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RPTA-8

NARAYANA IIT ACADEMY


INDIA
Sec: Sr.IIT-IZ-CO-SPARK Date: 02-10-16
Time:2.00 P.M TO 5.00 P.M Max. Marks:198

Name of the Student: ___________________ H.T. NO:


PAPER-II
02-10-16_Sr.IIT-IZ-CO-SPARK_RPTA-8_Weekend Syllabus
MATHS:

QUADRATIC EQUATIONS AND LOGARITHMS: Quadratic Equations In Real And

Complex Number System And Their Solutions, Relation Between Roots And Coefficients,

Nature Of Roots, Formation Of Quadratic Equation With Given Roots, Logarithm And Their

Properties

PHYSICS:

TOTAL SHM AND VISCOSITY

CHEMISTRY:

Alkali Metals, Alkaline Earth Metals, Group-13


Narayana IIT Academy 02-10-16_Sr.IIT-IZ-CO-SPARK_JEE-ADV_(2012_P2)_RPTA-8_Q’Paper
IIT-JEE-2012-P2-Model
Time:2:00 PM to 5:00 PM IMPORTANT INSTRUCTIONS Max Marks: 198

PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 8) Questions with Single Correct Choice 3 -1 8 24
Questions with Comprehension Type
Sec – II(Q.N : 9 – 14) 3 -1 6 18
(3 Comprehensions : 2+2+2 = 6Q)
Questions with Multiple Correct
Sec – III(Q.N : 15 – 20) 4 0 6 24
Choice
Total 20 66
CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 21 – 28) Questions with Single Correct Choice 3 -1 8 24
Questions with Comprehension Type
Sec – II(Q.N : 29 – 34) 3 -1 6 18
(2 Comprehensions : 3+3 = 6Q)
Questions with Multiple Correct
Sec – III(Q.N : 35 – 40) 4 0 6 24
Choice
Total 20 66
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : (41 – 48) Questions with Single Correct Choice 3 -1 8 24
Questions with Comprehension Type
Sec – II(Q.N : (49 – 54) 3 -1 6 18
(3 Comprehensions : 2+2+2 = 6Q)
Sec – III(Q.N : 55 – 60) Questions with Multiple Correct Choice 4 0 6 24
Total 20 66

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PHYSICS: Max. Marks : 66
SECTION – I
(SINGLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONLY ONE is correct
1. A string secured at its ends is stretched with a force of tension F. The mass of the
string and the force of gravity can be neglected. A point weight with a mass m is
attached to the middle of the string. What is the time period of small oscillations of the
weight? (Neglect any change in the magnitude of tension of the string during
oscillations)
m

 m
l
 is small

ml 2ml
A) 2 B) 2
F F

ml ml
C) 2 D) 2
2F 4F

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2. A uniform solid cone of specific gravity less than one performs small vertical
oscillations while floating in water with time period T1 . When inverted from shown
position and again small vertical oscillations are performed time period was found to
be T2 . Then

A) T1  T2
B) T1  T2
C) T1  T2
D) Relation between T1 &T2 cannot be determined
3. Suppose that you hang an object of mass M on the end of a spring, and when the
object is in equilibrium the spring is stretched a distance h. The frequency of vertical
oscillations of this block-spring system is the same as that of small oscillations of a
simple pendulum of mass m and length h. This
A) happens only for M = m B) happens only for M  m
C) happens for any finite M, m D) never happens
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4. A uniform plank of mass “m” free to move in horizontal direction only is placed on
the top a solid cylinder of mass “2m” and radius R. The plank is attached to a fixed
wall by means of a light spring of spring constant K. There is no slipping between the
cylinder and the plank and between cylinder and ground. The time period of small
oscillations of system is

7m 3m
A) 2 B) 2
4k k

2m 5m
C) 2 D) 2
k 3k

5. An air bubble of radius 1 cm rises through a liquid of density 1.5 g/c.c., at a constant
speed of 0.25 cm/s. What is coefficient of viscosity of liquid, neglecting the density of
air?  g  9.8 m / s 2 

