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úfYaI úNd. fmryqre mÍlaIK

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Two hours
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Total Marks
ku - '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
úNd. wxlh - '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
mdi, - '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
m%Yak m;% mx;shg muKla iyNd.S fõ kï yßhla () fhdod olajkak' -

Wmfoia :
* m%Yak m;%fha kshñ; ia:dkfha Tfí wkkH;djh yÿkd .ekSug wjYH o;a; ,shkak'
* fuu m%Yak m;%h msgq 08 lska hqla; fõ'
* ish¨ u m%Yak j,g ms<s;=re imhkak'
* ms<s;=re W;a;r m;%fha muKla l;srhla () fhdod olajkak'

id¾j;% jdhq ksh;h R = 8.314 J K-1 mol-1 wej.dâfrda ksh;h NA = 6.022 x 1023 mol-1
ma,dkalaf.a ksh;h h = 6.626 x 10-34 Js wdf,dalfha m%fõ.h C = 3 x 108 ms-1

1. ksjerÈ m%ldY f;darkak'

^1& Ok lsrK fidhd .kakd ,oafoa f;dïika úisks'
^2& Ok lsrKj, e/m wkqmd;h fidhd .kq ,enqfõ ro¾*¾â úisks'
^3& Ok lsrK fm%dafgdak f,i kï lrk ,oafoa ro¾*¾â úisks'
^4& f.da,aâiaghska Ok lsrKj, .=K mÍCIKd;aulj wOHdmkh lrk ,§'
^5& isÿre iys; lef;davhla m<uq jrg Ndú; lrl Ok lsrK wOHhkh lrk ,oafoa f;dïika úisks'

2. X uQ,øjHh c,Sh ødjKfha § úhq.au bf,lafg%dak 5 la we;s ia:dhS X3+ whkh idohs' N+ñ wjia:dfõ §
X uQ,øjHh mrudKqjlg úhq.au bf,lafg%dak 4 la we;' X uQ,øjHh jkqfha"
^1& Fe ^2& Cr ^3& Sc ^4& Co ^5& Mn

3. lafjdkagï wxl l = 1 jk yd ml = -2 jk ghsfÜkshï mrudKqjl (Ti = 22) bf,lafg%dak .Kk ms<sfj<ska

^1& 8 yd 1 ^2& 8 yd 2 ^3& 12 yd 1 ^4& 12 yd 2 ^5& 10 yd 2

4. uOH ldnka mrudKqfõ úoHq;a RK;djh wdfrdayKh jk wdldrh jkafka"

^1& CO2 < HCN < HCOH < HCOOH ^2& CO2 < HCN < HCOOH < HCOH
^3& HCOOH < HCN < HCOOH < HCOH ^4& HCN < CO2 < HCOH < HCOOH
^5& HCOH < HCOOH < HCN < CO2

5. my; i`oyka ixfhda.fha IUPAC kduh jkqfha"

^1& 3-oxo-4-propyl-5-hydroxyhex-4-enoic acid
CHO ^2& 3-formyl-4-propyl-5-hydroxy-4-enoic acid
CH3CH2CH2 - C - CH - CH2 - COOH ^3& 3-formyl-5-hydroxy-4-propylhex-4-enoic acid
=

HO - C - CH3 ^4& 5-hydroxy-3-formyl-4-propylhex-4-enoic acid

^5& 4-formyl-2-hydroxy-3-propylhex-2-enoic acid

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
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6. my; § we;s m%fNaoj, uOh mrudKqfõ ixhqc;dj yd TlaislrK wxlh ksjerÈj olajd we;s hq.,h
y÷kd.kak'
m%fNaoh ixhqc;dj TlaislrK wxlh
^1& H 3O + 4 -2
^2& CH 2 O 4 -2
^3& SCN -
4 +2
^4& MnO4 2-
6 +7
^5& NO 2 3 +4

7. s f.dkqj ms<sn| wi;H jkafka"

