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FINAL JEE–MAIN EXAMINATION – JANUARY, 2023

Held On Monday 30th January, 2023
TIME : 09:00 AM to 12:00 PM

SECTION-A HD CO2 CO2HC

31. Which of the following compounds would give the
HA HA
following set of qualitative analysis ?
(i) Fehling’s Test : Positive > >
(ii) Na fusion extract upon treatment with sodium
nitroprusside gives a blood red colour but not HB
N HD CO2HC CO2HC
HD
(1) CHO
N HA
N
>
(2) CHO
O HB
N
(3) CHO
33. Given below are two statements : one is labelled as
S
Assertion (A) and the other is labelled as Reason
N
(R).
(4)
S CHO Assertion (A) : Ketoses give Seliwanoff’s test
Official Ans. by NTA (4) faster than Aldoses.
Allen Ans. (4) Reason (R) : Ketoses undergo -elimination
Sol. Aromatic aldehydes do not give Fehling's test.. followed by formation of furfural.
Both nitrogen and sulfur must be present to obtain
blood red colour In the light of the above statements, choose the
Sodium nitroprusside gives blood red colour with correct answer from the options given below :
S & N.
(1) (A) is false but (R) is true
32. What is the correct order of acidity of the protons
(2) Both (A) and (R) are true and (R) is the correct
marked A–D in the given compounds ?
H explanation of (A)
CO2HC
D
(3) (A) is true but (R) is false
HA (4) Both (A) and (R) are true but (R) is not the
correct explanation of (A)
Official Ans. by NTA (3)
HB
Allen Ans. (3)
(1) HC > HD > HB > HA Sol. Seliwanoff 's test is a differentiating test for Ketose
(2) HC > HD > HA > HB
and aldose. This test relies on the principle that the
(3) HD > HC > HB > HA
keto hexose are more rapidly dehydrated to form
(4) HC > HA > HD > HB
Official Ans. by NTA (2) 5-hydroxy methyl furfural when heated in acidic
Allen Ans. (2) medium which on condensation with resorcinol,
Sol. acidity of an acid depends upon the stability of its
Cherry red or brown red coloured complex is
conjugate base
formed rapidly indicating a positive test.

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34. In the extraction of copper, its sulphide ore is Sol.

heated in a reverberatory furnace after mixing with
silica to :
CH3 CH3 CH3
(1) separate CuO as CuSiO3
H3C – C = CH2 CH3 – C = CH – C – CH3
(2) remove calcium as CaSiO3
(B
(3) decrease the temperature needed for roasting of H CH3
Cu2S
O– – SO3H
(4) remove FeO as FeSiO3 CH3
Official Ans. by NTA (4) CH3
H3C – C – CH3 CH2 
Allen Ans. (4)  CH3
H2O
Sol. The copper ore contains iron, it is mixed with silica
before heating in reverberatory furnace. FeO slags CH3 CH3
off as FeSiO3. H3C – C = CH2 H3C – C – CH3
FeO  SiO2 
 FeSiO3 (A)
OSO3H
H
35. Amongst the following compounds, which one is CH3
an antacid ? O–SO3H
H3C – C – CH3
(1) Ranitidine (2) Meprobamate 

(3) Terfenadine (4) Brompheniramine 37. Benzyl isocyanide can be obtained by :

Official Ans. by NTA (1) CH2Br
AgCN
Allen Ans. (1) (A)
Sol. 1. Ranitidine: Antacid
2. Meprobamate: Tranquilizer CH2NH2
3. Terfenadine: Antihistamine CHCl3
(B)
4. Brompheniramine: Antihistamine Aq. KOH
36. The major products ‘A’ and ‘B’, respectively, are
CH2 NHCH3
CHCl3
(C)
Aq. KOH

CH3 CH3 CH3 CH2OTs

(1) H3C C CH3 KCN
CH3 C CH C CH3 (D)
OSO3H CH3
CH3 CH3 CH3 Choose the correct answer from the options given
(2) CH3 C CH C CH3 CH3 C CH3
below :
CH3 OSO3H
(1) A and D
CH3 CH3 CH3
(3) CH3 CH CH2CH2 CH CH3 H3C C CH3
(2) Only B
OSO3H (3) A and B
CH3 CH3 CH3 (4) B and C
(4) H3C C CH3 CH3 CH CH2CH2 HC CH3 Official Ans. by NTA (3)
OSO3H Allen Ans. (3)
Official Ans. by NTA (1)
Allen Ans. (1)

