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Id-19702005 (Bulk Technology)
Id-19702005 (Bulk Technology)
Submitted to
Dr. Md. Shah Alam
Associate Professor
Department of Electrical & Electronic Engineering
University of Chittagong
Submitted by
In microelectronics and semiconductors, "Bulk technology" means making tiny parts like
transistors inside a material. It's like crafting something within a block of wood. This
traditional method faces challenges as things get tinier, causing energy leakage and
heat.
Zone Refining: Zone refining is a common method for purifying Germanium and Silicon.
In this process, a rod of the impure material is passed through a high-temperature zone
created by an induction heater. The impurities tend to concentrate in the molten zone
and can be moved along the rod to a separate location. By repeating this process
multiple times, the material becomes progressively purer.
Czochralski Process: The Czochralski process is a widely used technique for growing
single crystals of Germanium and Silicon. In this method, a seed crystal is dipped into a
crucible of molten material and slowly pulled out while rotating. As the crystal grows, it
absorbs the pure material from the melt, resulting in a single crystal with fewer
impurities.
Fig:Czochralski process
Bridgman Technique:The Bridgman technique is a crystal growth method used for
several semiconductor materials, including Germanium and Silicon.
Fig:Bridgeman Technique
Crucible: A crucible is prepared with the material to be melted and crystallized. The
material is heated until it melts.
Cooling Gradient: The crucible is slowly pulled upward while it's being cooled from the
top. This creates a controlled temperature gradient within the crucible.
Solidification: As the crucible is pulled upward and cooled, the molten material solidifies
from the bottom to the top. This results in the growth of a single crystal with a
controlled crystalline structure.
The Bridgman technique allows for the controlled growth of large single crystals, which
are then sliced into wafers for semiconductor device fabrication. This method helps
reduce impurity concentration and create higher-quality materials for microelectronics.
For applications in electronics, optics, and other sectors, the traveling Heater Method is
useful for creating big, flawless crystals. It makes it possible to precisely regulate the
crystal's development conditions, producing crystals with predictable qualities. This
process is used to produce materials with specialized properties required for a variety
of technologies in both industrial and research contexts.
crystal ingots that can be sliced into wafers for the fabrication of semiconductor
devices such as integrated circuits.
The Czochralski process involves the controlled solidification of a melt to form a single
crystal with controlled purity and crystalline structure.
Junction:
Alloy Technique:
The "Alloy Technique" refers to a process in which two or more elements are mixed
together to form a compound with desired properties. In microelectronics and
semiconductor technology, this might involve creating semiconductor materials by
combining different elements in precise proportions to achieve specific electrical
properties or bandgap characteristics.
Alloy technique involves mixing specific elements to create compound materials with
desired properties, often used in microelectronics to tailor semiconductor
characteristics for specific applications.
Crystal growth techniques involve the controlled solidification of a material from a liquid
or vapor phase to create single crystals with well-defined structures. Techniques like the
Czochralski process and the Bridgman technique, as discussed earlier, are examples of
crystal growth techniques used in microelectronics to produce high-quality
semiconductor crystals.
Growth techniques are methods to create single crystals with controlled properties,
such as the Czochralski process, Bridgman technique, and epitaxial growth, crucial for
producing high-quality semiconductor materials.
Diffusion Technique:
Diffusion techniques introduce dopant atoms into semiconductor materials to alter their
electrical properties in a controlled manner, playing a pivotal role in creating different
regions of conductivity within microelectronic devices.
Planar Technology:
Planar technology is a fabrication approach where thin film layers of various materials
are deposited and patterned to create integrated circuits on a flat surface.
Epitaxial Growth:
Vapor phase epitaxy (VPE) is a technique where a crystal layer is grown on a substrate
by introducing vapor-phase reactants into a reaction chamber. The reactants combine
on the substrate surface to form a crystalline layer. VPE can be further categorized into
techniques like Metal Organic Vapor Phase Epitaxy (MOVPE) and Molecular Beam
Epitaxy (MBE), which offer more precise control over layer properties.
MOVPE is a specific type of vapor phase epitaxy that involves using metal organic
precursors to introduce materials onto a substrate surface. Organometallic compounds
in vapor form are used to deposit thin layers of semiconductor materials with high
precision. MOVPE is known for its ability to grow complex semiconductor structures
with varying compositions and doping profiles, making it essential for advanced
optoelectronic and semiconductor devices.
● Introducing metal organic precursor gasses and a carrier gas into the reactor.
● Decomposing the metal organic precursors at elevated temperatures.