^1& CIdÍh mdxY= f,day yhsfv%dlaihsvj, c, ødjH;dj ldKavfha my<g jeä fõ'
^2& CIdÍh mdxY= f,dayj, øjdxl tu wdj¾;fhau we;s CIdr f,dayj, øjdxlj,g jvd jeäh'
^3& CIdr f,day yd CIdÍh mdxY= f,day c,h m%n, f,i m%;l
s h
s% d j f,day yhsfv%dlaihsvh yd yhsv%cka jdhqj idohs'
^4& CIdßh mdxY= f,day i,af*agj, c, ødjH;djh ldKavh Tiafia my<g wvq fõ'
^5& ,s;shï yd ue.akSishï jd;fha oykfha§ Tlaihsvh yd khsg%hsvh idohs' tajd c,hg ±uQ úg wefudakshd
msg lrhs'

8. pd,l ridhksl iïnkaOfhka jk my; m%ldYk w;=ßka ksjerÈ m%ldYkh l=ula o@

^1& m%;sl%shd n÷kl WIaK;ajh jeä l< úg m%;sl%shd fõ.h jeä jkafka il%shk Yla;sh wvq jk neúks'
^2& ksh; WIaK;ajhlska we;s oDv n÷kll isÿjko jdhquh m%;sl%shdjlg WÉp jdhq tla l< úg" moaO;sfha
mSvkh jeä ù m%;sl%shd fõ.h jeä fõ'
^3& ksh; WIaK;ajfha§ m%;sl%shdjl" m%;sl%shl idkaøKh jeä l< úg iM, .egqï ixLHdj jeä jqj o iM,
.egqï Nd.h fkdfjkiah'
^4& >k m%;sl%shlhla ishqïj l=vq l< úg m%;sl%shd fõ.h jeä jkafka" m%;sl%shlj, pd,l Yla;sh jeä jQ neúks'
^5& W;afm%arlhla fh¥ úg moaO;sfha G Ok isg RK olajd fjkia fõ'

9. idkaøKh iudk CH3COOH(aq) yd NH3(aq) ødjK 2 l iu mßud tlsfkl ñY% lrk ,§' tu wjia:djg
wod< tka;e,ams" tkafg%dms yd .síia Yla;s úm¾di ksjerÈj olajd we;af;a"
H S G H S G
^1& + + + ^2& - - -
^3& + + - ^4& - + -
^5& - - +

10. MgCO3 yd CaCO3 hk ,jK ñY%Khla 1000 0C WIaK;ajhl ksh; ialkaOhla ,efnk f;la r;a lrk
,§' msg jQ jdhq mßudj /ia lrk ,o w;r mSvkh 7 × 104 Pa hgf;a jdhqfõ mßudj 83.41 dm3 la úh'
wdrïNl ñY%Kh c,fha Èh fldg thg (NH4)C2O4 jeämqr mßudjla tl;= l< úg wjlafIam jQ CaC2O4
ys ialkaOh 25.6 g úh' wdrïNl ñY%Kfha ;snQ MgCO3 ialkaOh fldmuK o@
[Ca = 40 , Mg = 24 , C = 12 , O = 16]
^1& 8.4 g ^2& 16.8 g ^3& 21 g ^4& 42 g ^5& 84 g

11. c,Sh ødjKhl§ A, B iy C hk m%;sl%shl tlsfkl m%;sl%shd lr m%;sM, ,ndfohs'

A + B + C  m%;sM,
by; m%;sl%shdj my; § we;s uQ,sl mshjr yryd isÿjk nj mÍlaIKd;aulj fidhdf.k we;'
A+C P ^fõ.fhka isÿ fõ'&
P+C Q ^fõ.fhka isÿ fõ'&
Q + B T ^fiñka isÿ fõ'&
T + nC + nB  m%;sM,
by; uq,a m%;sl%shdfjys YS>%;d kshuh jkafka"
^1& R = K[Q][B] ^2& R = K [A] [C] ^3& R = K [A] [B] [C]
^4& R = K[A] [C] 2
^5& R = K [A] [B] [C] 2

