= Dept. of TE \ ‘EES =e — bw. — hugh e | Seer = Marks: 20 | J Full Mark =20 cr Time! 25(Minutes) , Answer all Questions:- aR CaS, sen Se simx, Qiiit) JamescotD : a QW Gaya 4 ee ICourse: Hum-1121 + Time: 40 mins Marks:20 Q Why is ‘what to’ and ‘how to produce’’ problems in every economy? - . ony Make a comparative analysis between market and command‘to solve these problems.Dept. of TE bee —_ yh 7 7 Marks: 20 | Derive an equation which correlates the elevation of boiling point with lowering of vapour pressure. o Bu) Define reverse osmosis. Describe the reverse osmosis processes for the purification of wastewater. A cant of dry ar was passed through a soon of 264g ofbaazac acid in 30.0g of eiber (CsHsOC2Hs) and then through pure ether. The loss in weight of the Soluffén Was 0.645 oni eee agus g. What is the molecular mass of benzoic acid? Silene yet = 15) State and Gerive Raoult’s law for lowering of vapour pressure. How is this law used for the determination of () Time: 30 mins molecular mass of a non-volatile solute?Khulna University of Engineering & Technology Dept. of Textile Engineering Polymer Engineering (TE 1123) Class rest Mark: 20 (10+10) ‘Time: 20 min 1. Prove that larger the polydispersity index, broader the molecular weight distribution. 2. How Tg and Tm is related with amorphous region?Class Test: 20 Marks (Polymer Engineering) ‘Time: 25 Min I. Define Polymer, Functionality. 2. Why is Nylon 6,6 Co-polymer? : 3, What kind of thermal polymer is PVC? And why? 4, Write down the monomer with the chemical structure below the polymer (i) Polypropylene (ii) Polyester 5. What is aromatic polyamide? Give an example of the reaction of aromatic polyamide. RoweMarks: 20 Time:25 mins Math-1119 Combined CT_TE_Ch 1121_30 Minute_20 Mark LC oF Part-A, Show that the sum of transport num ge of of ation apd anion of an woe, is equal to one. (05) The standard reduction potential of 2hv2n and A Ag electrodes are -0.76 and 0.08V respectively. Calculate the EMF of the cell: Zn/Zn?" (0.0001 M)liAg'(0.1 MY/Ag. (03) Part-B | What is emulsion? Classify it with examples, (3) | Define i) Gold Number; ii) Peptization; iii) Flocculation value; iv) Suspension (4) | How will you prepare sol by aggregation method? (3) |lic acid solution is not required to standardize but NaOII solution is need to standardize -Why? raw the schematic diagram of conical flask, pipette and burette. rite down the equation that helps to determine the neutralization curves by measuring pH and express the Za ieanings of each term, Zany slight excess of SnClz is necessary for Fe determination? Calculate the amount of hardness in g/L when 5.5 mL of 0.01MEDTA solution was required to titrate 10 mL of the sample solution, Vv Ss (2 Why the conductance at the neutralizing point is not zero? ‘Why did you add HCl during iron determination? Write down all the reactions involved in Fe estimation. 2ODraw the pH titration curve of strong acid vs strong base and weak acid vs strong base. !Sketch the plot of conductance ¥s volume of NaOH added for 0.1M HCI and indicate the ions presence before ‘and after the endpoint in the plot.Time:25 mins Math-1119 Marks: 20 5 Veorx sa) évatuate [2 OE de 05 1 1(b) Evaluate lim ,,,.. Geant os 2,(a) ‘State Euler theorem and verity it forthe function f(xy) = y*In@®).Department : TE Full Mark =20 c Time : 25(Minutes Answer all Questions:- " ae Qu. Test the continuity and differentiability of the Function: 1 whenx <0 a=)1+sinx whenO0 sx <1n/2 f@)= any ePre! 24D? whenx 0/2 ee aI Q2. Find &, + (sinx)&°* +(cosx)" Q3. If y=sin(axtb) then find Yn - a eS[Eoure Cod Math 1121] Total Marks: 20] Time: 30 min. 1 2 Date: 7 February 2023 ‘Answer all the questions Evaluate the following integral: ‘ 1 @ Jaa 7 1 Gi) Sam (iii) ORD ay Why we use a constant in indefinite integral? 06 05 03Answer all the questions le 1, Evaluate the fllowing integral a a 3% (3x2+27x+59) " dx @ See % Olea 2, Obtain a reduction formula for fx" sin x dx and hence evaluate J x" sin x dx. Inn acid-base titration is designed in such a way that strong base is added drop wise from burette to weak acid solution which is kept in conical flask. Sketch the pH neutralization curve of this reaction. How can you determine the end point in these experiment precisely? (3) What is HSAB? Classify the following substances as HSAB: I, Ag’, PO4 H", Na*, N°(4) Define conjugate acid and base with examples. (2) “Diphenylamine acts as a redox indicator” ustify. (2) State Arthenius concept of acid-base, What are the drawbacks of this theory? (2) hi “Water acts as an amphoteric substances” Explain. (2) ie AA buffer solution contains 0.015 mole of ammonium hydroxide and 0.025 mole of émonium chloride Caleulate the pH value of solution. At room temperature{dissociation constant of NH4OH is 1.8x10-5. (3) Mention some applications of buffer solutions (2) ¥ phy? a SIS= hurrotte to weak, Class Test." Full Marks: 30 Time: 30 Minutes lines. 6 4 ZZ How do you measure quality of steam? Explain. %& Show that enthalpy of fluid before throttling is equal to the enthalpy of the fluid after throttling. 5 4, Differentiate between sensible heat and latent heat. 5 |& How do you measure the deviation ofa gas from ideal gas behavior? Explain ihre phase change diagram for water and show different regions, points and with the help of principle of corresponding states. gj ‘Why is the heat engine not 100% efficient? 3 4 Work is a path function but properties are ‘point functions. Explain.