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Materials Today: Proceedings 68 (2022) 2026–2031

Contents lists available at ScienceDirect

Materials Today: Proceedings


journal homepage: www.elsevier.com/locate/matpr

Use of industrial wastes as a filling materials in foam concrete: A short


review
Y. Sivananda Reddy, S. Anandh ⇑, S. Sindhu Nachiar, P.T. Ravichandran
Department of Civil Engineering, College of Engineering and Technology, SRM Institute of Science and Technology, Kattankulathur, Chengalpattu 603203, India

a r t i c l e i n f o a b s t r a c t

Article history: The building sector is concerned about the environment, so dedicated to fabricating more strong and dur-
Available online 2 September 2022 able concrete is a responsibility for the new era. As a result, normal concrete materials can be replaced
with innovative and sustainable materials, reducing environmental issues. Foam Concrete (FC) is one
Keywords: such material, which is a lightweight substance made from cement, sand, water, and a foaming agent.
Sustainable concrete It has numerous benefits. Yet, it fails to offer enough strength and shrinkage behavior to concrete. The
Foaming agent paper’s major goal is to look at industrial wastes as a filler material for concrete that can substitute for
Shrinkage behavior
the shortcomings of foam concrete. The review also looks at the stability, bulk densities, strength qual-
Pore size & pore structure
ities, pore size and pore structure, and other aspects of the material.
Copyright Ó 2022 Elsevier Ltd. All rights reserved.
Selection and peer-review under responsibility of the scientific committee of the 4th International Con-
ference on Advances in Mechanical Engineering (ICAME 2022).

1. Introduction ash [3]. Silica fume is a by-product of the silicon and ferrosilicon
alloy industries. It is an ultrafine powder, also known as micro sil-
Construction is a major industry that consumes heavy ica, that contains 75 % silicon [4]. GGBS is a by-product of the iron
resources, which in turn results in the economic development of and steel manufacturing processes. It is made by reducing smelted
a country. In another light, it is also an industry that has a greater iron and blast furnace slag with water or steam. One tone of GGBS
impact on environmental. Cement production alone contributes 8– production uses 1300 MJ of energy and emits 0.07 tonnes of CO2
10 % of global greenhouse gas emissions, with the value expected [5]. Copper slag is generated from smelting ores. Most of the time,
to rise to from time to time [1]. It is obvious that wasting natural it is granulated into the size of sand, with particles size not bigger
resources has negative environmental consequences. Green con- than 5 mm and not smaller than 1 mm [6].
crete should be used to limit the usage of natural resource. Foam Cement, fine aggregate, and water make up the slurry. A foam-
concrete is a type of material made from foam, cement, sand, ing agent and water are used to make foam. Foam solution and
and water. Green concrete is made by mixing industrial wastes cement-based slurry are combined together to make foam con-
with foam in the concrete mix. crete. Foam Concrete (FC) provides a number of advantages over
Globally, industrial wastes are a major cause for concern. Envi- standard concrete, including high flowability, density, excellent
ronmental, economic, and health problems arise when this waste is temperature resistance, and the requisite compressive strength.
primarily buried in landfills. fly ash, silica fume, ground granulated By maintaining the optimum foam dosage, FC density can range
blast furnace slag, and copper slag are all examples of significant from 400 kg/m3 to 1800 kg/m3. FC could be used in a variety of
industrial wastes [2]. India has the most coal mines and thermal structural components, including partitions, insulation, and infill
power plants that use coal to make electricity. On the other hand, grades [7–9]. Fan and Wang were the first to get a patent for FC
bituminous and non-bituminous coal both have a 40 % ash content. with Portland cement [10] and Valore was the first one to study
At present, thermal power plants make 120–150 million tons of fly on cellular concrete in 1954 [11].