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
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12. CH 3
COOH
c.HNO3 PCl5
A B C
Cl c.H2SO4 ks¾' AlCl3
by; i|yka m%;sl%shd wkqms<sfjf<ys A, B, C ys jHqy ms<sfj<ska"
COOH COCl O
NO 2
^1& NO 2 NO 2 Cl C CH 3
Cl Cl
O NO
^2& COOH COCl 2
C
Cl Cl CH3
NO 2 NO 2 Cl
^3& COOH COCl O NO 2
CH3 C
NO 2 Cl NO 2 Cl Cl

COOH COCl O Cl
^4&
CH3 C NO 2
Cl Cl
NO 2 NO 2
COOH COCl O NO 2
^5& NO 2 NO 2 CH3 C
Cl Cl Cl

13. A kï jdhqfõ 4 mol la ksh; mßud Ndckhl my; mßÈ iu;=,s; ùug bv yßk ,§'
2A(g) A2(g)
127 0C § iu;=,s; moaO;sfha iuia; mSvkh 8.314 × 105 Pa yd jdhq ñY%Kfha >k;ajh 10 kg m-3 fõ' A ys
id' m' ia 30 kï A2(g) ys wdxYsl mSvkh jkqfha"
^1& 2.77 × 105 Pa ^2& 4.16 × 105 Pa ^3& 5.54 × 105 Pa ^4& 8.31 × 105 Pa ^5& 1.25 × 105 Pa

14. A kï ldnksl ixfhda.hla HNO2 iu. m%;l s %shd lr N2 jdhqj msglr m%ldY iudjhúl;djh fkdfmkajk
B kï ixfhda.h njg m;ajk w;r" B , Br2 Èhr új¾K fkdlrhs' B idkaø H2SO4 iu. m%;sl%shdfjka C
kï cHdñ;sl iudjhúl;djh fmkajk ixfhda.h idok w;r C, Br2 Èhr új¾K lr m%ldY iudjhúl;djh
fmkajk D idohs' fï wkqj A úh yelafla"
CH 3 CH 3 CH 3
^1& H 2 N CHCNH2 ^2& H2 NCH 2 CH2CHNH2
CH 3
CH 3 CH 3
^3& H2 NCH 2 CCH2NH2 ^4& CH 3 CH2 CNH2
CH 3 CH 3
CH 2CH 3
^5& H2 NCH 2 CNH2
CH 2CH 3
15. øjhl jdIamSlrKfha tka;e,ams fjki yd jdIamSlrKfha tkafg%dms fjki ms<sfj<ska 45.00 kJ mol-1 yd
90.0 JK-1 mol-1 fõ' øjfhys ;dmdxlh jkqfha"
^1& 45.0 0C ^2& 62.7 0C ^3& 100.0 0C ^4& 135.0 0C ^5& 227.0 0C

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
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16. 25 0C § M kï f,dayfha M(OH)2 ys Ksp = 1.0 × 10-10 mol3 dm-9 fõ' 25 0C § 0.01 mol dm-3 M2+(aq)
ødjKhlska M(OH)2 wjlafIam fkdùu i|yd ix;Dma; NH3 ødjKhl ;sìh hq;= wju NH4Cl idkaøKh
fldf;la o@ 25 0C § ix;Dma; NH3 ødjKhl idkaøKh [NH4+(aq)] [OH-(aq)] = 1.6 × 10-5 mol2 dm-6 fõ'
^1& 0.16 mol dm-3 ^2& 0.26 mol dm-3 ^3& 0.32 mol dm-3
^4& 0.40 mol dm-3
^5& 4.00 mol dm -3