A) 1.31 x 104 poise B) 2.62 x 104 poise


C) 1.31 x 103 poise D) 2.62 x 103 poise

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6. The system shown is lying on a smooth horizontal surface. Mass m is constrained to
move along the line 3. Springs 1 and 2 at right angles with respect to one another are
symmetrically arranged with respect to 3 which is an elastic cord. The force constants
of 1, 2 and 3 are k each and they are all just taut in the condition shown. For small
oscillations of m along 3, time period is

m m
A) 
2k
1 2  B) 2
k

1 2 
3 m 2m
C)
2 k

1 2  D) 
k1 2 

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7. For the spring block system shown mass is m and force constant is k. With spring in
relaxed condition, position of block is taken as origin and downward direction is taken
as positive y-direction. The block oscillates with maximum possible amplitude. The
3mg
equation of motion of SHM is given by (initially block is at y  and it is moving
2k

k
upwards). (Here   )
m

mg mg 2mg mg
A)
k

k

cos t  
3  B)
k

k

cos t  
3 
mg mg mg
C)
k

k

cos t  
3  D)
k
sin  t

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8. A semicircular uniform wire of radius R= π can rotate freely about x-axis. The centre
of curvature is at origin as shown. The acceleration due to gravity is given by

g   x2 j units. For small oscillations of the wire its time period is given by
y

A) 3 B) 2 C) 6 D) π

SECTION - II
(COMPREHENSION TYPE)
This section contains 6 multiple choice questions relating to three paragraphs with two questions on each
paragraph. Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONE is correct.
Paragraph for Questions 9 and 10

A hoop of mass m and radius r performs small oscillations with respect to the
spherical cup without friction over the internal surface of the spherical cup in each of
the three cases shown. The internal radius of the cup is R   r  . Acceleration due to
gravity is g.
Case-1:
The cup is fixed and the time period of small oscillations is T1

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R

Case-2:
The time period of small oscillations of the hoop with respect to cup is T2 when,
besides the force of gravity, the cup is acted upon by a force F directed vertically
upward. The mass of the cup M is much greater than that of m.

Case-3:
The time period of small oscillations of the hoop with respect to cup is T3 if the cup is
placed on a smooth horizontal surface over which it can move without friction. Now
answer the following questions.

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9. The value of T1 and T2 respectively are
2R RM R RM
A) 2 , 2 B) 2 , 2
g F g Mg  F
2R 2 RM R RM
C) 2 , 2 D) 2 , 2
g Mg  F g F
10. Mark the most appropriate statement
A) T1  T2 B) T1  T3 C) T1  T2 D) T1  T3

Paragraph for Questions 11 and 12

In the shown arrangement, both the springs are relaxed. The coefficient of friction
between m2 and m1 is  . There is no friction between m1 and the bottom surface. If
the blocks are displaced slightly, they perform S.H.M

11. The frequency of oscillation if they move together is


1 k1  k2 1 k1k2
A) B)
2 m1  m2 2  m1  m2  k1  k2 
C)
1 k1 k2
 D)
1  k1  k2  m1  m2 
2 m1 m2 2 m1m2

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12. If the frictional force on block m2 is to act in the direction of its displacement from
mean position then
m1 k1 m1 k1
A)  B)  C) m1  m2  k1  k2 D) m1  m2  k1  k2
m2 k2 m2 k2

Paragraph for Questions 13 and 14


Three cylindrical shells of mass M and radius R are pushed to the right by a force F on
a smooth horizontal surface as shown. A simple pendulum of mass m and length l is
suspended from top of the upper shell. Cylinders are massive while pendulum is light.
The shells always remain together as shown without losing contact with one another.
The pendulum undergoes small oscillations.