⇑ Corresponding author.
E-mail addresses: sy3802@srmist.edu.in (Y. Sivananda Reddy), anandhs@srmist.
edu.in (S. Anandh), sindhus@srmist.edu.in (S. Sindhu Nachiar), ravichap@srmist.
edu.in (P.T. Ravichandran).

https://doi.org/10.1016/j.matpr.2022.08.354
2214-7853/Copyright Ó 2022 Elsevier Ltd. All rights reserved.
Selection and peer-review under responsibility of the scientific committee of the 4th International Conference on Advances in Mechanical Engineering (ICAME 2022).
Y. Sivananda Reddy, S. Anandh, S. Sindhu Nachiar et al. Materials Today: Proceedings 68 (2022) 2026–2031

2. Materials and properties 2.2. Silica fume (SF)

2.1. Fly ash (FA) As a waste product, SF is made when silicon material or ferrosil-
icon alloys are made. Most of the time, you can get SF in two colors,
The coal ash that is left over after burning coal is one of the as seen in Fig. 2. SF is a cementitious additive that makes concrete
principal factors of FA production. Fig. 1 shows how much FA is much stronger and more durable. Adding SF to concrete makes it
used in different parts of India. The hydrated cement ingredients less likely to break down by reducing the porous permeability
from the Gateway cement plant are put to good use when FA is and improving the pore structure. This makes it less likely for cal-
used in concrete. Also, FA in foam concrete tends to make the con- cium hydroxide to move through the concrete and makes it more
crete stronger because the pores are spread out evenly and the resistant to sulphate attacks by increasing its content. One of the
number of connected pores goes down [12,13]. For better results, best ways to use silica fume is in concrete.
foam concrete should have a high level of FA activity [14].
2.2.1. Impact of SF on the properties of foam concrete
Chung et al. [28] used 10 % of SF along with cement, and it is
observed that in the early stage of growth, SF can stop bleeding
and make the concrete paste more uniform and stick together.
When 10 % SF was added to lightweight concrete, the percentages
2.1.1. Impact of FA on the properties of foam concrete.
of strength went up based on how heavy the two materials were
Foamed concrete showed greater results in its hardened state
[29].
properties when FA is used in concrete to a certain extent. Wet
In his research [30], author used SF as a stabilizer in FC and
ground FA can enhance the hydration activity and bubble distribu-
found that it might be helpful for stabilizing foam. But stabilizing
tion of foamed PC-WGFA concrete [15]. Using the FA/C ratio in lar-
has different effects when added at different times. Table 2 shows
ger content makes the hydration action slower and leads to slow
how the properties of the foam concrete change when SF is added.
compressive strength [16]. Foam Concrete has a compressive stress
When SF and slag powder are mixed together in a mortar with
that is directly proportional to its dry density [13,17,18]. The
foam, the structure of the pores can be improved. Once 30 % of slag
amount of FA added and the strength of concrete are directly
and 6 % of SF are added to foam concrete, it makes the concrete
related. This is because the amount of calcium (CaOH2) in the con-
more resistant to freezing. Compared to the control group, the test
crete is going down [19]. But strength development is low after
group lost mass by up to 1.99 %, stress by up to 14.49 %, and poros-
28 days. However, concrete with 30 % FA has a small increase in
ity by up to 0.513.
compression stress [20].
Some studies say that FA made foam absorb more water for the
same amount of foam. So, the amount of FA used depended a lot on 2.3. Ground granulated blast furnace slag (GGBS):
its experimental conditions, like the type of foaming agent, mineral
admixture, and density [21]. Table 1 shows how the properties of GGBS was made from iron and steel production. Slag is formed
foamed concrete change when FA is introduced. Porosity is a cru- as limestone, iron ore, and coke are combined in a kiln, and iron is
cial element that impacts the physical, thermal, and durability generated. There are many different ways to cool and harden iron
properties of foam concrete. In comparison to lightweight aggre- ore, but one common method is immersion in water. GGBS is cre-
gates in concrete, foam concrete has a lower splitting tensile ated by drying the resulting liquid to a fine powder. In 1972, Joseph
strength. On the other hand, fly ash-based mixtures did better than Davidovits began developing GGBS as an alternative to OPC [33].
fine aggregate [13,22,23]. FA and silica fume (SF) were added to Every year, 400 million tons of steel slag are produced by steel
foam concrete to increase its flexural strength, which ranged from companies around the world [34,35]. Fig. 3 shows the increase in
4.02 Mpa to 5.29 Mpa [24]. the use of GGBS in concrete manufacturing since 2015. Environ-

Fig. 1. Utilization of Fly Ash in India [51].

