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    Calculos Practica 8

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    Yanin Ramírez
    The document contains experimental data from a chemical reaction experiment including concentration measurements over 10 time periods. It then performs calculations to determine the rate constant K and other reaction parameters through linear regression of the logarithmic form of the rate law equation. The calculated values are K = 1.1107, the activation energy Ea = 22250.025 J/mol K, and the pre-exponential factor A = 59.68.

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    Calculos Practica 8

    Uploaded by

    Yanin Ramírez
    2 views3 pages
    The document contains experimental data from a chemical reaction experiment including concentration measurements over 10 time periods. It then performs calculations to determine the rate constant K and other reaction parameters through linear regression of the logarithmic form of the rate law equation. The calculated values are K = 1.1107, the activation energy Ea = 22250.025 J/mol K, and the pre-exponential factor A = 59.68.

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    CALCULOS PRACTICA 8

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    The document contains experimental data from a chemical reaction experiment including concentration measurements over 10 time periods. It then performs calculations to determine the rate constant K and other reaction parameters through linear regression of the logarithmic form of the rate law equation. The calculated values are K = 1.1107, the activation energy Ea = 22250.025 J/mol K, and the pre-exponential factor A = 59.68.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    Download as docx, pdf, or txt
    2 views3 pages

    Calculos Practica 8

    Uploaded by

    Yanin Ramírez
    The document contains experimental data from a chemical reaction experiment including concentration measurements over 10 time periods. It then performs calculations to determine the rate constant K and other reaction parameters through linear regression of the logarithmic form of the rate law equation. The calculated values are K = 1.1107, the activation energy Ea = 22250.025 J/mol K, and the pre-exponential factor A = 59.68.

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    © All Rights Reserved
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    of 3

    Datos experimentales

    CA=? T4=2.3454MIN T8=8.00.86

    T1=46.04 SEG T5=3.33.29MIN T9=11.32.07

    T2=1.15 MIN T6=4.39.37MIN T10=21,00.25

    T3=1.53 MIN T7=6.03.65MIN

    C1V1=C2V2

    Ca=C2=(0.05M)(0.02L)/(0.207L)

    C2=0.004830 M

    No. De moles del H2O2

    CA= X/V 0.05= X/0.207 L

    X=(0.05M)(0.207L)

    X= 0.01035 MIL

    CA= X- n(0.001)/0.207+(n-1)(2ml)

    TIEMPO 1

    CA=(0.01035)-(1)(0.001)/(0.207)+(1-1)(2mil)= 3.78X10-3

    TIEMPO 2

    CA=(0.01035)-(2)(0.001)/(0.207)+(2-1)(2mil)=3.78X10-3

    TIEMPO 3

    CA=(0.01035)-(3)(0.001)/(0.207)+(3-1)(2mil)=1.7470X10-3

    TIEMPO 4

    CA=(0.01035)-(4)(0.001)/(0.207)+(4-1)(2mil)=1.023X10-3

    TIEMPO 5

    CA=(0.01035)-(5)(0.001)/(0.207)+(5-1)(2mil)=6.51X10--4

    TIEMPO 6

    CA=(0.01035)-(6)(0.001)/(0.207)+(6-1)(2mil)=4.26X10-4
    TIEMPO 7

    CA=(0.01035)-(7)(0.001)/(0.207)+(7-1)(2mil)=2.7443X10-4

    TIEMPO 8

    CA=(0.01035)-(8)(0.001)/(0.207)+(8-1)(2mil)=1.6541X10-4

    TIEMPO 9

    CA=(0.01035)-(9)(0.001)/(0.207)+(9-1)(2mil)=8.3297X10-5

    TIEMPO 10

    CA=(0.01035)-(10)(0.001)/(0.207)+(10-1)(2mil)=1.9223X10-3

    A CA °
    Dca/dt= KCA Dca/CA=Kdt ∫ dCA =Kdf In Ca ∫ ¿ Kt In CA°-InCa=Kt
    ❑ CA CA

    CA°
    In =Kt → In CA°/CA/t=k
    CA
    0.05 0.05
    K a T1 In 0.04516 K a T6 In 4.26 x 10−4
    =k 1=2.2454 =k 6=1.0854
    0.7671 4.39
    0.05 0.05
    K a T2 In 3.75 x 10−3 K a T7 In 2.74 x 10−4
    =k 2=2.2454 =k 7=0.8634
    1.15 6.03
    0.05
    K a T3 In 1.74 x 10−3
    =k 3=2.19 0.05
    1.15 3
    K a T8 In 1.65 x 10−4
    =k 8=0.7142
    0.05 8
    K a T4 In 1.023 x 10−3
    =k 4=1.62 0.05
    2.39
    K a T9 In 8.32 x 10−5
    =k 9=0.5652
    0.05 11.32
    K a T5 In 6.51 x 10−4
    =k 5=1.303 0.05
    3.35
    K a T10 In 1.95 x 10−5
    =k 10=0.3745
    21

    K=1.1107
    K=A*e(fa/Rt)

    InK=InA*Ine InK=InA*(-Fa/Rt)

    InK= (-Ea/R) (I/T)+ InA

    −Ea
    =-2677.5
    R
    Ea=-2677.5(8.31)= 22250.025 J/MOL K

    InA=4.0882

    A=e 4.0882

    A=59.68

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