21112023 Class Practice Test # 02 Ranker Batch

ORGANIC & INORGANIC CHEMISTRY

(Topic : Salt Analysis & Nucleic Acids)
(for JEE-Mains & Advanced 2024)
Time : 45 : 00 Min. Max. Marks :136
* Each question + 4 (for correct answer) & - 1 (for wrong answer)
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01. A mixture when heated with conc.H2SO4 with MnO2 brown fumes are formed due to :
*(a) Br– (b) NO3– (c) Cl– (d) I–
02. When Cl2 water is added to a salt solution containing chloroform, chloroform layer
turns violet. Salt contains :
(a) Cl *(b) I– (c) NO3– (d) S2–
03. Phosphate radical with ammonium molybdate gives precipitate of which colour :
(a) Violet (b) Pink *(c) Canary yellow (d) Green
04. A mixture when heated with dil. H2SO4 gives vapours which turn starch iodide pa-
per blue. This is a test for the radical :
*(a) Nitrite (b) Iodide (c) Nitrate (d) Nitrite and Iodide
05. Mark the gas which turns lime water milky :
(a) H2S *(b) SO2 (c) Cl2 (d) None of these
06. In the test of sulphate radical, the white precipitate of sulphate is soluble in :
(a) Conc. HCl *(b) Conc. H2SO4 (c) Conc. HNO3 (d) None of these
07. A salt gives bright red colour to the flame. This colour indicates the presence of :
(a) Ba2+ *(b) Sr2+ (c) Ca2+ (d) Cr3+
08. Which of the following give white precipitate when HCl is added to its aqueous solu-
tion:
*(a) Hg+ (b) Mg+ + (c) Zn++ (d) Cd++
09. When H2S is passed through in II group some times solution becomes milky. It indi-
cates the presence of :
(a) Acidic salt *(b) An oxidising agent
(c) Thiosulphate (d) A reducing agent
10. Which one of the following salt give green coloured flame when the salt is tested by
Pt wire :
*(a) Barium salt (b) Calcium salt (c) Borate (d) Lead salt
11. Reagent used in the qualitative analysis of IVth group is :
(a) HCl *(b) H2S(alkaline) (c) (NH4)2S (d) None of these
12. Sodium sulphite on heating with dilute HCl liberates a gas which :
(a) Turns lead acetate paper black
*(b) Turns acidified potassium dichromate paper green
(c) Burns with a blue flame
(d) Smells like vinegar
13. A 0.3 M HCl solution contains the following ions Hg++, Cd++, Sr++, Fe++, Cu++. The
addition of H2S to above solution will precipitate :
*(a) Cd, Cu and Hg (b) Cd, Fe and Sr
(c) Hg. Cu and Fe (d) Cu, Sr and Fe