13. The maximum time period of oscillation is


3l 27 l 27l
A) 2 l 3 2 g B) 2 C) 2 2g
D) 2 2g
2g
14. The minimum time period of oscillations is

3l 27 l 27 l l 3
A) 2 B) 2 C) 2 D) 2
2g 28 g 2g 28 g
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SECTION – III
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE is/ are correct
15. Two mathematical pendulums each with a length l are connected by a weightless
spring as shown in figure. The coefficient of elasticity of the spring is k. In
equilibrium the pendulum occupy vertical position and the spring is not deformed. The
angular frequencies of the small oscillations of the two linked pendulums when they
are deflected in one plane through equal angles

g 2k
A) in one direction (oscillations in phase) is 
l m
g
B) in opposite directions (oscillations in anti-phase) is
l
g
C) in one direction (oscillations in phase) is
l
g 2k
D) in opposite directions (oscillations in anti-phase) is 
l m
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16. Three cars of mass m each are held at rest on an inclined smooth railway track of
inclination  using an elastic cable (Assume that the cable behaves like a spring even
during compression) that is parallel to the incline. The cable is observed to stretch by a
length x just before a coupling breaks, detaching one of the cars.

1 3g sin 
A) the frequency of the resulting oscillations of the remaining two cars is
2 x

1 3g sin 
B) the frequency of the resulting oscillations of the remaining two cars is
2 2x
2x
C) the amplitude of the oscillations mentioned in above options is
3
x
D) the amplitude of the oscillations mentioned in above options is
3

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17. Four small lead balls of volume 1 cm3, 2 cm3, 3 cm3 and 4 cm3 are descending down
through the same liquid with their terminal velocities
A) viscous force is more on 4 cm3 ball
B) terminal velocity is more for 4 cm3 ball
C) viscous force is more for 1 cm3
D) terminal velocity is more for 1 cm3 ball
18. A bob of mass 2m hangs by a string attached to the block of mass m of a spring blocks
system. The whole arrangement is in a state of equilibrium. The bob of mass 2m is
pulled down slowly by a distance x0 and released.

2m

3mg
A) For x0 = ,maximum tension in string is 4mg
k
3mg
B) For x0 > , minimum tension in string is mg
k
k1
C) Frequency of oscillation of system is , for all non-zero values of x0
2
3m
3mg
D) The motion will remain simple harmonic for x0 
k
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19. A solid spherical ball of radius r made of a material of a given density  is dropped in
a viscous liquid of coefficient viscosity  .Then chose the correct option(s).
A) Linear momentum of the ball after achieving terminal velocity is proportional to r 2
B) Instantaneous power developed by the drag force is proportional to the r 5
C) After steady state, angular momentum of the ball about the centre of the ball is
proportional to r 3
D) Power developed by the force of buoyancy is proportional to the r 5
20. A body of mass m is in a field where its potential energy is given by U  ax 3  bx 4 ,
where a and b are positive constants. Then, [The body moves only along x]
A) x  0 is a point of equilibrium
3a
B) x  is a point of stable equilibrium
4b
3a
C) x  is a point of unstable equilibrium
4b
D) for small displacements from stable equilibrium position the body executes SHM

3a
with angular frequency
2 bm

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CHEMISTRY: Max. Marks: 66
SECTION – I
(SINGLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONLY ONE is correct
21. Which of the following can be used to extinguish the magnesium fire (burning
magnesium)
A) Water B) Carbon dioxide
C) Nitrogen D) Carbon tetrachloride
22. Basic character of hydroxides of 1A group metals down the group can be attributed
mainly to
A) Decrease in hydration energy
B) Decrease in effective nuclear charge
C) Increase in size of alkali metal ion which causes increase in bond length
D) Decrease in ionization potential
23. Thermal decomposition temperature increases for carbonates of IIA group element
from BeCO 3 to BaCO3 because
A) Decrease in the difference of lattice energies of MCO3 (carbonate) and MO
(decomposition product)
B) Increase in the lattice energies of carbonates from BeCO3 to BaCO3
C) Increase in the bond length
D) Increase in the electropositive character