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Sol. 39. Match List I with List II

List I List II
CH2Br CH2—NC A Cl CH3 I Fitting
AgCN reaction

Benzyl Isocyanide
B Cl II Wurtz
Fitting
CH2NH2 CH2– NC
CHCl3 reaction
(Carbylamine
Aq. KOH
reaction) C N2Cl Cl III Finkelstein
Benzyl Isocyanide reaction
CH2–NHCH3
CHCl3 D C2H5Cl + NaI  C2H5I + IV Sandmeyer
Aq.
No reaction
KOH NaCl reaction
(1) A – II, B – I, C – III, D – IV
CH2OTs CH2–CN
KCN
(2) A – III, B – II, C – IV, D – I
(3) A – IV, B – II, C – III, D – I
(4) A – II, B – I, C – IV, D – III
Official Ans. by NTA (4)
Allen Ans. (4)
38. Given below are two statements : one is labelled as
Sol.
Assertion (A) and the other is labelled as Reason (R). LIST-I LIST-II
Assertion (A) : In expensive scientific instruments, Cl CH3 Wurtz-
silica gel is kept in watch-glasses or in semipermeable A. fitting
+ CH3Cl reaction
membrane bags.
Reason (R) : Silica gel adsorbs moisture from air via Cl
Fitting
adsorption, thus protects the instrument from water B.
+ 2Na reaction
corrosion (rusting) and / or prevents malfunctioning.
In the light of the above statements, choose the N2+Cl– Cl
Sandmeyer
correct answer from the options given below : C.
+N2 reaction
(1) (A) is false but (R) is true
(2) (A) is true but (R) is false Finkelstein
D. C2H5Cl + NaI  C2H5I + NaCl
reaction
(3) Both (A) and (R) are true and (R) is the correct
40. Caprolactam when heated at high temperature in
explanation of (A) presence of water, gives
(4) Both (A) and (R) are true but (R) is not the (1) Teflon (2) Dacron
correct explanation of (A) (3) Nylon 6, 6 (4) Nylon 6
Official Ans. by NTA (4)
Official Ans. by NTA (3)
Allen Ans. (4)
Allen Ans. (3)
O
Sol. Silica gel prevents water corrosion (rusting) and
O
instrument malfunction by adsorbing moisture N–H H2O,
Sol. —C–(CH2)5–NH—
from the air. n
Caprolactam Nylon -6

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41. The alkaline earth metal sulphate(s) which are 44. During the qualitative analysis of SO32 using
readily soluble in water is/are:
dilute H 2SO 4 ,SO 2 gas is evolved which turns
(A) BeSO4
(B) MgSO4 K 2 Cr2 O 7 solution (acidified with dilute H2SO4 ):
(C) CaSO4
(1) Black (2) Red
(D) SrSO4
(E) BaSO4 (3) Green (4) Blue
Choose the correct answer from the options given Official Ans. by NTA (3)
below:
Allen Ans. (3)
(1) A only (2) B only

(3) A and B (4) B and C Sol. Cr2 O72  SO32 
H
 Cr 3  SO 42
Green
Official Ans. by NTA (3)
Allen Ans. (3) 45. To inhibit the growth of tumours, identify the
Sol. Due to high hydration energy Be2+ and Mg2+, compounds used from the following:
BeSO4 and MgSO4 are readily soluble in water. (A) EDTA
42. Which of the following is correct order of ligand
(B) Coordination Compounds of Pt
field strength?
(1) CO  en  NH3  C2 O42  S2 (C) D – Penicillamine

(2) S2  C2 O42  NH3  en  CO (D) Cis – Platin

Choose the correct answer from the option given
(3) NH3  en  CO  S2  C2 O42
below:
(4) S2  NH3  en  CO  C2 O42
Official Ans. by NTA (2) (1) B and D Only
Allen Ans. (2) (2) C and D Only
Sol. The increasing order of field strength of ligands (3) A and B Only
(according to spectrochemical series)
(4) A and C Only
S2  C2O42  NH3  en  CO
Official Ans. by NTA (1)
43. Formation of photochemical smog involves the
following reaction in which A, B and C are Allen Ans. (1)
respectively. Sol. Cis – Platin is used in chemotherapy to inhibits the
h
(i) NO2  A  B growth of tumors. (cis[Pt(NH3)2Cl2])
(ii) B  O 2  C 46. In the wet tests for identification of various cations
(iii) A  C  NO2  O2 by precipitation, which transition element cation
Choose the correct answer from the options given
doesn’t belong to group IV in qualitative inorganic
below:
(1) O, NO& NO3 (2) O, N 2 O& NO analysis?

