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Safety Data Sheet

Revision Number: 004.1 Issue date: 06/29/2016

1. PRODUCT AND COMPANY IDENTIFICATION


Product name: Loctite(R) Nordbak(R) Wearing IDH number: 702295
Product type: Epoxy resin Item number: 99812_10233000
Restriction of Use: None identified Region: United States
Company address: Contact information:
Henkel Corporation Telephone: (860) 571-5100
One Henkel Way MEDICAL EMERGENCY Phone: Poison Control Center
Rocky Hill, Connecticut 06067 1-877-671-4608 (toll free) or 1-303-592-1711
TRANSPORT EMERGENCY Phone: CHEMTREC
1-800-424-9300 (toll free) or 1-703-527-3887
Internet: www.henkelna.com

2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
WARNING: CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.

HAZARD CLASS HAZARD CATEGORY


SKIN IRRITATION 2
EYE IRRITATION 2A
SKIN SENSITIZATION 1

PICTOGRAM(S)

Precautionary Statements

Prevention: Avoid breathing vapors, mist, or spray. Wash affected area thoroughly after handling.
Contaminated work clothing should not be allowed out of the workplace. Wear protective
gloves, eye protection, and face protection.
Response: IF ON SKIN: Wash with plenty of water. IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation or
rash occurs: Get medical attention. If eye irritation persists: Get medical attention. Take off
contaminated clothing.
Storage: Not prescribed
Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local
governmental regulations.

Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the
United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).

See Section 11 for additional toxicological information.

3. COMPOSITION / INFORMATION ON INGREDIENTS


Hazardous Component(s) CAS Number Percentage*

IDH number: 702295 Product name: Loctite(R) Nordbak(R) Wearing


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Aluminium oxide 1344-28-1 30 - 60
Epoxy resin Proprietary 10 - 30
Silicon carbide 409-21-2 5 - 10
Silicon dioxide 7631-86-9 1-5
Magnesium oxide 1309-48-4 1-5
Treated fumed silica 67762-90-7 1-5
Neopentyl glycol diglycidyl ether 17557-23-2 1-5
Titanium dioxide 13463-67-7 0.1 - 1
Substituted silane Proprietary 0.1 - 1

* Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections.

4. FIRST AID MEASURES


Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention.

Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove
contaminated clothing and footwear. Get medical attention. Wash clothing
before reuse.

Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Get medical attention.

Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel.


Never give anything by mouth to an unconscious person. Get medical
attention.

Symptoms: See Section 11.

5. FIRE FIGHTING MEASURES


Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide.

Special firefighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as
turn-out gear.

Unusual fire or explosion hazards: In case of fire, keep containers cool with water spray. Closed containers may
rupture (due to build up of pressure) when exposed to extreme heat.

Hazardous combustion products: Oxides of carbon. Aldehydes. Irritating vapors.

6. ACCIDENTAL RELEASE MEASURES


Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected
personnel.

Environmental precautions: Do not allow product to enter sewer or waterways.

Clean-up methods: Ensure adequate ventilation. Wear appropriate personal protective equipment.
Refer to Section 8 "Exposure Controls / Personal Protection" prior to clean up.
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder,
universal binder, sawdust). Scrape up spilled material and place in a closed
container for disposal.

IDH number: 702295 Product name: Loctite(R) Nordbak(R) Wearing


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7. HANDLING AND STORAGE
Handling: Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist.
Wash thoroughly after handling. Use only with adequate ventilation. Keep
container closed.

Storage: Keep container tightly closed and in a cool, well-ventilated place away from
incompatible materials. Store away from heat, sparks, flames, or other
sources of ignition. Protect from direct sunlight.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION


Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure
controls and protective equipment for each task performed.

Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER


5 mg/m3 PEL
1 mg/m3 TWA Respirable fraction.
Aluminium oxide None None
Respirable fraction. 15 mg/m3 PEL Total
dust.
Epoxy resin None None None None
3 mg/m3 TWA
Respirable fraction. 5 mg/m3 PEL
10 mg/m3 TWA Respirable fraction.
Silicon carbide None None
Inhalable fraction. 15 mg/m3 PEL Total
0.1 FIBERS/CM3 dust.
TWA Fiber.
20 MPPCF TWA 3 mg/m3 TWA
Silicon dioxide 6 mg/m3 TWA None
0.8 mg/m3 TWA Respirable fraction.
10 mg/m3 TWA 15 mg/m3 PEL Total
Magnesium oxide None None
Inhalable fraction. particulate.
10 mg/m3 TWA 15 mg/m3 TWA Total
Inhalable dust. dust.
Treated fumed silica None None
3 mg/m3 TWA 5 mg/m3 TWA
Respirable fraction. Respirable fraction.
Neopentyl glycol diglycidyl ether None None None None
15 mg/m3 PEL Total
Titanium dioxide 10 mg/m3 TWA None None
dust.
Substituted silane None None None None

Engineering controls: Use local ventilation if general ventilation is insufficient to maintain vapor
concentration below established exposure limits.