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Y. Sivananda Reddy, S. Anandh, S. Sindhu Nachiar et al. Materials Today: Proceedings 68 (2022) 2026–2031

Table 1
Characteristics of concrete made with fly ash as a cement substitute.

Effect of fly ash on Hardened properties of foam concrete


S. No Major Hardened state properties References
Ingredients
MC WD CS TC DEM WA Porosity
(%) (kg/m3) (Mpa) (W/m.K) (Mpa) (%) (%)
1 PC, FA, LSP 20 800 7.26 x x x x [15]
2 FA, FS, MP 30 500 3.19 0.134 x x x [19]
3 FA, RFA F.A-4 & RFA-25 600 2.69 0.16 2357 70.5 40.8 [25]
4 FA 66.67 1245 6.2 0.035 x x x [12]
5 FA-f, FA-c FAf-30, fAc-50 1400 5.7 x x x 0.252 [13]
6 FA 40 700 1.18 x x 42 x [26]
7 FA 25 1600 16.63 x x x x [27]
8 FA, P-F 50 1500 40 x xx x x [16]

Note: MC-Material Content, WD-Wet Density, CS-Compressive Strength, TC-Thermal Conductivity, DEM-Dynamic Elastic Modulus,
WA-Water Absorption, PC-Portland Cement, FA-Fly Ash, LSP-Lime Stone Powder, FS-Furnace Slag, MP-Mineral Powder, RFA-Recycled Fined Aggregate, FAf-Fly Ash Fine, fAc-
Fly Ash Coarse, P-F- Pozz Fill.

Zhao [37] used different amounts of GGBS with cement and


found that the strength of GGBS increased by 25 % when cement
was used to replace 30 % of it. If you use more than 30 % GGBS,
it could make the foam concrete less strong. It has been seen that
carbonation goes up when 50 % of the GGBS is replaced with
cement. This can be fixed by giving it more time to cure [41].

2.4. Copper slag (CuS):

CS comes from a pyrometallurgical process used to make cop-


per. It is also considered to be an oxide-based waste [43]. In gen-
eral, compounds of iron, silica, aluminum, calcium, and copper
Fig. 2. Silica fume in white and grey colour. are found in CuS, In order to make 1 ton of pure copper, about
2.2–3.0 tons of CuS will be made [44]. More than 24.6 million tons
of CuS are made annually. When there is less than 0.8 % copper in
mental risks and ecological degradation have resulted from the
slag, it’s also sold as a product that is similar to regular basalt
dumping of byproducts like slag from factories and mills in open
(which is crystalline) or obsidian (which is not crystalline) [43].
places over the years. Since steel slag has become increasingly
When the amount of calcium oxide in this material goes up or
important in research and development, it is being used to create
when sodium hydroxide is added, it can be used as a partial or full
new recycling and utilization methods around the world [35,36].
replacement for Portland cement [45]. Many researches were done
on using copper slag as fine aggregate replacement and succussed
2.3.1. Impact of GGBS on the properties of foam concrete in gaining required properties.
Due to its higher fine content, GGBS, when used as a 50 %
cement replacement, which shown to reduce the slump value of 2.4.1. Impact of CuS on the properties of foam concrete
mortar with foam [37], Using GGBS can increase the workability The smooth surface of CuS aggregate makes it easier to work
of concrete, but the mix is still sticking together. GGBS have a flat with mortar mixes. Workability also goes up as content grows.
finish and less water is seen when they are mixed [38]. When 30 % The flow value of the mortar made with 100 % CuS is 107 % higher
to 70 % GGBS is used in foam concrete, compressive strength than the flow value of the control mix [46]. Table 4: Properties of
increases by a lot [37,39]. Table 3 shows properties of foam con- concrete with copper slag as a fine aggregate replacement, The
crete with GGBS as a cement replacement. A high dose of GGBS specific gravity ranges from 2.8 to 3.8, depending on how much
could make volume changes in foam concrete. The lowest shrink- iron is in the rock [43].
age strain is seen when 20 % of the concrete is replaced with GGBS The unit weight of CuS is a little bit higher than that of the tra-
[40]. ditional aggregate. The ability of the material to soak up water is

Table 2
Characteristics of concrete made with silica fume as a cement substitute.