(3) N,O 2 &O3 (4) NO,O &O3 (1) Fe3

Official Ans. by NTA (4) (2) Zn 2
Allen Ans. (4)
(3) Co2
Sol. NO 2g  NOg  Og
hv

A  B (4) Ni 2
Og  O 2g O3g Official Ans. by NTA (1)
 B C
Allen Ans. (1)
NOg  O3g 
 NO 2g  O 2g Sol. Zn 2 , Co 2 , Ni 2  IV th Group
A C
Fe3  III rd Group

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47. Match List I with List II 49. Lithium aluminium hydride can be prepared from

the reaction of
LIST–I LIST–II
(molecules/ions) (No. of lone pairs of e– (1) LiCl and Al2 H6
on central atom) (2) LiH and Al2 Cl6
(A) IF7 I. Three
(3) LiCl,Al and H 2
(B) ICl4 II. One
(C) XeF6 III. Two (4) LiH and Al  OH 3

(D) XeF2 IV. Zero Official Ans. by NTA (2)

Choose the correct answer from the options given Allen Ans. (2)
below:
(1) A – II, B – III, C – IV, D – I Sol. 8LiH  Al2Cl6 
 2 LiAlH 4  6 LiCl
(2) A – IV, B – III, C – II, D – I
(3) A – II, B – I, C – IV, D – III 50. Match List – I with List – II
(4) A – IV, B – I, C – II, D – III
Official Ans. by NTA (2)
Allen Ans. (2) LIST–I LIST–II
Sol. IF7 zero lone pair (Atomic number) (Block of periodic
ICl4 two lone pair table)

XeF6 one lone pair (A) 37 I. p–block

XeF2 three lone pair (B) 78 II. d–block

48. For OF2 molecule consider the following: (C) 52 III. f–block
(A) Number of lone pairs on oxygen is 2. (D) 65 IV. s–block
(B) FOF angle is less than 104.5o . Choose the correct answer from the options given
(C) Oxidation state of O is –2. below:
(D) Molecule is bent ‘V’ shaped. (1) A – II, B – IV, C – I, D – III
(E) Molecular geometry is linear. (2) A – I, B – III, C – IV, D – II
Correct options are: (3) A – IV, B – III, C – II, D – I
(1) C, D, E only (4) A – IV, B – II, C – I, D – III
(2) B, E, A only Official Ans. by NTA (4)
(3) A, C, D only Allen Ans. (4)
(4) A, B, D only Sol.
Official Ans. by NTA (4) Atomic number Block
Allen Ans. (4)
37 (K) s-block
78 (Pt) d-block
Sol. F 52 (Te) p-block
 Two lone pair one oxygen 65 (Tb) f-block
 Molecule is ‘v’ shaped
 Bond angle is less than 104.5°(102º)
 O·S· of ‘O’ is + 2

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SECTION-B 53. A solution containing 2 g of a non–volatile solute

51. Consider the cell in 20 g of water boils at 373.52 K. The molecular

Pt  s  H 2  g,1atm  H   aq,1M  Fe3  aq  , Fe2  aq  Pt  s  mass of the solute is _______ g mol1 . (Nearest

When the potential of the cell is 0.712 V at 298 K, integer)

the ratio  Fe 2  /  Fe3  is _________. Given, water boils at 373 K, K b for water
(Nearest integer)  0.52K kg mol1
Given: Fe3  e  Fe2 , E o Fe3 , Fe2 Pt  0.771
Official Ans. by NTA (100g)
2.303RT
 0.06 V Allen Ans. (100g )
F
Sol. Tb  373.52  373
Official Ans. by NTA (10)
= 0.52
Allen Ans. (10)
Tb  Kb  m
Sol
Pt  s  H 2  g,1atm  H   aq,1M  || Fe3  aq  , Fe 2  aq  | Pt s  0.52  0.52 
2