Respiratory protection: Use a NIOSH approved air-purifying respirator if the potential to exceed
established exposure limits exists.

Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should
be used if the potential for splashing or spraying of product exists. Safety
showers and eye wash stations should be available.

Skin protection: Use chemical resistant, impermeable clothing including gloves and either an
apron or body suit to prevent skin contact.

9. PHYSICAL AND CHEMICAL PROPERTIES


Physical state: Paste
Color: Gray
Odor: Mild
Odor threshold: Not available.
pH: Not available.
Vapor pressure: Not available.
Boiling point/range: Not available.
Melting point/ range: Not available.

IDH number: 702295 Product name: Loctite(R) Nordbak(R) Wearing


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Specific gravity: 2.3337
Vapor density: >1
Flash point: > 93 °C (> 199.4 °F) ; Estimated
Flammable/Explosive limits - lower: Not available.
Flammable/Explosive limits - upper: Not available.
Autoignition temperature: Not available.
Flammability: Not applicable
Evaporation rate: Not available.
Solubility in water: Insoluble
Partition coefficient (n-octanol/water): Not available.
VOC content: < 1.0 %; < 10 g/l (value for resin and hardener together) (estimated)
Viscosity: Not available.
Decomposition temperature: Not available.

10. STABILITY AND REACTIVITY


Stability: Stable under normal conditions of storage and use.

Hazardous reactions: None under normal processing.

Hazardous decomposition Oxides of carbon. Aldehydes. Irritating vapors.


products:

Incompatible materials: Strong acids. Strong bases. Strong oxidizing agents.

Reactivity: Not available.

Conditions to avoid: Keep away from heat, ignition sources and incompatible materials.

11. TOXICOLOGICAL INFORMATION


Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion

IDH number: 702295 Product name: Loctite(R) Nordbak(R) Wearing


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Potential Health Effects/Symptoms

Inhalation: Inhalation of vapors or mists of the product may be irritating to the respiratory system.
Skin contact: Causes skin irritation. May cause allergic skin reaction.
Eye contact: Causes serious eye irritation.
Ingestion: May cause gastrointestinal tract irritation if swallowed.

Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects
Aluminium oxide None Irritant, Nuisance dust, Corrosive
Epoxy resin None Allergen, Irritant
Silicon carbide None Nuisance dust
Oral LD50 (Rat) = > 22,500 mg/kg
Silicon dioxide Nuisance dust
Oral LD50 (Mouse) = > 15,000 mg/kg
Blood, Central nervous system, Immune
Magnesium oxide None
system, Irritant
Treated fumed silica None Irritant
Allergen, Blood, Bone Marrow, Immune
Neopentyl glycol diglycidyl ether None
system, Irritant, Reproductive
Irritant, Respiratory, Some evidence of
Titanium dioxide None
carcinogenicity
Substituted silane None Allergen, Irritant

OSHA Carcinogen
Hazardous Component(s) NTP Carcinogen IARC Carcinogen
(Specifically Regulated)
Aluminium oxide No No No
Epoxy resin No No No
Silicon carbide No Group 2A No
Silicon dioxide No No No
Magnesium oxide No No No
Treated fumed silica No No No
Neopentyl glycol diglycidyl ether No No No
Titanium dioxide No Group 2B No
Substituted silane No No No

12. ECOLOGICAL INFORMATION


Ecological information: Not available.

13. DISPOSAL CONSIDERATIONS


Information provided is for unused product only.

Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal.

Hazardous waste number: Not a RCRA hazardous waste.

14. TRANSPORT INFORMATION


The transport information provided in this section only applies to the material/formulation itself, and is not specific to any
package/configuration.

U.S. Department of Transportation Ground (49 CFR)


Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None

IDH number: 702295 Product name: Loctite(R) Nordbak(R) Wearing


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International Air Transportation (ICAO/IATA)
Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None

Water Transportation (IMO/IMDG)


Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None

15. REGULATORY INFORMATION


United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act
Inventory.
TSCA 12 (b) Export Notification: None above reporting de minimis

CERCLA/SARA Section 302 EHS: None above reporting de minimis.


CERCLA/SARA Section 311/312: Immediate Health, Delayed Health
CERCLA/SARA Section 313: This product contains the following toxic chemicals subject to the reporting requirements of
section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40
CFR 372). Aluminium oxide (CAS# 1344-28-1).

California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This
product contains a chemical known to the State of California to cause birth defects or other
reproductive harm.

Canada Regulatory Information

CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic
Substances List.

16. OTHER INFORMATION


This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format.

Prepared by: Rebecca Coons, Regulatory Affairs Specialist

Issue date: 06/29/2016

DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel
Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods
Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods
mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and
persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing,
Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular
purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.

IDH number: 702295 Product name: Loctite(R) Nordbak(R) Wearing


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