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12.12.21 - SR - STAR CO-SC - MODEL-A & B - Jee - Adv - 2017 - P1 - PTA-12 - QP - F
12.12.21 - SR - STAR CO-SC - MODEL-A & B - Jee - Adv - 2017 - P1 - PTA-12 - QP - F
12-12-21_SR.STAR CO-SUPERCHAINA(MODEL-A&B)_JEE-ADV_PTA-12_SYLLABUS
CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions With Multiple Correct Choice
Sec – I (Q.N : 19 – 25) +4 -2 7 28
(partial marking scheme) (+1,0)
Sec – II (Q.N : 26 – 30) Questions With Integer Answer Type +3 0 5 15
3 column paragraph
Sec – III (Q.N : 31 – 36) +3 -1 6 18
Questions With Single Answer Type
Total 18 61
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions With Multiple Correct Choice
Sec – I (Q.N : 37 – 43) +4 -2 7 28
(partial marking scheme) (+1,0)
Sec – II (Q.N : 44 – 48) Questions With Integer Answer Type +3 0 5 15
3 column paragraph
Sec – III (Q.N : 49 – 54) +3 -1 6 28
Questions With Single Answer Type
Total 18 61
A) The maximum volume of the water that can be stored when the vessel is accelerated
is hcb 2
hcb hg
C) Force F that must be applied when maximum water stored is M
2 c
hcb lg
D) Force F that must be applied when maximum water stored is M
2 c
4. A circular cylinder of radius ‘R’ and height ‘H’ is filled with water to a height 2 / 3 H .
It starts rotating about its axis with constantly increasing angular speed. Choose the
correct alternatives
2 1 mg
2 1 mg
7. A light cylindrical tube T of length l and radius r containing air is inverted in water of
density d. One end (lower end) of the tube is open and the other end (upper end) is
closed. A block B of density 2d is kept on the tube as shown in figure. The tube stays in
equilibrium in the position shown. (Assume the atmospheric pressure to be P0 ) Pick up
the correct statement(s)
r 2l
A) The volume of block B is
3
2 r 2l
B) The volume of block B is
3
9. A closed tube of length ‘ l ’ completely filled with water has a small air bubble trapped in
it. When the tube is held at an angle 300 with vertical and rotated at a constant angular
velocity ' ' about the vertical axis through its lower end, the bubble settles at some
intermediate position in the tube. The distance of the bubble from the lower end of the
10. A plastic sphere of radius ‘r’ floats almost fully submerged in a liquid as shown in the
figure. Density of the liquid is , acceleration of free fall is ‘g’. The force exerted by the
liquid on the lower half of the sphere excluding contribution of the atmospheric pressure
n
is r 3 g . Find ‘n’
3
12. A soap bubble for radius ‘r’ is made in vacuum by blowing a diatomic gas in it. Surface
tension of the soap solution is and density . The molar specific heat of the gas in the
bubble in terms of molar gas constant R is nR . Find ‘n’
SECTION – III
(SINGLE CORRECT ANSWER TYPE)
This section contains 6 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
Answer Q,13, Q,14 and Q,15 by appropriately matching the information given in the three
columns of the following table.
Having obtained the value of the resultant thrust on an immersed vertical plane in a ideal
static fluid, we can determine the point of the plane through which this resultant force
acts, then this point being known as centre of pressure. This is the point about which
torque of the thrust force is zero. In each of the cases in column-I a vertical plane is just
submerged in a liquid over which atmospheric pressure is to be neglected. Column-II
refers to the thrust force (F) by liquid on the one side of the plane and Column-III refers
to the depth of the centre of pressure from the liquid surface in each case. Take the
product of density of liquid and acceleration due to gravity as 1 unit.
Column-I Column-II Column-III
I) A unit square plate just immersed in the i) 1 P) 5
3 4
liquid with its edge horizontal
T 0.075 N / m, R 0.5mm
103 kg / m3 , H 4cm
T 0.075 N / m, R 0.5mm
103 kg / m3 , H 2cm
T 0.075 N / m, R 0.5mm
0.5 103 kg / m3 , H 8cm
T 0.075 N / m, R 0.5mm
0.5 103 kg / m3 , H 2cm
A) Cu 1 disproportionates.
B) Cu and Cu 2 comproportionates (reverse of disproportionation into Cu )
C) E 0Cu|Cu E Cu
2
0
1
|Cu
is positive
D) All of these.
25. The standard reduction potentials of some half cell reactions are given below:
PbO 2 4H 2e Pb 2 2H 2O E 0 1.455V
MnO 4 8H 5e Mn 2 4H 2 O E 0 1.51V
Ce 4 e Ce3 E 0 1.61V
SR.IIT_*CO-SC Page. No. 11
Narayana IIT Academy 12-12-21_SR.IIT_*CO-SC(MODEL-A&B)_JEE-Adv_PTA-12_Q’P
H 2 O 2 2H 2e 2H 2 O E 1.71V
0
27. 100 ml, 0.05M CuSO 4 solution is electrolyzed by using current of 0.965A for 100min.
Find the pH of solution at the end of electrolysis.
28. The E 0cell 1.18V for
Zn(s) | Zn 2 (1M) || Cu 2 (1M) | Cu(s)
x
Determine the value of if when excess granulated zinc is added 1M Cu 2 solution the
10
2.303RT
[Cu 2 ]eq. becomes 10 x M . (T 298K, 0.059)
F
29. The e.m.f. of a cell corresponding to the reaction
Zn 2H (aq) Zn 2 (0.1M) H 2 (g)(1 atm)
is 0.26 volt at 25º C . Calculate the pH of the solution at the hydrogen electrode.
30. For the cells in opposition,
Zn(s) | ZnCl2 (sol.) | AgCl(s) | Ag | AgCl (s) | ZnCl2 (sol.) | Zn(s)
C1 0.02M C2 0.5M
emf RT
Find out the (in millivolt) of the resultant cell? (Take log 2 0.3, at 298 K 0.060)
14 F
Answer Q,34, Q,35 and Q,36 by appropriately matching the information given in
the three columns of the following table.
Column I Column II Column III
(i) Lechlanche (a) Cell reaction (p) R x n at cathode
cell 2H 2 O 2 2H 2 O
MnO 2 NH 4 e MnO(OH) NH 3
(ii) Ni – Cd cell (b) Does not involve any ion in (q) R x n at cathode
solution and is used in NiO H 2 O 2e Ni 2OH –
hearing aids
ellipse
x 5
2
y 3
2
48. A semicircle is drawn outwardly on chord AB of the circle with centre O and unit radius.
The perpendicular from O to AB meets the semicircle on AB at C. Then length of AB so
that OC has maximum length is K . Then K is equal to,
2) 2x y 5 0 b) length of perpendicular Q) 15
distance from origin 2
between coordinate
axes
xy = 0
52. Which of the following is a CORRECT combination ?
A) 1,d,P B) 1,b,S C) 1,d,R D) 2,c,Q
53. Which of the following is a CORRECT combination ?
A) 3,b,R B) 3,c,P C) 3,a,Q D) 4,b,Q
54. Which of the following is an INCORRECT combination ?
A) 2,a,Q B) 4,c,S C) 1,a,P D) 4,d,Q