17. Q kï ldnksl ixfhda.h my; ksÍCIK ,nd ÿks'

(a) wefudakSh AgNO3 iu. ߧ levm;la ,nd fkdÿks'
(b) ;kql NaOH m%;sl%shd lrhs'
(c) PCC iu. m%;sl%shd lrhs'
(d) f,dayuh Na iu. oaúmrudKql jdhqjla ,nd ÿks'
by; ksÍCIKj,g wkqj my; ljrla P ixfhda.h úh yels o@
CH 2OH
CHO O
^1& ^2& CCH 3 ^3&
OCH 3
OH
OH
O O
CHCCH3 CH2CCH 3
^4& ^5&
OH OH
18. ialkaOh 50.00 g la jQ Zn ;yvqjla mßudj 100 cm3 la jQ c,Sh AgNO3 øjKhl .s,aÆ úg lsishï
ld,hlg miq f,day ;yvqfõ ialkaOh 53.02 g la nj fidhd .kakd ,§' fuu wjia:dj jk úg ødjKfha
Zn2+ idkaøKh fldmuK o@ ( id'm'ia' Zn = 65, Ag = 108 )
^1& 0.020 mol dm-3 ^2& 0.140 mol dm-3 ^3& 0.200 mol dm-3
^4& 0.285 mol dm-3
^5& 0.464 mol dm-3

19. idkaøKh 2 mol dm-3 jQ NaOH ødjK 100 cm3 iy 1 mol dm-3 ødjK 100 cm3 ñY% lr ms<sfh, l< ødjK
ms<sn| ksjerÈ m%ldYh l=ula o@ (NH3 Kb w.h 2 × 105 mol dm-3)
^1& fuh wï, yd NIau idkaøK wiudk c,Sh ødjKhls'
^2& fuys§ iEfok ødjKh mQ¾K iajdrCIl fkdfõ'
^3& fuu ødjKfha pH w.h 9 - 10 w;r fõ'
^4& ñY%Kh ;=< NH4+ whk u.ska ,ndfok H3O+ idkaøKh NH3 u.ska ,ndfok OH- idkaøKhg jvd by< fõ'
^5& fuu ødjKhg wï,fhka ;j;a 100 cm3 tl;= l< úg ødjKh WodiSk fõ'

20. d f.dkqfõ uQ,øjH iïnkaOfhka i;H m%ldY $ m%ldYhg jkqfha"

^1& 3d uQ,øjHj, úoHq;a RK;dj mrudKql l%udxlh iu. jeä fõ'
^2& d f.dkqfõ iuyr uQ,øjH WKq c,h iu. m%;sl%shd lr H2 jdhqj ,nd foa'
^3& ish¨u wdka;ßl uQ,øjHj, legdhk c,h fyda c,Sh NH3 iu. j¾Kj;a ixlS¾K idohs'
^4& Mn2O3 ÿn, wdï,sl .=K orK Tlaihsvhls'
^5& d f.dkqfõ iuyr uQ,øjH ixfhda. idok úg bf,lafg%dak wIaGlh iïmQ¾K lrhs'

21. my; i|yka l=uk m%ldYh wi;H fõ o@

^1& wO%eùh ^iy-ixhqc& ødjlj, iødjK tka;e,amsh úYd,h'
^2& MgCl2 j, iødjK tka;e,amsh" oe,sia tka;e,amshg jvd úYd, ksid c,fha ødjH fõ'
^3& ,jKhg Bg u ,dlaIKsl ødjH;djla we;s w;r" th WIaK;ajh u; /§ mj;s'
^4& AgCl jeks iaj,am jYfhka ødjH whksl ixfhda.hl c,Sh ødjK ;=< tajdfha whk iajdëkj mj;s'
^5& Cl- whk ødjKhl HgCl j, ødjH;dj" ixY=oaO c,fha HgCl ys ødjH;djg jvd wvq h'

22. AgBr yd AgCl j,ska ix;Dma; ødjKhl § Ag+ idkaøKh (mol dm-3) fldmuK o@
AgCl ys Ksp = 1 × 10-18 mol2 dm-6 | AgBr ys Ksp = 3 × 10-18 mol2 dm-6
^1& 1.0 × 10 -9
^2& 1.73 × 10-9
^3& 2.0 × 10-9 ^4& 7.07 × 10-10 ^5& 3.08 × 10-10

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
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23. T WIaK;ajfha§"
A2(g) + B2(g) 2AB(g) hk iu;=,s;fha iu;=,s; ksh;h K1
2AB(g) + B2(g) 2AB2(g) hk iu;=,s;fha iu;=,s; ksh;h K2
T WIaK;ajfha§ AB2(g) 1/2 A2(g) + B2(g) ys iu;=,s; ksh;h jkqfha"
^1& K1K2 ^2& K1K2 / 2 ^3& 2 / 2K1K2 ^4& 2 / K1K2 ^5& K1K2

