hyperbola with
respect to the circle is  3 sec   x   2 tan   y  9 (1)
Let M (h, k) be the mid point of (1), then equation of (1) in terms of the mid – point is
hx  ky  h2  k 2 (2)
Since (1) and (2) represent the same line.
3h 9k
sec   2 , tan   s
h k 2
2 h  k2
2
 

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AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023 16

 locus of (h, k) is
9x 2 81y 2
 2
 2
1
 x 2  y2  4  x2  y 2 
2

or 4 x 2  y 2   bx2  cy 2
 a  4, b  36, c  81
a  b  c 2  16  1296  6561  7873
2 2

48. 5
Sol. Let r  b  c and c    xi  yj  . Since c and b are perpendicular, we have
 4 
4x  3y  0  c  x i  j 
 3 
r .b  b  c  .b b.b
1  proj. of r on b   
b b b
 b.c  0 
1
  b  5 . Hence  
5
r .c
Also, 2  proj. of r on c 
c


 b  c  .c   c 
5
x
c 3
6
Thus, x   . Therefore,
5
1 6 4 
r   4i  3j    i  j     2i  j 
5 5 3 
1 6 4   2 11 
r   4i  3j    i  j      i  j 
5 5 3   3 5 
Thus there are four such vectors
4 2
2 2 2 11
i 1
ri  2 2i  j  2  i 
5 5
j  20

49. 1
Sol. Let f  x   sin x  tan x  2x . Then g  x   f '  x 
 cos x  sec 2 x  2
 g'  x    sin x  2 sec 2 x tan x
 2 
 sin x  1 
 cos3 x 
 1  cos3 x  1 
 sin x  
 cos3 x 

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17 AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023


Since for 0  x  , we have 0  cos3 x  1, g is an increasing function. Hence
2
g  x   g  0  , i.e. cos x  sec 2 x  2  0 . Therefore f is an increasing function, so
  1
f  x   f  0  for 0  x  . Hence sin x  tan x  2x . Thus g    1
2 4 2

50. 1
Sol. The inverse of 2 × 2 matrices C = [Cij]2×2 with integer entries is a matrix with integer
entries if and only if |c| =  1
 1 adj  C  1 
C  & C 1  
 C C 
So lets take a polynomial.
P(x)  A  xB
as per the problem P(0),P(1),P(2),P(3),P(4)  1,1
three of these must be same
and P(x) has degree at most 2.
 it is constt.
 A  xB  1, x
 A  5B  1

51. 2
Sol. a1  a3  ...  a99  50
 a   a  2d    a  4d  ...   a  98d  50
 50a  2d 1  2  ...  49   50
2d  50  49 
 50a   50
2
 a  49d  1
 a1  a3  a5  a7  a9  a11  ...  a 93  a 95  a 97  a99
(26 negative terms and 24 positive)
 a1  a99  2a  98d  2  2
52. 1
Sol. Given a  b  c  1 ………(1)
9a  3b  c  7 ………(2)
18  25a  5b  c  22 ………(3)
 From above (1), (2) and (3) 4  7a  b  c  8
4  7a  b  a  1  8
5  8a  9
a  1, b  1, c  1
a  1, b  1, c  1

For question (2) h  x   ln x  x  1  x
2

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AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023 18

53. 4
i1
Sol. Let z1  z1e and
z1 z 2  z1z 2  z1z2  z1 z 2
z2  r2 ei2   2 cos  1  2   2cos  1  2 
z1z 2

54. 3
abc abaac
Sol. 
ba ba
2a  c
 1
ba
2
Now: f  x   ax  bx  c
Given f  x   0  x f  2   0
4a  2b  c  0
2a  c  2  b  a 
2a  c
2
ba
abc
 3
ba

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