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24. Alkaline earth metal compounds are less soluble in water than corresponding alkali
metal compounds because
A) Alkaline earth metal compounds are hydrated while the corresponding alkali metal
compounds are anhydrous
B) The lattice energy of alkaline earth metal compounds are less than lattices energies

of corresponding alkali metals

C) Alkaline earth metal compounds are more covalent than the corresponding alkali

metal compounds

D) Alkaline earth metals have higher ionisation energies than the ionisation energies

of alkali metals

25. The wrong statement among the following

A) Li2CO3 is least stable carbonate among alkali metal carbonates

B) LiF is almost insoluble in water due to its high covalent character

C) Ba(OH)2 is most soluble hydroxide among alkaline earth metal hydroxides

D) BeSO4 is more soluble than BaSO 4

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26. The false statement among the following is

A) KHCO 3 is less soluble in water than K2CO 3

B) NaHCO3 is less soluble in water than KHCO3

C) Na2CO3 is less soluble in water than K2CO 3

D) Na2CO3 is less soluble in water than NaHCO3

27. Which of the following is different from others chemically?


A) Quick lime B) Slaked lime
C) Lime water D) Milk of lime
28. The product formed when beryllium hydroxide is added to excess of barium hydroxide
and heated to above 500ºC is

A) A solid mixture of BeO and Ba(OH)2

B) A solid mixture of Be(OH)2 and Ba(OH)2

C) A solid compound BaBe(OH)4

D) A solid compound BaBeO2.

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SECTION - II
(COMPREHENSION TYPE)
This section contains 6 multiple choice questions relating to two paragraphs with three questions on each
paragraph. Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONE is correct.
Paragraph for Questions 29 and 30:
Alkaline earth metal salts when crystallized from their aqueous solutions. crystallizes
mostly as hydrated salts. Anhydrous chlorides, bromides and iodides of Ca, Sr and Ba
can be prepared directly by heating their hydrated compounds. Halides of Be and Mg
hydrolyses with the water of crystallization on heating. Anhydrous nitrates of alkaline
earth metals also cannot be prepared by heating hydrated compounds as they
decompose.
29. Which of the following statement is wrong about solid anhydrous beryllium chloride.
A) It contains tetrahedral beryllium units
B) All the atoms are in same plane
C) It contains three centred four electron bond
D) It has polymeric structure
30. By which of the following method, anhydrous beryllium fluoride/chloride cannot be
prepared
A) BeO  2 NH 3  4 HF   NH 4 2  BeF4  
Heat

Heat
B) BeO  C  Cl2  
Heat
C) BeO  CCl4  
 aq 
D) BeO  HCl  

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Paragraph for Questions 31 and 32:

When boron halides are reduced with alkali metal hydrides, boron hydrides
particularly diborane will be formed. The diborane on heating with other metal
hydrides give tetrahydrido borates.
31. Which of the following statement is wrong regarding tetrahydrido borates
A) Alkali metal hydrides are ionic
B) LiBH 4 can be crystallized from cold water
C) NaBH 4 can be used as reducing agent in aqueous as well as alcoholic solutions
D) Tetrahydrido borates are electron deficient compounds
32. Which is not correct about aluminium borohydride

A) In aluminium borohydride  BH 4  group act as ligand
B) It contain six hydrogen bridge bonds
C) Around aluminium, there are some Al-H and Al-H-B bridge bonds
D) Around boron there are some B-H and some B-H-Al bridge bonds

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Paragraph for Questions 33 and 34:

Solutions of alkali metal in liquid ammonia have been developed as versatile reducing

agents which effect reductions of organic compounds that are otherwise difficult. As

the concentration of the alkali metal increases blue colour changes to bronze colour

33. Blue solution of sodium in liquid ammonia is themselves unstable because of ---- on

standing

A) amide formation of Na B) azide formation of Na

C) nitride formation of Na D) hydride formation of Na

34. Which is false statement?

A) Bronze coloured solution is less denser than blue coloured solution

B) Magnetic character of blue and bronze coloured solutions are different


C) Solubility is favoured by low metal lattice energy, low ionization energy and high
solvation energies
D) Electrical conductivity of blue solution increases upto 0.05M and then becomes
zero in saturated solution due to pairing of electrons.