24. 25 0C § tal NdIañl ÿn, wï,hla jk CH3COOH ys 0.1 mol dm-3 jk c,Sh ødjKhl pH = 3 fõ'
wï,fha ú>gk ksh;h jkafka"
^1& 1.0 × 10-5 mol dm-3 ^2& 1.0 × 10-4 mol dm-3 ^3& 1.0 × 10-3 mol dm-3
^4& 1.0 × 10-2 mol dm-3 ^5& 1.0 × 10-1 mol dm-3

25. my; ±lafjk ;ks mshjr m%;sl%shdj i,lkak'

A(g) 2B(g) + 3C(g)
m%;sl%sjdj ødj n÷kla ;=< P0 mSvkfha we;s A(g) jdhq idïm,hlska wrUk ,§'
;;amr t ld,hlg miq moaO;sfha mSvkh P úh'
tu fudfydf;a m%;sl%shdfõ YS>%;d;j iudkqmd;sl jkqfha"
^1& 3P - P0 ^2& 5P - P0 ^3& P - P0 ^4& 2P - P0 ^5& P - 2P0

26. my; ±lafjk ixfhda. i,lkak'

NH 2 NH 2 CH2NH2 NH 2
OH

CH 2 OH NO 2 COOH

(A) (B) (C) (D)

my; § we;s ksÍlaIK ish,a,u olajkq ,nk ixfhda. jkqfha"
(i) C6H5N+NCl- iu. j¾Kj;a ,jK idohs'
(ii) Na2CO3 iu. CO2 msg fkdlrhs'
(iii) NaNO2 / HCl iuÕ ldur WIaK;ajfha § m%;sl%shd lrjd ,efnk M,hg H3O+ / K2Cr2O7 tl;=
lr WKqiqï l< úg fld, meye;s ødjKhla iEfoa'
^1& A iy B muKs' ^2& A iy C muKs' ^3& B iy D muKs'
^4& C muKs' ^5& A muKs'

27. iu ujq, NiCl2 yd SnBr2 wvx.= c,Sh ødjKhla .%emhsÜ bf,lafg%dav fhdodf.k úoHq;a úÉfþokh lrhs'
m<uqj isÿjkafka ñka ljrla o@
iïu; TlaisyrK úNj E/ V
Ni (aq) + 2e
2+
Ni(s) -0.236
Sn (aq) + 2e
2+
Sn(s) +0.141
Br2(aq) + 2e 2Br (aq)
-
+1.077
Cl2(g) + 2e 2Cl-(aq) +1.360
^1& lef;davh u; ksl,a ;ekam;a jk w;r wefkdavfha § laf,daÍka jdhqj ksoyia fõ'
^2& lef;davh u; ksl,a ;ekam;a jk w;r wefkdavfha § Br2(g) iEfoa'
^3& lef;davh u; Sn(s) ;ekam;a jk w;r wefkdavfha § Br2(g) iEfoa'
^4& lef;davh u; Sn(s) ;ekam;a jk w;r wefkdavfha § Cl2(g) iEfoa'
^5& wefkdavh u; Sn(s) ;ekam;a jk w;r lef;davfha § Br2(g) iEfoa'

28. H2C2O4(aq) + 2H2O(l) 2H3O+(aq) + C2O42-(aq)

oaúfm%daàl wï,hla jk Tlai,sla wï,h i|yd Ka1 = 5.36 × 10-2 jk w;r Ka2 = 5.3 × 10-5 fjhs' fï wkqj
by; m%;sl%shdj i|yd iu;=,s;;d ksh;h jkafka'
^1& 5.36 × 10-2 ^2& 1.9 × 10-16 ^3& 3.3 × 10-8 ^4& 1.9 × 10-13 ^5& 2.8 × 10-6

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
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29. c, ¥IKh iïnkaOfhka my; l=uk m%ldYh wi;H fõ o@

