Measurement Repeatability

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measurement pH of the buffer solution

repeatability
4,01 ± 0,001 Bias 7,00±0,001 Bias 10,000±0,001 bias

1 4,01 0,000 7,02 -0,003 10,01 -0,001


2 4,01 0,000 7,01 -0,001 10,03 -0,003
3 4,00 0,002 7,00 0,000 10,02 -0,002
4 4,02 -0,002 7,01 -0,001 10,01 -0,001
5 4,00 0,002 7,02 -0,003 10,00 0,000
6 4,00 0,002 7,00 0,000 10,00 0,000
7 4,01 0,000 7,01 -0,001 10,00 0,000
Average 4,01 0,001 7,01 -0,001 10,01 -0,001
Standard deviation (SD) 0,008 0,002 0,008 0,001 0,012 0,001
Correction (C) 0,00 -0,001 -0,001

AVERAGE :
n

Ubias =
∑ (bias)2n
i=l
n
Ubias = Uncertainty of bias

n = NUMBER OF REPETITIONS

STANDARD DEVIATION


n

SD= ∑ (xi−x )
i =l
n−1
Sd = standard deviation

X = Average measurement result

Xi = MEASUREMENT TO i

n = NUMBER OF REPETITIONS

CORRECTION:

K=µ-x

K = THE DIFFERENCE BETWEEN CRM VALUES AND MEASUREMENT RESULTS

µ = VALUES CRM Ph

X = average values Ph

µ−x
Bias =
µ
Bias = the difference between the pH measurement result and the CRM pH value, divided by the
CRM pH value
X = average measurement pH

µ = values CRM pH

UBIAS 0,002 0,002 0,001


UESDM 0,001 0,0004 0,0004
UCRM 0,001 0,001 0,001
bias uncertainty 0,002 0,002 0,002
precision uncertainty 0,003 0,003 0,004
resolution uncertainty 0,003 0,003 0,003
combined etiquette 0,005 0,005 0,006
U95%, K=2 0,01 0,01 0,01

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