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SECTION – III
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE is/ are correct
35. The correct statements among the following are

A) Thermal stability of carbonates of both IA and IIA group elements increases from

top to bottom in the group

B) Solubility of the carbonates of both IA and IIA group elements decreases from top

to bottom in the group

C) Evaporation of solutions of IA group elements in liquid ammonia gives metals but

IIA elements in liquid ammonia give ammoniates

D) Electrical conductivity of fused chlorides of IA and IIA group elements decreases

from top to bottom

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36. Regarding colemanite the correct statements are

A) It consists of four tetrahedral borate and two planar trigonal borate units

B) It is a hexa metaborate

C) The number of water molecules existing as water of crystalisation is 2

D) When it is fused with soda ash it forms sodium meta borate and sodium tetraborate

37. What is the best description of the change that occurs when KO2 is dissolved in water

A) Oxidation number of oxygen increases

B) Oxidation number of oxygen decreases

C) Oxide ion is formed and donates a pair of electrons

D) A gas, supporter of life, is released

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38. The correct statements among the following is/are
A) All the alkali metals give flame colours when their compounds are introduced in
the bunsen flame
B) Among alkaline earth metals beryllium and magnesium do not exhibit flame colour
as their electrons are strongly bound to nucleus
C) By using the intensity of the flame colour the amounts of the alkali and alkaline
earth metals can be determined by flame photometry
D) Magnesium burns with white dazzling light containing UV radiation
39. The correct statement(s) is/are
A) Though the coordination number of magnesium is six, in Epsom salt magnesium
ion is coordinated by seven water molecules
B) Solubility of CaSO4 in water decreases with increase in temperature
C) Solubility of CaSO4 in water increases in the presence of conc H2SO 4
D) On heating gypsum above 200ºC converts into dead burnt plaster
40. Diborane form addition compound either by symmetric cleavage or by unsymmetric
cleavage. With which of the following substances diborane forms adducts with
symmetric cleavage
A) CO B)  CH 3 3 N C)  CH 3 2 O D) CH 3 NH 2

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MATHS: Max. Marks: 66
SECTION – I
(SINGLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONLY ONE is correct
  
log 2.5 1/3 1/32 ......... 

41. (0.16) 

A) 2 2 B) 2 C) 4 2 D) 4

1
42. If log (2 x  3)  6 x 2  23x  21  4  log (3 x 7)  4 x 2  12 x  9  , then the value of  4x  3 is

A) 2 B) 1 C) 8 D) -1/4
 x 2 8 x 15 
 
 

 x 2 
43. The number of solutions of the equation x 3  1 is

A) 3 B) 2 C) 0 D) 4

44. If  x1 , y1  and  x2 , y2  are solutions of the system of simultaneous equations

 x  log 8 x
log8  xy   3log8 x.log8 y and 4log 8    ; then the value of x1 x2  y1 y2 is
y
  log 8 y

A) 4 B) 6 C) 2 D) 8
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45. If p is prime number such that both roots of the equation x 2  px  (444) p  0 are

integers, then p must be equal to

A) 2 B) 3 C) 31 D) 37

46. The number of integral values of x satisfying

2
 x  1  5 x  1 and ( x  1) 2  7 x  3 simultaneously , is

A) 1 B) 2 C) 4 D) 0

47. Let a, b be positive real numbers. If the equations x 2  ax  2b  0 and

x 2  2bx  a  0 have real roots, then minimum value of a  b is

A) 4 B) 6 C) 8 D) 2

48. Let a, b, c and d be non zero real numbers. If c and d are roots of the equation

x 2  ax  b  0 and a and b are the roots of the equation x 2  cx  d  0 , then the

value of ( a  b  c  d ) is

A) 1 B) 2 C) 3 D) 4

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SECTION - II
(COMPREHENSION TYPE)
This section contains 6 multiple choice questions relating to three paragraphs with two questions on each
paragraph. Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONE is correct.
Paragraph for Questions 49 and 50