^1& NO3- yd PO43- whk" c,fha ødjH Tlaiscka m%udKh wvq lsÍug odhl fõ'
^2& c,fha Èh jQ ldnksl øjH we;súg c,fha ødjH Tlaiscka m%udKh wvq fõ'
^3& ner f,day whk we;s úg c,fha ødjH Tlaiscka m%udKh wvq fõ'
^4& NO3- whk wêl f,i wvx.= c,h mdkh lsÍfuka reêrfha Tlaiscka mßjyk l%shdj,shg ndOd isÿ fõ'
^5& we;eï nelaàßhd j¾. c,hg hlv tl;= lsÍug odhl fõ'

30. idkaøKh C jk c,Sh NH4OH ødjKhl pH fiùu i|yd Ndú; l< yelafla"
^1& pH = pKW + 1/2 pKb + 1/2 log C ^2& pH = pKW - 1/2 pKb + 1/2 log C
^3& pH = pKW + 1/2 pKb - 1/2 log C ^4& pH = pKW + pKb - log C
^5& pH = 1/2 pKW + 1/2 pKb - 1/2 log C

 wxl 31 isg 40 olajd jq m%Yak j,g my; Wmfoia mßÈ ms<s;=re imhkak'

(1) (2) (3) (4) (5)

(a) iy (b) (b) iy (c) (c) iy (d) (d) iy (a) m%;spdr tlla muKla fyda fjk;a
muKla muKla muKla muKla m%;spdr ixLHdjla fyda ksjerÈh'
ksjerÈh ksjerÈh ksjerÈh ksjerÈh

31. my; ljr m%;sl%shd § we;s tka;e,ams úm¾hdih ksjerÈj olajhs o@

(a) Cl ys nkaOk ú>gk tka;e,amsh Cl2(g) 2Cl(g)
(b) Br ys mrudKqlrK tka;e,amsh Br2(l)  2Br(g)
(c) Mg ys ic,k tka;e,amsh
2+
Mg2+(aq)  M2+(g)
(d) Ca ys fojk whkSlrK tka;e,amsh Ca(g)  Ca2+(g) + 2e

32. lsishï m%;sl%shdjla A kï m%;sl%shlhlg idfmaCIj fofjks fm< fõ' ñka woyia jkafka"
(a) m%;sl%shdj m%Odk mshjr follska isÿ fõ'
(b) fõ.fhka isÿjk mshjf¾ A ys iafgdhslsfhdañ;sl ix.=Klh fol fõ'
(c) A jeh ùfï iS>%;djh A ys idkaøKfha j¾.hg iudkqmd;sl fõ'
(d) w;rueÈ il%sh ixlS¾Kh iE§fï§ A ys wKql;djh folls'

33. A2+(aq) / A(s) iy B+(aq) / B(s) kue;s bf,lafg%dav fofla E0 w.hhka ms<sfj<ska -0.14 V iy -0.74 V fõ'
fuu bf,lafg%dv a iy tu.ska idokq ,nk fldaIh iïnkaOfhka my; l=uk j.ka;h s $ j.ka;s ksjerÈ fõo@
(a) A bf,lafg%%davh wi, § TlaislrKhla o B bf,lafg%davh wi, TlaisyrKhla o isÿ fõ'
(b) E0cell = + 0.60 V jk w;r fldaI m%;sl%shdj A2+(aq) + 2B(s) 2B+(aq) + A(s) fõ'
(c) B bf,lafg%davfha isg A bf,lafg%davh fj;g bf,lafg%dak Odrdjla .uka lrhs'
(d) B yd ,jK ødjKhla A uQ,øjHh iu. m%;sl%shdfjka B uQ,øjHh úia:dmkh l< yelsh'

34. pd,l wkqljdofha Wml,amk jkafka"

(a) jdhq wKq w;r wka;¾ wKql wdl¾IK n, fkdi,ld yeßh yelsh'
(b) wKq w;r we;sjk iEu .eàulau mQ¾K m%;Hia: fõ'
(c) wKql fõ.h ksrfmaCI WIaK;ajh u; muKla r|d mj;S'
(d) ´kEu jdhqjl uOHkH pd,l Yla;sh ksh;hla fõ'

