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Lecture Note 5 Key Synthesis Steps PDF
Lecture Note 5 Key Synthesis Steps PDF
Process Synthesis
Steps for Basic
Chemicals
Learning Outcome
R4. Thermal cracking of dicholoroethane from R5. Balanced Process for Chlorination of Ethylene
oxychlorination of ethylene
C2H4 + 2HCl + ½ O2 → C2H4Cl2 + H2O C2H4 + Cl2 → C2H4Cl2
C2H4Cl2 → C2H3Cl + HCl C2H4 + 2HCl + ½ O2 → C2H4Cl2 + H2O
C2H4 + HCl + ½ O2 → C2H3Cl + H2O 2C2H4Cl2 → 2C2H3Cl + 2HCl
C2H4 + HCl + ½ O2 → 2C2H3Cl + H2O
Advantages:
• Attractive solution
• Occurs spontaneously at a few hundred celcius
Disadvantages:
• Low percentage of yield
• Producing large amount of byproducts (Dichloroethylene)
• Half of the expensive Cl is consumed
11
Advantages:
• Good conversion (98%)
• Moderate reaction conditions
• Temp : 150 ◦C, Catalyst: HgCl2, Pressure: 1 atm
Disadvantages:
• Flammability of C2H2
12
Advantages:
• Conversion Ethylene to Dichloroethane is 98% (90 ◦C , 1 atm, Catalyst: FeCl3)
• Conversion of intermediate is 65% (spont. at 500 ◦C)
Disadvantages:
• Produce HCl
13
Advantages:
• Highly exothermic reaction with 95% conversion (250 ◦C , Catalyst: CuCl2)
oxychlorinates ethylene 1,2-dichloroethane
Disadvantages:
• Economics dependent on cost of HCl
14
Advantages:
• Combines path 3 and 4
• All Cl2 converted to Vinyl Chloride
• No by-products
15
C2H4Cl2
DIRECT
PYROLYSIS
CHLORINATION
C2H4 C2H3Cl
Cl2
HCl
C2H4Cl2
DIRECT
PYROLYSIS
CHLORINATION
C2H4 C2H3Cl
Target
100,000 lb/h
*For preliminary calculation, assume 100% conversion.
22
Step 2: Distribute the chemicals by matching sources and sinks
Cl2
HCl
113,400 lb/h 58,300 lb/h
C2H4Cl2
DIRECT
PYROLYSIS
CHLORINATION
C2H4 C2H3Cl
Target
44,900 lb/h 100,000 lb/h
*For preliminary calculation, assume 100% conversion.
24
Step 2: Distribute the chemicals by matching sources and sinks
58,300 lb/h
Cl2
158,300 lb/h HCl
98% conversion
(neglect the unconverted)
113,400 lb/h
C2H4Cl2 HCl
DIRECT
PYROLYSIS C2H3Cl
CHLORINATION
C2H4Cl2
C2H4
Target
C2H3Cl
44,900 lb/h
100,000 lb/h
25
Step 2: Distribute the chemicals by matching sources and sinks
58,300 lb/h
Cl2 158,300 lb/h HCl
98% conversion 60%
(neglect the unconverted) conversion
113,400 lb/h
C2H4Cl2 HCl
DIRECT
PYROLYSIS C2H3Cl
CHLORINATION
C2H4Cl2
C2H4
Target
C2H3Cl
44,900 lb/h
100,000 lb/h
Pyrolysis Recycle Mass Balance 105,533 lb/h
(1-0.6) x 158,300 lb/hr = 105,533 lb/hr
0.6
26
Reaction path 3
Energy Balance
52 × 106 Btu/hr 58,300 lb/h
Cl2 150 × 106 Btu/hr 158,300 lb/h HCl
113,400 lb/h
DIRECT C2H4Cl2 PYROLYSIS HCl
CHLORINATION 500oC C2H3Cl
90oC, 1.5 atm 26 atm C2H4Cl2
C2H4
C2H3Cl
44,900 lb/h
100,000 lb/h
105,533 lb/h
27
C2H3Cl
158,300 lb/h HCl
Cl2 100,000 lb/h
C2H3Cl
113,400 lb/h -26.2 oC 33 oC
DIRECT PYROLYSIS C2H4Cl2
C2H4Cl2
CHLORINATION 500oC
90oC, 1.5 atm 112 oC 26 atm
C2H4 Liquid at
Assign for the last column first. Set a pressure
44,900 lb/h Assignwhere:
for the next upstream
Bubble
o
column. Set93 aoCpressure where: 146 oC
Point, 6 C
• The top product can be condensed by•cooling water
Pressure (avoid from
gradient the use high to100,000
low lb/h C2H3Cl
105,500 lb/h C H Cl
of refrigerant). • The condenser temperature
C2H4Cl2
not too low2 4 2
• The reboiler can heat up the bottom by • using MPS can
The reboiler heat
105,500 lb/hup the bottom by using LPS
• The operating
Boiling Points andcondition
Critical Constants
is far from T•c and
ThePcoperating
. condition is far from Tc and Pc.
Normal Boiling Point (oC) Critical Constants
Boiling
Chemical
Point 4.8 atm 12 atm 26 atm Tc (oC) Pc (atm)
(1 atm, oC)
HCl -84.8 -51.7 -26.2 0 51.4 82.1
C2H3Cl -13.8 33.1 70.5 110 159 56
C2H4Cl2 83.7 146 193 242 250 50
29
Step 3: Eliminate Differences in Composition
Design separation systems with suitable temperature & pressure.
Distillation 58,300 lb/h Distillation
Tower HCl Tower
12 atm 4.8 atm
52 × 106 Btu/hr
C2H3Cl
150 × 106 158,300 lb/h
Cl2 100,000 lb/h
Btu/hr
113,400 lb/h -26.2 oC 33 oC
DIRECT C2H4Cl2 PYROLYSIS
CHLORINATION 500oC
90oC, 1.5 atm 112 oC 26 atm
C2H4
Liquid at
44,900 lb/h Bubble
Point, 6 oC 93 oC 146 oC
100,000 lb/h C2H3Cl
105,533 lb/h C2H4Cl2
C2H4Cl2
105,533 lb/h
30
DP
Distillation Distillation
58,300 lb/h Tower
Calculate Temp.
Tower
12 atm HCl 4.8 atm
C2H3Cl
energy Change 100,000 lb/h
90 oC 26 atm DP DP
Change Change
4.8 atm
6 oC
3.4 x 106 12 atm
Temp. 93 oC 146 oC
Btu/hr
Change 100,000 lb/h C2H3Cl
105,533 lb/h C2H4Cl2
34
Cooling
Spray Water Distillation
58,300 lb/h
Distillation
Tower Tower
Quench 12 atm HCl 4.8 atm
Temp. C2H3Cl
Tank Cooler 100,000 lb/h
Change
90 oC -26.2 oC 33 oC
4.8 atm 170 oC Phase Temp.
26 atm DP DP
Change Change PRV o PRV
Cooling 6 C
Refrigerant
Water Condensor 12 atm
Temp. 93 oC 146 oC
Change 100,000 lb/h C2H3Cl
Cooler 105,500 lb/h C2H4Cl2
DP
PRV
36
Steam
Cooling
Water
Cooling
Water
Distillation Distillation
Tower 58,300 lb/h Tower
12 atm HCl 4.8 atm
C2H3Cl
Cooling
100,000 lb/h
Water
Final flowsheet -26.2 oC 33 oC
after task
integration for Refrigerant
the vinyl- 93 oC 146 oC
process.
37