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Periodic Table 01-Invert
Periodic Table 01-Invert
Periodic Table
Om Pandey
TOPICS TO BE COVERED
1. Genesis Of Periodic Table
4 Nature of Oxides
.
Dobereiner’s Traids
That when elements are arranged in order of increasing atomic masses, every
eighth element has properties similar to the first. Newlands called it law of
octaves because similar relationship exists in the musical notes also.
VIII
Lanthanide series
Actinide series
Dobereiner’s Known to
triads Mendeleev Known to Ancients
Modern Periodic Table
70
36
32 60
Atomic number
Atomic weight
28 50
24 40
20 30
16 20
12 10
𝐅𝐫𝐞𝐪𝐮𝐞𝐧𝐜𝐲
Periodic Table
He
H
B C N O F Ne
Li Be
Na Mg Al Si P S Cl Ar
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te l Xe
Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
Fr Ra Ac Rf Db Sg Bh Hs Mt Ds Rg Uub Nh Fl Mc Lv Ts Og
Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
Electronic Configuration
He
H
B C N O F Ne
Li Be
Na Mg Al Si P S Cl Ar
K Ca Ga Ge As Se Br Kr
Rb Sr In Sn Sb Te l Xe
Cs Ba Tl Pb Bi Po At Rn
A Alkali’s
113 Nihonium
Z e–
Z
e–
Shielding / Screening
Constant
Screening Effect
There is a reduction in nuclear charge due to presence of screen b/w test
electron and nucleus.
Penetration effect
s p d f : Penetration power
: Shielding effect
A He+
B Li2+
C Be3+
D In all cases
Atomic radius
Radius =
H2 H2
Atomic radius
Practice
❖ B P S Cl Br
❖ C S Al Cs
Atomic radius
He
Li Be B C N O F Ne
Na Mg Al Si P S Cl Ar
K Ca Ga Ge As Se Br Kr
Rb Sr In Sn Sb Te l Xe
Cs Ba Tl Pb Bi Po
Lanthanide Contraction
Electronic Configuration of La, Hf, Ac, Rf, Ce, Lu, Th, Lr ?
4f Series : Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
D-block
4 Sc Ti V Cr Mn Fe Co Ni Cu Zn
5 39Y 40Zr Nb Mo Tc Ru Rh Pd Ag Cd
Be Be+ Be2+
Cation
Anion O O– O2–
Isoelectronic species
N3– O2– F– Na+ Mg2+ Al3+
A Lanthanoid contraction
B Diagonal relationship
C Actinoid contraction
Ionisation Energy
He
Li Be B C N O F Ne
Na Mg Al Si P S Cl Ar
K Ca Ga Ge As Se Br Kr
Rb Sr In Sn Sb Te l Xe
Cs Ba Tl Pb Bi Po
Ionisation Energy
❖ Li Be B C N O F Ne
❖ Na Mg Al Si P S Cl Ar
n
❖ Be B
4 Sc Ti
Mg Al
5 39Y 40Zr
Ca Ga
6 57La 58Ce 71Lu 72Hf
Consider the following ionization enthalpies of two elements 'A' and
Q. ‘B‘ Which of the following statements is correct ?
B Both 'A' and 'B' belong to group-2 where 'A' comes below 'B'.
C Both 'A' and 'B' belong to group-2 where 'B' comes below 'A'
D Both 'A' and 'B' belong to group-1 where 'A' comes below 'B'
A [Ne]3s23p1
B [Ne]3s23p3
C [Ne]3s23p2
D [Ar]3d104s24p3
The 1st Ionisation enthalpy of Na, Mg and Si are 496, 737, 776 kJmol–1
Q.
respectively then what will be the 1st ionisation enthalpy of Al in
kJmol–1
Diagonal Relationship
n=2 Li Be B C N
n=3 Na Mg Al Si P
Size : Li Li+
Mg Mg2+
B C N
In Sn Sb
Tl Pb Bi
PbO2
PbCl2
Electron Affinity
E.A. = E.A. =
H = H =
Li Be B C N O F Ne
Na Mg Al Si P S Cl Ar
Electron Affinity
Variation in Group Variation in Period
Cl
F
❖ B C N O F
❖ Al Si P S Cl
He
B C N O F Ne
Al Si P S Cl Ar
Ga Ge As Se Br Kr
In Sn Sb Te I Xe
Tl Pb Bi Po
Note : (1) Oxygen has min. EGE in family.
(2) Halogen family has max. EGE in periodic table.
(3) Any element from G-17 has higher EGE wrt other element in PT.
The formation of the oxide ion O2–(g), from oxygen atom requires first an
Q. exothermic and then an endothermic step as shown below :
𝑶 𝒈 + 𝒆− → 𝑶− 𝒈 ; ∆𝒇 𝑯 = −𝟏𝟒𝟏 𝒌𝑱 𝒎𝒐𝒍−𝟏
𝑶− 𝒈 + 𝒆− → 𝑶𝟐− 𝒈 ; ∆𝒇 𝑯 = +𝟕𝟖𝟎 𝒌𝑱 𝒎𝒐𝒍−𝟏
Thus process of formation of O2- in gas phase is unfavorable even though
O2- is isoelectronic with neon. It is due to the fact that
A Electron repulsion outweighs the stability gained by achieving noble gas configuration
❖ Cl Br S O ❖ I S Se O
❖ Li B
A Li– C Be–
B B– D C–
He
Li Be B C N O F Ne
Na Mg Al Si P S Cl Ar
K Ca Ga Ge As Se Br Kr
Rb Sr In Sn Sb Te I Xe
Cs Ba Tl Pb Bi Po
Electronegativity
A B
= E A − B − E A − A EB − B
A − B = 0.208 k cal mol−1
Electronegativity
Li Be B C N O F
Na Mg Al Si P S Cl
K Ca Br
Rb Sr I
Cs Ba
A Lithium
B Carbon
C Boron
D Beryllium
As
Non – metal oxides Metalloid oxides CaO TiO2 CrO3
Sb
As2O5 Sb2O5
MgO ZrO2 Mn2O7
SeO2 TeO3 Se
GeO2 Te
A SeO2
B Al2O3
C Sb2O3
D Bi2O3
Match the following :
Q. Oxide Nature
(a) CO (i) Basic
(b) BaO (ii) Neutral
(c) Al2O3 (iii) Acidic
(d) Cl2O7 (iv) Amphoteric
Which of the following is correct option?
(a) (b) (c) (d)
Thank You !