● The decomposed species react with other gasses or the substrate surface to
deposit material.
● Achieving controlled layer growth by adjusting temperature and precursor flow
rates.
● The deposited material follows the substrate's crystal structure due to epitaxial
growth.
Crystal Growth: Using advanced techniques like the Czochralski process, Bridgman
technique, or epitaxial growth to create single crystals. This involves carefully
controlling temperature, pressure, and other parameters to ensure the crystal's quality
and properties.
Ingot Formation: For methods like the Czochralski process, a crystal ingot is grown by
pulling a seed crystal from a melt. The ingot forms a cylindrical shape.
Slicing: Cutting the grown ingot into thin slices called wafers using precision diamond
saws. The wafers are typically a few hundred micrometers thick.
Polishing: The wafers undergo mechanical and chemical polishing to achieve a smooth,
flat surface suitable for device fabrication.
Fig:Preparation of Single Crystals
Preparation of Wafers:
Oxide Growth or Deposition: Depending on the application, grow a thin layer of silicon
dioxide (oxide) on the wafer's surface using thermal oxidation or deposit other thin films
using techniques like chemical vapor deposition (CVD) or physical vapor deposition
(PVD).
Etching: Using chemical or plasma etching to selectively remove material from the
wafer's surface according to the patterned resist, creating defined structures.
Doping: Introducing dopant atoms into specific regions of the wafer using diffusion or
ion implantation to modify the electrical properties of the material.
Deposition: Depositing additional thin films of various materials onto the wafer surface
to create layers with specific functionalities, such as conductive, insulating, or
semiconducting properties.
Packaging: Once all desired structures and layers are created, wafers are further
processed to connect devices, encapsulate components, and prepare for integration
into electronic systems.
Throughout these steps, precise control over parameters like temperature, pressure,
and material composition is crucial to ensure the quality, uniformity, and reliability of the
resulting semiconductor devices.
4) Zone Movement:
● Gradually moving the molten zone along the length of the rod while
maintaining the solid-liquid interface within the desired region.
5) Impurity Concentration:
● As the molten zone moves, impurities tend to concentrate within the liquid
phase of the molten zone.
6) Solidification:
● Allowing the molten zone to solidify as it moves along the rod.
● The impurities remain concentrated in the liquid phase, while the solidified
region becomes purer.
7) Repeat the Process:
● Moving the molten zone back and forth along the rod multiple times, each
time concentrating impurities in the liquid and leaving behind a more
purified solid region.
8) Multiple Passes:
● The number of passes depends on the desired level of purification. More
passes result in higher purity.
9) Annealing (Optional):
● After completing the zone refining process, the final rod or ingot may
undergo an annealing process to relieve internal stresses and improve the
overall crystal quality.
The Zone Melting Process is effective in removing impurities from the material, as the
impurities tend to concentrate in the molten zone and are gradually pushed along the
length of the rod. This technique is essential for producing high-purity semiconductor
materials used in microelectronics, where even tiny amounts of impurities can affect
device performance.
Segregation Coefficient:
In bulk technology in microelectronics and semiconductor t , the segregation coefficient
(also known as partition coefficient) is a parameter that describes how different
elements or impurities distribute between the solid and liquid phases during the
crystallization or solidification process. It quantifies the tendency of an element to
preferentially concentrate in one phase over the other.
K= Cs ∕ Cl
where,
A segregation coefficient greater than 1 indicates that the element has a higher affinity
for the solid phase, meaning it tends to concentrate in the crystal as it grows during
solidification. On the other hand, a segregation coefficient less than 1 suggests that the
element prefers to remain in the liquid phase and is excluded from the crystal.
Dielectric films are insulating materials that are used to electrically isolate different
components within semiconductor devices. Dielectric film deposition involves the
process of depositing a thin layer of insulating material onto a semiconductor
substrate. This layer acts as an electrical insulator to prevent current leakage and
interference between adjacent conductive components.
Chemical Vapor Deposition (CVD): Precursor gases react on the substrate surface to
form a solid dielectric layer.
Spin-Coating: A solution containing the dielectric material is spun onto the substrate,
forming a uniform thin film.
Atomic Layer Deposition (ALD): Precursor molecules are sequentially adsorbed and
reacted on the substrate, creating precise thin films layer by layer.
Dielectric films are crucial in microelectronics to insulate and protect active electronic
components, reduce parasitic capacitance, and enhance device performance and
reliability.
● Insulation: Dielectric films are used to insulate and isolate different components
within integrated circuits and semiconductor devices, preventing electrical
interference and leakage between adjacent conductive layers.