35. .;sl iu;=,s;;djfha mj;sk my; moaO;sh i,lkak'

2P(g) + Q(g) 2R(g) ; H > 0
(a) WIaK;ajh jeä l< úg miq m%;sl%shd iS>%;dj wvq fõ'
(b) ksh; WIaK;ajfha§ P ys idkaøKh fo.=Khla lr Q ys idkaøKh w¾Ohla l< úg iu;=,s;;d ,CIH
fjkia fkdfõ'
(c) ksh; WIaK;ajfha§ moaO;sfha iuia; mßudj jeäl< úg R ys wdxYsl mSvkh jeä fõ'
(d) ksh; WIaK;ajfha§ P ys idkaøKh jeä l< úg" Q ys idkaøKh wvq jk w;r R idkaøKh jeä fõ'

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
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36. l=re÷ f;,a ;=< wvx.= iskue,aäyhsâj, jHqyh my; wdldr fõ'
CH = CHCHO

iskue,aäyhsâ ms<sn| ksjerÈ m%ldYh $ m%ldY jkqfha"

(a) fuh ixfhda. wdldr follska mj;S'
(b) fuys ish¨ ldnka mrudKq tlu ;,hl we;'
(c) fuys ish¨ mrudKq tlu ;,hl mj;S'
(d) Br2 / CCl4 yd m%;sl%Shd lr ldnksl ixfhda. tllg jvd ,nd foa'

37. ixY=oaO c,fha l,dm igyk my; ±lafõ'

mSv kh
B
C
X Y

1.0
0.006 Z
T
²P
A
WIaK;ajh
273.16 373.15

by; l,dm igyk iïnkaOfhka ksjerÈ j.ka;s^h& jkqfha"

(a) ;%sl ,CIHfha we;s ñY%Kfha WIaK;ajh ksh;j ;nd mSvkh jeä lsÍfï§ øj c,h muKla b;sß fõ'
(b) TC jl%h u.ska whsia yd c,jdIam w;r iu;=,s;j mj;sk WIaK;aj mSvk fmkajhs'
(c) ;%sl ,CIHfha we;s øjHfha mSvkh ksh;j ;nd WIaK;ajh wvq lrf.k hdfï§ øj l,dmh muKla b;sß fõ'
(d) mSvkh ksh;j ;nd P kï ixhq;sh iys; øjHfha WIaK;ajh wvq lrf.k hdfï§ u,a ;=ySk we;s fõ'

38. my; i|yka tajdhska l=ula i;H fõ o@

(a) úoHq;a úÉfþokfha § RK w.%fha iEuúgu TlaisyrKhla isÿ fõ'
(b) úoHq;a ridhksl fldaIhl È wefkdavfha TlaislrKhla isÿjk w;r úoHq;a úÉfþokfha § wefkdavfha
TlaisyrKhla isÿ fõ'
(c) iEu úoHq;a ridhksl TlaislrKhl § u WodiSk mrudKq Ok whk njg m;aùu isÿ fõ'
(d) úoHq;a úÉfþokfha § bf,lafg%dav u; iu;=,s; bf,lafg%dav m%;sl%shd isÿ fõ'

39. c,fha my; iu;=,s; moaO;sh l%shd;aul fõ'

-
H2O(l) H+(aq) + OH (aq) = +57 kJ mol-1 , 298 K §
c,fha whksl .=Ks; my; iólrKfhka m%ldY l< yel'
-
[H+(aq)][OH (aq)] = 1 × 10-14 mol2dm-6 , 298 K §
by; o;a; wkqj tlÕúh yels m%ldY $ m%ldYh f;darkak'
(a) c,h r;a lrk úg [H+(aq)] idkaøKh jeä fõ'
-
(b) c,h r;a lrk úg [OH (aq)] idkaøKh jeä fõ'
(c) 25 0C g jeä WIaK;ajj, § ixY=oaO c,fha pH w.h 7 g jvd jeä fõ'
(d) c,fha whksl .=Ks;h WIaK;ajh wkqj fjkia fkdfõ'

