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  • Perhitungan MDL

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    Alfat Isnawansyah
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    The document discusses the method detection limit (MDL) test for COD. It states that the estimated spike for MDL testing is 1-5 times the estimated MDL value. Various calculations are shown to determine the MDL estimate based on testing spike levels of 1x, 2x, 3x, 4x, and 5x the estimated MDL. The document concludes by determining the volume of standard solution that should be pipetted for the MDL spike test based on the calculated concentration.

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    The document discusses the method detection limit (MDL) test for COD. It states that the estimated spike for MDL testing is 1-5 times the estimated MDL value. Various calculations are shown to determine the MDL estimate based on testing spike levels of 1x, 2x, 3x, 4x, and 5x the estimated MDL. The document concludes by determining the volume of standard solution that should be pipetted for the MDL spike test based on the calculated concentration.

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    © All Rights Reserved
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    14 views3 pages

    Perhitungan MDL

    Uploaded by

    Alfat Isnawansyah
    The document discusses the method detection limit (MDL) test for COD. It states that the estimated spike for MDL testing is 1-5 times the estimated MDL value. Various calculations are shown to determine the MDL estimate based on testing spike levels of 1x, 2x, 3x, 4x, and 5x the estimated MDL. The document concludes by determining the volume of standard solution that should be pipetted for the MDL spike test based on the calculated concentration.

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    UJI BERDASARKAN METODE DETECTION LIMIT (MDL)

    Pemerikasaan limit deteksi pada COD di lakukan dengan MDL


    Jadi perkiraan spike untuk MDL = (1 – 5) X MDL estimasi
    MDL estimasi = Nilai IDL

    Jadi perkiraan spike untuk MDL =


    a. 1 X MDL Estimasi =2.04 mg/L
    = (1 x 0.68) d. 4 X MDL Estimasi
    =0.68 mg/L = (4 x 0.68)
    b. 2 X MDL Estimasi =2.72 mg/L
    = (2 x 0.68) e. 5 X MDL Estimasi
    =1.36 mg/L = (5 x 0.68)
    c. 3 X MDL Estimasi =3.4 mg/L
    = (3 x 0.68)

    Syarat keberterimaan 2 – 5%
    - 2% = 2/100 x 50 = 1 mL  maka 1 mL larutan KHP standar di add kan dengan air bebas mineral
    sampai tanda tera 50 mL
    - 3% = 3/100 x 50 = 1 mL  maka 1.5 mL larutan KHP standar di add kan dengan air bebasmineral
    sampai tanda tera 50 mL
    - 4% = 4/100 x 50 = 1 mL  maka 2 mL larutan KHP standar di add kan dengan air bebas mineral
    sampai tanda tera 50 mL
    - 5% = 5/100 x 50 = 1 mL  maka 2.5 mL larutan KHP standar di add kan dengan air bebas
    mineral sampai tanda tera 50 mL

    perhitungan konsentrasi MDL estimasi

    A. 2% d. 4 x MDL estimasi = 2.72


    a. 1 x MDL estimasi = 0.68 mg/L V1 . N1 = V2 . N2
    V1 . N1 = V2 . N2 50 mL . 2.72 mg/L = 1 mL x N2
    50 mL . 0.68 mg/L = 1 mL x N2 N2 = 136 mg/L
    N2 = 0.68 mg/L e. 5 x MDL estimasi = 3.4 mg/L
    b. 2 x MDL estimasi = 1.36 mg/L V1 . N1 = V2 . N2
    V1 . N1 = V2 . N2 50 mL . 3.4 mg/L = 1 mL x N2
    50 mL . 1.36 mg/L = 1 mL x N2 N2 = 170 mg/L
    N2 = 68 mg/L B. 3%
    a. 1 x MDL estimasi = 0.68 mg/L
    c. 3 x MDL estimasi = 2.04 mg/L V1 . N1 = V2 . N2
    V1 . N1 = V2 . N2 50 mL . 0.68 mg/L = 1.5 mL x N2
    50 mL . 2.04 mg/L = 1 mL x N2 N2 = 0.4 mg/L
    N2 = 102 mg/L b. 2 x MDL estimasi = 1.36 mg/L
    V1 . N1 = V2 . N2 e. 5 x MDL estimasi = 3.4 mg/L
    50 mL . 1.36 mg/L = 1.5 mL x N2 V1 . N1 = V2 . N2
    N2 = 45.5 mg/L 50 mL . 3.4 mg/L = 2 mL x N2
    N2 = 85 mg/L
    c. 3 x MDL estimasi = 2.04 mg/L D. 5%
    V1 . N1 = V2 . N2 a. 1 x MDL estimasi = 0.68 mg/L
    50 mL . 2.04 mg/L = 1.5 mL x N2 V1 . N1 = V2 . N2
    N2 = 68 mg/L 50 mL . 0.68 mg/L = 2.5 mL x N2
    d. 4 x MDL estimasi = 2.72 N2 = 0.272 mg/L
    V1 . N1 = V2 . N2 b. 2 x MDL estimasi = 1.36 mg/L
    50 mL . 2.72 mg/L = 1.5 mL x N2 V1 . N1 = V2 . N2
    N2 = 90.6 mg/L 50 mL . 1.36 mg/L = 2.5 mL x N2
    e. 5 x MDL estimasi = 3.4 mg/L N2 = 27.2 mg/L
    V1 . N1 = V2 . N2
    50 mL . 3.4 mg/L = 1.5 mL x N2 c. 3 x MDL estimasi = 2.04 mg/L
    N2 = 113.3 mg/L V1 . N1 = V2 . N2
    C. 4% 50 mL . 2.04 mg/L = 2.5 mL x N2
    a. 1 x MDL estimasi = 0.68 mg/L N2 = 40.8 mg/L
    V1 . N1 = V2 . N2 d. 4 x MDL estimasi = 2.72
    50 mL . 0.68 mg/L = 2 mL x N2 V1 . N1 = V2 . N2
    N2 = 0.34 mg/L 50 mL . 2.72 mg/L = 2.5 mL x N2
    b. 2 x MDL estimasi = 1.36 mg/L N2 = 54.4 mg/L
    V1 . N1 = V2 . N2 e. 5 x MDL estimasi = 3.4 mg/L
    50 mL . 1.36 mg/L = 2 mL x N2 V1 . N1 = V2 . N2
    N2 = 34 mg/L 50 mL . 3.4 mg/L = 2.5 mL x N2
    N2 = 68 mg/L
    c. 3 x MDL estimasi = 2.04 mg/L
    V1 . N1 = V2 . N2
    50 mL . 2.04 mg/L = 2 mL x N2 Perhitungan volume yang akan di pipet pada
    N2 = 51 mg/L larutan standar
    d. 4 x MDL estimasi = 2.72
    V1 . N1 = V2 . N2 V1 . N1 = V2 . N2
    50 mL . 2.72 mg/L = 2 mL x N2 V1 . 1000mg/L = 50 mL x 51
    N2 = 68 mg/L mg/L.
    V1 = 2.55 mL.

    Jadi ambil larutan standar 2.55 mL pada 1000 ppm dan masukkan ke dalam labu 50 mL dan di
    tambahkan sampel hingga tanda batas. Larutan ini di sebut larutan spike dan di ukur panjang
    gelombangnya untuk memperoleh nilai MDL.

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