Polycrystalline films are composed of small crystalline grains that are randomly
oriented, in contrast to single crystals with well-defined orientations. Polycrystalline film
deposition involves growing thin films made up of these small crystalline grains. These
films are often used for various applications, including thin-film transistors (TFTs),
photovoltaic cells, and memory devices.
Sputtering: Energetic ions bombard a target material, causing atoms to be ejected and
deposited onto the substrate.
Chemical Vapor Deposition (CVD): Precursor gasses react on the substrate surface to
form polycrystalline films.
Evaporation: Material is heated until it evaporates and then condenses on the substrate
to form a thin film.
Polycrystalline films are useful when single crystals are not practical or necessary for
the device's function. They can be engineered to exhibit specific properties based on
grain size and composition.
Both dielectric and polycrystalline film deposition are essential techniques in the field of
microelectronics and semiconductor technology, contributing to the fabrication of a
wide range of electronic and optoelectronic devices.
Junction Formation:
In microelectronics and semiconductor technology, "Junction Formation" refers to the
intentional creation of a region within a semiconductor material where the electrical
properties, such as conductivity and carrier concentration, change abruptly. This region
is called a "Junction."
PN Junction:
Bipolar transistors, such as NPN and PNP transistors, consist of two PN junctions in
close proximity. These transistors are essential components in amplification and
switching circuits. The behavior of bipolar transistors relies on the control of current
flow at these PN junctions.
Junction formation involves precise control over the doping concentrations of the P-
type and N-type materials, as well as the techniques used to bring these materials
together. Doping is the process of intentionally introducing impurities (dopants) into the
semiconductor crystal lattice to alter its electrical properties.
These masks are crucial for defining patterns, controlling material deposition, and
isolating specific regions of the substrate during device fabrication.
Oxide Masks:
Oxide masks are thin layers of silicon dioxide deposited on a semiconductor substrate
to act as a barrier or mask during subsequent processing steps. They are typically
formed through processes like thermal oxidation or chemical vapor deposition (CVD).
Etching Mask: Oxide masks can resist certain etching processes, allowing selective
removal of exposed regions of the substrate. This is useful for defining patterns in the
substrate.
Implantation Mask: During ion implantation, oxide masks can block ions from
penetrating the substrate in certain areas, controlling the doping of specific regions.
Diffusion Barrier: Oxide masks can prevent the diffusion of dopant atoms, isolating
regions of the substrate and controlling the formation of doped areas.
Gate Oxide: In MOS (Metal-Oxide-Semiconductor) devices, the oxide layer serves as the
gate insulator, controlling the flow of current between the gate electrode and the
semiconductor channel.
Nitride Masks:
Etching and Implantation Mask: Nitride masks can resist etching and ion implantation,
making them useful for defining patterns and controlling doping in specific regions.
Strain Engineering: Silicon nitride layers can induce strain in the underlying
semiconductor material, which can modify its electronic properties and improve device
performance.
Stress Engineering: Nitride masks can be used to engineer mechanical stress in the
substrate, affecting carrier mobility and enhancing device characteristics.
Both oxide and nitride masks play vital roles in microelectronics and semiconductor
technology by enabling precise material deposition, doping, and patterning processes.
Their selectivity in blocking certain processes while allowing others allows for the
creation of intricate and functional semiconductor devices.
Drift Transistors:
"Drift transistors" refer to a specific type of transistor designed to operate in a "drift"
mode, where the flow of charge carriers (electrons or holes) is primarily governed by the
drift process rather than diffusion. Drift transistors are used for high-power and high-
voltage applications due to their ability to handle larger currents and voltages compared
to conventional diffused transistors.
The operation of a drift transistor involves the controlled movement of charge carriers
through a drift region, often a lightly doped or intrinsic semiconductor layer. This drift
region extends between the source and the drain terminals of the transistor. Drift
transistors are particularly suited for devices that require efficient power amplification,
such as in radio frequency (RF) and power management circuits.
Characteristics of Drift Transistors:
● High Voltage Handling: Suitable for power applications with high voltages,
avoiding breakdown due to excessive electric fields.
● Low On-Resistance: Lower on-resistance than diffused transistors, reducing
power losses during conduction.
● Breakdown Voltage: Engineered for high breakdown voltages, tolerating
substantial voltage differences.
● Charge Carriers Drift: Efficient current conduction through charge carrier drift
under an electric field.
● Substrate Doping: Lightly doped drift region enhances charge carrier mobility.
● Power amplifiers
● Voltage regulators
● Motor control
● RF circuits and high-power switching devices.