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Numericsl Chapter 2-1
Numericsl Chapter 2-1
Answer:
Λ°m(HAC) = λ°H+ + λ°AC–
= λ°CH3COOH = λ°H+ + λ°CH3COO–
= 349.6 S cm2 mol-1 + 40.9 S cm2 mol-1
= 390.5 S cm2 mol-1
9. Calculate the emf of the following cell at 25°C : Ag(s) | Ag+ (10-
3
M) || Cu2+ (10-1 M) | Cu(s) Given E0cell = +0.46 V and log 10n = n.
(All India 2013)
Answer:
Given: Cell notation is incorrect. Correct cell formula is
Cu2+ (10-1 m) | Cu(5) || Ag+ (10-3 M) | Ag(s)
According to Nernst equation
= -2 × 96500 × 2.71 (∵ n = 2)
= -523,030 J mol-1 = -523.03 KJ mol-1
(b) Fuel cell was used in Apollo space programme for providing
electrical power
11. Calculate emf of the following cell at 25°C :
Fe | Fe2+ (0.001 M) || H+ (0.01 M) | H2(g) (1 bar) | Pt(s)
E0(Fe2+ | Fe) = -0.44 V E0(H+ | H2) = 0.00V (Delhi 2015)
Answer:
Fe | Fe2+ (0.001 M) || H+ (0.01 M) | H2(g) (1 bar) | Pt(s)
= 0.4105 Volts
12.Conductivity of 2.5 × 10-4 M methanoic acid is 5.25 × 10-5 S cm-
1
. Calculate its molar conductivity and degree of dissociation.
Given : λ0(H+) = 349.5 Scm2 mol-1
and λ0(HCOO–) = 50.5 Scm2 mol-1. (All India 2015)
Answer:
Concentration is 2.5 x 10-4 M
K = 5.25 × 10-5 Scm-1.
Λcm=K×1000 Concentration
ELECTROCHEMISTRY - NUMERICALS
.
13.Calculate e.m.f. of the following cell at 298 K: 2Cr(s) +
3Fe2+ (0.1 M) → 2Cr3+ (0.01 M) + 3 Fe(s)
Given: E0(Cr3+| Cr) = -0.74 V E0(Fe2+ | Fe) = -0.44 V (Delhi 2016)
Answer:
Cell reaction: 2Cr(s) + 3Fe2+ (0.1 M) → 2Cr3+ (0.01 M) + 3Fe(s)
Given: E0(Cr3+/Cr) = -0.74
E0(Fe2+/Fe) = -0.44 V
ELECTROCHEMISTRY - NUMERICALS