40. nyqwjhúl iïnkaOfhka i;Hh jkqfha"

(a) fíla,hsâ iu`. Br2 b;d fyd¢ka m%;sls%hd fkdlrhs'
(b) PET, terithalic acid yd ethylene glycol tlaùfuka iEfok w;r tys § NH3 wKqjla bj;a fõ'
(c) iajNdúl rn¾ i|yd tal wjhjhla bÈßm;a fkdlrhs'
(d) khsf,daka ;dm ia:dmk lD;su nyqwjhjhls'

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
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 wxl 41 isg 50 olajd m%Yak j,g my; Wmfoia mßÈ ms<s;=re imhkak'

m%;spdrh m<uq m%ldYh fojk m%ldYh

. ^1& i;Hh i;H jk w;r" bka m<uqjekak ksjerÈj myod fohs'
^2& i;Hh i;H jk w;r" bka m<uqjekak ksjerÈj myod fkdfohs'
^3& i;Hh wi;Hh'
^4& wi;Hh i;Hh'
^5& wi;Hh wi;Hh'

m<uq m%ldYh fojk m%ldYh

41. NaOH yd l2 w;r m%;sl%shdfjka NaIO, NaI NaOH j,g Tlaisldrlhla f,i l%shd l< yelsh'
iy H2O iefoa

42. hSiaÜ fhdod iSks meiSfï § ,efnk ødjKfha idkaø t;fkda,a ødjK ;=< § hSiaÜj,g Ôjh
t;fkda,a 12 ] muK we;' mj;ajd .; fkdyel'

43. buta-1,3-diene iu`. HBr m%;l s% dlr 3-bromobut-1-ene

s h fuu buta-13-diene yd HBr w;r" m%;sl%shdfjka
iy 1-bromobut-2-ene idohs' iïm%hqla; jdHqy we;s lrhs'

44. legdhk úYaf,aIKfha § III ldKavfha legdhk III ldKavfha legdhk wjlafIam lsÍu i|yd
i|yd mÍCId lsÍug fmr ødjKh kgjd H2S NH4OH / NH4Cl tl;= l< úg H2S ;snqKfyd;a
ish,a, bj;a lrhs' IV ldKavfha legdhkh o wjlafIam fõ'

45. *Sfkda,a c,Sh Br2 Èhr iu. iqÿ wjlafIamhla ,nd *Sfkda,a c,fha uo jYfhka ødjH w;r NaOH(aq)
fohs' ;=< fyd¢ka Èhjk w;r NaHCO3(aq) iu`.
m%;sl%shdfjka CO2(g) ,nd fkdfoa'

46. 2NH3(g) N2(g) + 3H2(g) fuys ú>gk m%;sl%shdjl iu;=,s;;d ksh;h (Kp) WIaK;ajh u;
m%;sY;h WIaK;ajh u; muKla r|d mj;S' muKla r|d mj;S'

47. ksh; mSvkhl § isÿjk jdhquh ;dmodhl ksh; mSvkhl § m%;sl%shdjlska ksl=;ajk ;dmfhka
m%;sl%shdjl WIaK;ajfha ke.Su" tu m%;sl%shdj fldgila moaO;sh m%idrKh ùu i|yd wjfYdaIKh
ksh; mßud ;;a;aj hgf;a isÿ l< úg §g jvd flf¾'
wvqh '

48. idkaø NaCl ødjKhlg idkaø HCl tl;= l< idudkHfhka by< ødjH;djla we;s ixfhda.
úg wjlafYamhla iEfoa' i|yd ødjH;d .=Ks;h fkdfhfoa'

49. iajNdúl rn¾j, m%;Hia:;djh by< h' rn¾ j,alkhsia lsÍfuka tys m%;Hia:;djh by<
kexfõ'

50. iqfmdaIKhg fya;=jk m%Odk;u whk jkafka c,fha ødjH ldnksl ixfhda. jeäjk úg
NO3- iy PO43- whk fõ' COD w.h wvq fõ'

*****

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]