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 14. Which of the following will not produce a precipitate with AgNO3 solution :
*(a) F– (b) Br – (c) CO3–2 (d) PO43–
15. When KBr is treated with conc. H2SO4 a reddish brown gas is evolved. The evolved
gas is :
*(a) Bromine (b) Mixture of bromine and HBr
(c) SO2 and HBr (d) NO2
16. Mark the compound which turns black with NH4OH :
(a) Lead chloride *(b) Mercurous chloride
(c) Mercuric chloride (d) Silver chloride
17. Addition of solution of oxalate to an aqueous solution of mixture of Ba++, Sr++, and
Ca++ will precipitate :
(a) Ca++ (b) Ca++ and Sr++ (c) Ba++ and Sr++ *(d) All the three
18. Distinguishing reagent between silver and lead salts is :
(a) H2S gas *(b) Hot dilute HCl solution
(c) NH4Cl(solid) + NH4OH solution (d) NH4Cl(solid) + (NH4)2CO3 solution
19. Nessler’s reagent is used to detect :
(a) CrO42– (b) PO43– (c) MnO4– *(d) NH4+
20. In fifth group, (NH4)2 CO3 is added to precipitate out the carbonates. We do not add
Na2CO3 because :
(a) CaCO3 is soluble in Na2CO3
(b) Na2CO3 increases the solubility of fifth group carbonates
*(c) MgCO3will be precipitated out in fifth gruop
(d) None of these
21. The composition of ‘Golden spangles’ is :
(a) PbCrO4 *(b) PbI2 (c) As2S3 (d) BaCrO4
22. On adding excess of ammonium hydroxide to a copper sulphate solution :
(a) Blue precipitate of copper hydroxide is obtained
(b) Black precipitate of copper oxide is obtained
*(c) A deep blue solution is obtained (d) No change is observed
23. Lead sulphate is soluble :
(a) In conc. nitric acid (b) In conc. hydrochloric acid
*(c) In a solution of ammonium acetate (d) In water
24. A white solid ‘A’ on heating gives off a gas which turns lime water milky. The resi-
due is yellow when hot but turns white on cooling. This solid ‘A’ is :
(a) Zinc sulphate *(b) Zinc carbonate
(c) Lead sulphate (d) Lead carbonate
25. The colour of CuCr2O7 solution in water is green because :
(a) Cr2O72–ions are green (b) Cu++ ions are green
(c) Both ions are green
*(d) Cu++ ions are blue and Cr2O72– ions are yellow
26. Which of the following substances are soluble in concentrated HNO3 :
(1) BaSO4 (2) CuS (3) PbS (4) HgS
Correct answer is
(a) 1, 2, 3 *(b) 2, 3, 4 (c) 1, 3, 4 (d) All

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 27. Br2 vapour turns starch + KI paper to :
*(a) Blue (b) Brown (c) Red (d) None
28. Heamoglobin is a complex of :
(a) Fe3+ *(b) Fe2+ (c) Fe4+ (d) Cu2+
One or More Than One Option Correct Type #
29. Mark the correct statements :
*(a) I group basic radicals precipitate as chlorides
*(b) IV group basic radicals precipitate as sulphides
*(c) V group basic radicals precipitate as carbonates
*(d) III group basic radicals precipitate as hydroxide.
30. The sugar component involved in the formation of a Nucleic acid is (A). The function
of this nucleic acid is to transfer genetic information. Which of the following is/ are
correct for (A) .
(a) The cyclic structure of (A) has 4 chiral carbons.
*(b) The cyclic structure of (A) contains 2 secondary alcoholic groups.
*(c) The cyclic structure of (A) has hemiacetal group.
*(d) The number of oxygen atoms per molecule of (A) are equal to the number of
nitrogen atoms permolecule of purine.
31. Which of the following is/ are correct :
*(a) In the formation of Nucleic acids the sugar involved is pentose sugar.
*(b) In Nucleoside phosphorous is not present.
*(c) In Nucleotide phosphorous is present.
*(d) The sugar part of RNA contains four chiral carbons.
32. There are two pyrimidine bases (A) & (B) involved in the formation of RNA. Which
of the following is/are correct :
*(a) Molecular mass of (A) and (B) are equal.
(b) One of the two bases contain sp3 carbon.
*(c) The sum of oxygen atoms in 1 molecule each of (A) and (B) is equal to the
number of chiral carbons in cyclic structure of one molecule of sugar involved in the
formation of DNA.
*(d) The difference in nitrogen atoms in the molecular formulae of (A) and (B) is
equal to the difference in number of oxygen atoms in molecular formulae of Adenine
and Guanine.
Integer Type #
33. Among the following how many are heterocyclic compounds :
(i) Guanidine (ii) Pyrimidine (iii) Cysteine (iv) Cytosine
(v) Urotropine (vi) Adenine (vii) Caprolactum (viii) Imidazole
(ix) Succinic -anhydride (x) Histidine Ans : 8
34. Calculate the sum of nitrogen atoms in 1 molecule each of four bases involved in
DNA .
Ans : 15

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