1
Molar Mass 20 10 3
 2H   2e
at anode H 2 
3  2 Molar Mass = 100g/mol
At cathode Feaq  e 
 Feaq
54. If compound A reacts with B following first order
E  EH |H  E Fe3 |Fe2  0  771V
2
kinetics with rate constant 2.011  103 s 1 . The
0  06 Fe 2 time taken by A (in seconds) to reduce from 7 g to
E  E  log 3
1 Fe
2 g will be ________. (Nearest Integer)
2
0  06 Fe
0  712   0  0  771  log 3 [ log5  0.698,log 7  0.845,log 2  0.301 ]
1 Fe
Fe 2 0  059 Official Ans. by NTA (623)
log  1
Fe3 0  06 Allen Ans. (623)
Fe2 Sol. ABP
 10
Fe3 t=0 7g
52. A 300 mL bottle of soft drink has 0.2 M CO2 t=t 2g
dissolved in it. Assuming CO2 behaves as an ideal at constant volume
gas, the volume of the dissolved CO2 at STP is
2.303 A0
_________ mL. (Nearest integer) t log
Given: At STP, molar volume of an ideal gas is K At
22.7 L mol1 2  303 7
 3
log
2  01110 2
Official Ans. by NTA (1362)
2  303  0  544

Allen Ans. ( 1362 ml) 2  011 103
Sol. Mole of CO2 = 0.2 M × (300 × 10–3) L = 622.989
= 0.06 Mole  623
Volume of 0.06 mole CO2 at S.T.P
= 0.06 × 22.7
= 1.362 L

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55. The energy of one mole of photons of radiation of 59. A trisubstituted compound ‘A’, C10 H12 O 2 gives
1
frequency 2  10 Hz in J mol
12
is _______. neutral FeCl3 test positive. Treatment of
(Nearest integer)
compound ‘A’ with NaOH and CH3 Br gives
34
(Given: h  6.626  10 Js
C11H14 O 2 , with hydroiodic acid gives methyl
1
NA  6.022  10 mol )
23
iodide and with hot conc. NaOH gives a compound
Official Ans. by NTA (798) B, C10 H12 O 2 . Compound ‘A’ also decolorises
Allen Ans. (798) alkaline KMnO4 . The number of  bond/s
Sol. For one photon E = hv
present in the compound ‘A’ is _______.
For one mole photon,
59 Official Ans. by NTA (4)
E  6  023 1023  6  626 1034  2 1012
Allen Ans. (4)
= 798·16 J
 798 J
56. The number of electrons involved in the reduction
of permanganate to manganese dioxide in acidic
medium is ________.
Official Ans. by NTA (3)
Allen Ans. (3)
7 4
Sol. Mn O4  4H   3e  
 Mn O 2  2H 2O
57. When 2 litre of ideal gas expands isothermally into
vacuum to a total volume of 6 litre, the change in
internal energy is ______ J. (Nearest integer)
Official Ans. by NTA (0)
60. Some amount of dichloromethane  CH 2 Cl2  is
Allen Ans. (0)
Sol. For ideal gas U = f (T) added to 671.141 mL of chloroform  CHCl3  to
and for isothermal process,  U  0 prepare 2.6  103 M solution of CH 2 Cl2  DCM  .
58. 600 mL of 0.01M HCl is mixed with 400 mL of The concentration of DCM is ______ ppm (by
0.01 M H2SO4 . The pH of the mixture is mass).
2
________ 10 . (Nearest integer) Given: Atomic mass : C = 12; H : 1; Cl = 35.5
[Given log 2  0.30 , log 3  0.48 density of CHCl3  1.49g cm3
log 5  0.69 log 7  0.84 Official Ans. by NTA (221)
log11  1.04 ] Allen Ans. (148)
Official Ans. by NTA (186) mole
Sol. Molarity 
Allen Ans. (186) volume
Sol. Total milimoles of H+ = (600×0.01) + (400×0.01×2) x / 85
2.6 103 
=14 0.67141
14 x = 0.148 g
 H     14 103
1000 0.148
pH = 3 – log 14 conc. Fo DCM in ppm  106
1.49  671.141
= 1.86
= 148 ppm
= 186 × 10–2

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