It is given that
log a  bc   log a b  log a c, a  1, a  0, b  0, c  0
b
log a    log a b  log a c, a  1, a  0, b  0, c  0
c
n
log a m b n  log a b , a  1, a  0, b  0, m  0
m
log a b  log c b / log c a, a  1, c  1, a  0, b  0, c  0
1
log a b  , a  1, b  1, a  0, b  0, a  b
logb a

49. If a  0, b  0 , ab  1, a 3  b 5 and a 2  b 2  7 ab, then which of the following is true?

ab ab
A) 2 log    log( ab) B) log    log(ab)
 3   3 
2
ab a  ab 
C) log    log   D) log    log a  log b
 3  b  3 

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log3 135 log 3 5
50. The value of  is equal to
log15 3 log 405 3
A) 4 B) 5 C) 3 D) 0
Paragraph for Questions 51and 52
To solve equation of the form (ax 2  bx  c)(ax 2  bx  d )  k

use the substitution ax 2  bx  y , so that the given equation transforms into a

quadratic equation in y which can be solved.

1 1 1
51. The number of real solutions of the equation  2
 is
x( x  2) ( x  1) 12

A) 2 B) 1 C) 0 D) 4

24 15
52. The equation 2
 2  2 has
x  2x  8 x  2x  3

A) all positive solutions

B) three positive and one negative solutions

C) two non-negative and two negative solutions

D) two real and two imaginary solutions


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Paragraph for Questions 53 and 54

Let f ( x)  ax 2  bx  c and a  0. If  and  are roots of f ( x)  0, then

    b / a and   c / a. Further, if  and  are real roots with    , then

f ( x) and a have the same sign for all x   or x   , and f ( x) and a have opposite

sign for all   x   . Consider the quadratic equation

(1  m) x 2  2(1  3m) x  (1  8m)  0 , where m is parameter ;

Now, answer following two questions based on this information.

53. The sum of real values of m such that the roots of the given quadratic equation are in

the ratio 2:3 is

81 1 1 1
A) B) C) D) 
16 96 81 32
54. The set of exhaustive values of m such that both the roots of the given quadratic
equation are positive is
A) ( , ) B) 1  m  3 C) 3  m   D) ( , 1)  (3, )  {0}

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SECTION – III
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE is/ are correct
55. Which one of the following are correct?
A) logb a.log c b.log d c.log a d  1, where a, b, c, d     {1}
4
B) 22.2 log 2 5 
5
C) 34log3 5  (27)log9 36  741
 log 2 3 121  (1/3) 
 
 
D) 8  242
56. If x, y, z simultaneously satisfy the equations
log 2 x  log 4 y  log 4 z  2
log 3 y  log9 z  log 9 x  2
log 4 z  log16 x  log16 y  2
then which of the following is (are) true?
A) xy  9 / 4 B) yz  36
C) zx  64 / 9 D) x  y  z  xyz

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57. If a, b, and c are integers, then the discriminant of ax 2  bx  c  0 can be of the form
(where k is an integer)

A) 4k B) 4k  1 C) 4k  2 D) 4k  3

58. Let a, b and c be distinct, non zero real numbers .Further Let  and  be the roots of

ax 2  bx  c  0 , such that  2  1,  2  1. Then a root of the equation

a 3 x 2  (abc ) x  c 3  0, can be

A)  3  2 B)  3 2 C)  2  D)  2

59. Consider the quadratic equations ax 2  2bx  c  0, bx 2  2cx  a  0 and

cx 2  2ax  b  0 . If all the equations has to have only positive roots, then

A) b 2  ca B) c 2  ab

C) a 2  bc D) a  b  c

60. Let a and b be two real numbers. If all the roots of the equation x 2  ax  b  0 are real
and have their modulus less than 1, then which of the following option(s) is/are true?

A) b  1 B) a  b  1

C) b  a  1 D) a  b  1
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