Effect of silica fume on hardened properties of foam concrete


S. No Major Hardened Properties References
Ingredients
Density C.S F.S T.S Porosity T.C W.A
(kg/m3) (Mpa) (Mpa) (Mpa) (%) (W/m.K) (%)
1 SF, LWA 1000 8.3 1.5 x 30 0.32 x [28]
2 SF, ECA 1300 24.3 x 1.63 34 x 22.1 [29]
3 SF as stabilizer 1400 24.8 x x x x x [30]
4 SF, FA 1900 51.88 x x 22.4 x x [31]
5 SF, FA, FGBFS 1500 23.7 x x x 0.74 x [32]

Note: SF-Silica Fume, LWA-Light Weight Aggregate, C.S-Compressive Strength, F.A-Flexural Strength, TS-Tensile Strength, TC-Thermal Conductivity, ECA-ceramsite based
expanded clay aggregate, W.A-Water Absorption, F.A- Fly Ash, FGBFS-fine granulated blast furnace slag.

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Y. Sivananda Reddy, S. Anandh, S. Sindhu Nachiar et al. Materials Today: Proceedings 68 (2022) 2026–2031

Fig. 3. GGBS consumption from 2015 to 2018 in cement production.

Table 3
Characteristics of concrete made with GGBS as a cement substitute.

Effect of GGBS on hardened properties of foam concrete


S. No Major MC Hardened Properties References
Ingredients (%)
Density C.S F.S T.C (W/m.K)
(kg/m3) (Mpa) (Mpa)
1 GGBS 1300 6.8 x 0.7 [37]
2 GBS, GGBS 30 1450 19.2 1.2 x [39]
3 FA, GGBS FA-50, 1690 21.76 x x [42]
GGBS-10
4 GGBS, FA FA-40, 1550 44.1 x 0.75 [32]
GGBS-8

Note: MC-Material Content, GGBS-Ground Granulated Blast Furnace Slag, C.S-Compressive Strength, F.A-Flexural Strength, TS-Tensile Strength, W.A-Water Absorption, TC-
Thermal Conductivity, F.A- Fly Ash.

Table 4
Characteristics of concrete made with copper slag as a fine aggregate substitute.

Effect of Copper slag hardened properties of concrete


S. No Ingredients MC Hardened Properties References
(%)
Density C.S F.S T.S W.A
(kg/m3) (Mpa) (Mpa) (Mpa) (%)
1 CuS, GGBS 100 2336 30 4.43 x x [46]
2 FA, CuS 100 2200 33 x x x [47]
3 CuS 30 x 48 7.4 5.1 x [48]
4 CuS 20 x 33.6 x x x [35]
5 CuS, Pumice 5 x 28.8 4.62 4.5 x [49]
6 CuS 100 x 56.3 5.3 x 8.5 [50]

Note: MC-Material Content, C.S-Compressive Strength, F.A-Flexural Strength, TS-Tensile Strength, TC-Thermal Conductivity, W.A-Water Absorption, F.A- Fly Ash, GGBS-fine
granulated blast furnace slag, CuS- Copper Slag,

often very low (0.1 percent). Granulated CuS has a lower specific 3. Conclusion
gravity and can absorb more water than CuS that has been cooled
by air. Granulated CuS is made up of sharp, regular-shaped pieces Introducing foam into concrete is beneficial in the construction
that typically range from 4.75 to 0.075 mm (No. 200 sieve) [43]. industry as well as for the environment. Foam concrete reduces the
consumption of natural resources. It also has high flowability and

2029
Y. Sivananda Reddy, S. Anandh, S. Sindhu Nachiar et al. Materials Today: Proceedings 68 (2022) 2026–2031

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